27 2651 01 Dow Home Care Solutions
27 2651 01 Dow Home Care Solutions
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Sustainability
The upcoming decades will be of vital importance to                  We are proud to share how Dow applies its scientific and
humankind and the earth we dwell upon. According to UN               engineering experience to overcome global challenges with
reports, the global population will reach 9 billion by 2050,         sustainable innovations. At Dow, we commit that by 2030 we will
and each one of those people will need healthy food, clean           reduce our net annual carbon emissions by 15% versus the 2020
water sources, sanitary facilities, spaces for living, mobility,     baseline. By 2050, we intend to be carbon neutral. Regarding our
education and medical care. Ensuring these needs are met             circular economy ambitions, Dow will reduce waste production
will require that we—                                                by enabling 1 million metric tons of plastic to be collected, reused
•   Take more initiative to preserve the planet.                     and recycled by 2030. By 2035, we will fully enhance the circular
                                                                     economy of plastic by enabling 100% of Dow products sold into
•   Explore the potentials of humanity and science.
                                                                     packaging applications to be reusable and recyclable.
•   Establish strong collaboration with our customers.
                                                                     For more information please visit:
                                                                     www.dow.com/sustainability/goals.
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Automatic dishwashing (ADW)                                                                                                          a low toxicity profile but can cause excessive algae development
                                                                                                                                     and eutrophication of water reservoirs. And while phosphates
Formulating an automatic dishwashing detergent requires
                                                                                                                                     brought multiple benefits like ion chelation, surface protection,
developing a particular combination of ingredients that deliver
                                                                                                                                     improved cleaning and alkalinity control, several chemicals are
the glassware shine and cleanliness that consumers expect.
                                                                                                                                     now required to reach the same performance.
Contrarily, the variety of food components that enter the dish
washer makes their removal complex. Various food categories                                                                          Aside from the classical compacted tablet formulations, multiple
and quantity, water quality and detergent composition are factors                                                                    compartment monodoses combining powder, gel and/or liquid
that determine the results; that is, they determine whether these                                                                    phases are gaining importance. These formats lead to additional
food components are removed or redeposited. Food degradation                                                                         flexibility in formulation as they enable separation of incompatible
is achieved by enzymes, bleaching agents or by high alkalinity                                                                       ingredients and various attractive visuals. Liquid gels are also
coming from builders and supported by surfactants ensuring                                                                           increasingly present in several markets, although they represent
emulsification. Chelating agents, dispersants and surfactants                                                                        a smaller product category.
function to prevent redeposition of food components.                                                                                 Simultaneously, automatic dishwasher suppliers have been
Formulation strategies have become more diverse in recent                                                                            working to reduce water and electricity consumption. For example,
years. This change is driven by several factors, such as phosphate                                                                   such reduction can be made by lowering cycle temperature.
use reduction as of 2017 in the European Union. Phosphates have
Automatic dishwashing
Anti-spotting
                                                                                                                                       Easy rinsing
    Technology
Carbonate
                                                                                                          residues
                                                                                                          Organic
                                                                 scale
scale
Material
*Supports the ecolabel criteria at typical use level. Detailed statement available upon request.
4
Qualitative performance data of ACUSOL™ Dispersants                                 ACUSOL™ 445N, 420N and 402N Homopolymers would help
in a generic automatic dishwashing formula
                                                                                    manage mostly calcium carbonate scale, while ACUSOL™
                                     Carbonate
                                     4
                                                                                    588G Polymer controls insoluble silicate salts and calcium
                                     3.5
                                                                                    polyphosphonate redeposition. ACUSOL™ 588G Polymer, a
              Plastic                 3                                             sulfonate copolymer, can be combined with acrylic homopolymers
               care                                            Silicate
                                     2.5                                            to minimize limescale filming in certain formulations. This
                                      2                                             combination is recommended particularly for the all-in-one
                                     1.5                                            tablets, to alleviate the heavy precipitating conditions arising
                                     1                                              from higher calcium and magnesium levels during wash cycles.
                                     0.5                                            These products exist in liquid, powder and neutralized forms, and
                                      0
                                                                                    can be applied based on the specific formulation needs. ACUSOL™
      Metal
      care
                                                                      Phosphonate   527 and 528 Copolymers are free of sulfonated monomers and
                                                                                    are recommended for similar formulations, as they show superior
                                                                                    performance on carbonate, silicate, and phosphonate simultaneously.
                                                                                    Reduction of food residue redeposition can be achieved by adding
                                                                                    ACUSOL™ 460N Polymer. Acting as a food soil dispersant, it
                   Organic film                     Spotting
                                                                                    prevents the adhesion of particles on surfaces that impedes
                    ACUSOL™ 402N/420N             ACUSOL™ 528                       sheeting and ultimately causes spotting. The polymer enhances
                    ACUSOL™ 588                   ACUSOL™ 460N                      the sheeting action of water, making it an effective additive in
                    ACUSOL™ 445/445N              ACUSOL™ 527G                      automatic dishwasher detergents.
                                                                                    Further shine improvements can be achieved by the addition of
                                                                                    members of the new ECOSURF™ Bright class of surfactants.
Boosting shine
                                                                                    These low-foaming nonionic surfactants demonstrate best-
Dow offers a wide range of ingredients to support formulators                       in-class anti-spotting performance in low to no MGDA based
designing ADW detergents in this changing market.                                   formulations. It also enables lower formulation cost by reducing
                                                                                    the need for expensive builders.
                                                                                    Improving cleaning
                                                                                    Two different classes of surfactants can be used to drive primary
                                                                                    cleaning. In one class, DOWFAX™ 20B102 Surfactant and
                                                                                    ECOSURF™ LFE-1410 Surfactant improve cleaning efficiency
                                                                                    and control foam.
                                                                                    In the other class, TERGITOL™ 15-S Surfactant Series can boost
                                                                                    primary cleaning efficiency, but it requires the additional use of an
                                                                                    antifoam or a foam control ingredient, e.g. TERGITOL™ L-Series
                                                                                    Surfactant. ECOSURF™ LFE-1410 Surfactant and TERGITOL™
                                                                                    L-Series will also bring shine benefits in a rinse aid formulation.
                                                                                    Additional benefits
                                                                                    In the classic tablet format, solid CARBOWAX™ PEG materials
                                                                                    are used to ensure the tablet integrity. Alternatively, some of
                                                                                    the basic acrylic homopolymers, such as ACUSOL™ 445NG
              Copolymer of acrylic                       Acrylic
                                                                                    Polymer, can be used as tableting aids.
              and sulphonic acids                      homopolymer
Pictures of glasses after the 30 cycle build-up test, in carbonate/citrate/high     Preventing foam development during the cycle can be achieved
HEDP base.                                                                          thanks to DOWSIL™ GP-4503 Powdered Antifoam – a silicone
                                                                                    foam control agent available in granulated format.
