FullCourseTest D04 Oct 2024 Chem
FullCourseTest D04 Oct 2024 Chem
Column-I Column-II
(U) Raoult’s law for volatile (i) PA = p0A × X A
solute and volatile solvent
(V ) Raoult’s law for gaseous
A B
(
(ii) PA = p0 + p0 + p0A X B )
solute and liquid solvent p0 - p
1 1 n2
(W) Raoult’s law for non-volatile (iii) 0
=
p n1 + n 2
solute and volatile solvent 1
Column-I Column-II
(m) Zn(s) ® Zn+2
(aq) + 2e – (i) Lead storage cell
(n) Zn(Hg) + 2OH–(aq) ® ZnO (s) + H2O + 2e – (ii) Leclanche cell
(o) Pb(s) + SO–2 4(aq) ® PbSO 4 + 2e – (iii) Mercury cell
(p) 2H2(q) + 4OH– (aq) ® 4H2O + 4e – (iv) Fuel cell of H2
(v) Ni-Cd cell
(A) m ® (v), n ® (iii), o ® (i), p ® (ii) (B) m ® (ii), n ® (iii), o ® (i), p ® (iv)
(C) m ® (ii), n ® (iii), o ® (v), p ® (i) (D) m ® (iv), n ® (ii), o ® (iii), p ® (iv)
4. ) Due to which reason, O2 gas librates from the blood of tissues of animal bodies ?
(A) Partial pressure of oxygen gas is less in tissues.
(B) Partial pressure of oxygen is more in tissues.
(C) Partial pressure of carbon dioxide is less in tissues.
(D) Less temperature of tissues.
5. ) 12 gm of urea is dissolved in 2 liter solution at 300 K temperature. How many gram of NaCl should
be dissolved in 10 liter solution so that it becomes iso-osmotic with urea solution ?
[At. wt. of Na = 23, Cl = 35.5 gm/mole]
(A) 29.25 gm (B) 7.31 gm (C) 5.85 gm (D) 19.5 gm
166) KH value for Ar(g), CO2(g), HCHO(g) and CH4(g) are 40.39, 1.67, 1.82 ´ 10–5 and 0.413 respectively.
6.
Arrange these gases in the order of their increasing solubility.
(A) HCHO < CH4 < CO2 < Ar (B) Ar < CO2 < CH4 < HCHO
(C) HCHO < CO2 < CH4 < Ar (D) Ar < CH4 < CO2 < HCHO
7. ) For given solutions, which is the correct order of their elevation in boiling point ?
(i) 0.1 M CH3 COOH(aq)
(ii) 0.1 M CH3 COOH(C6H6)
(iii) 0.1 M CF COOH
) For given solutions, which is the correct order of their elevation in boiling point ?
(i) 0.1 M CH3 COOH(aq)
(ii) 0.1 M CH3 COOH(C6H6)
(iii) 0.1 M CF3 COOH(aq)
(iv) 0.1 M CH3 COONa(aq)
(A) iv > i > iii > ii (B) iv < iii < i < ii (C) iii < iv < i < ii (D) iv > iii > i > ii
8. What is cell potential of cell
d
– Ni|Ni2+ Au3+(1M)|Au Å ?
(1M) ||
[EoNi2+ | Ni = –0.25V, EoAu3+ | Au = 1.5V]
(A) +1.75V (B) +1.25V (C) 3.25V (D) –1.75V
9. Statement (A) : Zinc will free Cu metal from copper sulphate solution.
Reason (R) : At 288 K temperature,
o
Eo = –0.76 Volt and E Cu 2 + |Cu = 0.34 Volt
Zn 2 + |Zn
(A) Both statement and reasons are true. And reason is correct explanation of statement.
(B) Both statement and reasons are true, but reason is not the correct explanation of statement.
(C) But reason is not correct explanation of statement. (Statement is true but reason is false.
(D) Statement is false but reason is true.
