12th JEE Main

AJLM3/02 Test- 02

DURATION : 180 Minutes DATE : 17/11/2024 M.MARKS : 300

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (1) 26. (3) 51. (2)
2. (1) 27. (4) 52. (1)
3. (3) 28. (3) 53. (4)
4. (2) 29. (3) 54. (4)
5. (2) 30. (4) 55. (4)
6. (2) 31. (2) 56. (3)
7. (1) 32. (3) 57. (4)
8. (4) 33. (3) 58. (1)
9. (4) 34. (1) 59. (2)
10. (1) 35. (4) 60. (1)
11. (2) 36. (2) 61. (1)
12. (2) 37. (1) 62. (3)
13. (1) 38. (3) 63. (4)
14. (2) 39. (1) 64. (3)
15. (4) 40. (2) 65. (4)
16. (3) 41. (4) 66. (2)
17. (2) 42. (4) 67. (1)
18. (1) 43. (2) 68. (4)
19. (1) 44. (1) 69. (1)
20. (3) 45. (4) 70. (3)
21. (50) 46. (7) 71. (0)
22. (10) 47. (8) 72. (1)
23. (50) 48. (5) 73. (30)
24. (9) 49. (5) 74. (2)
25. (11) 50. (6) 75. (3)

[1]
 SECTION-I (PHYSICS)
1. (1) Eq. (ii) – eq. (i) gives
Given, XC = 400π, f = 100Hz hc hc
− = E − E'
At resonance, current is maximum and impendence  
will be minimum 3
 X L = XC hc
 −2 = E − E '
 L = 400 
400 2hc
 L= =2H  E'= E +
2  100 
E  + 2hc
imax =
V E'=
Z min 
[29 July, 2022 (Shift-I)]
Z min = R = 8k
500 6. (2)
imax = D
8  103 First minima =
imax = 62.5 mA a
3D
[26 Aug, 2021 (Shift-I)] First maxima =
2a
2. (1) 3D ( 540 ) D
 =   = 360 nm
1 2a a
XC = C
= 104 
7. (1)
Erms 200 2
 I rms = = = 20 mA By working for locus of a point spaced equally from
2XC 2  104 the two point sources we can see that the central
fringe will be Circular on P1 and straight lines on P2
3. (3)
8. (4)
dy
x = d sin  = 5
D A2 P − A1P = (Condition of 3rd minima)
2
10−3  5.24  10−3 5
=  D2 + a2 − D =
2 2
= 2.62μm 1/2
 a2  5
[2 Sep, 2020 (Shift-I)]  D 1 + 2  −D=
 D  2
 
4. (2)
1 a 2 5
U<x<1  =
2 D2 2
For
 a = 5D
K.E.= E0
h 5 = 5  600  10−9  0.03
= = = 0.3 mm
p 2mk .E
h [29 Jan, 2023 (Shift-I)]
1 =
2mE0
x 1 9. (4)
K .E. = 2 E0 Resonance
h 1 1
2 = = =
2m ( 2 E0 ) LC 3  10−3  4  10−3
1
= 2 103
2 = rad / s
12

5. (2) 10. (1)

hc
−= E ….(i) Resolving power, RP 
1
 
hc Limit of resolution  λ
− = E' ….(ii)

3
[2]
 1 15. (4)
and   Power = Energy of photon × Number of photons
mv
emitted per sec
1
 LR  hc
mv  P = n

