General Instructions 1. There are 35 questions in this question paper with internal choice.
JI 2. Section A consists of 18 multiple-choice questions carrying 1 mark each, 3. Section B consists of 7 very short answer questions carrying 2 marks each. 4. Section C consists of 5 short answer questions carrying 3 marks each. 5. Section D consists of 2 case-based questions carrying 4 marks each. 6. Section E consists of 3 long answer questions carrying 5 marks each. 7. All questions are compulsory. LA 8. Use of log tables and calculators is not allowed.
SECTION-A The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. The major product formed by acid catalysed dehydration of 3-methylhexanol is (a) 1-methylcyclohexane (b) 3-methylcyclohexene (c) 1-methylcyclohexene (d) 1-methylcyclohex-2-ene A 2. Which one of the following compound is more reactive towards SN2 reaction? (a) (CH3)3C—Br (b) (CH3)2CHBr (c) CH3—CH2—Br (d) CH3—Br 3. [V(H2O)6] Cl3 compound is coloured due to (a) d-d transitions B
(b) unpaired electrons in d-orbital of V
(c) charge transfer from metal to ligand (d) charge transfer from ligand to metal 4. What is the half-life period for the decomposition of N2O5 in seconds? (Given : Rate constant for the decomposition of N2O5 is 6 × 10-4 s-1. The reaction follows first order kinetics? (a) 11.55 (b) 115.5 (c) 1155 (d) 1.155 5. The molar conductance at infinite dilution for CH3COONa is 92.5 S cm2 mol-1. Using graph and given information, the molar conductivity of CH3COOH will be
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(a) 399.4 S cm2 mol-1 (b) 175 S cm2 mol-1 (c) 22.42 S cm2 mol-1 (d) 124 S cm2 mol-1
JI 6. For a reaction, A + B → AB, the order w.r.t. A and B is 1 and 2 respectively. What will be the change in the rate of reaction if the concentration of A and B doubled? (a) Increases four times (b) Decreases four times (c) Increases eight times (d) Decreases eight times 7. Arrange the following in the decreasing order of their boiling points A : C6H5OH B : (CH3)2NH C : C2H5NH2 LA (a) B > C > A (b) C > B > A (c) A < B < C (d) A > C > B 8. The CFSE of a complex, [ML4] is x cm-1. The CFSE for [ML6] complex will be (a) x (b) (c) (d) 9. What would be the major product of the following reaction? A (a) A = CH3 —CH2—CH2—OH, B = CH3 —CH2—CH(CH3)2 (b) A = CH3—CH2—CH2—OH, B = CH3—CH2 —C(CH3)2 —I (c) A = CH3—CH2—CH2—I, B = CH3—CH2—C(CH3)2—OH (d) A = CH3—CH2—CH3, B = CH3—CH2—C(CH3)2—I 10. Which of the following statements is false about primary amines? B
(a) Alkyl amines are stronger bases than ammonia
(b) Alkyl amines are stronger bases than arylamines (c) Alkyl amines react with nitrous acid to produce alcohols (d) Aryl amines react with nitrous acid to produce phenol 11. Which of the following tests/reactions is not given by aldehydes as well as ketones? (a) 2, 4-DNP test (b) Tollen's test (c) Fehling test (d) NaHCO3 test 12. The temperature dependence of the rate constant, k is expressed as , when a
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plot b/w log k and is plotted, we get the graph as shown. What is the value of slope in the graph?
(a) (b) - (c) log A (d) -
13. The no. of ions formed on dissolving one molecule of K2SO4 . Al2(SO4)3 . 24 H2O in water is
JI (a) 5 (b) 6 (c) 7 (d) 8 14. Which of the following will not result in the formation of carbon-carbon bonds? (a) Reimer-Tiemann reaction (b) Cannizzaro reaction (c) Wurtz reaction (d) Friedel-Crafts acylation LA Direction (Q. no. 15-18) In the following questions an Assertion (A) is followed by a corresponding Reason (R) use the following keys to choose the appropriate answer. (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (c) A is true but R is false. (d) A is false but R is true. 15. Assertion (A) Picric acid contains carboxylic acid. Reason (R) 2, 4, 6-trinitrophenol is called picric acid. A 16. Assertion (A) Enzymes are biological catalysts. Reason (R) Enzymes are proteins but all proteins are not enzymes. 17. Assertion (A) In first transition series, chromium has highest paramagnetic moment. Reason (R) Chromium has no unpaired electrons. B
18. Assertions (A) Aniline is less basic than aliphatic amines.
Reason (R) Lone pair at —NH2 group of aniline is delocalised due to mesomeric effect.
