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Assignment CA2

The document outlines a CA2 assignment with a total of 25 marks, focusing on thermodynamic laws, cell potential, and periodic properties. It includes specific tasks such as deducing relations in thermodynamics, proving the efficiency of heat engines, explaining periodic properties, and detailing reaction mechanisms for organic compounds. Each section specifies the marks allocated and the concepts to be covered, emphasizing the application of theoretical principles.

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17 views1 page

Assignment CA2

The document outlines a CA2 assignment with a total of 25 marks, focusing on thermodynamic laws, cell potential, and periodic properties. It includes specific tasks such as deducing relations in thermodynamics, proving the efficiency of heat engines, explaining periodic properties, and detailing reaction mechanisms for organic compounds. Each section specifies the marks allocated and the concepts to be covered, emphasizing the application of theoretical principles.

Uploaded by

s36347032
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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CA2 Assignment

Full Marks: 25
CO3: Apply thermodynamic laws and cell potential to explain bulk properties and
processes (15)
1. Deduce the relation between ∆H = ∆U + ∆ngRT (3)

2. Show that for 1 mole of an ideal gas Cp –Cv =R (3)

3. Using Carnot Cycle, prove that the efficiency of a heat engine is always less than one. (3)

4. Prove that for an ideal gas in adiabatic condition: (2 X 3 = 6)

(i) TV R/Cv = constant

(ii) PV R/Cv = constant

(iii) T R/Cv P 1- R/Cv = constant

CO4: Explain periodic properties such as ionization potential, electronegativity,


oxidation states, polarizability, acidity, basicity (5)
1. Define ionization energy. Give the order of ionization energy of group 16 elements. (2+1)

2. Explain the anomalous behaviour of fluorine. (2)

CO6: Develop reaction pathways to synthesize desired organic compounds (5)

1. Explain the mechanism of SN1 and SN2 reaction with suitable energy profile diagram(s). (5)

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