( LR ) me m 1 According to question,
 = = e =
( LR )e m 4m p 4  1830 Px = 3P
1 hc n
( LR ) = ( LR )e  n1 = 3  2
7320 1 2
[18 March, 2021 (Shift-II)] n1 
 = 3 1
n2 2
11. (2) 2 1
D = 3 =
since, x = (  − 1) t 600 100
d [3 Sep, 2020 (Shift-II)]
xd 5  10−3  2  10−3
  −1 = = = 0.2
Dt 1  50  10−6 16. (3)
 = 1 + 0.2 = 1.2
As power factor cos 
Where,  is phase difference between v
12. (2) And i
 5 2  
cos  −  = cos = 0.866
 6 3  6
As current lags voltage
Therefore, 0.866 lags.
dD dD 
( 2 − 1) − (  − 1) = 17. (2)
x 2x 2
For maximum kinetic energy, we need to take
dD D
( 4 − 2 −  + 1) = higher frequency.
2x 2x
6  1015
( 3 − 1) d =  i.e. f = Hz
2
 Kmax = hf – ϕ
d=
3 − 1 4 6  1015
=  10−15  −2
[12 April, 2019 (Shift-I)] 3 2
=4–2
13. (1) = 2eV
3 [29 June, 2022 (Shift-II)]
 3x 2 + x 2 − x =
2
18. (1)
3
 2x − x = e =
h
…..(i)
2 pe
 x = 1.5 λ
h
[10 Jan, 2019 (Shift-II)] and  ph = ….(ii)
p ph
14. (2) According to the question,
Path difference at central maxima x = (μ – 1)t, e 3
=
whole pattern will shift by same amount which will  ph 2
D D
be given by (  − 1) t = n 1
pe v
d d Ee
 =2 ….(iii)
 (μ – 1) t = nλ E ph p ph c
n 1  ph v
 = +1 =
t 2 e c
5  600  10−9
= +1 =
1 2v

10−5 2 3c
= 1.3 v
[9 April, 2019 (Shift-I)] =
3c
[26 June, 2022 (Shift-I)]
[3]
19. (1) vp
vs =
Given v = 2v0iˆ and E = E0 ˆj 2
v 2p vp
 = 0.8  i p = = 12.5 A
40v p i p 32

 eE t  22. (10)
v = 2v0iˆ +  0  ˆj ω = 2πf = 100π rad/s
 m 
XL = ωL = 100 π × 10π × 10–3
2eE0 ˆ
v at t =2sec = 2v0iˆ + j = 10 
m
1 1 1 0.2  106
2 XC = =  = = 20 
 eE  C 100 500  10−6 1  104
v = v = 2 v02 +  0 
 m  
Z = R2 + ( X L − X C )
h 2
de Broglie wavelength is given by  =
mv
(10 3 )
2
+ ( 20 − 10 )
2
h Z=
initial =
2mv0
= 300 + 100
h
 final = = 400
2
 eE  = 20 
2m v02 + 0 
 m  200
I= = 10A
2  −1/2
h   eE0 
20
= 1+    [25 June, 2022 (Shift-II)]
2mv0   v0 m  
 
23. (50)
h  1  eE0  
2
= 1−  2  
 =  =
2mv0  2  v0 m    4 2
 

Magnitude of fractional change in de Broglie I = I 0 cos 2
wavelength is 2
2 
 1  eE0  = 100  cos 2
=   4
 2  mv0  = 50 Lumens
[27 July, 2022 (Shift-I)] [6 Sep, 2020 (Shift-II)]

20. (3) 24. (9)

From Einstein-Photoelectric effect, Using Malu's law,
1 I' = I cos2ϕ
mV 2max = hf − 0
2 I
I ' = 0  cos 2 53
Photoelectric effect can be explained by particle 2
nature of light. Threshold wavelengths is 2
I  3
maximum wavelength at which emission takes = 0  
place. 2 5
[27 July, 2022 (Shift-II)] 9I
= 0
50
21. (50) x=9
Ps vs is [24 Feb, 2021 (Shift-I)]
= = 0.8
Pp v p i p
25. (11)
1240
hv = eV
400
= 3.1 ev
K .E.max = (3.1 − 2) eV
vs  vs / 10 = 1.1eV
 = 0.8
vp  ip

[4]
 SECTION-II (CHEMISTRY)
26. (3) COOH
The correct sequence for the given columns is H3O
+

given as, (I) - (R), (II) - (P), (III) - (S), (IV) - (Q). CH 3
[27 July, 2022 (Shift-II)]

27. (4) 34. (1)

The ratio of  for tetrahedral and octahedral PhCOOH ⎯⎯⎯
3 NH
→ PhCOONH 4 ⎯⎯⎯
→
Heat

4 A
complex is given as  t =  0 . So  t for PO H
9 PhCONH 2 ⎯⎯⎯
2 5
→ PhCN ⎯⎯⎯ 2 → PhCH NH
2 2
  Ni/ 
 B C  D
CoCl4 2− =
4 18000
 cm −1 = 10000 cm −1
9 0.8 Br
PhCONH 2 ⎯⎯⎯
2 → PhNH
2
KOH
|CFSE| = 1.2 t

28. (3) 35. (4)

Cis–[CoCl2(en)2]+ is optically active.

