Chemistry
Chemistry
CHEMISTRY SYLLABUS
FORMS 5 - 6
2024 - 2030
ACKNOWLEDGEMENTS
The Ministry of Primary and Secondary Education wishes to acknowledge the following for their valued
contribution in the production of this syllabus:
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Chemistry Syllabus Forms 5 - 6
CONTENTS
ACKNOWLEDGEMENTS .....................................................................................................................i
CONTENTS ...........................................................................................................................................ii
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1.4 Assumptions
1.0 PREAMBLE
It is assumed that learner:
1.1 Introduction
• have passed ‘O’ level Chemistry
This two-year Heritage-based Chemistry syllabus is • are familiar with ICT Tools and Braille/Jaws soft-
designed to put greater emphasis on the understanding ware
and application of chemistry concepts and principles in • have passed ‘O’ level Mathematics syllabus A or B
an environmentally friendly and sustainable manner. It • are familiar with laboratory apparatus
makes learners identify and solve problems practically in • are aware of laboratory safety precautions
a scientific manner. The Form 5 and 6 Chemistry
syllabus is inclusively made to cater for all categories of
learners in an increasingly technological world
1.5 Cross - cutting issues
1.2 Rationale The Heritage-based Chemistry learning area encompasses
the cross-cutting themes listed below:
Chemistry plays a pivotal role in the technological
• Environmental Management
development of any country since it is embedded in our
• Indigenous knowledge system
everyday life.
• Business enterprise skills
• Health and wellbeing
The study of Chemistry enables learners to be creative
• Disaster and risk management
and innovative in industry and society by promoting the
• Climate Change
application of Chemistry in industrial processes for value
addition, beneficiation of natural resources and harness-
ing of available opportunities for entrepreneurship.
2.0 PRESENTATION OF
SYLLABUS
1.3 Summary of Content
The Form 5 and 6 Heritage-based Chemistry syllabus is a
Form 5 and 6 Chemistry syllabus will cover theory and single document covering Forms 5 and 6.
practical activities in the following areas:
• Physical Chemistry
3.0 AIMS
• Inorganic Chemistry
The aims are to:
• Organic Chemistry
• Applied Chemistry
• enable learners to develop fundamental principles
of Chemistry for application in life and as a basis for
further studies in Chemistry and related disciplines.
• inculcate in learners the need for safety and
protection of the environment in the study of
Chemistry.
• create opportunities for learners to acquire research,
experimental, practical, enterprising and
technological skills in Chemistry.
• appreciate the usefulness and limitations of the
scientific method in the study of Chemistry.
• stimulate in learners the desire to apply Chemistry for
the benefit of society as guided by the principles of
Ubuntu/ Unhu/Vumunhu.
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Chemistry Syllabus Forms 5 - 6
• promote awareness that the applications of For adequate coverage of the syllabus, a time allocation
Chemistry may be both beneficial and of 5 theory 60 minutes periods and a block of 4 practical
detrimental to the individual and the periods per week is recommended. Learners should be
community. engaged in at least one Educational Tour per term, one
• develop in learners the appreciation of the use exhibition per year, and an attachment of one week in
of Chemistry in value creation, addition and any chemical related industry during the course
beneficiation.
