The document outlines a complex chemical reaction pathway involving various compounds and conditions, including the use of concentrated sulfuric acid, calcium carbonate, and different reagents like NaNH2 and Cl2. It describes the transformation of dextro and laevo rotatory solutions, leading to the formation of black particles and other products through multiple steps. The reactions involve high temperatures and specific catalysts, ultimately resulting in aromatic compounds and other derivatives.
The document outlines a complex chemical reaction pathway involving various compounds and conditions, including the use of concentrated sulfuric acid, calcium carbonate, and different reagents like NaNH2 and Cl2. It describes the transformation of dextro and laevo rotatory solutions, leading to the formation of black particles and other products through multiple steps. The reactions involve high temperatures and specific catalysts, ultimately resulting in aromatic compounds and other derivatives.
The document outlines a complex chemical reaction pathway involving various compounds and conditions, including the use of concentrated sulfuric acid, calcium carbonate, and different reagents like NaNH2 and Cl2. It describes the transformation of dextro and laevo rotatory solutions, leading to the formation of black particles and other products through multiple steps. The reactions involve high temperatures and specific catalysts, ultimately resulting in aromatic compounds and other derivatives.
The document outlines a complex chemical reaction pathway involving various compounds and conditions, including the use of concentrated sulfuric acid, calcium carbonate, and different reagents like NaNH2 and Cl2. It describes the transformation of dextro and laevo rotatory solutions, leading to the formation of black particles and other products through multiple steps. The reactions involve high temperatures and specific catalysts, ultimately resulting in aromatic compounds and other derivatives.
Conc. H2SO4 A (Solution is dextro rotatory) Black particles (B) specific rotation = +66° H2O
Conc. H2SO4 Same
A1 + A2 A1 or A2 Black particles dextro Laevo observed rotatory rotatory (Overall mixture of A1 and A2 is laevorotatory) + Black + H2O CaCO3 CO2 + CaO D E Particles /
red hot E F G (Not aromatic) NaNH2 Fe tube Cl2 / 500 K (2 eq) (873 K) H (Aromatic) I Cl2 + AlCl3 H2(Ni) (excess) (dark cold) CH3I high pressure Cl2 + AlCl3 (anhydrous) (2 eq) P Se / R and Na / D.E. temp. NBS J RO– / ROH / Red hot Br2 Alcohol +F M N O Q Fe tube h KOH / +H +
(Mono K bromo product) KMnO4 (excess) HNO3 Fe + HCl NaNO2 (high temp.) P S T U + H2SO4 (Major + Conc. H2SO4 Steam product) L (cyclic trianhydride)