In order to help enhance shine benefits, Dow offers a portfolio                     Structuring the gels
of dispersants which can be purposed according to the                               One of the challenges in developing ADW gels is achieving the
formulation direction. Water-soluble acrylic based homopolymers                     appropriate rheology for products typically containing a high
or copolymers will prevent crystal growth of carbonates,                            level of salts. ACUSOL™ Millennium ER Rheology Modifier and
phosphonates and silicates, dispersing the precipitates in the                      ACUSOL™ 805S Rheology Modifier were developed to suspend
washing bath, minimizing redeposition and thus limiting filming                     actives, while ACUSOL™ 810 Rheology Modifier and ACUSOL™
on glassware and other substrates.                                                  820 Rheology Modifier can help to control the rheology of the gel.
                                                                                    *Greater than 30% via OECD 302B
                                                                                                                                                        5
Hand dishwashing (HDW)                                                                               order to achieve the optimum profile. Consumers expect
                                                                                                     generous, long-lasting foam, and beyond surfactants, many
Hand dishwashing is a product category requiring multiple
                                                                                                     additives can contribute to the refinement of the foam profile.
chemistries and benefits for various consumer needs. Typical
formulations are first and foremost cleaning formulations that                                       Polymers can offer many other features for a good hand dish
incorporate raw materials with the ability to soften, swell, lift                                    care formulation. For example, the quality of the formulation will
or roll a varied set of soil types from dishware. These typical                                      also be judged by its richness and ease-of-dosing. Polymeric
ingredients include surfactants, solvents and amines. Additional                                     rheology modifiers can contribute greatly to achieving such
chemistries can be added to maximize the effect of such                                              desired effects. And beyond the ease-of-dosing, there is a
cleaning ingredients by enabling them to overcome variable                                           sensorial element of texture and visual effect. Consumers expect
elements, such as water hardness, that would otherwise                                               not only that the formulation will not irritate their skin but that
compromise the cleaning process. Chelants and dispersants                                            they will gain a great skin feel after the dish cleaning routine.
play this supplemental role.                                                                         Moreover, consumers desire the drying stage of the cleaning
                                                                                                     routine to be as short as possible without any compromise in
But cleaning goes far beyond the simple removal of soils from
                                                                                                     the final result of cleanliness and shine.
dishware. Other elements are observed by the consumer and,
therefore, must be considered in formulation designs in
 Hand dishwashing
                                                                                                                            Foam     Sensorial    Fast      EU        Nordic
                                                                      Cleaning           Viscosity   Suspension   Opacity
                                                                                                                            boost     benefits   drying   Ecolabel*   Swan*
                                                                              Soil
                                                               Mileage
                                                                            removal
MEA (Monoethanolamine) X X
                     MIPA (Monoisopropanolamine)                  X              X                                                                           X          X
 Amine
DIPA (Diisopropanolamine) X X X X
TIPA (Triisopropanolamine) X X X X
*Supports the ecolabel criteria at typical use level. Detailed statement available upon request.
6
Dow offers a rich range of chemistries that meet every one           Number of plates
of these Hand Dish Care needs. We provide multiple options
for cleaning specifically with nonionic surfactants within
                                                                     Standard formulation
the families of primary and secondary alcohol ethoxylates.           14.5% total surfactant
These options include TERGITOL™ 15-S-9 Surfactant and
ECOSURF™ SA-7 Surfactant. We also offer options, such as
TRITON™ Alkyl Polyglucosides, for cleaning specifically with         Hand dish with low
mild surfactants. These liquid surfactants are very easy to          surfactant level
                                                                     (10% total)
formulate into multiple chassis and enable the development
of the desired cleaning profile. Dow Dispersants also enable
great cleaning performances across formats. The most                 Hand dish with low
recommended product is ACUSOL™ 588 Polymer.                          surfactant level
                                                                     +0.6% Polyglycol
                                                                     P2000E (10% total)
Cleaning
Dow’s large collection of solvents and amines enables further                                 0      5          10          15         20
refinement of the formulated product’s cleaning profile, as these
materials can be very useful for swelling soils, which aids in the   of low-shear viscosity, required for suspension, and an easy-pour.
removal of burnt-on soils in particular. They also may improve       If suspension and richer pour is necessary, ACUSOL™ 805S
the foam profiles of low-surfactant formulations. For example,       Rheology Modifier should be the product of choice.
Polyglycol P2000E has been demonstrated to enable reduction          Our range also includes some cellulosic technologies—such
of surfactant levels by up to 30% in some formulations, while        as SupraCare™ 340 Polymer—which in addition to building
maintaining suds mileage characteristics as illustrated by the       viscosity may also boost foam quality. SupraCare™ 430 Polymer
graph to the right. SupraCare™ 430 Additive helps to boost the       is the best-in-class material for providing perceivable sensorial
degreasing attributes in a HDW formulation. It increases the         benefits during and after use, even at dosages below 0.1%.
foam mileage by cleaning higher number of plates.                    SupraCare™ 780 Additive is the product of choice for high yield
                                                                     thickening where product transparency is required.
Beyond cleaning
                                                                     When the washing routine is completed, SupraCare™
Beyond the improvements in cleaning, the experience of HDW
                                                                     212 Polymer can also help speed the drying of dishware.
can be enhanced by additional technologies. Dow Rheology
                                                                     SupraCare™ 212 Polymer is a cellulosic based additive
Modifiers enable the formulator to achieve specific aesthetic
                                                                     the effect of which is water repellency and altered surface
effects with stable suspension or to deliver the desired pouring
                                                                     properties. This additive comes in powder form and has a
flow and dosing while improving foam quality. Suspension
                                                                     cationic nature, but at the required usage level, it is easy to
stability with good transparency can be achieved using
                                                                     incorporate in formulations.
acrylates technologies. ACUSOL™ Millennium ER Rheology
Modifier is the best in class with a great combination
                                                                                                                                       7
Laundry powders                                                                                                                               to reach optimal cleaning performance, enabling formulation
                                                                                                                                              flexibility and cost efficiency. Additionally, dispersants can provide
Powder detergent is one of the largest home care categories
                                                                                                                                              processing benefits in the spray drying process for powder laundry
globally, traditionally dominating the developing markets. For
                                                                                                                                              by reducing slurry viscosity and thus saving energy.
consumers, powder detergents are associated with powerful
cleaning mechanisms and represent the most effective format                                                                                   Cleaning enablers
particularly on white clothes, due to the presence of bleach.                                                                                The cleaning performance of powder laundry detergent is
The drivers for the category are the need for reducing cost                                                                                  obtained by a combination of anionic and nonionic surfactants.
and increasing sustainability without compromising cleaning                                                                                  In general, anionics work well for particulate soil removal, and
efficiency as well as compaction steps implemented across                                                                                    nonionics work well for greasy soil removal. TERGITOL™ 15-S-9
various geographies.                                                                                                                         Surfactant is an easy-to-formulate surfactant which exhibits
There are a variety of laundry powders that fall within two main                                                                             superior detergency; allows efficient cleaning of oily soils,
categories: high- and low-suds. Automatic-front and top-load                                                                                 sebum, particulate soils, including from collars and cuffs; and
laundry machines require low suds detergents, while high-suds                                                                                is associated with a rapid dissolution and a good rinseability.
powders are used for semi-automatic and fully manual laundry                                                                                 ECOSURF™ SA-7 Surfactant and SA-9 Surfactant constitute
processes. Dow offers a range of performing surfactants and                                                                                  a new generation of seed oil-based surfactants featuring no
dispersants which can be combined in powder detergents                                                                                       aqueous gel ranges and rapid dissolution even in cold water
  Laundry powders
                                                                                                                                                                                               Easy
                                                                                                                                                                                      Long-
                                                                                                         Whiteness     Anti-                                              Softness             rinse
                                                                                                                                Foam                  Foam    Sensorial              lasting             EU        Nordic
                                                          Cleaning                                        mainte-    encrus-                                               through                /
                                                                                                                                control               boost   benefits                fresh-           Ecolabel*   Swan*
                                                                                                          nance       tation                                              the wash             Easy
                                                                                                                                                                                       ness
                                                                                                                                                                                               drain
                                                                                     Collars and cuffs
                                               Oily soil/ Sebum
Particulate soil
In-process
In-wash
              ACUSOL™ 445/445N/
                                                                                                             X         X                                                                                  X          X
              445G/445NG Polymer
DOWSIL™APW-4248 Antifoam X X X
*Supports the ecolabel criteria at typical use level. Detailed statement available upon request.
