Silane
Treatment
INCI Name: Triethoxycaprylylsilane
Code: Treatment 11S
Triethoxycaprylylsilane is a very
reactive surface-treating agent, H OC2H5 OH
3 C2H5OH
because the hydrolysis of Si-O bond
─
─
O + C2H5O ─ Si ─ CnH2n+1 HO ─ Si ─ CnH2n+1
takes place readily in presence of
─
─
H OC2H5 OH Route 2
moisture to form silanol.
Route 1 OH OH
OH OH
The caprylylsilyl group is then CnH2n+1 CnH2n+1
chemically bonded to the pigment H2O
─
─
HO ─ Si ─── O ─── Si ─ OH
via a condensation reaction between
─
OH OH CnH2n+1
the silanol group formed above and
─
H2O HO ─ Si ─ OH
the hydroxyl groups of the pigment OH OH
─
OH OH CnH2n+1 CnH2n+1 OH O
surface. This reaction is thus
─
Si ─── O ─── Si OH OH
especially suitable for treament of O O
metal oxides. At the completion of O O
the reaction, all ethoxy groups are CnH2n+1 Si(OH)3
substituted and caprylylsilyl groups H2O H2O H2O
Hydrophobic Treated Pigment Surface
are crosslinked to the pigments to
form a very stable coating, even at
low pH.
While they offer maximum water repellency, triethoxycaprylylsilane treated
Silicone treated pigments disperse pigments, because of the lipophilic caprylyl groups, are easy to disperse in
well in cyclomethicones. They have esters, hydrocarbons and silicone fluids : higher pigment loading can be achieved
a very low surface tension and as compared to methicone treated pigments.
excellent hydrophobicity, but they
sometimes have poor wettability in The treatment is also physicochemically stable, even at pH 3, has no residual
common organic vehicles. methanol, and, due to the absence of Si-H bonds, has zero hydrogen potential.
Trade Name INCI Name Product type
BRO-11S2 Iron Oxides (CI 77491) (And) Triethoxycaprylylsilane Red Iron Oxide
BYO-11S2 Iron Oxides (CI 77492) (And) Triethoxycaprylylsilane Yellow Iron Oxide
BBO-11S2 Iron Oxides (CI 77499) (And) Triethoxycaprylylsilane Black Iron Oxide
BGCO-11S3 Chromium Oxide Greens (And) Triethoxycaprylylsilane Green Chromium
BHG TM-11S2 Chromium Hydroxide Greens (And) Triethoxycaprylylsilane Green Chromium Hydroxide
BEUB-11S2 Ultramarines (And) Triethoxycaprylylsilane
Ultramarine Blue
BUV CG-11S2 Ultramarine Violet
BTD-V-11S2
BTD-11S2 Titanium Dioxide (And) Triethoxycaprylylsilane Pigmentary TiO2
RBTD-671-11S2
ZnO-PCC-11S2 Zinc Oxide (And) Triethoxycaprylylsilane Pigmentary ZnO
USA BRASIL UK FRANCE ASIA PACIFIC
Technical Literature ref 11S-001 - March 15, 2024 www.koboproducts.com
Trade Name INCI Name Product type
BLUE 1AL-11S4 Blue 1 Lake (And) Triethoxycaprylylsilane FD&C Blue No. 1 Aluminum Lake
RED 6BA C-11S5 Red 6 Lake (And) Triethoxycaprylylsilane D&C Red No. 6 Barium Lake
RED 7CA C-11S5 Red 7 Lake (And) Triethoxycaprylylsilane D&C Red No. 7 Calcium Lake
RED 27AL-11S3 Red 27 Lake (And) Triethoxycaprylylsilane D&C Red No. 27 Aluminum Lake
RED 28AL C-11S3 Red 28 Lake (CI 45410) (And) Triethoxycaprylylsilane D&C Red No. 28 Aluminum Lake
RED 33AL-11S2 Red 33 Lake (And) Triethoxycaprylylsilane D&C Red No. 33 Aluminum Lake
YELLOW 5AL-11S2 Yellow 5 Lake (And) Triethoxycaprylylsilane FD&C Yellow No. 5 Aluminum Lake
YELLOW 6AL-11S2 Yellow 6 Lake (And) Triethoxycaprylylsilane FD&C Yellow No. 6 Aluminum Lake
RED 6SS-11S2 Red 6 (And) Triethoxycaprylylsilane D&C Red No. 6
GMS-11S2 Sericite
Mica (And) Triethoxycaprylylsilane
MICA S-11S4 Mica
KoboMica 1000S-11S2 Synthetic Fluorphlogopite (And) Triethoxycaprylylsilane Synthetic Fluorphlogopite
ASO-11S2 Aluminum Starch Octenylsuccinate (And) Triethoxycaprylylsilane Aluminum Starch Octenylsuccinate
MT-600B-11S5 Titanium Dioxide (And) Triethoxycaprylylsilane UV-Attenuation TiO2
A120-ZNO-11S3
MZO-35-11S5
ZnO-660SS-11S5 Zinc Oxide (And) Triethoxycaprylylsilane UV-Attenuation ZnO
ZNO FSF-11S4
ZNO XZ-11S3L
Titanium Dioxide (And) Aluminum Hydroxide
A1K-TiO2-11S2 (And) Triethoxycaprylylsilane IR-Attenuation TiO2
TiO2-IR300-11S2 Titanium Dioxide (And) Triethoxycaprylylsilane
KPP-064P
Pressed Powder with CARESS® BN12
Part 1 Manufacturing Procedure
● SERICITE GMS-4C - Kobo Products: Mica 70.48% 1. Micropulverize Part 1 until color is fully developed.
● BTD-11S2 - Kobo Products: Titanium Dioxide 2. Add Part 2 to Part 1.
(And) Triethoxycaprylylsilane 7.00% 3. Blend well.
● MST-203 - Kobo Products: Polymethylsilsesquioxane 5.00% 4. Press at 500 psi.
● CARESS® BN12 - Bent Tree/Kobo Products: Boron Nitride 5.00%
● ZINC MYRISTATE (MB) - Kobo Products: Zinc Myristate 2.00% Description
● BYO-11S2 - Kobo Products: Iron Oxides (CI 77492) This powder features Kobo's CARESS® BN12, Boron Nitride, for superior
(And) Triethoxycaprylylsilane 1.00% softness and tactility, superb spreadability, excellent adherence, long lasting
● BRO-11S2 - Kobo Products: Iron Oxides (CI 77491) effect, and good coverage. SERICITE GMS-4C gives a glide-on application.
(And) Triethoxycaprylylsilane 0.86% The Silane-Treated Pigments disperse easily, adhere to the skin, and resist
● BBO-11S2 - Kobo Products: Iron Oxides (CI 77499) darkening during wear. MST-203 gives slip and a great creamy feel. ZINC
(And) Triethoxycaprylylsilane 0.46% MYRISTATE (MB) also contributes to great feel and adherence on the skin.
● Propyl Paraben NF - International Sourcing: Propylparaben 0.10%
● Methyl Paraben NF - International Sourcing: Methylparaben 0.10%
Part 2
● Lexol® PG-865 - Inolex Chemical Company:
Propylene Glycol Dicaprylate/Dicaprate 2.50%
● ELEMENT14 PDMS 20 - Momentive: Dimethicone 2.50%
● ELEMENT14 PDMS 350 - Momentive: Dimethicone 2.00%
● SS4267 - Momentive: Dimethicone (And) Trimethylsiloxysilicate 1.00%
Silane Treatment
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