HEXON QUALITY ASSURANCE
LABORATORY
Hexon Quality Assurance Laboratory
Measurement Uncertainty Form
Document No: HEXON/QAL/7.6/F-16
Test Title Acetamiprid 20%
Test Method CIPAC MODIFIED ACETAMIPRID METHOD
Method Reference CIPAC Vol L page # 4-15 (CIPAC modified validated method)
Test Date 18-04-2019,30-04-2019
Equipment HPLC Method
S # Observations repeatability Reproducibility SD (R)
1 Reading 1 20.02 20.05 -
2 Reading 2 20.02 20.02 -
3 Reading 3 19.99 19.99
4 Reading 4 20.00 20.07
5 Reading 5 20.03 20.06 -
4 Average 20.012 20.038 0.018
5 SD (r) 0.016 0.033 -
Uncertainty of Repeatability i.e. SD (r) 0.033 units
Uncertainty of Reproducibility i.e. SD (R) 0.018 units
Average from MAX SD (r) 20.038 units
Average from SD (R) 20.025 units
UNCERTAINTY MEASUREMENT (Budget)
S# Sources Uncertainty Type A/B Divisor Unc Cont
1 Repeatability 0.033 A 1 0.033
3 Calibration Certificate 0.000 B 2 0.0001
4 HPLC Precision
concentration 0.010 B 2 0.005
5 CRM 0.100 B 1.73 0.058
6 1/2 Resolution 0.0001 B 2 0.00005
7 Dilution (weight/Volume) 0.004 A 1.73 0.00231213873
Combined Uncertainty (Uc) 0.067 @ 68 % CL
Confidence Level (K) 2 = 95% CL
Expanded Uncertainty (Ue) 0.134 @ 95% CL
0.200
Result Summary
Expanded Uncertainity 0.200
Upper Result Limit (+) 20.225 units
Average 20.025 units
Lower Result Limit (-) 19.825 units
no need
Acetamiprid 20.025 ± 0.2 this is reported results
Prepared by Lab Assistant Approved by Quality Assurance Manager
Formulas Used in Calculation of Measurement of Uncertainty
S_x = √((∑_( i=1)^( n)▒ 〖
Standard Deviation (x_i-x ̅ ) 〗 ^2 )/(n-1))
_____________________________________
x ̅ = The mean of x_i
n = The number of data points
x_i = Each of the values of the data
CU = √(∑▒ 〖〖 U 〗 _r^2+ 〗
Combined Uncertainty
U_R^2+U_e^2+U_m^2 )
U_r = Uncertainty of Repeatability
____________________________________________
U_R = Uncertainty of
U_e =
Reproducibility
U_m =
Uncertainty of Equipment
Uncertainty of Method