10. If lClCH2COONa = 224 Ohm–1 cm2 gm equ–1, lNaCl = 38.2 Ohm–1 cm2 gm equ–1 and lHCl = 203
Ohm–1 cm2 gm equ–1, then what is the value of lClCH2COOH ?
(A) 288.5 Ohm–1 cm2 gm equ–1 (B) 289.5 Ohm–1 cm2 gm equ–1
(C) 388.5 Ohm–1 cm2 gm equ–1 (D) 59.5 Ohm–1 cm2 gm equ–1
11. Reduction of Al2O3 is occurred at low potential and high current through electrolysis. If 4.0 ´ 104
ampere current is pass through molten Al2O3 solution for 6 hours then how much aluminium is
obtained ? (atomic mass of aluminium is 27 gm / mol at 100% efficiency)
(A) 8.1 ´ 104 gm (B) 2.4 ´ 105 gm (C) 1.3 ´ 104 gm (D) 9.0 ´ 103 gm
16. For the reaction, A + B ® Product, rate = k [A]3[B]0. If concentration of A is doubled and the
concentration of B is halved, then the rate of reaction will increase by...
(A) 4 times (B) 8 times (C) 2 times (D) 10 times
17. Which of the following statements is incorrect about Arrhenius equation ?
(A) It gives relation between K and T. (B) T increases as K increases and A decreases.
(C) Ea increases as K increases. (D) If Ea = 0, then K = A.
18. Hydrogenation of ethene is ....... reaction.
(A) zero order (B) first order (C) second order (D) third order
19. A catalyst increases the rate of reaction because it....
(A) increases the activation energy. (B) decreases the energy barrier for reaction.
(C) decreases the collision diameter. (D) increases the temperature coefficient.
20. Activation energy of a chemical reaction can be determined by.....
(A) Changing concentration of reactants.
(B) Evaluating rate constant at standard temperature.
(C) Evaluating rate constants at two different temperatures.
(D) Evaluating velocities of reaction at two different temperatures.
21. For the non - stoichiometre reaction 2A + B ® C + D, the following kinetic data were obtained in
three separate experiments, all at 298 K.
Initial Initial Initial rate of
Concentration Concentration formation of C
(A) (B) (mol L–S–)
0.1 M 0.1 M 1.2 ´ 10–3
0.1 M 0.2 M 1.2 ´ 10–3
0.2 M 0.1 M 2.4 ´ 10–3
37. The compound with molecular formula C4H10O does not reacts with sodium metal but with excess HI
it gives one alkyl halide compound. Which is the compound ?
(A) Methoxy methane (B) Methoxy propane (C) Ethoxy ethane (D) 2–Butanol
38. Which of the Grignard reagent will use to prepare 3-methyl 2-butanol ?
(A) 2 – butanon + Methyl magnesium bromide
(B) Acetone + Ethyl magnesium bromide
(C) Acetaldehyde + Propyl magnesium bromide
(D) Ethyl propionate + Methyl magnesium bromide
39. Both alcohol and ether having same molecular formula ether is more volatile than alcohol, why ?
(A) Presence of intermolecular H-bond in alcohol (B) Ether is polar
(C) Resonating structure of alcohol (D) Presence of intermolecular H-bond in ether.
40. A : The major products formed by heating C6H5CH2OCH3 with Hl are C6H5CH2l and CH3OH.
R : Benzyl cation is more stable than methyl cation.
(A) Statement-I is correct but Statement-II is incorrect.
(B) Statement-I is incorrect but Statement-II is correct.
(C) Both Statement-I and Statement-II are correct.
(D) Both Statement-I and Statement-II are incorrect.
42. Which product will obtain if the mixture of benzaldehyde and formaldehyde with aqueous NaOH ?
(A) Benzyl alcohol and sodium formate (B) Sodium benzoate and methyl alcohol
(C) Sodium benzoate and sodium chromate (D) Benzyl alcohol and methyl alcohol
43. Which of the following statement is not true ?
(A) Aldehyde and ketone give nucleophilic addition reaction.