6.0 TOPICS
4.0 SYLLABUS OBJECTIVES 6.1 Physical Chemistry:
Learners should be able to:
- Atoms, Molecules and Stoichiometry
- Atomic structure
• follow instructions in practical work
- Chemical bonding
• make and record observations
- States of matter
• use ICT Tools and Braille/Jaws software to
- Chemical energetics
simulate Chemistry phenomena
- Electrochemistry
• apply safety measures in all practical work
- Equilibria
• present, analyse and interpret data to establish
- Reaction kinetics
relationships
• demonstrate knowledge on facts, laws, definitions
and concepts of Chemistry
6.2 Inorganic Chemistry:
• measure and express quantities to a given level of
accuracy and precision - Chemical Periodicity of period 3
• design a practical solution to a real- life problem - Chemistry of Group II elements
using knowledge of Chemistry - Chemistry of Group IV elements
- Chemistry of Group VII elements
Atoms, Molecules and Stoichiometry • Relative masses of atoms and molecules • Stoichiometric reaction ratios
• Mass spectra • Titration
• The mole and Avogadro constant • Percentage yield and percentage purity
• Empirical and molecular formulae
• Stoichiometric calculations
Atomic structure • Sub-atomic particles
• Electronic configurations
• Ionisation energy
Chemical bonding • Ionic bonding
• Covalent bonding
• Bond reactivity
• Dative bonding
• Shapes of molecules
• Metallic bonding
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Hydrocarbons • Nomenclature
• Isomerism
• Preparation and occurrence
• Physical properties
• Chemical properties
• Reaction mechanisms
Halogen derivatives • Nomenclature
• Isomerism
• Preparation
• Physical properties
• Chemical properties
• Reaction mechanisms
Hydroxy compounds • Nomenclature
• Isomerism
• Manufacture
• Preparation and occurrence
• Physical properties
• Chemical properties
• Reaction mechanisms
Carbonyl compounds • Nomenclature
• Isomerism
• Preparation
• Physical properties
• Chemical properties
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FORM 5 SYLLABUS
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Chemical bonding • Describe ionic bonding as in • Ionic bonding • Discussing ionic bonding • Form 5 and 6
sodium chloride, magnesium • Drawing ‘dot and cross’ Science Kit
oxide and aluminium oxide. diagrams. • ICT Tools and
• describe covalent bonding • Discussing covalent bonding. Braille/Jaws
as in hydrogen, oxygen, • Covalent bonding • Drawing ‘dot and cross’ software
chlorine, carbon dioxide, diagrams.
hydrogen chloride, ethane,
ethene and benzene in
terms of orbital overlap.
• compare the reactivity of • Relating bond reactivity to
covalent bonds in terms of • Bond reactivity bond energy, bond length and
bond length, bond energy bond polarity.
and bond polarity.
• describe dative bonding as
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Chemical Energetics • explain that chemical • Enthalpy changes of: • Experimenting to show • Form 5 and 6
reactions are accompanied - Reaction energy changes (exothermic Science Kit
by energy changes mostly in - Formation and endothermic). • ICT Tools and
the form of heat energy. - Combustion • Discussing the various Braille/Jaws
• explain the terms - Neutralisation enthalpy changes software
• enthalpy changes, - Hydration • Experimenting to make
• standard enthalpy changes, - Solution fertilizer and calculating heat
• bond energy and lattice - lattice changes.
energy - electron affinity • Carrying out thermometric
• calculate enthalpy changes titrations.
using vc∆𝑇 • Plotting graphs of quantity
• apply Hess Law to construct • Hess Law and Born-Haber against temperature.
energy cycles and Born- cycles • Constructing and analyzing
Haber cycles. Born-Haber cycles.
• calculate enthalpy changes • Charge density
using energy cycles and
Born-Haber cycles.
• explain the factors affecting • Discussing factors affecting
the size of lattice energy. lattice energy.
Electrochemistry • describe redox processes in • Redox processes • Discussing reduction and • Form 5 and 6
terms of electron transfer oxidation in terms of electron Science Kit
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• Constructing reaction
• Mechanism of reactions mechanisms.
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• Aluminium chloride
Chemistry of Group • interpret the trends in physical • Trends in Physical properties • Justifying trends in • Data booklet
II elements properties. physical properties using
data booklet values.
• describe the reactions of the
• Trends in Chemical properties • Experimenting on the
elements with oxygen and water.
reactions of elements with
water and oxygen. • A level Science kit
• describe the behaviour of oxides • Dissolving oxides in water
with water. and testing for pH.
• pH meter
• explain the variation in thermal • Heating carbonates and
decomposition of the carbonates nitrates; testing products
and nitrates. produced.
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• state the properties and uses of • Properties and uses of Group II • Discussing uses of • magnesium oxide,
compounds magnesium oxide, calcium oxide,
group II compounds.
calcium oxide, calcium calcium carbonate,
carbonate, magnesium, magnesium
sulphate, calcium sulphate, calcium
sulphate, barium sulphate, barium
sulphate, magnesium sulphate,
hydroxide and magnesium
magnesium trisilicate hydroxide and
(MMT) magnesium
trisilicate (MMT)
• Site visits
Chemistry of Group • explain the variations in melting • Trends in Physical properties • Discussing trends in • Form 5 and 6
IV elements and in electrical conductivity of physical properties. Science Kit
the elements.