SECTION-B This section contains 7 questions with internal choice in two questions. The following questions are very short answer type and carry 2 marks each. 19. A reaction of first-order is 20% complete in 10 minutes. Calculate the time required for 75% completion of the reaction. 20. What happens when D-glucose is treated with the following reagents?
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(a) Ammoniacal AgNO3 (b) NH2OH Or Account for the following. (a) Cellulose in our diet is not nourishing, (b) Pyranose structure of glucose. 21. Give reason for the following. (a) Iodination of benzene is difficult. (b) Aryl halides do not give a white precipitate with aqueous AgNO3. . Or (a) Which out of HCl or SOCl2 is better for converting ethanol to chloroethane?
JI (b) Name the product when benzene is heated with methanai and HCl in presence of anhvdrous ZnCl2. 22. The formula Co(NH3)5 Br SO4 could represent a sulphate or bromide. Write the structures and names of possible isomers. 23. Write down the possible reactions for corrosion of Mg occurring at anode, cathode and overall reaction to provide protection to iron. 24. Explain how and why the rate of reaction is affected by LA (a) catalyst (b) temperature 25. Write the reaction and IUPAC name of the product formed when 2-butanone is treated with LiAlH4 followed by heating in presence of acid.
SECTION-C This section contains 7 questions with internal choice in one questions, The following questions are very short answer type and carry 3 marks each. 26. Write the equations for the following reaction A (a) Sodium benzoate is heated with soda lime. (b) Ethanol is treated with HBr. (c) Cyclohexanol is treated with Cu/300°C. 27. Using VBT, explain the following in relation to the paramagnetic complex, [Fe(H2O6)]3+. (a) Hybridisation B
(b) Magnetic moment value
(c) Type of complex-inner, outer orbital complex 28. Answer the following questions. (a) State Henry‟s law and explain why soda bottles kept at room temperature fizzes on opening. (1) (b) O2 is bubbled through water at 293 K. Assuming that O2 exerts a partial pressure of 0.98 bar. Calculate the solubility of O2 in gL-1. (Given, Henry‟s constant for O2 is 34.84 kbar). (1) 29. Give reasons for any 3 of the following observations.
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(a) Aliphatic amines are soluble in water and aromatic amines are not. (b) Dimethyl amine is stronger base than trimethylamine. (c) Aniline is converted into acetanilide before nitration, (d) C6H5N (CH3)2 is more basic than C6H5NH2. 30. (a) Identify the major product formed when styrene is treated with Br2 followed by NaNH2 and CH3I. (1) (b) Why are haloalkanes more reactive than haloarenes? (2) Or (a) Explain why n-butyl bromide has higher boiling point than tert-butyl bromide. (2)
JI (b) Identify the major product formed when propene is treated with Cl2 at 500°C. (1)
SECTION-D The following questions are case-based questions. Each question has an internal choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow. 31. Carbohydrates are hydrates of carbon, containing carbon, hydrogen and oxygen. Their general molecular formula is Cx(H2O)y; „x‟ mayor may not be equal to „y‟. The advancing LA definition of carbohydrates may be given as “polyhydroxyaldehydes and ketones and all those compounds which give polyhydroxy aldehydes and ketones on hydrolysis are called carbohydrates”. Carbohydrates are calssified as monosaccharides, oligosaccharides and polysaccharides. Monosaccharides are simplest carbohydrates. Oligosaccharides on hydrolysis give two to ten monosaccharide molecules. Polysaccharides on the other hand are polymer of monosaccharides. Answer the following questions. (a) Give example of a polysaccharide made of fructose. (b) Rhamnose (C6H12C5) is a compound which has the molecular formula different from general A formula of carbohydrates. Is it a carbohydrate? . (c) Starch and cellulose both are polysaccharide of glucose. What is the difference between them? Or What is essentially the difference between the α-form of glucose and 0-form of glucose? B
