1.

In solution, solvent can be separated from solute by one of the following

process.
(a) decantation
(b) filtration
(c) distillation
(d) sedimentation

2. A mixture of oil and water is separated by

(a) filtration
(b) fractional distillation
(c) sublimation
(d) using Separating Funnel

3. The mixture of iodine and sodium chloride can be easily separated by

(a) fractional distillation
(b) steam distillation
(c) chromatography
(d) sublimation

4. Anthracene is purified by
(a) filtration
(b) distillation
(c) crystallisation
(d) sublimation

5. Fractional distillation is useful in distillation of

(a) petroleum
(b) cool-tar
(c) crude alcohol
(d) all of these

6. Impure Glycerine can be purified by

(a) steam distillation
(b) simple distillation
(c) vacuum distillation
(d) extraction with a solvent

7. Vacuum distillation is used to purify liquid which

(a) are highly volatile
(b) are explosive in nature
(c) decompose below their boiling points
(d) have high boiling point

8. Which of the following is useful for making pure water from a Solution of salt in
water?
(a) filtration
(b) distillation
(c) chromatography
(d) steam distillation

9. Fractional crystallizations is carried out to separate a mixture of

(a) organic solids mixed with inorganic solids
(b) organic solids slightly soluble in water
(c) organic solids having small difference in their solubilities in suitable solvent
(d) organic solids having greater difference in their solubilities in suitable solvent

10. A mixture of camphor and Benzoic acid can be easily separated by

(a) sublimation
(b) extraction with solvent
(c) fractional Crystallisation
(d) chemical method

11. A mixture of acetone and methanol can be separated by

(a) steam distillation
(b) vacuum distillation
(c) fractional distillation
(d) none of these

12. Sublimation is a process in which a solid

(a) changes into vapour form
(b) changes into another allotropic form
(c) changes into liquid form
(d) none of the above.

13. Absolute alcohol cannot be obtained by simple fractional distillation because

(a) pure C2H5OH is unstable
(b) C2H5OH forms hydrogen bonds with water
(c) boiling point of C2H5OH is very close to that of water
(d) constant boiling azeotropic mixture is formed with water

14. A mixture of iron fillings and sulphur cannot be separated by

(a) heating
(b) magnet
(c) shaking with CS2
(d) washing in a current of water

15. Steam distillation is based on the fact that vapourisation of organic liquid takes
place at
(a) lower temperature than its boiling point
(b) higher temperature than its boiling point
(c) its boiling point
(d) water and organic liquid both undergo distillation

16. Essential oils can be isolated by

(a) crystallization
(b) steam distillation
(c) sublimation
(d) distillation

17. Sublimation can’t be used for purification of

(a) benzoic acid
(b) camphor
(c) urea
(d) naphthalene

18. Which of the substance is purified by sublimation?

(a) naphthalene
(b) benzoic acid
(c) camphor
(d) all of these

1. The Lassaigne’s extract is boiled with dilute HNO3 before testing for halogens
compound?

(a) Ag2S is insoluble in HNO3

(b) AgCN is soluble in HNO3

 (c) Na2S and NaCN are decomposed by HNO3

(d) silver halides are soluble in HNO3

2. In Kjedahl’s method, nitrogen present is estimated as

(a) N2 (b) NH3

(c) NO2 (d) None of these

3. A gaseous hydrocarbon has 85% carbon and vapour density of 28. The
possible formula of the hydrocarbon will be

(a) C 3 H6 (b) C 2 H4

(c) C 2 H2 (d) C 4 H8

4. Two elements X (atomic weight = 75) and Y (atomic weight = 16) combine to
give a compound having 75.8% X. The formula of the compound is

(a) XY (b) X2 Y

(c) X2 Y 2 (d) X2 Y 3

5. The most suitable method for separation of 1 : 1 mixture of ortho and para –
nitrophenols is

(a) sublimation (b) chromatography

(c) crystallization (d) steam distillation

6. An organic compound contains C = 40 %, O = 53.34 % and H = 6.60 %. The

empirical formula of the compound is

(a) CH2O (b) CHO

(c) CH4O2 (d) C 2 H2 O

7. The compound that does not give a blue colour in Lassaigne’s test is
 (a) aniline (b) glycine

(c) Pyrene (d) urea

8. The maximum number of isomer for an alkene with the molecular formula
C4H8 is

(a) two (b) three

(c) four (d) five

9. 0.24 g of an organic compound on combustion produced 0.036 g water and

0.22 g of CO2. Calculate the % of oxygen in that compound

(a) 12.65 (b) 46.65

(c) 85.45 (d) 73.34 %

10. 0.257 g of a nitrogenous waste digested with sulphuric acid and then distilled
with excess of strong alkali. The gas evolved was absorbed in 50 mL N/10
H2SO4. At the end of the experiment, the acid required 20.2 mL of N/10 NaOH
for neutralization. Determine the % of nitrogen in the substance.