8
with fast foam collapse rates. They are particularly suitable for        Enhanced consumer experience for manual powders
low-suds powders wherein you can achieve low foam with                   A drawback of manual laundry powders is the harsh feeling
cleaning benefits.                                                       they leave on hands. SupraCare™ 430 Polymer improves
Cleaning efficiency can be further enhanced using Dow’s                  the sensorial perception of hand wash laundry detergents by
dispersant technologies. ACUSOL™ 445N Polymer and                        reducing the harsh feeling on hands after the wash and giving
ACUSOL™ 420N Polymer are anti-graying polymers which                     a slippery, velvet feel during the wash.
deliver improved secondary cleaning (anti-redeposition) of clay          Many consumers associate cleaning impact with the amount
and oily soils. In addition, ACUSOL™ 420N Polymer provides               of foam generated during manual laundry. Thus, they overdose
anti-ashing/anti-encrustation benefit. ACUSOL™ 402 Polymer               products to reach the expected foam level. Dow performance
was designed to remove particulate soils such as garden soils.           boosters help modify foam stability to give longer lasting, rich
ACUSOL™ 588 Polymer in combination with ACUSOL™ 402                      and creamy foam, thereby enhancing the cleaning experience.
Polymer boosts particulate soil removal. Combining TERGITOL™             This can be achieved by using SupraCare™ 340 Polymer.
15-S-9 Surfactant with ACUSOL™ 588 Polymer and ACUSOL™
402 Polymer can also enhance cleaning of oily soils and sebum,           Foam management
particulate, and collar and cuff soils.                                  Excessive foam may also be produced in the washing machine,
                                                                         causing it to perform additional rinse cycles, wasting water,
EasyRinse                                                                energy and time. Added to powder detergent formulations,
                                                                         DOWSIL™ GP-4248 Powdered Antifoam, DOWSIL™ GP-
                                 DOWSIL™               DOWSIL™           4253 Powdered Antifoam or DOWSIL™ GP-4680 Granules
             Reference       EasyRinse GP-4633     EasyRinse GP-4633
                             Granulates at 0.68%   Granulates at 1.36%   helps control foam levels throughout the washing process to
                                                                         give consumers the perception of cleaning efficiency without
                                                                         negatively impacting the laundry operation. DOWSIL™ APW-
                                                                         4248 Antifoam is a basic granulated antifoam particularly suitable
Rinse 1                                                                  for zeolite containing powders. DOWSIL™ GP-4680 Granules
                                                                         offer premium anti-foam performance while ensuring optimal
                                                                         drainage throughout the entire washing cycle. DOWSIL™ GP-
                                                                         4253 Powered Antifoam is a fast-soluble option offering excellent
                                                                         antifoam properties from the beginning of the wash cycle.
Rinse 2                                                                  In hand wash markets, the level of in-wash foam and its longevity
                                                                         connect with consumer perception of better cleaning performance.
                                                                         Therefore, use of foam boosters such as SupraCare™ 340 can
                                                                         help by making the foam more creamy and lasting for longer in
                                                                         order to improve consumer experience.
Rinse 3                                                                  DOWSIL™ EasyRinse GP-4633 Granules provide consumers
                                                                         washing their laundry manually with an effective cleaning
                                                                         experience, while reducing foam during the rinse steps and
                                                                         thereby enabling reduction of water consumption by almost
                                                                         50% and saving time and effort.
Rinse 4
Rinse 5
Rinse 7
                                                                                                                                            9
Laundry liquids and monodose                                                                                                                 the reduction of transportation costs and optimization of
                                                                                                                                             retail shelf space. Convenience of use was then the driver for
While powder detergents continue to dominate markets of
                                                                                                                                             the success of monodoses, the most recent format of liquid
developing countries, the last decade has seen a trend towards
                                                                                                                                             detergent. Further compaction and sustainability combined
the use of liquid laundry detergents. This transition is driven
                                                                                                                                             with maintained or even improved cleaning efficiency are the
by liquid detergents’ higher convenience, the ability to use the
                                                                                                                                             next foreseen challenges in the development of laundry formats.
liquids for pre-treating stains and consumer’s perception that
                                                                                                                                             Dow offers a range of performing surfactants, dispersants,
liquids dissolve more quickly and leave less residues on fabrics.
                                                                                                                                             solvents and amines which can be combined in liquid
This perception has been strengthened by a decrease in the
                                                                                                                                             detergents to reach optimal cleaning performance, enabling
laundry machine temperatures. Over the years, liquid detergents
                                                                                                                                             formulation flexibility and efficiency.
have evolved towards more concentrated formulations, allowing
                                                                                                             White-                                                                                        Long-
                                                                                                                                                                                               Softness                          EU
                                                                                                              ness                 Suspen-   Opa-    Foam                  Foam    Sensorial              lasting                      Nordic
                                                           Cleaning                                                    Viscosity                                                                through             Stability   Ecola-
                                                                                                             mainte-                sion     city   control                boost   benefits                fresh-                      Swan*
                                                                                                                                                                                               the wash                          bel*
                                                                                                             nance                                                                                          ness
                                                                                         Collars and cuffs
                                                    Oily soil/Sebum
Particulate soil
In-process
                                                                                                                                                                 In-wash
                     ACUSOL™ 845 Polymer                                                                       X          X                                                                                                       X      X
 Dispersant
                     MEA (Monoethanolamine)             X
 Amine
MIPA (Monoisopropanolamine) X X X
DIPA (Diisopropanolamine) X X X
                     Thickener
                     ACUSOL™ 810A, 820 Rheology
                                                                                                                          X                                                                                                       X      X
                     Modifier
                     ACUSOL™ 805S Rheology
                                                                                                                          X          X                                                                                            X      X
                     Modifier
                     ACUSOL™ Millennium ER
                                                                                                                           X         X                                                                                            X      X
                     Rheology Modifier
 Opacifier
*Supports the ecolabel criteria at typical use level. Detailed statement available upon request.