• explain the variations in bonding, • Experimenting with Lead • Lead (IV) oxide
acid-base nature and thermal (IV) oxide, charcoal and
stability of the oxides of oxidation
coal. • ICT Tools and
Braille/Jaws
states II & IV.
software
• describe the bonding, molecular
shape and volatility of the • Constructing molecular
tetrachlorides. shapes using models.
• explain reactions of the • Site visits
• Trends in Chemical properties
tetrachlorides with water in terms • Discussing the behaviour
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• describe the trends in volatility • Trends in Physical properties • Discussing the trends in • Form 5 and 6
and colour of chlorine, bromine volatility and colour of Science Kit
and iodine. chlorine, bromine and
• interpret the volatility of elements iodine. • ICT Tools and
• Trends in Chemical properties Braille/Jaws
in terms of Van der Waal forces.
software
• explain the relative reactivity of
Chemistry of Group elements as oxidising agents
• Site visits
VII elements with reference to E0 values.
• explain the reactions of elements • Calculating E0 cell values
and changes in oxidation
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FORM 6 SYLLABUS
Electrochemistry • use redox titration results in • Redox titration • Performing redox titrations • Form 5 and 6
quantitative analysis. • Discussing the composition and Science Kit
• describe how the hydrogen electrode reactions of fuel cells. • ICT Tools and
oxygen fuel cell operates. Braille/Jaws
• deduce electrode reactions from • Citing advantages and software
a given fuel cell. • Fuel cells disadvantages of fuel cells over
• compare fuel cells with conventional cells.
conventional cells.
• Determining the quantity of
• calculate the quantity of charge, • Quantitative electrolysis charge, mass and or volume of
mass and or volume of substance substance liberated during
liberated during electrolysis using electrolysis
the relationship, F=Le (Faraday
constant, the Avogadro constant
and the charge on the electron)
• describe how to determine a
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Equilibria • explain how buffer solutions • Buffer solutions • Discussing buffer solutions • Form 5 and 6
control pH. including their role in controlling Science Kit
• calculate the pH and/or pOH of blood and soil pH. • ICT Tools and
buffer solutions. • Preparing buffer solutions Braille/Jaws
• apply the concept of solubility • Solubility products • Determining pH and pOH of software
product, Ksp buffer solutions
• calculate Ksp from concentrations • Calculating solubility products
and vice versa from concentrations and vice
• explain the common ion effect versa including common ion
effect
Reaction kinetics • Outline the different modes of • Catalysis • Discussing the different modes of • Form 5 and 6
action of homogeneous and - Homogeneous action of homogeneous and Science Kit
heterogeneous catalysis as - Heterogeneous heterogeneous catalysis such as • ICT Tools and
exemplified in the Haber process, Fe in the Haber process and Fe2+ Braille/Jaws
catalytic removal of oxides of in I-and S2O82- reaction. software
nitrogen in the exhaust gases • Carrying out experiments on
from car engines, the redox decomposition of hydrogen
reaction between I- and S2O82- peroxide catalysed by
and catalytic role of NOxin the manganese (IV) oxide.
oxidation of atmospheric sulphur
dioxide.