(a) 14.6% (b) 15.6%

(c) 12.5% (d) 13.2%

11. 0.50 g of a substance containing bromine gave 0.86 g of silver bromide. Find
the % of Br in the compound.

(a) 65.85% (b) 73.19%

(c) 78.52% (d) 84.23%

12. In an experiment, 0.36 g of an organic compound gave 0.35 g of BaSO 4.

Calculate the % of sulphur in the compound.

(a) 15.32% (b) 14.32%

 (c) 15.45% (d) 13.35%

13. If in an organic compound the weights of C,H,O in taken is 6:1:8 ratio. The
molecular formula of the compound is

(a) C2H4O2 (b) C2H4O4

(c) C3H6O3 (d) CH2O2

14. In Kjeldahl method, the gas evolved from 1.325 g sample of a fertilizer is
passed into 50 mL of 0.2030 N H2SO4. 25.32 mL of 0.198 N NaOH is needed for
the titration of the un-used acid. Find the N% here.

(a) 10.66% (b) 5.3%

(c) 16.29% (d) 25.73%

15. On combustion 0.2 g of an organic compound containing C, H and O yields

0.147 g CO2 and 0.12 g water. The % of C, H, O in the compound

(a) 22.5, 8.7, 68.8 (b) 20, 6.7, 73.3

(c) 18.2, 9.5, 72.3 (d) 28.9, 12.8, 58.8

16. 9.9 g of an amide with molecular formula C4H5NxOy on heating with alkali
liberated 1.7 g of ammonia. If the % of oxygen is 32.33 %, then the ratio of N
and O atoms in the compound is

(a) 2:1 (b) 1:2

(c) 2:5 (d) 2:3

17. An organic compound containing carbon, hydrogen and oxygen contains

52.2% carbon, 13.04% hydrogen, vapour density of the compound is 23. Its
molecular formula will be

(a) C 4 H8 O (b) C 3 H8 O
 (c) C 2 H6 O (d) C5H10O

18. If the enzyme peroxidase anhydrase, the % of Se by mass is 0.5%. If the atomic
mass of Se is 78.4 U, then minimum molecular mass of peroxidase anhydrase
enzyme is

(a) 1.568 x 103 U (b) 1.568 x 104 U

(c) 1.568 U (d) 2.136 x 104 U

19. 5 g of certain metal, X (atomic mass = 27) is converted into 61.7% crystalline
sulphate containing 48.6% by mass of water of crystallization. The simplest
formula of the compound is

(a) X2(SO4)3 18H2O (b) X2(SO4)3 14H2O

(c) X2(SO4)3 16H2O (d) X2(SO4)3 12H2O

20. If 0.1 g of an organic compound containing phosphorous gave 0.222 g of

Mg2P2O7, then the % phosphorous in the compound is

(a) 31 (b) 0.2

(c) 66 (d) 62

21. When 0.25 g of an organic compound is heated with HNO3 and AgNO3 in a
carius tube, it gives 0.35 g of AgCl. The % of chlorine in the compound is

(a) 36.6% (b) 45.3%

(c) 34.6% (d) 54.8%

22. 0.5 g of an organic compound in Kjeldahl experiment needs 29 mL of H2SO4
for complete neutralization of NH3. The N% is

(a) 16.2 (b) 8.1

(c) 24.3 (d) 32.4

23. In Lassaigne’s test, which of the following organic compound will produce a
blood red colour when its sodium extract is treated with FeCl 3 solution?

(a) (b)

(b) (d)

24. If a compound on analysis was found to contains C = 185%, H = 1.55%, O =

55.04%, O = 24.81%, then its empirical formula is

(a) CHClO (b) CH2ClO

(c) C2H5ClO (d) ClC2H5O

25. Sorbic acid consists of C = 64.3%, H = 7.2% and 28.5% oxygen. Find the
empirical formula

(a) C2H4O2 (b) C3H4O2

(c) C 3 H4 O (d) CH2O