10
Enabling primary cleaning                                             Foam control
As with powder detergents, the cleaning performance of liquid         Unwanted foam can slow the manufacturing of liquid
laundry detergent is obtained by a combination of anionic             detergents; therefore, most formulations contain silicone
and nonionic surfactants. In general, anionics work well for          antifoams for controlling foam and facilitate bottle-filling
particulate soil removal, and nonionics work well for greasy soil     operations. XIAMETER™ antifoams provide immediate and
removal. TERGITOL™ 15-S-9 Surfactant is an easy-to-formulate          persistent foam control action at low concentration levels.
secondary alcohol ethoxylate which exhibits superior detergency       Excessive foam may also be produced in the washing machine,
and allows efficient cleaning of oily soils, sebum, particulate       causing it to perform additional rinse cycles, wasting water, energy
soils, including from collars and cuffs. ECOSURF™ SA-7                and time. Added to liquid detergent formulations, DOWSIL™ AF-
Surfactant and SA-9 Surfactant constitute a new generation of         8017 Antifoam helps control foam levels throughout the washing
seed oil-based surfactants featuring non aqueous gel ranges and       process to give consumers the perception of cleaning efficiency
rapid dissolution even in cold water with fast foam collapse rates.   without negatively impacting the laundry operation.
Cleaning efficiency can also be enhanced by the use of Dow’s          Additional benefits
acrylic dispersants. ACUSOL™ 845 Polymer is an anti-graying
polymeric technology which delivers improved secondary                Softness and long-lasting fragrance are benefits which improve
cleaning (anti-redeposition) of clay and oily soils versus            the perception of the consumers regarding the detergent which
conventional polyacrylates. ACUSOL™ 845 Polymer was                   can influence their buying decision. SupraCare™ 133 Polymer
designed to work particularly well in systems with rheology           is a cationic cellulose which has demonstrated benefits with
modifiers that may otherwise reduce the secondary cleaning            regards to these properties, while not causing the redeposition
performance and can be used in any type of liquid detergent.          and greying problems observed with some other fabric care
                                                                      additives of cationic nature.
Right rheology
                                                                      Detergents for manual cleaning require additional ingredients
While surfactants and additives are the key ingredients for           to improve the consumer experience. SupraCare™ 430 Polymer
obtaining the cleaning efficiency, rheology modifiers, commonly       has demonstrated significant benefits in improving the sensorial
referred to as thickeners or viscosifiers, are the essential          perception of hand wash laundry detergents, reducing the harsh
ingredients for controlling the viscosity of the detergents,          soapy feeling on hands. In this application, the quality of foam
providing the required rheology profile and stability.                also influences the consumer’s perception of product quality. A
ACUSOL™ Rheology Modifiers are polymer emulsions, which               rich, creamy foam is associated with an efficient product that
can be grouped into three general classes: ASE’s (alkali              will not damage the clothes. Such foam can be obtained using
swellable emulsion), HASE (hydrophobically modified alkali-           cellulosic polymers such as SupraCare™ 340 Polymer.
swellable emulsions) or HEUR’s (hydrophobically modified
ethoxylated urethanes). ACUSOL™ Rheology Modifiers thicken
and stabilize high surfactant containing cleaning formulations.
They can be used to control flow properties, suspend particles
and control uniform dosing. They can be directly incorporated
into formulations without preparation of a separate thickener
solution. Viscosity is developed simply by adjusting the pH on
the alkaline side with any base. The products are supplied as
low viscosity emulsions and, therefore, are easy to handle. The
choice of the right grade will depend upon the required viscosity
of the final detergent: ACUSOL™ 810A and ACUSOL™ 820
Rheology Modifiers will be used for flowable liquids, while
ACUSOL™ 805S Rheology Modifier may be used if even higher
viscosity is required and will also provide suspension.
If thickening is desired independently of pH and of the presence
of electrolyte, cellulosic polymers can provide it efficiently,
the only restriction being their incompatibility with cellulase.
CELLOSIZE™ Hydroxyethyl Cellulose (HEC) and SupraCare™
Additives based on hydroxypropyl methyl cellulose (HPMC)
are cold water-soluble polymers that can thicken and stabilize
formulations. CELLOSIZE™ QP-100MH Rheology Modifier is
recommended particularly for obtaining very high viscosities.
SupraCare™ 760 Additive offers an interesting alternative
to balance cost and thickening performance. SupraCare™
340 Polymer is an efficient thickener and also exhibits foam
enhancement properties which can be leveraged in manual
laundry detergents.
                                                                                                                                        11
Laundry bars                                                                                 Beyond cleaning
Laundry and detergent bars are one of the traditional laundry                                Additional benefits such as improved foam or sensorial effect
categories of developing markets like India or Sub-Saharan                                   offer a way to differentiate in the market. Multiple technologies
Africa. They are typically used as a convenient, cost effective                              from Dow can help boost foam and make it more rich and
spot-soil stain remover or as a gentle alternative to powder                                 creamy. This can also improve the cleaning perception.
detergents for delicate or colored clothes.                                                  Performance additives such as SupraCare™ 340 Polymer can
                                                                                             boost foam and change its characteristics. SupraCare™ 430
Cleaning enablers
                                                                                             Polymer can improve skin feel during and after wash and can
Similar to powder detergents, primary cleaning with laundry                                  make foam creamier.
bars can be boosted by using specialty surfactants such
                                                                                             Improved structuring
as TERGITOL™ 15-S-9 Surfactant. Cleaning efficiency can
be further enhanced using Dow’s dispersants technology.                                      Because of the consumer usage pattern, the detergent bars are
ACUSOL™ 402 Polymer was designed to work particularly                                        prone to sogginess and mushing, leading to cracking or quicker
well for particulate soil removal like garden soil/mud. Use of                               dissolving bars, a trait disliked by consumers. Improved structuring
ACUSOL™ 588 Polymer in combination with ACUSOL™ 402                                          and binding of bars with the help of multiple technologies like
Polymer further boosts particulate soil removal. Combination of                              CELLOSIZE™ QP-100MH Thickener, SupraCare™ 760 or 780
TERGITOL™ 15-S-9 Surfactant with ACUSOL™ 588 Polymer                                         Additives, ACUSOL™ 445 Polymer, either standalone or in
and ACUSOL™ 402 Polymer can also enhance cleaning of oily                                    combination, makes bars last longer.
soils and sebum, particulate soils and collars and cuff.
Laundry bars
                                                                                                        Structur-
                                                                                           Whiteness                Foam    Sensorial           Easy      TFM*
                                                                Cleaning                                ing and                         Glide
                                                                                          maintenance               boost   benefits            rinse   reduction
                                                                                                        binding
              ACUSOL™ 445/445N/445G/445NG
                                                                                               X           X                                                X
              Polymer
12
Fabric softeners                                                             ACUSOL™ 880 Polymer and 882 Polymer are non-ionic water-
                                                                             soluble polymers from the family Hydrophobically Modified
Traditional fabric softeners use organic quaternary ammonium
                                                                             Ethoxylated Urethanes (HEUR) that are suitable for thickening
compounds commonly called “esterquats”. Esterquats can
                                                                             fabric softener formulations. Both ACUSOL™ 880 Polymer
deposit easily on fabrics like cotton, providing softness.
