=c=6 tne R~cH P20 tha} i) RCH, CHolt 0.0 6 | % 2 DDG BHAADN nnn >>> D> ol 7g, “0 0, 20, Go ye 25 a ine? Oo? “9, Presse ky Oo °. Y ake, 869 i Uy erate stg i aps 3 ee, i 3 oO : Zz Zz ty im 3 Ny ° YS 3 0 Oo ia g J l a ee F 1 saa alt |. i +} $5 ial Rl ° oe 74% 48 1 e=y 2 oy 2 [ 3° -S s eva a ' a+ v v ro —CeO OBwUY sao STEREOCHEMISTRY Branch of Chemiehy which explains epauial anangement ator. tee! f q brand chemichy nihich explaine &D geome or anie mote oy Shenoicoraigm ef the molecule will abtect on : sopeies 2) physical b) chemical 9 Birleg col ) Spechoscopicad ALI Clascyialon of teomers Compre with Same Molecular formula (Me ___Sapertpa ols (ed) Bona | Hoaonan | [Some bond Connechivity (ot) | Bhuchaval ison Chain [wtreoicomes (wp —_| Bron Poston — ——— viene Eapaaioal ett [Enppuatinal Tannen Wide” | Tesorestan ax onoer Ring chon, re ical | Acomeion, 1 Mages ame ap (vee) Ly (nig FRY, ood) Basic Ferme Confownationar! dsomers: dgomers which are ees by “the vetaton ae bond are Called Conpomational ‘Sorters - , thee fsomes are “nteronverbible. Therefore These isomers ae Coiled mamic ‘%omas & >» & A Ho , xX ah an RA LE se , can J GaucheAE A CT UREN ITE A eS chet, -chait boat rvict -boect Jr 4 Cctbhexane. Fin Beat i chow be arbilsly Choir > Twist-boat 7 | boat 7 heap chotr 4 Confisurational feomers > Foes which are foimed by the. Beakage tee bonde ome Known ae C *gurationel Sterevisomors: He - de Chiralaty ner An object or Compound which #8 not Supertemposatel« on ike minor fmage ft Catled chtrala tr obect (9 Comp"d iSRich hac right and lat-haad phenomenen fs Called chtralty- “Ex: Rightchand 3 lest hand ycheuy with hand pad rotabinggon. Andiawtcarmen'counr Gy Spring ( Cootl + Coon ROX, Ms ‘ 4 a al D- ladseacid —L-backcaud Achivedaby An ° |e [eorp’d which is Supertmaposable on tte mbyror @mage is Called achivalaty. © An object apd tohich is not “having right ond yt tand Phenomenon 4 G@lled Achiral £4: duster, chauepiewe Pen A lettey Conical est Coon =! cook eT cls ‘ chs Proponvicccid COC EH ee ee eb ODOpbicel ach the phenome tion of plane pola Ghee Sata esac” “UN Fe Pl ph az Obie phyptcal pe ep peperty: 7 opted ache chy ex lated by polartrneter - —r Am object oF ound whith wali. plane Plane Potedeed lt Houaide’ vightSide'/Clockwise direction % catiYl dextio whe —rAnobjeet at Compnd which vttatie plane plane pote 2 ht lowa rd. Side (on axbiclockwise olirection 's Called! Loevo fale Compound (2 -) i‘ =p “Kane relative Confit He uredions- Simple-tube 9 ophen wlalies — Bhs ED Peat G . Nieto nt ae Semple” ort? , | bght Py a1 ey oteat . opbyeally inactive optically ace Wy adie : t J r mo Olean Specific wlation XEROX ie shart oN args » 8 eh REE Secon \ 5 xe 6: Op ical vetfalton Te] 1 Meg Samp obey 2) C: Cont 4 ie sol®. ; ~ qm [ioe ml opel ackve Comp wd is raed in, ein Ie 5 tube Db optical ae +e8° Cleulete Sp “af i Th “Te. ’ > &B CE 004 ’ Q x00 $25 8 SBT L495 0108 & 5amma aE SE EE NLT 4 B goed (rere fe 500 ml pruent 2m don Sam Jefedoe Pts ophcal yolation equatto —f.2° -Gludete ite Specific tlabion velue, ote ore wart , o_ » dx oy -orpl E ol , oe 0 I, - a2 18 Axo pl “srg TOL -1a8 = Nabiiral Comphor has nas Qetdm. Clack g. Ap 254 | BA ogy x Ix0130 OS eo a 540 4.3% By Sto \ \B Se ee “tm optical active Comp’ has Speciic vefation Fac) 3 de Adm and ik, Conc is equal to 4-gmfco val Dey ote 35 5d = e coe 4xKO0Y. EROX Son NOOR gama ak THEA 500 029: doorong 48° oe amosens gaces0set Conditions Ophea ackutky 7 — p> [e.Gohetew ecto Chtval’ Cone — i D (i) Chiral axis: ” Hebkcity . Wy chin glee. DX “5 Chel r OF a4. i tae , 5 A —_ ees wiaben 95,4 ° .cx0% 130 90! ; a, s «7 owt UDuaver & e& tr oe ¢Arn object ov Compound oohich Sabicfies anajene othe above. Condition &s opicall achive () Chtyal Gnhe:- A Cenhe tohich ic bonded with 4 i qe §S Catled chival Cenke . Chiral Gibu elmt Tabidiation “must be Sp?tehahedral a AC atom ishith ib bonded with Jour dal. groupe is Called chiral ¢ 4 chival °C! Coveain’ Nee and a active Ceenssatly) ~ With Chiral end at compre tr op ical fnactive . «Meso lompnd, Racemic ami: 7 Mout chtral C Seme Comprals ane ophical active + Chiral axis, Chiral plone /helicly Confevivang Comp'de ; 2 transGalocelene rONA ete. Shes molecule is chiral dy ophial active °, lalcohel d)& yay mebutiyl alcohol by Gaby) alechol 9A bh! aeshel Pe, ou alle j > ol Avpru y~ Ay Jez wo f is chiral | optical acting ’ a) 2,a-clmathy! butawe by amethy! bulan — ) ziaerenatial Gis Cl ous HC— Oi Or Cb yg = dd Clg we es a — co dc, ) : 2 AT a2 diovety peters —WINAY XEROX buy on ol cu shop No. 5, Moghal Mare Building, ’ ee Orr DERABAD S00 Bio 4 ie st é Cell: 9848980636, 9866509941 4 WOF Comprd ic Optical achve - 2 f p . -Bromo 2-bhlor ponane 3 it dihlm prope aria deeppare 1 Borg to 5° ng Kenge fe aime, el aoa > J 4) 2 chlow, ¢-br0r ) oY ° ia Propane we— <> Hy BIBd! a a AR EEA A ONE 2 Whith enc ts Opkically adive [chiral > 27 tonn dlls ponane PacLrormopentone BS hexane « BY qh we — a fy KRAa, ¢ Cis: ee) 2, iol $22 bibanedie VINAY XEROX Ie aear CH Seopa tan a= Ms * pao du bu Cell: 9848980636, 866509941 ett the opbieal fnadtine aminoacid lousy Belytine 9) Monine. oe 4 “tal, a Oh COOH Goo ons fesen aay dhe ~En Cog, Nth NY % ox Gubshydicle comer is Ophicall tradive a) aldotriose 8) aldotehrnse, Yes Kdbotriose Kelotetnse. Na euow co cu, -on al ou he-p 4 \ co 1 -G-0H ae ae ° Chow ct oH cyyoH Cibo a wop hos Chiral Centre. one? 74) ae a 8) Ae act ae ce d) All. oe 4 ay UN bei ne pe opel x lie fnadive due pyemida 5 | Tnversion 50 TO (a nek oo =o Frverle mers oly -meel _, Optical active « cy, — Goethe tnay Br ? et-mg-£ WA ow Mee ener o S COO OlmMP ese wee= No of chival Contars in cach of the frflovi Y Tas | 4 = 23 7 2 7 +4 el 4 cl ety, 2 4 Ie dl By He Abs - auth cl by ~- 7 “5 ar) i a -3 => oa -° x -3 monty! chlowde. d-Pinene o mento} ad - Camper, -3 ol ° D ) -2 , D=threee - ) Ne Mbp. J = 7 a a Oyert tet , Bw \ ny cio ? D-Ribwse * > 7 Ce, A D~ Glucose = D-Mannose Y ytion 73 Need WO X - wy oF © oH Bg Zyel 24 x Cy -o h aa 28 53 3" > 2 lo->— et O8agg | ya 7 f + ise ae 34 D-Galaclore yo ae > \ = > cto D-~herucre $ “3 28 Cty-e wroH yp b2o fa 3 | Ho. oH wot Ho 3 luton ve 4 ~ ol colt 4 foeleact molecular wt eae Optical adive. Compound Oo Ci, 4 ¢- a ( ast b . 