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BHI-CRO3036Corrosion inhibitor.

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SAFETY DATA SHEET

Section 1. Identification
Product name : TECHNI-HIB 3036
Product code : CRO3036

Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Corrosion inhibitor.

Print date : 1/12/2023


Validation date : 1/12/2023
Version : 3.01

Supplier's details : Baker Petrolite LLC


12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/SDSs Call: 800-231-3606
(8:00 a.m. - 5:00 p.m. CST, Monday - Friday) 281-276-5400

Emergency telephone : CHEMTREC: 800-424-9300 (U.S. 24 hour)


number (with hours of Baker Petrolite: 800-231-3606
operation) (001)281-276-5400
CHEMTREC Int'l 01-703-527-3887 (International 24 hour)
BPC

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

GHS label elements


Hazard pictograms :

Signal word : Warning


Hazard statements : Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure. (hearing organs)
Precautionary statements

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TECHNI-HIB 3036

Section 2. Hazards identification


Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Do not breathe vapor. Wash thoroughly after handling.
Response : IF exposed or concerned: Get medical advice or attention. IF ON SKIN (or hair): Take
off immediately all contaminated clothing. Rinse skin with water. IF ON SKIN: Wash
with plenty of water. If skin irritation occurs: Get medical advice or attention. IF IN
EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Avoid contact with skin and clothing. Wash thoroughly after handling.
elements
Hazards not otherwise : Prolonged or repeated contact may dry skin and cause irritation.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture

Ingredient name % CAS number


Petroleum naphtha 50 - 60 64742-47-8
Ethylbenzene 10 - 20 100-41-4
Amine derivative 10 - 20 Trade secret.
Xylene 1-5 1330-20-7
Isopropanol 1-5 67-63-0
Heavy aromatic naphtha 1-5 64742-94-5
Amine derivative 1-5 Trade secret.
Toluene 0.1 - 1 108-88-3
Cumene 0.1 - 1 98-82-8
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified and hence require reporting in this section.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Continue to rinse for at least 10 minutes. Check for and remove any contact
lenses. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. In case of inhalation
of decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under medical surveillance for 48 hours.

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TECHNI-HIB 3036

Section 4. First aid measures


Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove
contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get
medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. Defatting to the skin.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:,pain or irritation,watering,redness
Inhalation : reduced fetal weight,increase in fetal deaths,skeletal malformations
Skin contact : irritation,redness,dryness,cracking,reduced fetal weight,increase in fetal deaths,skeletal
malformations
Ingestion : Adverse symptoms may include the following:,reduced fetal weight,increase in fetal
deaths,skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)


Additional information
If product is ingested and vomiting occurs naturally, have person lean forward to reduce the risk of aspiration into the lungs.

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
from the chemical fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides
decomposition products

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TECHNI-HIB 3036

Section 5. Fire-fighting measures


Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424-8802.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.

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TECHNI-HIB 3036

Section 7. Handling and storage


Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in a dry, cool and well-ventilated area, away from incompatible materials (see
incompatibilities Section 10). Store in original container, protected from direct sunlight. Store locked up.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. See
Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Petroleum naphtha ACGIH TLV (United States, 1/2022). Absorbed through
skin.
TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours.
Ethylbenzene ACGIH TLV (United States, 1/2022). Ototoxicant.
TWA: 20 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 545 mg/m³, 0 times per shift, 15 minutes.
STEL: 125 ppm, 0 times per shift, 15 minutes.
TWA: 435 mg/m³, 0 times per shift, 10 hours.
TWA: 100 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³, 0 times per shift, 8 hours.
TWA: 100 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 545 mg/m³, 0 times per shift, 15 minutes.
STEL: 125 ppm, 0 times per shift, 15 minutes.
TWA: 435 mg/m³, 0 times per shift, 8 hours.
TWA: 100 ppm, 0 times per shift, 8 hours.
Amine derivative None.
Xylene ACGIH TLV (United States, 1/2022).
TWA: 20 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 655 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Isopropanol ACGIH TLV (United States, 4/2014).
STEL: 400 ppm, 0 times per shift, 15 minutes.
TWA: 200 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2013).
STEL: 1225 mg/m³, 0 times per shift, 15 minutes.
STEL: 500 ppm, 0 times per shift, 15 minutes.
TWA: 980 mg/m³, 0 times per shift, 10 hours.
TWA: 400 ppm, 0 times per shift, 10 hours.
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TECHNI-HIB 3036