                                                                             and 882 Polymer are typically added at the beginning of the
However, some of the drawbacks related to their use are
                                                                             manufacturing process and have an excellent compatibility
linked to fabric yellowing or reduced water absorption (mainly
                                                                             with esterquats.
perceivable on towels and sportswear). This is why there is a
continuous trend on the market to reduce esterquat content to                Silicone emulsions
minimize the negative effects while bringing additional benefits             Silicone emulsions are well known for boosting sensory
to this product category. Dow has a broad range of additives                 benefits like softness, volume enhancement and ease of ironing,
designed to enable esterquat reduction and deliver consumer                  as well as improving water absorbency and fast drying effect
relevant benefits in fabric softener formulations.                           (ability to better drain water at the end of the wash cycle).
Rheology modifiers                                                           They can be used as partial replacement of esterquats (that is,
                                                                             esterquat level can be reduced by 50%, for example, from 10%
High viscosity of a fabric softener is interpreted as a richer
                                                                             to 5%, and the performance can be enhanced by and extra
and more efficient product by consumers and is becoming a
                                                                             2% of silicones) or added on top of an existing formulation.
challenge when esterquat concentration is reduced. Therefore,
                                                                             Silicone emulsions have an excellent compatibility with fabric
adding a rheology modifier can help to increase viscosity of
                                                                             softener formulations, are easy to incorporate and are generally
the formulation while keeping good pouring properties.
                                                                             added at the end of the process with perfume and dyes under
CELLOSIZE™ QP-100MH Thickener is a cellulosic thickener                      low-medium shear and ideally below 40°C. Level of addition
which dissolves in water easily and can be introduced to                     is generally between 0.5% and 3% active and depends on the
the formulation under low-medium shear rate to obtain a                      type of emulsion and benefit desired.
homogeneous solution and maximize thickening effect. The
typical amount added is 0.5 to 1.0%.
 Fabric softeners
                                                                                                Improved water                     Foam control/
                                                      Softness   Viscosity        Fast drying                    Ease of ironing
                                                                                                  absorbancy                        Process aid
                                                                                                                                               13
Hard surface cleaner                                                                                                       So many different types of chemistries are required to formulate
                                                                                                                           a stable product that is easy-to-deliver and efficient in cleaning
Hard Surface Cleaning is a vast category of consumer products
                                                                                                                           and which offers the right smell perception without damaging
meant to clean many different types of surfaces in consumers’
                                                                                                                           surfaces and while meeting VOC requirements where applicable.
houses. Multiple product formats, including concentrated and
diluted liquids, sprays, and wipes, have been developed to tackle                                                          Cleaning is obviously a primary driver of purchase intent.
many different types of soils. Dust and particulates can be found                                                          Therefore, solvents and surfactants will play a key role in every
on all surfaces. Limescale and soap scum are encountered in the                                                            formulation. Solvents are naturally good at breaking up and
bathroom; the kitchen is the site of many different kinds of food                                                          solubilizing dirt and help remove soil via wetting, penetration,
soils, including grease, proteins, carbohydrates (both raw and                                                             emulsification and suspension.
baked/burnt), as well as grease on windows.                                                                                Surfactants are also excellent in wetting, detergency, and foam
Some products can be specialized to some surfaces (kitchen,                                                                control, and, therefore, combine very well with solvents. A
oven, bathroom, window) and corresponding type of soil, but                                                                typical formulation would include more than one solvent and
others need to be all-purpose cleaners (APC).                                                                              more than one surfactant to achieve the right properties.
                                                                                                                                                          Easy              Fragrance       EU
                                                                                         Vis-             Vertical   Suspen-    Foam     Foam     Fast              Pro-                           Nordic
                                                      Cleaning      Shine                                                                                  next             solubiliza-    Eco-
                                                                                        cosity             cling      sion     control   boost   drying           tection                          Swan*
                                                                                                                                                          clean                tion       label*
                                                                 Streak-free
                                                                                                High pH
                                                                                       Low pH
                                                                               Gloss
MEA (Monoethanolamine) X
                     MIPA (Monoisopropanolamine)         X          X                                                                                                                       X        X
 Amine
DIPA (Diisopropanolamine) X X X X
TIPA (Triisopropanolamine) X X X
*Supports the ecolabel criteria at typical use level. Detailed statement available upon request.
14
Cleaning is not limited to smart selection of surfactants and solvents    Improving grease removal with ACUSOL™ PRO
as careful choice of amines will also be paramount given their critical
                                                                                                         Kitchen cleaner with 0.5%
role in swelling soils, neutralizing fatty acids and controlling pH.        Kitchen cleaner alone
                                                                                                         ACUSOL™ PRO Polymer
Designing a formulation according to all desired performance
parameters is a challenge that requires having a broad toolbox
to draw from. Cleaning can be assessed by the ability to remove
some soils, but it is also ultimately measured by the surface shine
and absence of filming and streaking. Beyond the initial cleaning,
another compelling benefit that can be factored in a formulation,
particularly by using appropriate polymers, is surface modification
to minimize re-soiling and achieve an easier next cleaning. The
cleaning routine also requires ease-of-use, for which additives such        Kitchen cleaner alone
                                                                                                         Kitchen cleaner with 1.0%
as rheology modifiers are essential as they can ensure the product                                       ACUSOL™ PRO Polymer
                                                                                                                                            15
Floor care polish                                                        on the floor. Another product format in the market is based
                                                                         on the Clean & Shine concept according to which the product
Floor care finishes
                                                                         should be easy to apply, not build-up and provide extra shine
Floor finishes are water-based coatings that are easily removed          benefits as well as cleaning.
with conventional floor stripping agents. They are designed to
                                                                         Today’s polymer finishes generally contain metal or mixed metal
function as the wear layer of a floor finish system. The finish
                                                                         ionically cross-linked polymers. A metal crosslinked polymer is
should take the abuse, not the floor itself. Therefore, floor care
                                                                         usually one in which substituents on two separate polymer chains
products are known by consumers for protecting their floors,
                                                                         coordinate to the same metal ion. The metal reacts with ammonia
giving shine and reviving the floor colors. While the traditional
                                                                         or amines, so most strippers today have amines in them. When
maintenance regime of buffable pastes and emulsions requires
                                                                         the amines react with finishes containing these polymers, the
significant effort on the end user side, the modern floor
                                                                         detachment of the metal ions from the polymer enables the
care finishes evolved towards easy-to-apply emulsions that
                                                                         finishes to be removed from a floor with ease. The polymer is
provide excellent film forming properties and do not require an
                                                                         the main film-forming component of modern floor finishes.