29. (3)
F is the most electronegative element in periodic
table and hence shows only negative oxidation state
i.e. 1. 36. (2)
F can not expand its octet due to unavailability of
vacant d-orbital.
[27 June, 2022 (Shift-II)]

30. (4)
Amylose contains α–glycosidic linkage only.
[24 June, 2022 (Shift 1)]
[15 April, 2023 (Shift-I)]
31. (2)

37. (1)
[Fe(CN)6]4– = Octahedral, d2sp3, low spin
complex. Diamagnetic.
[28 June, 2022 (Shift-I)]

38. (3)

[11 April, 2023 (Shift-I)]

32. (3)
DiBAL-H reduces cyanide, esters, lactones,
amide & carboxylic acid into corresponding
aldehyde (partial reduction).
Therefore, ester group is reduced into aldehyde.
[26 July, 2022 (Shift-II)]
[11 April, 2023 (Shift-I)]
33. (3)
Conc. H2SO4 39. (1)
CH3
OH
is most acidic
Br CN
NBS KCN
CH 3 CH3

[5]
40. (2) 46. (7)
Due to involvement of .p. of nitrogen in XeF6 + 3H2O → XeO3 + 6HF
resonance in pyrrole (B), it will show least basic
character
: Nitrogen .p. participate in resonance and

increase the stability of the compound due [18 March, 2021 (Shift-II)]
to aromicity.
B<D<C<A 47. (8)
[9 Jan, 2020 (Shift-II)] Self and cross-aldol condensation reaction.
41. (4)
O
For iodoform reaction CH3 − CH − or CH3 – C –
|
OH
group should be present. Each product shows Geometrical Isomerism.
[29 June, 2022 (Shift-II)]
42. (4)
Melting point order Si > Ge > Sn < Pb. 48. (5)
Heat
43. (2) 2MnO2 + 4KOH + O2 ⎯⎯⎯
→ 2K 2 MnO4 + 2H 2 O
The order of the E-H bond’s bond dissociation (A)
energy in group 15 hydrides is:
NH3 > PH3 > AsH3 > SbH3 2K 2 MnO4 + 4HCl → 2KMnO4 + MnO2 + H 2 O + KCl
[30 Jan, 2023 (Shift-II)]
(A) ( B)
44. (1)

MnO−4 + 8H + + 5Fe 2+ + 5e− → Mn 2+ + 5Fe3+ + 4H 2 O

[29 June, 2022 (Shift-1)]

49. (5)
O.S. of sulphur in H2S2O8, H2SO5, H2SO4,
H2S2O7 and SO2Cl2 is equal to +6.

[1 Feb, 2023 (Shift-II)]

50. (6)
45. (4) 3×2×1=6
[24 Jan, 2023 (Shift-I)]

SECTION-III (MATHEMATICS)
51. (2) dV
V + x = V + V 2 + 16
Given equation of rearrangement gives dx
y 2 + 16 x 2 dV
dy y
= + x = V 2 + 16
dx x x dx
Put y =V· x in the above eqn and Apply variable separable method, we get
dV dx
dy
=V + x
dV
, we get  =  + ln C
dx dx V 2 + 16 x

[6]
  n V + V 2 + 16 = nCx  c = b + a
( ) (
 c = piˆ + 13 ˆj + 4kˆ +  4iˆ + 3 ˆj + 10kˆ )
y y 2 + 16 x 2
 + = Cx = ( p + 4 ) iˆ + (13 + 3 ) ˆj + ( 4 + 10 ) kˆ
x x
Given y (1) = 0  C = 4 ….(1)
Now at x = 2 Given a  c = 75
y y 2 + 16  4  4 p + 125 = −4 …. (2)
 + = 42
2 2 (
c  iˆ + 2 ˆj − 3kˆ = 4 )
 y + y + 64 = 16 2
 p − 20 = −10 ….. (3)
 y 2 + 64 = (16 − y ) 2 Solving 2 & 3
36 266
= y 2 + 64 = y 2 − 32 y + 162 = ,p=−
205 41
 y=6
[8 April, 2023 (shift-I)]
[29 June, 2022 (shift-I)]
56. (3)
52. (1) 2
9x + 4
x
1
5
+ 3x 2 + x
dx