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• Combustion
• describe the mechanism of free • Reaction mechanisms
radical substitution, electrophilic • Free radical substitution by
addition and electrophilic chlorine and its mechanism
substitution • Discussing the chemistry of
alkenes as exemplified by the
following reactions of ethene:
• Electrophilic addition of steam,
hydrogen halides and halogens
including mechanism
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Halogen • use the nomenclature and • Nomenclature • Drawing displayed structures • Form 5 and 6
derivatives displayed formula of and naming them Science Kit
halogenoalkanes and • ICT Tools and
halogenoarenes Braille/Jaws
• describe the isomerism associated • Isomerism • Discussing isomerism software
with halogen derivatives associated with halogen • Journals
derivatives • Bromoethane
• Chemical properties • Silver nitrate
• describe the following nucleophilic • Experimenting with • Aerosols
substitution reactions of bromoethane, silver nitrate and • Plastics
halogenoalkanes as exemplified hot water to show substitution
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• explain the uses of fluoroalkanes • Uses and environmental • Discussing the uses of
and fluoro halogen alkanes in impact fluoroalkanes and fluoro
terms of their relative chemical halogen alkanes and their
inertness effects on the environment
• recognise the concern about the
effect of chlorofluoro alkanes on
the ozone layer
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• describe the reactions of alcohols • Chemical properties of • Discussing reactions of alcohols • Ethanol
as exemplified by ethanol during alcohols • Distinguishing between primary, • Acidified
combustion, substitution to give secondary and tertiary alcohols potassium
halogenoalkanes, reaction with by oxidation reactions dichromate
sodium, oxidation to carbonyl • Propan – 2-ol
compounds and carboxylic acids, • 2methylpropan –
dehydration and ester formation 2-ol
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Carbonyl • use the nomenclature and • Nomenclature • Discussing the nomenclature • Form 5 and 6
compounds displayed formulae to describe the and displayed formulae of Science Kit
structure of aldehydes and aldehydes and ketones • ICT Tools and
ketones Braille/Jaws
software
• Drawing structures to illustrate
• explain the isomerism associated • Isomerism the isomerism in carbonyl
with aldehydes and ketones compounds
• Ethanol
• describe the formation aldehydes • Preparing aldehydes and • Acidified
and ketones from primary and • Preparation ketones from respective potassium
secondary alcohols respectively alcohols dichromate
• Propan – 2-ol
• outline the mechanism of • Chemical properties • Analysing the mechanism of
nucleophilic addition reaction of nucleophilic addition reaction of
hydrogen cyanide with aldehydes hydrogen cyanide with
and ketones aldehydes and ketones
• describe the reduction of • Discussing the reactions of
aldehydes and ketones using carbonyl compounds, with
NaBH4 NaBH4, 2.4-DNPH, Fehling’s
• suggest a suitable test for a given solution, alkaline iodine and
carbonyl compound Tollens reagent
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• describe the acid and base • Manufacturing soap from fats • Fats
hydrolysis of esters and oils • Oils
• Ash
• state the uses of carboxylic acids • Uses of carboxylic acids • Investigating uses of carboxylic
and esters and esters acids and esters
Nitrogen • describe the formation of • Preparation and • Discussing the formation of • Form 5 and 6
compounds ethylamine by reduction of nitrile occurrence ethylamine by reduction of nitrile Science Kit
and of phenylamine by reduction and of phenylamine by • ICT Tools and
of nitrobenzene reduction of nitrobenzene Braille/Jaws
software
• Comparing the relative basicity
• explain the relative basicity of • Chemical properties of ammonia, alkylamines and
ammonia, alkylamines and phenylamines in terms of their
phenylamines in terms of their structures
structures
• Discussing the reactions of
phenylamine with aqueous
• describe the reaction of bromine and with nitrous acid
phenylamine with: • Discussing the hydrolysis of
- aqueous bromine diazonium salt to give phenol
- nitrous acid • Synthesizing dyestuff
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• Visiting sites
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Transition Elements • explain what is meant by • Characteristic • Discussing characteristic • Form 5 and 6
transition, in terms of d-block properties properties of transition elements Science Kit
element forming one or more
stable ions with incomplete d- • ICT Tools and
orbitals • Working out the electronic Braille/Jaws software
• analyse the electronic configuration of the first-row
configuration of the first-row transition elements and their
transition elements and their ions
ions
• recognise that the atomic radii, • Analyzing atomic radii, ionic
ionic radii and first ionisation radii and first ionisation
energies of the transition metals energies data of the transition
are relatively invariant metals
• contrast qualitatively the melting • Comparing the melting points,
point, density, atomic radius, densities, atomic radii, first
first ionisation energy and ionisation energies and
conductivity of the transition conductivities of the transition
elements with those of calcium elements with those of calcium
as a typical s-block element as a typical s-block element
• describe the tendency of
transition elements to have • Experimenting to show variable
variable oxidation states oxidation states
• explain the formation of
complexes in terms of co- • Discussing formation of
ordinate bonds and the splitting complexes