1-0-2 least an wt Covetarine oplead active. olipns 4e — -> t leat Mut Corton alophatic aoe Atydiocosten ie] chiral) Canben must be quateme ~ ye eROX we - fon) wl ANAS en ae BH oly, ee cell: 9348980! a An Ophiced acline oth has rmeleclon frre Cotta Peal the. Compound . Hoe = CHCl ake or ty Opt-adiiva ¢ leche [rar mofeculay C5itjo Ddents ag Compound ome pac Cou 4 W0- + Mt Compl faz Chiral Contre. a CHa, rE PB TT me Ney Dt et, only 4 is opkeatly aku 204 — lene Poi isan Pyromides verion. ed _ Chiral I~ GH me oh Oplical Sag adlive & | Aired BGK opt TTT Ce a as 2 2 2 ) J ,me I Chiral ¢ on 4 Adhivol opt PPX 6 a \ Nhs ea af) ve optical inachsne* et. 2 a ol” i es ed mex P—GI4 -sP itetahedyal = an mn Oph active v 18 “Spc adiue = Chivol Bras 8. Oplacal ackivily ‘tn atlene Compo ou oe terminal hydrogen 4 yer 4 oc att > Optical inactive ry bl ane perpen vondivales W Sau 1 : co Tes ne va He. Oy SO a 4 eee RS ae how Teed ye Sa a Lhaclive Wo reer bp nt ) oo iS a active: aS Sige Py So . _/* “ae vb og , 2 SE Binatone 7 remhy Pnatlive J a d \ 7b aN a = “tC =c= i =e ; 7 v cH S vee a Vann _adbiue y \ a ,7 Neeee vb fa 3 Nene mel — tréiblive b Oo bo! Q > 4 \ i a b 52 “ace ad a Nacacd actin, > bf Cc we of ‘4 > ay ’ a, {7 pereneGe™ eee a ) & opt Ko a 2 tnacive = opt inactive.A 4 CX & a \ececac’” fradive 4 Ycac-cec He 2 / ™d » ce 4 ~ ‘mache 7 b \ 7 gS > Ca =C=Cac \ b 5 ~ = CaC eC sts s bY 6 a cx ae Pantie Bastin Oe \ = z SS C=C aC =C=C =e. : Ao OX aT / \ _ Gnactive L PES a Nn Le erp ee we eer ¥ 2 we SO aC = =O SC aaa és GOn terminal ‘c! two AeHerent Erups ee no Cumulatine dienes are plical active becouse bothrthe teafminal Supe Me preent in papendiculan plane- On terminal c’ Game proups Gerilatrin: even n0 04 ; "Se oe Oprical techno -becaute Danes Syrrma ("8 Present fn these molecules G Utter Some soups (29. ent pyoups Corctainin: odd no QGumulatine dienes ane phcal Pnactive /because bobh the termtaal szoups ane fmeeaeiie Sarne plane. G Plow Sr (oJortente + Symmetry (em Seapeper omnis 4 money Sq) Conlainting Comprds one Optically enacline 2 AWOF Comprd ig Optical adive [Uhnal : 3) Va-fpropecdieme, Bb) V+ butadiene 72:3-Penladiene 0 7 “yes cH ae C 7 Neseed, bs 8 Wee sarah em Gurnulabine § ! i e 4 4 i i UN Y ee OOD 2 4) 2 -mathy| aid Perladione_ even 90 of t-bonde. 5 , y Were cn alcil, ' oso nena, ® = Without “dusCarben WOOF is optical active o 92 13-hexadiene By aibromo4-thlow 218 pertadiene. We tc= =c—ay- db, Wergac=G- Cus oy cl- BF brome» chlow 42 propadien F513 ichlo 12 propacien Wo=c= i (au) Ne venge" bY cl | x cl | cu = cacael 8 5 che tls Ny Cscae He “Hy Optical active Opt. ackine a mn et Nea ac% a= eacac7& Ww Nets Ww Sa opt- odie optcal active Cig 2g 5 x ay COW 4 388 eZ 7 ene Bakes Ag Re Ree Nu 8538 ef 0 cb, W222 5 Practue se 5ge8 opt - ackne t %SESe ¢ cl res = A wend Ze “ er a Nel S48=° 7 2 =c =c7 a 4 fe 3 ~o : 66 & Cees opt inacdine Ne K AY Me, Nee ce eared 2 CHcecec’ = ercHena ay 4 SH ef Opt- dnaclive opt Snaclive1, aman Bcs EEA CER As RCA bak RRB wn re de & ° —— en ae Ne =Cec =c= acl 5 Z ‘er oe ts ef opt thadine opt: achive x a el \ 7 7 MERC RCRE SC =C=C=C=0 = ” ne ° Note FERC HC RC Ok Inactive Opt -fnacliwe cgen Coolt =cel we CC, ‘gee ae =e BC SCHCl = © Keecec/ b), Ww a Opt-actne. 