9 x −4 + 4 x −5
2
= 
1
1 + 3 x −3
+ x −4
dx

(
Put 1 + 3x −3 + x −4 = t  −9 x −4 − 4 x −5 dx = dt )
1 1
 =−  t dt = ln  t 
Area =  x dy 2
−   1   80 
 = ln  −3 −4  
= ln   .
2   1 + 3x + x  1  23 
=  1 + y 2 dy
−
= 2 57. (4)
Rearranging the given equation we get
53. (4)
Let r = xiˆ + yiˆ + zkˆ 
dy
=−
2x 2 y − 1 ( )
( )
r  iˆ + 2 ˆj − kˆ = iˆ + kˆ
dx 2 y 2x − 1 ( )
2y 2x
−( y + 2 z )iˆ + ( x + z ) ˆj + ( 2 x − y ) kˆ = iˆ + kˆ  dy = −  2 x − 1dx
2y −1
Compare
r = xiˆ + ( 2 x − 1) ˆj − xkˆ for x  R

loge 2 y − 1( ) = − loge ( 2x − 1) + loge c
log e 2 log e 2 log e 2
54. (4)
d  dy  dy
(
 2 y − 1 2x − 1 = c )( )
 x  = ln x  x = x ln x − x + c  c = 0 y (1) = 1
dx  dx  dx
dy c = 1
= −1 )
( )( )
(A (1, 1) and
dx  2 y − 1 2x − 1 = 1
dy
x = x ln x − x  dy = ( ln x − 1) dx For x = 2
dx
 y = x ln x − x − x + c1  c1 = 3 ( 2 y − 1) 3 = 1
1 4
55. (4)  2y −1 =  2y =
3 3
Given a  c = a  b Taking log to base 2.
a  (c − b ) = 0  y = 2 − log 2 3
a = c − b [27 June, 2022 (Shift-I)]
[7]
58. (1) 
 tan −1 2 = 1 +
Here, a3log a 2 x = 8 x3 similarly for other terms. 4
[11 April, 2023 (Shift-I)]
8 x3 + 20 x 2 2x + 5
f ( x) =  dx = 4 dx
x 4 + 5 x3 − 7 x 2 x2 + 5x − 7 62. (3)

= 4ln x 2 + 5 x − 7 + c
f (1) = 4ln 1 + c  c = 0
f (0) = 4 ln 7
[25 Feb, 2021 (Shift-II)]

59. (2)
37
I = x + 3 – 4 x – 1 + x + 8 – 6 x – 1.dx
5
(
2ABC = BC  BA = c − b  a − b ) ( )
( ) ( )
37 2 2
= x –1 – 2 + x – 1 – 3 .dx
= (a  b + b  c + c  a )
5
37 10 37
= ( x − 1 − 2 dx + )  (3 − )
x − 1 dx + ( )
x − 1 − 3 dx  2a + 3c   2b + c    4a + 3b   2b + c  
2XYZ =  −     − 
 5   3    7   3  
5 5 10

= 122.

60. (1) ( 2a + 3c )  ( 4a + 3b ) ( 2a + 3c )  ( 2b + c )
= −
Given a = iˆ + ˆj − kˆ & b = 2iˆ + ˆj − kˆ 35 15
iˆ ˆj kˆ
−
( ) (
2b + c  4a + 3b ) +0
a b =  1 −1 21
2 1 −  6a  b + 12c  a + 9c  b 
= 3
(
= (1 − )iˆ +  2 − 2 ˆj + ( − 2)kˆ )  7 53
 4a  b + 2a  c + 6c  b 