additional maintenance step. They deliver shine and protection
right after the product dries and form a homogeneous coating
           CARBITOL™ Solvent                                                                                                        X
 Solvent
Forming protective layer                                                 PRIMAL™ E-1531B Emulsion is an alkali soluble resin that can
                                                                         form a homogeneous film without addition of a coalescent. It
Dow offers a range of film forming polymers under the
                                                                         can easily be formulated into a Clean & Shine type of product,
DURAPLUS™ and PRIMAL™ brands to address different consumer
                                                                         forming a protective layer on the floor that also brings the
needs. The film former selection requires the formulator to choose
                                                                         easy-next-clean benefit for the end user as it reduces the
between more conventional zinc-containing technology and Zn-free
                                                                         stain adhesion to the floors. Additionally, it revives the color of
floor care resins. DURAPLUS™ 3 Polymer is the product of choice
                                                                         the floor and provides additional gloss. In a typical floor care
for Zn-containing technology. This product is a modified acrylic
                                                                         emulsion containing floor care resins and developed to provide
polymer that provides high gloss and superior durability and is
                                                                         shine and protection, PRIMAL™ E-1531B Alkali Soluble Resin
specially modified to have excellent resistance to harsh detergent
                                                                         improves leveling and makes coalescents more effective. Dow
solutions. Additionally, DURAPLUS™ 3 Polymer based floor finishes
                                                                         offers a wide range of solvents, out of which CARBITOL™
are characterized by a unique combination of polish hardness,
                                                                         Solvent, DOWANOL™ DPM Glycol Ether and DOWANOL™
resilience and an undetectable level of ammonia odor. This allows
                                                                         DPnP Glycol Ether are typically applied as coalescents to form
such polishes to dissipate the energy of foot traffic, impacts and
                                                                         a homogeneous and durable film.
abrasion, providing excellent resistance to black marks and scuffing,
as well as gloss retention. PRIMAL™ E-2483 Polymer can be used
as an alternative as it is easy to formulate and has a very good
adhesion to various substrates, including old or worn floors.
PRIMAL™ NT-2624 Polymer offers an interesting alternative to
zinc containing technologies, providing gloss retention, even
after prolonged wear, as well as durability to floor finishes.
PRIMAL™ NT-DURABLE is a metal-free polymer designed
for industrial markets, also recommended for wood flooring
where it can be used to formulate home care products. It gives an
excellent long-term wear resistance with moderate gloss.
The new self-cross-linking technology allows the film to cure fast and
to develop good chemical resistance. It has an excellent adhesion
on critical substrates and requires a very low level of coalescent.
16
    Amines
                                                                          Physical form,                 Freezing point,          Flash point,          Specific gravity,         Viscosity,
                                               Name
                                                                               25℃                            °C                      °C                   25/4°C                 cps, 25°C
    MEA                               Monoethanolamine                          Liquid                            4                       96                  1.0113                   24
                                                                        Liquid (low freeze,
    MEA LFG 85                                                                                                  -14                  None                     1.025                    15
                                                                            15% H2O)
    DEA                                 Diethanolamine                          Liquid                            27                  138                      1.09                    453
    TEA                                 Triethanolamine                         Liquid                            21                  208                     1.126                    921
                                                                        Liquid (low freeze,
    TEA LFG 85                                                                                                   -5                  None                     1.123                  100
                                                                            15% H2O)
    MIPA                           Monoisopropanolamine                         Liquid                            31                  732                     0.9607                   23
    DIPA                             Diisopropanolamine                          Solid                           44   1
                                                                                                                                     135.5     3
                                                                                                                                                              0.992   8
                                                                                                                                                                                     87010
                                                                        Liquid (low freeze,
    DIPA LFG 85                                                                                                  131                 None4,5                  1.019                    450
                                                                            15% H2O)
    TIPA                             Triisopropanolamine                         Solid                           441                  1606                    0.9889
                                                                        Liquid (low freeze,
    TIPA LFG 85                                                                                                   51                 None5,6                   1.027                   240
                                                                            15% H2O)
1
    Overcooling: Freezing point is limited within a range         4
                                                                      L.T. Setaflash                                                  7
                                                                                                                                          20/4°C
2
    Tag closed cup                                                5
                                                                      Flashing point remains unobserved until the boiling point       8
                                                                                                                                          40/4°C
3
    H.T. Setaflash                                                6
                                                                      Cleveland open cup (No. F.P. via Closed Cup methods)            9
                                                                                                                                          70/4°C
                                                                                                                                      10
                                                                                                                                           30°C
Dispersants
Alphabetic codes correspond to product forms. N denotes ‘neutralized’, D denotes ‘dry powder’, G denotes ‘granulate’ and K denotes ‘preservative content’.
                                                                                                                                                                                               17
 Rheology modifiers
                                                                                                                                                                                                                          QP-100MH Thickener
                                   Rheology Modifier
Rheology Modifier
Rheology Modifier
Rheology Modifier
Rheology Modifier
Rheology Modifier
Rheology Modifier
                                                                                                                                                                               Rheology Modifier
                                                                                                                   ACUSOL™ 823 ER
                                                                                                                                       ACUSOL™ 830 ER
                                                                            ACUSOL™ 810A
                                    ACUSOL™ 801S
ACUSOL™ 805S
ACUSOL™ 820
ACUSOL™ 880
ACUSOL™ 882
                                                                                                                                                                                                                             CELLOSIZE™
 Product application
Abrasive cleaners X X X X
Acid cleaners X X
Alcohol-based formulations X X X X
All-purpose detergents X X X X X X X X
Fabric softeners X X X X X X
Floor cleaners X X X X X X X X X
Hard-surface cleaners X X X X X X X X X X
Laundry detergents X X X X X X X X X
Oven/grill cleaners X X X
Peroxide-containing formulators X X X
18
 Rheology modifiers
Salt tolerance
Rheology modifiers
                                                                                                                            ACUSOL™
                        ACUSOL™             ACUSOL™         ACUSOL™         ACUSOL™         ACUSOL™        ACUSOL™                          ACUSOL™              ACUSOL™
                                                                                                                            Millennium
                          801S                805S            810A            820            823 ER         830 ER                            880                  882
                                                                                                                                ER
Chemistry HASE HASE ASE HASE HASE ASE HASE HEUR HEUR
Association Very high Very high None Very high High None Very high Very high Very high
Ionic nature Anionic Anionic Anionic Anionic Anionic Anionic Anionic Nonionic Nonionic
Appearance Milky liq. Milky liq. Milky liq. Milky liq. Milky liq. Milky liq. Milky liq. Hazy liq. Hazy liq.