Section 8. Exposure controls/personal protection


OSHA PEL (United States, 2/2013).
TWA: 980 mg/m³, 0 times per shift, 8 hours.
TWA: 400 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 1225 mg/m³, 0 times per shift, 15 minutes.
STEL: 500 ppm, 0 times per shift, 15 minutes.
TWA: 980 mg/m³, 0 times per shift, 8 hours.
TWA: 400 ppm, 0 times per shift, 8 hours.

Heavy aromatic naphtha None.


Amine derivative None.
Toluene ACGIH TLV (United States, 1/2022). Ototoxicant.
TWA: 20 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 560 mg/m³, 0 times per shift, 15 minutes.
STEL: 150 ppm, 0 times per shift, 15 minutes.
TWA: 375 mg/m³, 0 times per shift, 10 hours.
TWA: 100 ppm, 0 times per shift, 10 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 560 mg/m³, 0 times per shift, 15 minutes.
STEL: 150 ppm, 0 times per shift, 15 minutes.
TWA: 375 mg/m³, 0 times per shift, 8 hours.
TWA: 100 ppm, 0 times per shift, 8 hours.
OSHA PEL Z2 (United States, 2/2013).
AMP: 500 ppm, 0 times per shift, 10 minutes.
CEIL: 300 ppm, 0 times per shift, 0 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
Cumene ACGIH TLV (United States, 1/2022).
TWA: 5 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020). Absorbed
through skin.
TWA: 245 mg/m³, 0 times per shift, 10 hours.
TWA: 50 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018). Absorbed through
skin.
TWA: 245 mg/m³, 0 times per shift, 8 hours.
TWA: 50 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
TWA: 245 mg/m³, 0 times per shift, 8 hours.
TWA: 50 ppm, 0 times per shift, 8 hours.

Consult local authorities for acceptable exposure limits.


If OSHA permissible exposure levels are shown above they are the OSHA 1989 levels or are from subsequent
OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker
Hughes recommends that these lower exposure levels be observed as reasonable worker protection.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Individual protection measures

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TECHNI-HIB 3036

Section 8. Exposure controls/personal protection


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Wear chemical safety goggles. When transferring material wear face-shield in addition
to chemical safety goggles.
Hand protection : Chemical-resistant gloves.
Skin protection : Wear long sleeves to prevent repeated or prolonged skin contact.
Respiratory protection : If a risk assessment indicates it is necessary, use a properly fitted, air purifying or
supplied air respirator complying with an approved standard. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.

Section 9. Physical and chemical properties


The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance
Physical state : Liquid.
Color : Brown. [Dark]
Odor : Aromatic.
Odor threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Initial Boiling Point : Not available.
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: 23.34°C (74°F) [TCC]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.
Lower and upper explosion : Not available.
limit/flammability limit
Vapor pressure : 22.1 kPa (165.5 mm Hg (3.2 psig)) @ 54.44°C (130 F) (Reid)
Relative vapor density : Not available.
Relative density : 0.93
Density : 7.74 (lbs/gal)
Solubility in water : Insoluble
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
VOC : Not available.
Pour Point : Not available.
Particle characteristics
Median particle size : Not applicable.