Projection of b  a on iˆ + ˆj + kˆ − 7
 7 53 
(b  a )  (iˆ + ˆj + kˆ)
 = 3  8b  a + 4c  a + 3c  b 
3 − 5
 7  5 3 
 a b 
 projection of a on b =


|b | 
=
(
30 a  b + b  c + c  a )
− 2 + 3 105

3
= 3=0
=
(
2 a b + b c + c a )
[26 July, 2022 (Shift-I)] 7
ABC 7
61. (1)  =
XYZ 2
Given data [24 Jan, 2023 (Shift-I)]
( )
1 + x 2 y 2 dx = ydx + xdy, y (1) = 1
63. (4)
y (2) = 
x = elnx
dx =
d ( xy )
1 + ( xy ) 2
  dx = 
d ( xy )
1 + ( xy )2
(
e )
( ln x −1)3 x + e(1−ln x )3 x ln xdx

x = tan −1 ( xy ) + c = e ( (
3 x ln x − x )
+e (
3 x − x ln x )
)
ln x dx
x = 1 then y = 1
 (
=  e3t + e−3t dt ) x ln x − x = t
ln x dx = dt
 c =1−
4 3t −3t
e e
 = + +
 x = tan −1
( xy ) + 1 − 3 −3
4
= e(
1 3 x ln x − x ) 1 3( x − x ln x )
x = 2, y =  − e +
3 3

2 = tan −1 2 + 1 −
4
[8]
 1 x 
3x
1 e 
3x  5
=   − + =
   6
3 e  3 x 
[10 April, 2023 (Shift-II)]  5
=
 3
64. (3) [25 Jan, 2023 (Shift-II)]
The given equation can be rewritten as
66. (2)
dy x2 − 1 x 2 ln x
+ y= …… (1)
( ) ( )
2
x  y
dx x x 2 + 1 x2 + 1 A( x) =  y ( x)dx =  
0 x
Which is linear. Also Differentiate both sides
x2 − 1 x 2 ln x x 2  2 yy '− y 2  2 x
P= and Q =
(
x x +1 2
) (x 2
+1) y=
x4
 2x 1 dy y x 2
 P dx =   2 −  dx  − =
 x +1 x  dx x 2
[Resolving into partial fractions] 1
I .F =
(
= ln x 2 + 1 − ln x ) x
1 x
 y  =  dx + 
 I.F. = e ( )
ln  x 2 +1 / x 
x2 + 1 
=
x 2
x y 1 x2
Hence the required solution of equation (1) is  =  +
x 2 2
(
y x2 + 1 ) =  ( x + 1)2
x 2 ln x
dx + c x3
y= + x
x x ( x + 1)
2
4
x = 2, y = 4
=  x ln x dx + c
  =1
1 1 x2
= x 2 ln x −  dx + c 1 3
2 x 2 y= x + x.
4
 x2 + 1  1 2 1
 y = x ln x − x 2 + c  5
 x  2 4 This passes through  , 
   4

65. (4)  3 + 4 − 5 = 0

L:
x +1 y z +1
−2
= =
3 −1
=  (let) (
 (  − 1)  2 +  + 5 = 0 )
α=1
[26 July, 2022 (Shift-I)]

67. (1)
  
1 1 1
Let foot of perpendicular is I= dx +  ex − 2 dx +  e x − 3 dx
0 1+ e
x
P ( −2 − 1,3, − − 1) 0 0
  
PA = (−2 )iˆ + (3 ) ˆj + ( −4 −  ) kˆ e− x e− x e− x
I= −x
dx +  1 − 2e− x dx +  1 − 3e− x dx
Now,  PA  b = 0 0 1+ e 0 0
−2
= 
= −
( −e− x ) dx + 
(
1 ( −2 ) − e
−x
) 
(
1 ( −3 ) − e
−x
)
2 0 1 − 2e − x 3 0 1 − 3e − x
7
−x
dx + dx
1+ e
 −3 −6 −5  0
P , , 
( )
 1  1 
 7 7 7 
=  − ln 1 + e− x  + ln 1 − 2e− x  + ln 1 − 3e− x 
  0 2  0 3  0
=2