pH (as supplied) 3.7 2.7 2.7 2.7 3.2 3 3.5 N/A N/A
Density 1.06 1.06 1.05 1.06 1.04 1.05 1.05 N/A N/A
Eq Weight* 253 225 124 218 191 218 Confidential N/A N/A
                         Short, non-         Short, non-      Long, non-    Short, non-      Short, non-                                                         Non stringy,
 Rheology                                                                                                    Short           Non-stringy     Smooth
                          stringy             stringy          stringy       stringy          stringy                                                              tacky
 Suspension                                 Moderate to
                            Low                                  Low           Low              Low        Moderate                High        Low                   Low
 capability                                    high
Shear thinning** Very high Very high Slight Very high Moderate Moderate Moderate Slight Slight
 Viscosity, cps
                             20                 <150              15            20                30           10                 <100        11,000                 5,000
 (as supplied)
                                                                                                                                                                                19
Silicone emulsions
Silicone antifoams
Granulated antifoams
20
 Performance boosters
SupraCare™ 420 Polymer Non-ionic Softness, water absorbency, fragrance deposition Fabric softeners
SupraCare™ 425 Polymer Non-ionic Sensorial benefits, shine, creamier foam Hand dishwashing
 Opacifiers
                                                           ACUSOL™                                     ACUSOL™                                    ACUSOL™
                                                         OP301 Opacifier                            OP303B* Opacifier                           OP305* Opacifier
 Chemical composition                                Polystyrene/Polyacrylic acid                 Polystyrene/Polyacrylamide                Polystyrene/Polyacrylic acid
Solid content, % 40 40 40
Polyethylene glycols
                                                                                                                                                                             21
 Solvents
                                                                                                                                                                                                                                                       Hand
                                                                                        Boiling                             Specific                  All-     Bath-
                                                                    Chemical                         Flash     Volatility              Viscosity                        Kitchen    Floor    Floor   Carpet     Glass     Oven     Laundry     Stain     dish-   Air care   Bleach
                                      Solvents                                        point °C at                           gravity                 purpose    room
                                                                   component                        point °C   nBuAc=1                 cP at 25°C                       cleaner   cleaner   care    cleaner   cleaner   cleaner    liquid   removed   washing     gel      cleaner
                                                                                      760 mm Hg                              25°C                   cleaner   cleaner
                                                                                                                                                                                                                                                       liquid
                                                                  Propylene Glycol
                              DOWANOL™ PM Glycol Ether                                   120          311         0.62       0.919        1.7                                                                    X
                                                                    Methyl Ether
                                                                Dipropylene Glycol
                              DOWANOL™ DPM Glycol Ether                                  190          751        0.035       0.951        3.7          X                                     X         X         X                                                 X
                                                                   Methyl Ether
                                                                Tripropylene Glycol
                              DOWANOL™ TPM Glycol Ether                                   243         1212      0.0026       0.965        5.5                                        X                                                                   X
                                                                    Methyl Ether
                                                                Dipropylene Glycol
                              DOWANOL™ DPMA Glycol Ether                                  209         862        0.015       0.977        1.7                                                                                                                      X
                                                               Methyl Ether Acetate
                                                                  Propylene Glycol
     P-Series Glycol Ethers
                                                                   Ethylene Glycol
                              Butoxytriglycol                                             280         1382      0.0004       0.987        7.9                                                                                                  X         X
                                                                    n-Butyl Ether
                                                                   Ethylene Glycol
                              Hexyl CELLOSOLVE™ Solvent                                   208         912       0.0082       0.866        4.5          X         X        X          X                 X         X         X
                                                                     Hexyl Ether
                                                                   Ethylene Glycol
                              Hexyl CARBITOL™ Solvent                                     259         1352      0.0006       0.931        6.2          X         X        X          X                 X         X         X                             X
                                                                     Hexyl Ether
                                                                   Ethylene Glycol
                              DOWANOL™ EPh Glycol Ether                                   244         1211       0.001       1.109        21.5         X                  X          X
                                                                    Phenyl Ether
                                                                   Ethylene Glycol
                              DOWANOL™ EPh6                                              >350        >149       <0,0001       1.12        90           X                   X                                                                                       X
                                                                    Phenyl Ether
Annotations:
(1) Setaflash Method (closed cup)
(2) Tag Closed Cup (TCC)
*Indices listed here are typical physical properties, not product standards.
22                                                                                                                                                                                                                                                                                23
    Nonionic surfactants
                                                                               Active substance
                               Product                                                                            Cloud point(1)                  HLB(2)                Pour point(3)   Appearance(4)                                                                         Characteristics
                                                                                    content
                                                                                                                                                                                                        ECOSURF™ EH-3 Surfactant is a water dispersible nonionic surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ EH-3 Surfactant                                                             100                        Insolubility                    7.9                     -21            Liquid
                                                                                                                                                                                                        cleaners, has superior wetting and excellent oily soil removal properties, rapid dissolution, no gel range and good rinseability.
                                                                                                                                                                                                        ECOSURF™ EH-6 Surfactant is a water soluble nonionic surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ EH-6 Surfactant                                                             100                              40                       10.8                      5             Liquid
                                                                                                                                                                                                        cleaners, has superior wetting and excellent oily soil removal properties, rapid dissolution, no gel range and good rinseability.
                                                                                                                                                                                                        ECOSURF™ EH-9 Surfactant is a water soluble nonionic surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ EH-9 Surfactant                                                             100                              61                       12.5                      16            Liquid
                                                                                                                                                                                                        cleaners, has superior wetting and excellent oily soil removal properties, rapid dissolution, no gel range and good rinseability.
                                                                                                                                                                                                        ECOSURF™ EH-14 Surfactant is a water soluble nonionic surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ EH-14 (90%) Surfactant                                                       90                              86                         14                      6             Liquid
                                                                                                                                                                                                        cleaners, degreasers, superior wetting and excellent oily soil removal properties, rapid dissolution, and good rinseability.
TERGITOL™ 15-S-7 Surfactant 100 37 12.1 1 Liquid TERGITOL™ 15-S-7 Surfactant is a secondary alcohol ethoxylate, nonionic surfactant used in applications such as prewash spot removers and cleaners.
TERGITOL™ 15-S-9 Surfactant 100 60 13.3 9 Liquid TERGITOL™ 15-S-9 Surfactant is a secondary alcohol ethoxylate, nonionic surfactant used in applications such as high-performance cleaners.
TERGITOL™ 15-S-12 Surfactant 100 89 14.5 22 Solid TERGITOL™ 15-S-12 Surfactant has good handling properties and is used in a wide variety of applications including high-performance cleaners.
TERGITOL™ 15-S-15 Surfactant 100 >100 15.4 29 Solid TERGITOL™ 15-S-15 Surfactant is used in multiple applications such as high-performance cleaners & detergents and solid cleaner.
TERGITOL™ 15-S-20 Surfactant 100 >100 16.3 35 Solid TERGITOL™ 15-S-20 Surfactant is used in multiple applications such as high-performance cleaners & detergents and solid cleaners.
                                                                                                                                                                                                        TERGITOL™ 15-S-30 Surfactant is a secondary alcohol ethoxylate, nonionic surfactant used in multiple applications such as high performance cleaners &
    TERGITOL™ 15-S-30 Surfactant                                                         100                            >100                       17.4                      39             Solid
                                                                                                                                                                                                        detergents and solid cleaners.
TERGITOL™ 15-S-40 (70%) Surfactant 70 >100 18.0 5 Liquid TERGITOL™ 15-S-40 (70%) Surfactant is a secondary alcohol ethoxylate, nonionic surfactant used as emulsion stabilizer.
                                                                                                                                                                                                        ECOSURF™ SA-4 Surfactant is a nonionic seed oil based surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ SA-4 Surfactant                                                             100                        Dispersible                     7.5                     -8             Liquid
                                                                                                                                                                                                        cleaners, characterized by low odor, no gel range, excellent wetting and emulsification properties.
                                                                                                                                                                                                        ECOSURF™ SA-7 Surfactant is a nonionic seed oil based surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ SA-7 Surfactant                                                             100                              37                        9.7                      3             Liquid
                                                                                                                                                                                                        cleaners, characterized by low odor, no gel range, fast dissolution, excellent wetting, cleaning and emulsification properties.
                                                                                                                                                                                                        ECOSURF™ SA-9 Surfactant is a nonionic seed oil based surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ SA-9 Surfactant                                                             100                              57                       11.1                      4             Liquid
                                                                                                                                                                                                        cleaners, characterized by low odor, no gel range, fast dissolution, excellent wetting, cleaning and emulsification properties.