(B) Aldehyde and ketone give electrophilic substitution reaction.
(C) Aldehydes and ketones posses polar carbonyl group.
(D) Aldehydes and ketone having lower molar mass are soluble in water due to H-bond.
44. Which aldehyde do not give a aldol condensation reaction ?
(1) Propenal (2) Trichloro ethenal
(3) Methanal (4) Ethenal (5) Benzaldehyde
(A) only 3 and 4 (B) only 3 and 5 (C) only 1, 2 and 3 (D) only 2, 3 and 5
45. What is the IUPAC name of compounds ?
(A) 2-methyl-3-bromo hexanal 1 CHO
2 4
(B) 3-bromo-2-methyl butanal 5
3
(C) 2-methyl-3-bromo butanal
Br
(D) 3-bromo-2-methyl pentanal
46. What is the IUPAC name of CH3COCH (CH3)2 ?
(A) 3-methyl-2-butenone (B) Isopropyl methyl ketone
(C) 2-methyl-3-butenone (D) 4-methyl isopropyl ketone
47. Fehling A and Fehling B is a......
(A) Solution of CuSO4 and solution of NH4OH
(B) Solution of CuSO4 and solution of sodium potassium tartract.
(C) Solution of CuSO4 and solution of sodium sytrate.
(D) Solution of CuSO4 and solution of NaOH.
Section B
//X
• Write the answer of the following questions. [Each carries 1 Mark] [1]
1. Which of the following compounds will undergo racemisation when solution of KOH hydrolysis ?
CH2Cl
(i) (ii) CH3CH2CH2Cl
CH3
CH3
C
(iv) H Cl
(iii) H3C – CH – CH2Cl
C 2H5
(A) (i) and (ii) (B) (ii) and (iv) (C) (iii) and (iv) (D) (i) and (iv)
Section C
//X
• Write the answer of the following questions. [Each carries 2 Marks] [16]
2. Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular
masses. Explain this fact.
3. Write the structures of the products of the following reactions.
(i) CH3 – CH = CH2 H2O/H+
O
CH3 – C – OCH3 NaBH4
(ii)
O
(iii) CH3 – CH2 – CH – CHO NaBH4
CH3
–
4. ) Which compound in the following pairs will react faster in SN2 reaction with OH ?
(CH3)3CCl or CH3Cl
5. What is the effect of temperature on the rate constant of a reaction ? How can this effect of
temperature on rate constant be represented quantitatively ?
6.1. Can you store copper sulphate solutions in a zinc pot ?
6.2. Calculate the emf of the cell in which the following reaction takes place :
_
Ni(s) + 2Ag+ (0.002M) ® Ni2+ (0.160M) + 2Ag(s) [ Ed
cell
= 1.05 V]]
7. Calculate the molarity of each of the following solutions :
(a) 30 g of Co(NO3)2 · 6H2O in 4.3 L of solution
(b) 30 mL of 0.5 M H2SO4 diluted to 500 mL.
8.1. Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is
0.75 atm 27°C at.
8.2. Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of
water at 25°C, assuming that it is completely dissociated.
9.1. Explain the difference between instantaneous rate of a reaction and average rate of a reaction.
9.2. Match the items of Column-I and Column-II.
Column - I Column - II
(A) Mathematical expression (1) rate constant
for rate of reaction
(B) Rate of reaction for zero (2) rate law
order reaction is equal to
(C) Units of rate constant for (3) order of
zero order reaction is same slowest step
as that of
(D) Order of a complex reaction (4) rate of a
is determined by reaction
Section D
//X
• Write the answer of the following questions. [Each carries 3 Marks] [18]
10. During nuclear explosion, one of the products is 90Sr with half-life of 28.1 years. If 1 mg of 90Sr was
absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after
10 years and 60 years if it is not lost metabolically.