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TECHNI-HIB 3036

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, acids and
alkalis.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Ethylbenzene LD50 Dermal Rabbit 15400 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Amine derivative LD50 Dermal Rabbit >23500 mg/kg -
LD50 Oral Rat >19000 mg/kg -
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 29 mg/l 4 hours
LD50 Dermal Rabbit 20000 mg/kg -
LD50 Dermal Rabbit >1700 mg/kg -
LD50 Oral Male rat 3523 mg/kg -
LD50 Oral Rat 3287 mg/kg -
Isopropanol LC50 Inhalation Vapor Rat >10000 ppm 6 hours
LD50 Dermal Rabbit 6.29 g/kg -
LD50 Oral Rat 4700 mg/kg -
Heavy aromatic naphtha LC50 Inhalation Vapor Rat >11.4 mg/l 6 hours
LD50 Oral Rat 3200 mg/kg -
LD50 Oral Rat >2000 mg/kg -
Amine derivative LD50 Oral Rat 1000 mg/kg -
Toluene LC50 Inhalation Vapor Female rat 5100 ppm 4 hours
LC50 Inhalation Vapor Rat 19 mg/l 4 hours
LC50 Inhalation Vapor Rat 49000 mg/m³ 4 hours
LD50 Oral Rat 4328 mg/kg -
Cumene LC50 Inhalation Vapor Mouse 10000 mg/m³ 7 hours
LC50 Inhalation Vapor Rat 39000 mg/m³ 4 hours
LD50 Dermal Rabbit 10600 mg/kg -
LD50 Oral Rat 2.9 g/kg -
Irritation/Corrosion
No available toxicity data.
Sensitization
No available toxicity data.
Mutagenicity
No available toxicity data.

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TECHNI-HIB 3036

Section 11. Toxicological information


Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
Ethylbenzene - 2B -
Xylene - 3 -
Isopropanol - 3 -
Toluene - 3 -
Cumene - 2B Reasonably anticipated to be a human carcinogen.
Reproductive toxicity
No available toxicity data.
Teratogenicity
No available toxicity data.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Xylene Category 3 - Narcotic effects
Isopropanol Category 3 - Narcotic effects
Heavy aromatic naphtha Category 3 - Narcotic effects
Toluene Category 3 - Narcotic effects
Cumene Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Ethylbenzene Category 2 - hearing organs
Aspiration hazard
Name Result
Petroleum naphtha ASPIRATION HAZARD - Category 1
Xylene ASPIRATION HAZARD - Category 1
Heavy aromatic naphtha ASPIRATION HAZARD - Category 1
Toluene ASPIRATION HAZARD - Category 1
Cumene ASPIRATION HAZARD - Category 1

Information on the likely : Routes of entry anticipated: Dermal, Inhalation.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. Defatting to the skin.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:,pain or irritation,watering,redness
Inhalation : reduced fetal weight,increase in fetal deaths,skeletal malformations
Skin contact : irritation,redness,dryness,cracking,reduced fetal weight,increase in fetal deaths,skeletal
malformations

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TECHNI-HIB 3036

Section 11. Toxicological information


Ingestion : Adverse symptoms may include the following:,reduced fetal weight,increase in fetal
deaths,skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : Suspected of damaging fertility or the unborn child.

Numerical measures of toxicity


Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
TECHNI-HIB 3036 66944.5 46740.3 212456 93.7 Not
available.
Ethylbenzene 3500 15400 Not 11 Not
available. available.
Xylene 3287 1100 5000 29 Not
available.
Isopropanol 4700 6290 Not Not Not
available. available. available.
Heavy aromatic naphtha 3200 Not Not Not Not
available. available. available. available.
Amine derivative 1000 Not Not Not Not
available. available. available. available.
Toluene 4328 Not Not 49 Not
available. available. available.
Cumene 2900 10600 Not 39 Not
available. available.