of d orbitals
• describe the shape of four-fold • Variable oxidation state
and six - fold complexes
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Phase Equilibria • explain steam distillation of two • Steam Distillation • experimenting on steam • Form 5 and 6
immiscible liquids distillation Science Kit
• demonstrate an awareness of • discussing methods of • ICT Tools and
the applications of steam distillation Braille/Jaws software
distillation
• explain the term partition
coefficient • Distribution between • working out partition coefficient
phases for a system
• calculate partition coefficient for
a system in which the solute is
in the same molecular state in
the two solutions • carrying out solvent extraction
• explain solvent extraction
• explain: paper, high- • Chromatography • Performing thin layer, column • Chromatography kit
performance liquid, ion and paper chromatography and chromatograms
exchange, thin layer, column • Discussing industrial and • Resource persons
and gas/liquid chromatography medical applications of
in terms of absorption and/or chromatography
partition, based on appropriate
practical experience
• demonstrate an awareness of
the applications of these
methods of chromatography in
industry and medicine
• describe the process of • electrophoresis
electrophoresis, and the effect
of pH
• describe the hydrolysis of
proteins, separation and • genetic fingerprinting • Discussing electrophoresis and
detection of the products by genetic fingerprinting
electrophoresis
• outline the process of analysis
of genes and genetic
fingerprinting
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Environmental • outline the main industrial • Air Pollution and • Discussing the main causes of • ICT Tools and
Chemistry methods of controlling sulphur Control air pollution Braille/Jaws software
dioxide emission (flue gas • Resource persons
desulphurisation, alkaline
scrubbing, use of limestone-
based fluidised beds)
• deduce environmental
considerations related to the
usage and generation of power • Discussing environmental
(with particular reference to impact of power generation
fossil fuels and nuclear energy) • Visiting sites
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9.0 ASSESSMENT
The Heritage-based Chemistry syllabus learning area for form 5 and 6 shall be assessed through School Based
Continuous Assessment (SBCA) and Summative Assessment (SA). These assessments shall be guided by the principles of
inclusivity, practicability, authenticity, transparency, flexibility, validity and reliability. The principles are crucial for creating a
supportive and effective learning environment that fosters growth and development in learners at secondary school level.
Arrangements, accommodations and modifications shall be visible to enable candidates with special needs to access
assessments.
This section covers the assessment objectives, the assessment model, the scheme of assessment, and the specification grid.
By the end of the Heritage-based Chemistry Syllabus learning area for form 5 and 6 learners will be assessed on their
ability to:
9.1.1 follow instructions in practical work
9.1.2 make and record observations
9.1.3 use ICT Tools and Braille/Jaws software to simulate Chemistry phenomena
9.1.4 apply safety measures in all practical work
9.1.5 present, analyse and interpret data to establish relationships
9.1.6 demonstrate knowledge on facts, laws, definitions and concepts of Chemistry
9.1.7 measure and express quantities to a given level of accuracy and precision
9.1.8 design a practical solution to a real-life problem using knowledge of Chemistry
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Assessment Of Learner
Performance in Chemistry
School
Based (Paper 1)
Project (Paper 2)
Profiling Multiple
20% Choice Structured Paper
Questions
In addition, learners shall be profiled and learner profile records established. Learner profile certificates shall be issued for
checkpoints assessment in schools as per the dictates of the Teacher’s Guide to Learning and Assessment. The aspects
to be profiled shall include learner’s prior knowledge, values and skills, and subsequently the new competences acquired
at any given point.
The table shows the Scheme of Assessment where 20% is allocated to School Based Continuous Assessment and 80% to
School or ZIMSEC Summative Assessment.
FORM OF ASSESSMENT WEIGHTING
School Based Continuous Assessment 20%
Summative Assessment 80%
Total 100%
Learners shall do one school-based project per form which contributes to 20% of the end of year final mark. The end of year
summative assessment shall then contribute 80%. However, for ZIMSEC public examinations, two (2) school-based projects
shall be considered as School Based Continuous Assessment at form 5 and 6. The two School Based Projects shall include
those done during form 5 and 6 sessions. Each will contribute 10%.
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The Table given below shows the Learning and Assessment Scheme for the School Based Project.
Project Execution Stages Project Stage Description Timelines Marks
1 Problem Identification January 5
2 Investigation of related ideas to February 10
the problem/innovation
3 Generation of possible solutions March 10
4 Selecting the most suitable April-May 5
solution
5 Refinement of selected solution June 5
6 Presentation of the final solution July 10
7 Evaluation of the solution and August-September 5
Recommendations
TOTAL 50
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9.3.2 Description of the ZIMSEC Summative Assessment
ZIMSEC Summative Assessment shall be a public examination at Form 6. The examination shall consist of four (4) papers
of different weighting.
