SCIENCE CLASSES
NAYAK SIR INITIATIVE
G-13, BAPUJI NAGAR, KOLKATA – 700092 | PH : 9433357026
CLASSES : JADAVPUR | GARIA | GARIAHAT | BALLYGUNGE
SECTION A (Maximum Marks: 80) This Section contains Twenty (20) questions for each subject.
Each question has four options. ONLY ONE of these four options is the most appropriate or best
answer, which will be considered the correct answer.
SECTION B (Maximum Marks:20) This Section contains Ten (10) questions. Out of these Ten (10)
questions, only Five (05) Questions need to be attempted.
Correct answer= +4 Unanswered = 0 Incorrect = -1
SECTION A
1. Certain mass, say x g of urea dissolved in 500 g of water and cooled upto 0.5 C, where by 128g of
ice separates out from the solution. If cryoscopic constant for water be 1.86 K kg mol 1, the value of „x‟
will be
(a) 6 g (b) 8 g (c) 12 g (d) 15 g
option=a
2. In the SN 2 reaction of iodide ion with CH3 2 CHCH 2CH 2 X , what is the order of decreasing reactivity
for the following X substituents?
(I) X OH (b) X CH3CO2 (c) X CF3SO3 (d) X CCl3CO2
(a) > II > III > IV (b) IV > III > II > I (c) III > II > IV > I (d) III > IV > II > I
Option=d
3. The Pk a of a weak acid HA is 4.8 and Pkb of a weak base BOH is 4.78. The pH of an aqueous
solution of corresponding salt BA will be
(a) 9.22 (b) 8.73 (c) 7.01 (d) 4.79
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Option-C
4.
The E0 in the given diagram is
(a) 0. 52 V (b)0. 61 V (c) 0.74 V (d) 0.83 V
option-B
5. If excess of AgNO3 solution is added to 100 mL of a 0.024M solution of dichloro bis(ethylene
diamine) cobalt(III)chloride. How many moles of AgCl be precipitated?
(a) 0.012 (b)0.0016 (c) 0.0024 (d)0.0048
2
Option-C
6. Consider the following statements
(A) Monosaccharides are optically active polyhydroxy carbonyl compounds.
(B) Fructose does not reduce Fehling‟s solution because it is a ketose
(C) a D () -glucose and D -glucose are anomers.
(D) D-glucose and D-Mannose are C-2 epimers
Which of the above statements are correct?
(a) A and B (b) A, B and C (c) A, B and D (d) A, C and D
OPTION-D
7. Major end product of the following sequence of reaction is:
CH3CH2CH2CONH2 X Z
2, Br NaOH
HNO2
(a) CH 3CH 2CH 2CONH 2 (b) CH 3CH 2CH 2OH (c) (d)
OPTION-C
8. A choral C5 H10O ether reacts hot HI to give a C5 H10 I 2 product. Treatment of this with hot KOH in
ethanol produces, 1, 3-pentadiene. What is structure of original ether?
(1)
3
OPTION=2
9. Calculate the work done by the system in an irreversible (single step) adiabatic expansion of 2 mole of
a polyatomic gas ( = 4 / 3) from 300 K and pressure 10 atm to 1 atm, against an external pressure of
1 atm
(a) - 227 R (b) -405 cal (c)-405 R ( d) - 3.367 J
OPTION-C
10. For the first order reaction A g 2B( g ) C( g ) the initial pressure PA = 90mm of Hg , the
pressure after 10 minute is found to be 180 mm of Hg. The rate constant of the reaction is:
(1) 1.15x10-3 sec1 (2))
2.3103 sec1 (3) 3.45 103 sec1 (4) 4.6 103 sec1
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OPTION-A
11. Compound „A‟ (molecular formula C3 H8O) is treated with pyridinium chloro chromate in CH2Cl2 to
form a product „B‟ (molecular formula C3H6O). „B‟ forms a chromate in CH2Cl2 to form a product „B‟
(molecular formula C3H6O). „B‟ forms a„C‟. Identify the structure of „C‟.
(a) CH3CH2CH = NNHCONH2 (b)
(C) (d) CH3CH2CH = NCONHNH2
OPTION-A
12. Molecules of benzoic acid (C6 H5COOH ) dime rise in benzene, „w‟ g of the acid dissolved in 30 g of
benzene shows a depression in freezing point equal to 2 K . If the percentage association of the acid to
form dimmer in the solution is 80, then w is : (Given that Kf = 5 K kg mol Molar mass of benzoic
acid = 122gmol-1 )
(a) 2.4g ` (b) l.Og (c) l.5g (d) 1.8 g
5
OPTION-A
13. Bond angle decreases except when
(a) NH 4 is converted to NH3 (b) NH 2 is converted to N3
(c) SO3 is converted to SO2 (d) CO2 is converted to CO32
OPTION-B
14. Four different octahedral complexes of the same metal ion “ M n ” with four different ligands a, b, c, d
are red, blue, green and violet. Then the order of the strength of the ligands is
(a) a b c d (b) a d b c (c) b d c a (d) d a c b
OPTION-B
15.