                                                                                                                                                                                                        ECOSURF™ SA-15 Surfactant is a nonionic seed oil based surfactant used in a wide variety of applications including hard surface and high performance
    ECOSURF™ SA-15 Surfactant                                                            100                            >100                       13.5                      27             Solid
                                                                                                                                                                                                        cleaners, characterized by low odor, no gel range, fast dissolution, excellent wetting, cleaning and emulsification properties.
TRITON™ CG-50 Surfactant 50 >100 - 0 Liquid Used in a wide range detergents, including glass cleaners and highly alkaline detergents.
                                                                                                                                                                                                        Chemically stable in the presence of acids, bases and salts, compatible with anionic, cationic, and other nonionic surfactants, characterized by excellent
    TRITON™ CG-600 Surfactant                                                             50                            >100                          -                      6             Liquid
                                                                                                                                                                                                        cleaning and foaming properties.
                                                                                                                                                                                                        Chemically stable in the presence of acids, bases and salts, compatible with anionic, cationic, and other nonionic surfactants, characterized by excellent
    TRITON™ CG-650 Surfactant                                                             50                            >100                          -                     -18            Liquid
                                                                                                                                                                                                        cleaning and foaming properties.
Annotations:
(1) Cloud point: °C, aqueous solution of 1% (mass percentage) active substance
(2) Range of balance between hydrophilicity and lipophilicity: <10 water-in-oil emulsifier, >10 oil-in-water emulsifier, 10~15 excellent wettability, 12~15 cleansing
(3) Pour point: °C
(4) Appearance at 25°C
24                                                                                                                                                                                                                                                                                                                                                                   25
 Low foam surfactants
                                                               Active substance
                        Product                                                                    Cloud point(1)                        HLB(2)                         Pour point(3)   Appearance                                                                              Characteristics
                                                                    content
TRITON™ DF-12 Surfactant 100 17 10.6 16 Liquid Excellent food soil defoaming properties, stable in alkaline conditions.
TRITON™ DF-16 Surfactant 100 36 11.6 -6 Liquid Excellent detergency and wetting properties, stable in acidic conditions.
TRITON™ DF-20 Surfactant 100 - - -25 Liquid Excellent detergency and wetting properties, stable in highly concentrated liquids.
                                                                                                                                                                                                     Efficient foam control agent because of its low foam characteristics and inverse water solubility. Low surface tension makes TERGITOL™ L-61 Surfactant
 TERGITOL™ L-61 Surfactant                                               100                               24                               3                               -32           Liquid     a particularly efficient rinse aid and low foam wetting agent in auto dish detergents, industrial and institutional cleaning, and in cleaning-in-place (CIP)
                                                                                                                                                                                                     applications such as food, dairy, and brewery cleaning.
                                                                                                                                                                                                     Provides both foam control and detergency. It is an efficient foam control agent because of its low foam characteristics and inverse water solubility.
 TERGITOL™ L-62 Surfactant                                               100                               32                               7                               -2            Liquid
                                                                                                                                                                                                     TERGITOL™ L-62 Surfactant is used in rinse aids, autodish detergents, industrial and institutional cleaning.
                                                                                                                                                                                                     Good wetting ability, a high degree of detergency, and low foam characteristics. It is readily miscible in water and can be used in combination with other
                                                                                                                                                                                                     surfactants in a wide range of aqueous formulations. TERGITOL™ L-64 Surfactant is an exceptional high temperature foam control agent due to its inverse
 TERGITOL™ L-64 Surfactant                                               100                               62                              15                                7            Liquid
                                                                                                                                                                                                     water solubility and low foam characteristics. TERGITOL™ L-64 Surfactant is used in rinse aids and in sanitizing solutions. TERGITOL™ L-64 Surfactant is
                                                                                                                                                                                                     the most hydrophilic of the TERGITOL™ L Series products.
                                                                                                                                                                                                     A viscous liquid at room temperature. Low foam characteristics and inverse water solubility make TERGITOL™ L-81 Surfactant an excellent foam control
 TERGITOL™ L-81 Surfactant                                               100                               20                               2                               -20           Liquid
                                                                                                                                                                                                     agent. TERGITOL™ L-81 Surfactant is used in rinse aids as well as industrial and institutional cleaning applications.
DOWFAX™ 20B102 Surfactant 95 32 11.2 -8 Liquid Low foaming surfactant used in cleaning and rinsing formulations, particularly suitable for automatic dishwashing applications.
DOWFAX™ 20A42 Surfactant 100 <4 3.7 <-10 Liquid Low foaming surfactant used in cleaning and rinsing formulations.
DOWFAX™ 20A64 Surfactant 100 30 7.5 -10 Liquid Good wetting, applicable to high pressure cleaners and automatic dishwashing detergents.
DOWFAX™ 20A55 Surfactant 100 29 6.5 <-10 Liquid Low-foaming surfactant used in cleaning and rinsing formulations, particularly suitable for automatic dishwashing applications
DOWFAX™ 20A84 Surfactant 100 40 8.6 <-10 Liquid Low-foaming surfactant used in cleaning and rinsing formulations, particularly suitable for automatic dishwashing applications
EcoSense™ HC-2100 Surfactant 50 >90 Liquid 100% biobased, readily biodegradable surfactant, rich in acidic form, easily water soluble.
EcoSense™ HC-2200 Surfactant 50 48 Liquid 100% biobased, readily biodegradable surfactant, rich in lactone form with limited water solubility.
                                                                                                                                                                                                     Specialty alkoxylated alcohol developed to address the most challenging needs of automatic dishwashing detergents. It is a waxy substance at room
 ECOSURF™ Bright 1 Surfactant                                            100                             20-25                            11.8                                          Waxy solid
                                                                                                                                                                                                     temperature and delivers exceptional shine benefits due to its strong anti-spotting characteristics.
ECOSURF™ Bright 12 Surfactant 70 11.7 Liquid Combines the anti-spotting benefits of ECOSURF™ Bright 1 with cleaning benefits, designed specially for the automatic dishwashing application.
ECOSURF™ LFE-1410 Surfactant 100 35 8.4 5 Liquid Water soluble nonionic surfactant developed for automatic dishwashing application to combine anti-spotting with foam reduction and cleaning benefits.
Annotations:
(1) Cloud point: °C, aqueous solution of 1% (mass percentage) active substance
(2) Range of balance between hydrophilicity and lipophilicity: <10 water-in-oil emulsifier, >10 oil-in-water emulsifier, 10~15 excellent wettability, 12~15 cleansing
(3) Pour point: °C
*Indices listed here are typical physical properties, not product standards.
26                                                                                                                                                                                                                                                                                                                                                                  27
About Dow
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mobility and consumer applications. Our global breadth, asset integration and scale, focused innovation, leading business positions and commitment
to sustainability enable us to achieve profitable growth and help deliver a sustainable future. We operate manufacturing sites in 31 countries and employ
approximately 35,900 people. Dow delivered sales of approximately $45 billion in 2023. References to Dow or the Company mean Dow Inc. and its
subsidiaries. Learn more about us and our ambition to be the most innovative, customer-centric, inclusive and sustainable materials science company
in the world by visiting www.dow.com.
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