32. Boiling point or freezing point of liquid solution would be affected by the dissolved solids in the liquid phase. A soluble solid in solution has the effect of raising its boiling point and depressing its freezing point. The addition of non-volatile substances to a solvent decreases the vapour pressure and the added solute particles affect the formation of pure solvent crystals. According to many researches the decrease in freezing point directly correlated to the concentration of solutes dissolved in the solvent. This phenomenon is expressed as freezing point depression and it is useful for several applications such as freeze concentration of liquid food and to find the molar mass of an unknown solute in the solution. Freeze concentration is a high quality liquid food concentration method where water is removed by forming ice crystals. This is done by cooling the liquid food below the freezing point of the solution. The freezing point depression is referred as a colligative property and it is proportional
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to the molar concentration of the solution (m), along with vapour pressure lowering, boiling point elevation, and osmotic pressure. These are physical characteristics of solutions that depend only on the identity of the solvent and the concentration of the solute. The characters are not depending on the solute's identity. Freezing point depression of different sucrose solutions and coconut water.) Answer the following questions. (a) Colligative properties depends on which factor? (b) Assume three samples of juices A, B and C have glucose as the only sugar present in them. The concentration of sample A, B and C are 0.1 M, 0.5 M and 0.2 M respectively. Which of them have highest freezing point? (c) 1.00 g of a non-electrolyte solute when dissolved in 50 g of benzene lowered the freezing
JI point of benzene by 0.40 K. What will be the molar mass of the solute? (Kf for benzene = 5.12 K kg mol-1) Or What will be the boiling point elevation for a solution prepared by adding 10 g of CaCl2 to 200 g of water. (Kb for water = 0.512 K kg mol-1, molar mass of CaCl2 = 111 g mol-1).
SECTION-E LA The following questions are long answer type and carry 5 marks each. Two questions have an internal choice 33. (a) State Kohlrausch law of independent migration of ions. (1) (b) What is mercury cell? Give the electrode reactions. (2) (c) The conductivity of 0.2 M solution of KCl at 298 K is 0.0248 S cm-1. Calculate the molar coductivity. (2) Or (a) Why for acetic acid can not be determined experimentally ? (2) A (b) Why does dry cell become dead after long time, even if it has not been used? (2) (c) How many Faraday‟s are needed to reduce 2 moles of Cu2+ to Cu metal? (1) 34. A, B and C are three non-cyclic functional isomers of a carbonyl compound with molecular formula, C4H8O. Isomer A and C give positive Tollen‟s test, whereas isomer B does not give Tollen's test but give positive iodoform test. Isomers A and B on reduction with Zn(Hg)/conc. B
HCl give same product D.
(a) Write the structures of A, B, C and D. (2) (b) Write the equations of A and C with Tollen‟s regent. (1) (c) Write the reaction of B showing positive iodoform test. (1) (d) Out of all (A), (B) and (C), which one is least reactive towards addition of HCN? (1) Or When liquid „A‟ is treated with freshly prepared ammonical silver nitrate solution it gives bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium hydrogen sulphite. Liquid „B ‟ also forms a white crystalline solid with sodium hydrogen sulphite but it does
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not give test with ammonical silver nitrate. (a) Which of the liquid is aldehyde and ketone? (b) Write the chemical equations of the reactions. (c) Write the equation of A giving Tollen's test. (d) If A and B contains three carbon atoms, write their structures. (e) Which will have more boiling point (A) or (B)? 35. Answer the following. (a) Why Zn, Cd and Hg are not considered as transition elements? (b) Why chromium is a hard metal, whereas mercury is a liquid?
JI (c) Why Cu+ and Ag+ are colourless? (d) Why f-block elements are called inner-transition elements? (e) Explain the observation, La3+ (Z = 57) and Cu3+ (Z = 71) do not show any colour in solution. LA A B