The final products are
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(a) (b)
(c) (d)
OPTION- D
16. Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : The first ionization enthalpy for oxygen is lower than that of nitrogen.
Reason R : The four electrons in 2p orbitals of oxygen experience more electron-electron repulsion.
In the light of the above statements, choose the correct answer from the options given below.
(a) Both A and R are correct and R is the correct explanation of A.
(b) Both A and R are correct but R is NOT the correct explanation of A.
(c) A is correct but R is not correct.
(d) A is not correct but R is correct.
OPTION-A
17. Among the following compounds, the one which shows highest dipole moment is
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OPTION-A
18. Match List-I with List-II.
List I List II
Choose the correct answer from the options given below:
(a) (A) - (II), (B) - (I), (C) - (IV), (D) - (III) (b) (A) - (IV), (B) - (III), (C) - (I), (D) - (II)
(c) (A) - (III), (B) - (IV), (C) - (I), (D) - (II) (d) (A) - (IV), (B) - (III), (C) - (II), (D) - (I)
OPTION-C
19. The major product obtained in the following reaction is:
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(a) (b)
(c) (d)
OPTION-D
(d) NH2 is a stronger base than OH , hence 1 equation of acetic anhydride will acetylate only NH2
group. Reaction involved:
20. The electrons are more likely to be found:
(a) in the region a and c (b) in the region a and b
(c) only in the region a (d) only in the region c
OPTION-A
(a) Probability of finding an electron will have maximum value at both „a‟ and „c‟. There is zero probability
of finding an electron at „b‟.
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SECTION B
21. The number of N atoms is 681 g of C7 H5 N3O6 is x1021. The value of x is _____________
N A
6.02 1023 mol 1 (Nearest Integer)
5418
22. The maximum number of lone pairs of electrons on the central atom from the following species is
__________________ ClO3 , XeF4 , SF4 , and I 3
23. Total number of possible stereoisomers of dimethyl cyclopentane is __________________.
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24. 10.0 mL of 0.05 M KMn04 solution was consumed in a titration with 10.0 mL of given oxalic acid
dihydrate solution. The strength of given oxalic acid solution is _______ 102 g / L.
(1575) According to law of chemical equivalence equivalent of KMnO4 equivalent of oxalic acid
0.05 5
N1V1 N2V2 M1 mj V1 M 2 nj V2 ( N Mnj ) 0.05 5 10 M 2 2 10 M 2 0.125
2
Strength of oxalic acid = Molarity Molar mass 0.125 126 15.75 1575 102 g / L
25. The sum of numbers of p d bonds present in XeO3 and XeO4 molecules, is ----------------------
7
26. The solubility product of AgCl is 4 1010 . The solubility of AgCl in 0.04 M CaCl 2 is m 10 n in
scienctific notation . What is the value of m n ?.....................................
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27. How many of the following statements regarding potassium permanganate and potassium dichromate
are correct?.......................................
(a) KMnO4 and K 2Cr2O7 Are primary standards.
(b) K 2Cr2O7 Can be obtained pure and it is stable upto its melting point.
(c) KMnO4 Is not stable towards heat and light.
(d) Mostly KMnO4 Contains impurity of MnO2
(e) Both can be used in the presence of hydrochloric acid
(f) K 2Cr2O7 Can be used only in acid medium
(g) K 2Cr2O7 Is astonger oxidizing agent than KMnO4 in acidic medium
28. A first order reaction is 50% completed in 40 mins and at 70 C and in 5 mins at 37 370 C .What is
the value of energy of activation of the reaction( in Kcal/mol)?...................................................
13.68
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29. What is the sum of aldehyde and ketone groups present in the product of the following
reaction?.......................................
30. The number of 4f electrons in the ground state electronic configuration of Gd 2 is___________ .
[Atomic number of Gd 64]
7
(7) Gd (64) [ Xe]4 f 7 5d 1 6s 2 Gd 2 [ Xe]4 f 7 5d 1 6s 0 So, the number of 4f electrons in the ground state
electronic configuration of GD 2 is 7.
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