 +  +  = −2 1 1
( 0 + ln 2 ) + ( 0 − 0 ) + ( 0 − ln 2 )
2 3

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 2 1 1
= ln 2  − =cc=0
3 8 8
[13 April, 2023(Shift-I)]  y 3 = −2 x

68. (4)
71. (0)
Shortest distance between the lines
 /4 − x
x2 − x1 y2 − y1 z2 − z1 0 e tan 25 xdx
a1 b1 c1  /4  /4 − x
 −e− x (tan x)25  + e (25)(tan x) 24 sec 2 x dx
a2 b2 c2 16  0 0
= =
iˆ ˆj kˆ  /4 − x  /4 − x
= −e− /4 + 0 + 25   e (tan x) 24 dx 
52
e (tan x) 26 dx + 
 0 0 
a1 b1 c1
a2 b2 c2
 0
 /4
= −e−/4 + 25   e− x (tan x)26 + (tan x)24 dx 

( )
[24 Jan, 2023 (Shift-I)]
 /4

69. (1)
 25 e
−x
( tan 24 x + tan 26 x ) dx
0
Equation of tangent : y − 1 = 3(x −1)
/4
i.e. y = 3x − 2 …(1) −x
− e tan 25 x dx = e−/4
y = x3 …(2)
0
Solving (1) & (2)
[13 April, 2023 (Shift-II)]
( x − 1)2 ( x + 2 ) = 0
1

 ( x − ( 3x − 2) ) dx
3 72. (1)
Area =
−2 y 2 dx + xy dy + x 2 y 2 dy = 0 ( )
1
x 3x 4  272
y dx + xdy dy
= − + 2x = + =0
 4 2  −2 4 x y2 2 y

 1 
 d  −  + d ( ln y ) = 0
 xy 
1
− + ln y + c = 0
xy
Curve passes through (1, 1)  c = 1
[12 April, 2023 (Shift-I)] 1
 1 + ln x =  1 solution
x2
70. (3) [25 June, 2022 (Shift-I)]
( xy 3
−x 2
) dy − ( xy + y ) dx = 0
4

73. (30)
 y 3 ( x dy − y dx ) − x ( x dy + y dx ) = 0  
I1 + I2 =  f ( x).sin x dx +  f ''( x)sin x dx
( x dy − y dx )
0 0
x y 2 3
− x ( x dy + y dx ) = 0 

x2 = f ( x). − cos x 0 +  cos x. f '( x)dx
 y 0
 x 2 y 3 d   − xd ( xy ) = 0 
x 
+ sin x f  ( x) 0 −  cos x. f ( x)dx
 Dividing by x3 y 2 , we get 0
 f ( ) + f (0) = 5( given)
y  y  d ( xy )
 d − 2 2 =0  f (0) = 5 − f () = 5 − 2 = 3
x x x y
2 74. (2)
1 y 1
Now integrating   + =c x
2 x  xy
 tf ( t ) dt = x f ( x ) , xf ( x ) = 2xf ( x ) + x f ' ( x )
2 2

It passes through the point ( 4, −2 ) 0

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 dy 2 dy dy 75. (3)
Let y = f ( x ) , xy = 2 xy + x 2 ,x = − xy, Any point on the line is
dx dx dx
y P = (6r1 + 2, 3r1 + 3, –4r1 –4).
=− Direction ratios of the line segment PQ are
x
6r1 + 3, 3r1 + 1, – 4r – 10  (where Q (–1, 2, 6)),
dy dx
 y
= −  ,log y = − log x + log c
x
If ‘P’ be the foot of altitude drawn from Q to the
given line, then
6 6(6r1 + 3) + 3(3r1 + 1) + 4(4r1 + 10) = 0.
log xy = log c, xy = c, c = 6, xy = 6, f ( x ) =
x  r1 = –1.
6 3 Thus, P = (–4, 0, 0)
f(6) =1, f(8) = = = 0.75, f(10) =
8 4  Required distance PQ = 9 + 4 + 36 = b
6 3 b = 7 units.,  = –4
= = = 0.6
10 5 +b=3
f(6) + f(8) +f(10)= 1 + 0.75 + 0.60 = 2.35

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