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Sikaflex-291i SDS

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SAFETY DATA SHEET

Sikaflex®-291i

Section 1. Identification
GHS product identifier : Sikaflex®-291i
Product type : Paste.

Relevant identified uses of the substance or mixture and uses advised against
Sealant/adhesive.
Supplier/Manufacturer Sika Australia Pty. Ltd.
55 Elizabeth Street
(Locked Bag 482 BDC)
Wetherill Park, NSW 2164
Australia
Telephone no.: +61 2 9725 11 45
Fax no. +61 2 9725 33 30
Emergency telephone : +61 1800 033 111
number

Section 2. Hazards identification


Classification of the : Not classified.
substance or mixture

GHS label elements


Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials and food and drink.
Disposal : Not applicable.

Other hazards which do not : None known.


result in classification

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers


CAS number : Not applicable.
EC number : Mixture.
Product code : 131725-4
Ingredient name % CAS number
Hardener LH (1,6-Hexanedialdimine) <10% 613222-52-9
bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate <10% 41556-26-7

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 1/9
Sikaflex®-291i

Section 3. Composition/information on ingredients


There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First-aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention if symptoms occur. In case of inhalation of decomposition
products in a fire, symptoms may be delayed. The exposed person may need to be
kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Do not induce vomiting
unless directed to do so by medical personnel. Get medical attention if symptoms
occur.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

See toxicological information (Section 11)

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 2/9
Sikaflex®-291i

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Put on appropriate personal
protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 3/9
Sikaflex®-291i

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8).
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabelled containers.
Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
None.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 4/9
Sikaflex®-291i

Section 9. Physical and chemical properties


Appearance
Physical state : Paste.
Colour : Various.
Odour : Faint odour.
Odour threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: >150°C (>302°F)
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not applicable.
(flammable) limits
Vapour pressure : Not applicable.
Vapour density : Not available.
Density : ~1.34 g/cm³ [20°C (68°F)]
Solubility : Insoluble in the following materials: water
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not applicable.
Decomposition temperature : Not available.
SADT : Not available.
Viscosity : Not available.

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 5/9
Sikaflex®-291i

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitisation
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.

Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 6/9
Sikaflex®-291i

Section 11. Toxicological information


Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Not available.

Section 12. Ecological information


Toxicity
Not available.

Persistence and degradability


Not available.

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and runoff and
contact with soil, waterways, drains and sewers.

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 7/9
Sikaflex®-291i

Section 14. Transport information


Regulation UN number Proper shipping name Classes PG* Label Additional information
ADG Not - - -
regulated.
ADR Not - - -
regulated.
IMDG Not - - -
regulated.
IATA Not - - -
regulated.
PG* : Packing group

Section 15. Regulatory information


Safety, health and : No known specific national and/or regional regulations applicable to this product
environmental regulations (including its ingredients).
specific for the product
Standard Uniform Schedule of Medicine and Poisons
7
Control of Scheduled Carcinogenic Substances

Australia inventory (AICS) : All components are listed or exempted.


EU Classification : Not classified.
HCS Classification : Irritating material
Carcinogen
Target organ effects

Section 16. Other information


History
Date of printing : 19.08.2014.
Date of issue/Date of : 19.08.2014.
revision
Date of previous issue : No previous validation.
Version : 1
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
Material Safety Data Sheets are updated frequently. Please ensure that you have a current copy. MSDS may
be obtained from the following website: aus.sika.com

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 8/9
Sikaflex®-291i

Section 16. Other information


The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of
publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please
consult the product data sheet prior to any use and processing.

Date of issue/Date of revision : 19.08.2014. Date of previous issue : No previous validation. Version :1 9/9

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