4 a opt acts, Optical activity 0 £ 10 bic clic Comprde woot eee. as fe " soe Some ot alle lat 4 H Opt a Soe ROOK, . oe active 2 CH cut Me Opt. ates opt ee ” ope tncrctine af 2 BOX, oph - active. “xX opt- inactive OOK OOK opt ‘inactive - me cl OX ek ot sinaclive opt - machine VINAY XEROX Shop No. 5, Moghal Mars auitcing, Opp: Deepak Theatre, Narayanaquas, HYDERABAD-500 929 Cell: 9848980535, 9866509041 ° weeuver oe Fe TOS Dee won () ) > I a ) , J ‘ @ ity in Cyclo hexibtcline, Compounds :.- Some ng © Optical achvity An Todo qr Cyclohew ane mq. mo het om | On ee bend me oy Cl, 4, 4 NOX WOE Ont , opt active opt - ocive opt - aLive 1 ¢ =, by —r, “ 7K Cy KX, . | “ ov 4 Ophea active opt. inarclive opt-actine a <— a ch Arh BOS OOS Ls ° ae ro p opt tnacliw Opt ochre opt-acbivé . 4 enyl Compounds - / Optica activity oh “po wt Seallsy~ OPE ¥ 7 dusty ee wtaben. ryt KE t. 5 betames P [botirthe phenyl qoups, betomes oune, lane | ee) ky pee: leule Ophcs| cline [ a a ab = bul an ~ Ron olecent tak lace aus. yetolien vt Ke vp Lo GQ npn atleact one phen! +P as, d _ ‘ ha, Same Vw Gey b-tnactive, me me wale becames oP : ar CS pate a VINAY KERg Se oO Shop No. 5, Moghai Mare Building \\ 2 Opp: Deepak Tt jarayanaguda, HYDERABAD. 100 029. DN Celt: seaagsvess 986650904, he H Opt. imac lve wetalion) = <<, (eomath ape he. Oph. Inaichin become, Same place)Woo os 0a Jo. Sy &) : ° coy : 7 Ra ra 7 opt. wrachue fi . - Opt -imachire P \ op! active. py dz CaN pe er “ “Go eS ‘ nee oplinctine ophuaativ one “ cl-ay ¢cl-# Tan Cuthocbine i, Oph active obe-to chiral plant” ay CI nnen-Superinpotab le ' mind images, = s 4 phil aetine. lens Vi = Heptalen. arena terns ong, — A Gi ‘Opp: Deapak Theatre, Nara) juda, Opbical acbive om tap mats Nowernun cx > Cell: 9848980636, 9866509941 4 Pores clophoe Cay boryhe acid ~Opbicatly ackne- “eo 7 Hy yroe | Geer \ ak Loh, = Hexehelecene * Opt -ackve dlueto helicity ' DNA also Oph active ' dva-to Aelacsly OOCL OLE Oe TOT OOO -G oOo onte-clock wise. Clbck wise.oy dimaric acid ren tehaCoxbeny! 46 olen Opkcal active®@ noon. = Fenocene = One ttng wit TT —> $e (co)¢ a J Cool} FT D / — Ope -actine oy Perchlore diphenyl amine is ophical actime dusto — na awe . a a] oy Prpetion plane (metingame) "4 9 Oph ack os | ¢ 4 Sph—but noe Pysamiclel Anvercion ~ -ENaNTIOMERS dhe bully Get Stereo isomers (o Optical isomers which ome. -non-Supesionposable ) ) d ) ) J 5 wivVor fmagee ane Called = Be (pom one enowtHomer +o another enadtomey te 9 become opposile atalchival Ender. ; aa Right Arand €} let And. Chair with trond pad fore Ey