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Paper 1: Theory: the paper consists of 40 compulsory multiple-choice items. 30 items will be of the direct choice type
and 10 of the multiple completion type. Each question shall have 4 response items.
Paper 2: Theory. The paper consists of 6 compulsory structured questions, 10 marks each. Learners answer all the
questions on the Question Paper
Paper 3: Theory
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10.0 GLOSSARY/APPENDICES
It is hoped that the glossary (which is relevant only to science subjects) will prove helpful to candidates as a guide,
i.e. it is neither exhaustive nor definitive. The glossary has been deliberately kept brief not only with respect to the
number of terms included but also to the descriptions of their meanings. Candidates should appreciate that the
meaning of a term must depend in part on its context.
1 Define (the term(s)…) is intended literally. Only a formal statement or equivalent paraphrase being required.
2 What do you understand by/What is meant by (the term(s)…) normally implies that a definition should be
given, together with some relevant comment on the significance or context of the term(s) concerned, especially
where two or more terms are included in the question. The amount of supplementary comment intended should be
interpreted in the light of the indicated mark value.
3 State implies a concise answer, with little or no supporting argument, e.g. a numerical answer that can be
obtained ‘by inspection’.
4 List requires a number of points, generally each of one word, with no elaboration. Where a given number of
points is specified, this should not be exceeded.
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5 Explain may imply reasoning or some reference to theory, depending on the context.
6 Describe requires candidates to state in words (using diagrams where appropriate) the main points of the
topics. It is often used with reference either to particular phenomena or to a particular experiment. In the former
instance the term usually implies that the answer should include reference to (visual) observations associated with the
phenomena.
In other contexts, describe and give an account of should be interpreted more generally, i.e. the candidate has greater
discretion about the nature and the organisation of the material to be included in the answer. Describe and explain
may be coupled in a similar way to state and explain.
7 Discuss requires candidates to give a critical account of the points involved in the topic.
9 Predict or deduce implies that the candidate is not expected to produce the required answer by recall but
by making a logical connection between other pieces of information. Such information may be wholly given in the
question or may depend on answers extracted in an earlier part of the question.
10 Comment is intended as an open-ended instruction, inviting candidates to recall or infer points of interest
relevant to the context of the question, taking account of the number of marks available.
11 Suggest is used in two main contexts, i.e. either to imply that there is no unique answer (e.g. in chemistry,
two or more substances may satisfy the given conditions describing an ‘unknown’), or to imply that candidates are
expected to apply their general knowledge to a ‘novel’ situation, one that may be formally ‘not in the syllabus’.
12 Find is a general term that may variously be interpreted as calculate, measure, determine etc.
13 Calculate is used when a numerical answer is required. In general, working should be shown, especially
where two or more steps are involved.
14 Measure implies that the quantity concerned can be directly obtained from a suitable measuring instrument,
e.g. length, using a rule, or angle using a protractor.
15 Determine often implies that the quantity concerned cannot be measured directly but is obtained by calcula-
tion, substituting measured or known values of other quantities into a formula, e.g. relative molecular mass.
16 Estimate implies a reasoned order of magnitude statement or calculation of the quantity concerned, making
such simplifying assumptions as may be necessary about points of principle and about the values of quantities not
otherwise included in the question.
17 Sketch, when applied to graph work, implies that the shape and/or position of the curve need only be qual-
itatively correct, but candidates should be aware that, depending on the context, some quantitative aspects may be
looked for, e.g. passing through the origin, having an intercept, asymptote or discontinuity at a particular value.
In diagrams, sketch implies that a simple, freehand drawing is acceptable: nevertheless, care should be taken over
proportions and the clear exposition of important details.
18 Construct is often used in relation to chemical equations where a candidate is expected to write a balanced
equation, not factual recall but by analogy or by using information in the question.
19 Compare requires candidates to provide both the similarities and differences between things or concepts.
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A knowledge of the following volumetric determination will be assumed: acids and alkalis using suitable indicators; iron
(II), ethanedioic acid (and its salts), by potassium manganate (VII); iodine and sodium thiosulphate. Simple titrations
involving other reagents may also be set but, where appropriate, sufficient working details will be given.
(ii) Candidates may be required to carry out an experiment that involves the determination of some quantity, e.g.
the enthalpy change of a reaction or, the rate of a reaction. Such experiments will depend on the simple manipulation
of usual laboratory apparatus.
