NAME REACTIONS

(BY M.R.CHOUDHARY,KVONGC MEHSANA)

Finkelstein CH3Br + NaI CH3-I + NaBr
1.
Swarts CH3Br + AgF CH3F + AgBr
2.
CH3

Friedel-Crafts Anhydrous AlCl3

Alkylation + H3C Cl
3.
COCH 3

Friedel-Crafts CH3COCl
Acylation
Anhydrous AlCl3
4.
2Na
Wurtz +
5.
H3C Cl Cl CH3 H3C CH3 + Na Cl
Cl Cl

Fittig 2Na
+ + Na Cl
6. Dry ether
Cl

Wurtz-Fittig 2Na
+ Cl CH3 CH3 + Na Cl
Dry ether
7.
OH OH
ON a
Na OH i) CO2 COOH
Kolbe
ii) H+
8.

Reimer-
Tiemann
9.
10. Williamson CH3-Br + CH3-ONa CH3-O- CH3 + NaBr
H3O+
Stephen H3C CN + SnCl2 + HCl H3C CH NH H3C CHO
11.
CH3 CHO

CrO2Cl2
Etard
H3O+
12.
CHO

Gatterman – CO / HCl
Koch
Anhydrous AlCl3
13.
 O H2 O
Rosenmund
C C
reduction H3C Cl Pd / BaSO4 H3C H
14.
O
Clemmensen Zn - Hg
C H3C CH2 CH3
reduction Conc. HCl
15. H3C CH3
O
Wolff-Kishner i) NH2-NH2
reduction C H3C CH2 CH3
16. H3C CH3 ii) KOH / Ethylene glycol /

17. Tollens’ test R-CHO + 2 [Ag(NH3)2]+ + 3 OH- R-COO- + 2Ag + 2H2O + 4 NH3
18. Fehling’s test R-CHO + 2 Cu 2+
+ 5 OH -
R-COO + Cu2O-
+ 3H2O
O
I2 / NaOH
Iodoform C CHI3 + CH3COONa
19. H3C CH3 OR, NaOI
OH
Aldol dil NaOH
2 H3C H3C CH CH2 CHO H3C CH CH CHO
20. condensation
CHO

Conc. NaOH
21.
Cannizzaro HCHO
+ HCHO HCOON a + H3C OH

i) Cl2 / Red Phosphorus

Hell-Volhard- H3C COOH H2C COOH
Zelinsky (HVZ) ii) H2O
22. Cl
O
Hoffmann Br2
bromamide H3C C NH2 H3C NH2
23. degradation NaOH

Carbylamine
24. R-NH2 + CHCl3 + 3 KOH R-NC + 3 KCl + 3 H2O
NH2 + -
N2 Cl

NaNO2 + dil HCl

Diazo
273 - 278 K
25.
+ -
N2 Cl Cl

Sandmeyer. CuCl / HCl

+ N2
26.
+ -
N2 Cl Cl

Gatterman Cu / HCl
+ N2
27.

+ - OH-
Coupling N2 Cl + H OH N N OH
28.