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TECHNI-HIB 3036

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Petroleum naphtha Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days
Acute LC50 2900 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 2930 to 4400 µg/l Fresh Daphnia - Daphnia magna 48 hours
water
Acute LC50 5200 µg/l Marine water Crustaceans - Americamysis 48 hours
bahia
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Chronic NOEC 1000 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Isopropanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1400000 µg/l Fish - Gambusia affinis 96 hours
Amine derivative Acute EC50 4300 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Larvae
Acute EC50 2400 µg/l Fresh water Fish - Poecilia reticulata 96 hours
Toluene Acute EC50 433 ppm Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch 96 hours
Chronic NOEC 500000 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
Cumene Acute EC50 2600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute LC50 7400 to 11290 µg/l Fresh Crustaceans - Artemia sp. 48 hours
water
Acute LC50 30500 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2700 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability


Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Ethylbenzene 3.6 - low
Xylene 3.12 8.1 to 25.9 low
Isopropanol 0.05 - low
Heavy aromatic naphtha 2.8 to 6.5 99 to 5780 high
Toluene 2.73 90 low
Cumene 3.55 94.69 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

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TECHNI-HIB 3036

Section 12. Ecological information


Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Vapor from product residues may create a highly flammable or
explosive atmosphere inside the container. Do not cut, weld or grind used containers
unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information


DOT Classification TDG Classification IMDG IATA
UN number UN1993 UN1993 UN1993 UN1993

UN proper FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID,


shipping name N.O.S. (Contains: N.O.S. (Contains: N.O.S. (Contains: N.O.S. (Contains:
Petroleum naphtha, Petroleum naphtha, Petroleum naphtha, Petroleum naphtha,
Ethylbenzene) Ethylbenzene) Ethylbenzene) Ethylbenzene)
Transport 3 3 3 3
hazard class(es)

Packing group III III III III


Environmental No. No. No. No.
hazards

Additional information
DOT Classification : Reportable quantity 4249.1 lbs / 1929.1 kg [547.97 gal / 2074.3 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
IMDG : Emergency schedules F-E S-E
IATA : The environmentally hazardous substance mark may appear if required by other
transportation regulations.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.


to IMO instruments
DOT Reportable Ethylbenzene, 1101 gal of this product.
Quantity Xylene, 549 gal of this product.

Marine pollutant Not available.

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TECHNI-HIB 3036

Section 14. Transport information


North-America NAERG : 128

Section 15. Regulatory information


U.S. Federal regulations : TSCA 12(b) one-time export: No products were found.
TSCA 12(b) annual export notification: No products were found.
United States inventory (TSCA 8b): All components are active or exempted.
Clean Water Act (CWA) 307: ethylbenzene; toluene; naphthalene; benzene
Clean Water Act (CWA) 311: ethylbenzene; xylene; toluene; naphthalene; potassium
hydroxide; benzene
United States - Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) :
List name Status Ingredient name Name on list Conc.
United States - Clean Air Act Section Listed Ethylbenzene Ethyl benzene 10 - 20
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Xylene Xylenes 1-5
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Toluene Toluene 0.1 - 1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Cumene Cumene 0.1 - 1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Naphthalene Naphthalene 0 - 0.1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Benzene Benzene 0 - 0.1
112(b) Hazardous Air Pollutants
(HAPs)

SARA 302/304 : No products were found.


SARA 311/312
Classification : FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
HNOC - Defatting irritant
SARA 313
Product name CAS number %

Supplier notification Ethylbenzene 100-41-4 10 - 20


Xylene 1330-20-7 1-5
Isopropanol 67-63-0 1-5
Cumene 98-82-8 0.1 - 1
California Prop. 65
WARNING: This product can expose you to chemicals including benzene, which is known to the State of California
to cause cancer and birth defects or other reproductive harm. This product can expose you to chemicals including
ethylbenzene, cumene and naphthalene, which are known to the State of California to cause cancer, and Toluene,
which is known to the State of California to cause birth defects or other reproductive harm. For more information go
to www.P65Warnings.ca.gov.
Canada
Canada (CEPA DSL): : All components are listed or exempted.

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TECHNI-HIB 3036

Section 16. Other information


National Fire Protection Association (U.S.A.)

3 Flammability BPC
Health 2 0 Instability
Special

History
Date of printing : 1/12/2023
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
NOTE: The information on this SDS is based on data which is considered to be accurate. Baker Hughes, however,
makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this
information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.

This SDS was prepared and is to be used for this product. If the product is used as a component in another
product, this SDS information may not be applicable.

1/12/2023 CRO3036 14/14

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