11. For the reaction R ® P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes.
Calculate the average rate of reaction using units of time both in minutes and seconds.
12.1. Explain why :
(i) the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride ?
(ii) alkyl halides, though polar, are immiscible with water ?
(iii) Grignard reagents should be prepared under anhydrous conditions ?
12.2. Arrange the compounds of each set in order of reactivity towards SN2 displacement :
(i) 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
(ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane
(iii) 1-Bromobutane, 1-Bromo-2, 2-dimethylpropane, 1-Bromo-2-methylbutane, 1-Bromo-3-
methylbutane.
13.1. The air is a mixture of a number of gases. The major components are oxygen and nitrogen with
approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at
a pressure of 10 atm. At 298 K if the Henry’s law constants for oxygen and nitrogen are 3.30 × 107 and
6.51 × 107 respectively, calculate the composition of these gases in water.
13.2. Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure
of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate
the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.
14. The conductivity of 0.001028 mol L–1 acetic acid is 4.95 × 10–5 S cm–1. Calculate its dissociation
constant if Lm
º for acetic acid is 390.5 S cm2 mol–1.
Section E
//X
• Write the answer of the following questions. [Each carries 4 Marks] [16]
16. Calculate the depression in the freezing point of water when 10g of CH3CH2CHCl COOH is added
to 250g of water. Ka = 1.4 ´ 10–3, Kf = 1.86 K kg mol–1.
17. Predict the products of electrolysis in each of the following :
(i) An aqueous solution of AgNO3 with silver electrodes.
(ii) An aqueous solution of AgNO 3 with platinum electrodes.
(iii) A dilute solution of H2SO4 with platinum electrodes.
(iv) An aqueous solution of CuCl2 with platinum electrodes.
18.1. The time required for 10 % completion of a first order reaction at 298 K is equal to that required for its
25 % completion at 308 K. If the value of A is 4 × 1010 s–1. Calculate k at 318 K and Ea.
18.2. 0) The first order rate constant for the decomposition of ethyl iodide by the reaction
C2H5I(g) D C2H4(g) + HI(g)
at 600K is 1.60 - 10–5 s–1. Its energy of activation is 209 kJ/mol. Calculate the rate constant of the
reaction at 700K.
19.1.5) Write chemical reactions to affect the following transformations :
(i) Butan-1-ol to butanoic acid
(ii) Benzyl alcohol to phenylethanoic acid
(iii) 3-Nitrobromobenzene to 3-nitrobenzoic acid
(iv) 4-Methylacetophenone to benzene-1,4-dicarboxylic acid
(v) Cyclohexne to hexane-1,6-dioic acid
(vi) Butanal to butanoic acid
19.2.4) An organic compound (A) with molecular formula C8H8O forms an orange-red precipitate with 2,4-
DNP reagent and gives yellow precipitate on heating with iodine in the presence of sodium
hydroxide. It neither reduces Tollens’ or Fehlings’ reagent, nor does it decolourise bromine water
or Baeyer’s reagent. On drastic oxidation with chromic acid, it gives a carboxylic acid (B) having
molecular formula C7H6O2. Identify the compounds (A) and (B) and explain the reactions involved.
Pi Square Academy
Chapters- 1,2,3,6,7,8 Std 12 : Chemistry Date : 06/10/24
Total Marks: 100 Full Course Test Time :3 Hours
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Section B
//X
• Write the answer of the following questions. [Each carries 1 Mark] [1]
1.
Section C
//X
• Write the answer of the following questions. [Each carries 2 Marks] [16]
2.
4.
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6.2.
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8.2.
9.2.
Section D
//X
• Write the answer of the following questions. [Each carries 3 Marks] [18]
10.
12.2.
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Section E
//X
• Write the answer of the following questions. [Each carries 4 Marks] [16]
16.
19.1.