(iii) An observational problem in which the candidate will be asked to investigate, by specified experiments, an
unknown substance. The substance may be an element, a compound or a mixture.
The substances to be investigated may contain ions not included in the above list: in such cases, candidates will not
be expected to identify the ions but only to draw conclusions of a general nature.
Candidates should not attempt tests, other than those specified, on substances, except when it is appropriate to test
for a gas.
Exercises requiring a knowledge of simple organic reactions, e.g. test-tube reactions indicating the presence of
unsaturated hydrocarbons, alcoholic, phenolic and carboxylic groups, may also be set, but this would be for the testing
of observation skills and drawing general conclusions only.
Candidates are NOT allowed to refer to note books, text books or any other information in the Practical examination.
Practical Techniques
The following notes are intended to give schools and candidates an indication of the accuracy that is expected in
quantitative exercises and general instructions for qualitative exercises.
(a) Candidates should normally record burette readings to the nearest 0.05cm3 and they should ensure that they
have carried out a sufficient number of titrations, e.g. in an experiment with a good end-point, at least two titres within
0.10cm3.
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(c) In qualitative analysis exercises, candidates should use approximately 1cm depth of a solution (1-2 cm3) for each
test and add reagents gradually, ensuring good mixing, until no further change is seen. Candidates should indicate
at what stage a change occurs, writing any deductions alongside the observation on which they are based. Answers
should include details of colour changes, precipitates formed, the names and chemical tests for any gases evolved
(equations are not required).
Marks for deductions or conclusions can only be gained if the appropriate observations are recorded.
10.2 APPARATUS FOR FORM 5 - 6 SCIENCE KIT
This list given below has been drawn up in order to give guidance to schools concerning the apparatus that are
expected to be generally available for examination purposes. The list is not intended to be exhaustive: in particular,
items (such as Bunsen burners, tripods and glass-tubing) that are commonly regarded as standard equipment in a
chemical laboratory are not included. Unless otherwise, the allocation is “per candidate”.
Two 50cm3burettes,
Two 25 cm3pipettes,
One 10 cm3pipette,
Teat pipette
One pipette filler
Three 250 cm3Conical flasks
Volumetric flasks, 100cm3 and 150 cm3
Measuring cylinders,10cm3 25 cm3, 50 cm3 and100cm3
500cm3Wash bottle
Two medium size filter funnels
Porcelain crucible, approximately 15 cm3, with a lid
Evaporating basin, at least 30 cm3
Beakers, squat form lip: 100 cm3, 250 cm3
Thermometers: -10oC to +110oC at 1oC; at 0.2oC precision
-5oC to +50oC at 0.2oC
Plastic beaker, e.g. polystyrene, of approximate capacity 150 cm3
Test-tubes (some of which should be Pyrex or hard glass) approximately 125 mm x 16 mm Boiling tubes, approxi-
mately 150 mm x 25 mm
Clocks (or wall-clock) to measure to an accuracy of about 1s. (Where clocks are specified, candidates may use their
own wrist watches if they prefer).
Balance, single-pan, direct reading, 0.01g or better (1 per 8-12 candidates).
Details of the requirements for a particular examination are given in the Instructions for Supervisors which are sent to
Centres several weeks prior to the examination. These Instructions also contain advice about colour-blind candidates.
Supervisors are reminded of their responsibilities for supplying the Examiners with the information specified in the
Instructions. Failure to supply such information may cause candidates to be unavoidably penalised.
The attention of Centres is drawn to the Handbook for Centres which contain a section on Science Syllabi which
includes information about arrangements for practical examinations.
48
Chemistry Syllabus Forms 5 - 6
cation
reaction with
NaOH(aq) NH3(aq)
[Lead (II) ions can be distinguished from aluminium ions by the insolubility of lead (II) chloride].
49
Chemistry Syllabus Forms 5 - 6
Reactions of anions
Ion Reaction
bromide, gives pale cream ppt. with Ag+(aq) (partially sol. in NH3(aq));
Br-(aq) gives yellow ppt. with Pb2+(aq)
sulphate, gives white ppt. with Ba2+(aq) or with Pb2+(aq) (insol. in xs dilute
SO42-(aq) strong acids)
H2
oxygen, relights a glowing splint
O2
sulphur dioxide, turns aqueous potassium dichromate (VI) from orange to green
SO2
50