wpe iMiCQs Corner ssessment i As mate complementary part of the learning process. t gives you a total insight whether the learning outcomes have nanan Seed ret Aer going teu creping CERT Took chapter hese qs ern He environment. Give yourself four marks for correct answer and deduct one mak for wrong answer. table is given at the end, that will help you plan your next step, Discovery of Sub-atomic Pa les ‘Theratioof chargeto mass ofan lectronin coulombs per gram was determined by J.J. Thomson. He determined this ratio by measuring the deflection of cathode rays in electric and magnetic fields. ‘What value did he find for this ratio? (a) -1.76 x 10° coulombs/g (b) 1.76 x 10°* coulombsig (0) -1.76 x 10"° coulombs/g (d) -1.76 x 10° coulombs/g The number of electrons which will together weigh one gram is {a) 1.098 x 10” electrons (b) 9.1096 x 10" electrons (©) Telectron (a) 1x 10! electrons. How many number of electrons are present in a particle which carries a charge of 5.5 x 10°" C2 {a) 3432. (b) 1560 (©) 8240 (d) 2432 Which experiment is responsible for finding out the charge on an electron? (a). Millikan’s oil drop experiment (b) Cathode ray discharge tube experiment (©) Rutherford’s ct-rays scattering experiment (d) Photoelectric experiment Match the values of column II with columa I and mark the appropriate ch Column I (A), Mass of electron (B)_ Mass of protor (i)_-1.602 x 10" C (©) Charge of electron (ii) 9.110" kg (D) elm for an electron (iv) 1.76 x 10° Cig fa) (A) 9 @, B) > Gi, (©) Gv), (D) > Gi) (b) (A) > Gi), (8) > @, (C) > Gi, (D) > iv) (©) (A)> Gi, (B) > Gi), (C) > Civ), D) > @) (@) (A) @), (B) > (iid), (C) > GH, (D) > Gv) Column tt (1.673 x10 kg | All the Best! © [PQ] Atomic Models 6 Which of the following statements about Thomson model of atom is correct? (a) Anatom possesses an elliptical shape in which the positive charge is uniformly distributed. Mass of the atom is assumed to be uniformly distributed over the atom. (c) This model was unable to explain the overall neutrality of the atom. (d) All of these Which of the following conclusions regarding the structure of atom is based on Rutherford’s ac-particle scattering experiment? (a) The positive charge is concentrated in a very small volume of the atom. ‘The positive charge is scattered with the electrons throughout the atom. ‘The volume occupied by the nucleus is half of the volume of atom. Most of the space in the atom is occupied by the neutrons. Which of the following observations was not correct during Rutherford’s scattering experiment? (a) Most of the a-particles passed through the gold foil undeflected. (b) Asmall fraction of the a-particles was deflected by small angles. (©) A large number of the a-particles were bounced back. (a) A very few a-particles (~1 in 20,000) were bounced back. How many neutrons are there in $3Sr? {a) 38 (b) 50 (c) 126 (d) 88 b) (b) © (d) |. An element with mass number 81 contains 31.7% ‘more neutrons as compared to protons. Find the symbol of the atom. (a) Se (© Uke Ser Rb (b) (d@) © scanned with Oken ScannerWhich of the following species is isoelectronic with, co? (a) HE (© NS 12. In which one of the following pairs the two species are both isoelectronic and isotopic? (Atomic numbers : Ca = 20, Ar = 18, K = 19, Mg = 12, Fe = 26, Na = 11) (a) ca and Ar (©) Mg? and Mg Developments Leading to the Bohr’s Model of Atom 13. Consider the figure of electromagnetic wave, z leet field component u. (d) 03 tb) YK and *K* (4) Na and Na" «Direction of propagation Magnetic field a component and choose the correct information related to it, (a) These components have same wavelength and speed. (b) They vibrate in two mutually perpendicular planes. (©) Electromagnetic waves do not require medium and can move in vacuum. (2) All of these. 14. What will be the wavenumber of yellow radiation hhaving wavelength 240 nm? (@) 1724x108 cmt (b) 4.16 x 106m (© 4x10! He (@) 219.3 x 10? em” 15. The wavelength of visible light is (a) 200mm - 370 nm (b) 780.nm - 890 nm (6) 380m -760 nm (4) 900 nm - 2000 nm 16. Observe the given figure carefully. h Intensity —p. a Too 70003000 Wavelength 2 (ama) —> Select the incorrect statement from the following. (a) As the temperature increases, maxima of the curve shift to short wavelength. 18. 19. 20, 21 22. 23. 24, mount of light emitted (i.e. intensity of (b) ton) from a black body and its spect distribution depends only on its temperature For the given figure, Ty > T>. ‘Ata given temperature, intensity of radiation emitted increases with the increase of Sravelength, reaches a maximum value at given wavelength and then starts decreasing (with further increase of wavelength, What will be the energy of one photon of radiation whose frequency is 5 x 10" Hz? : (a) 199.51 k} (&) 33x10) (©) 6.626 x 10°" J (d) 2.31 x 10°J ‘The energy of a photon is given as 3.03 x 10°, () (d) “The wavelength of the photon is (a) 6.56 nm (b) 65.6 nm (c) 0.656 nm (d) 656 nm What will be the energy of a photon which corresponds to the wavelength of 0.50 A? (a) 3.98 x 10° J (b) 3x 1085 () 39x 10°F (d) 3x 107 Compare the energies of two radiations £, with wavelength 800 nm and E> with wavelength 400 nm. (a), =2E: () =E @ &, (c) B= 2B, 35, Electromagnetic radiation of wavelength 242 nm is just sufficient to ionise the sodium atom. What is the ionisation energy of sodium per atom? (a) 494.5 x 10° Jfatom (b) 81695 x 10"? atom (©) 5.85 x 10°F Jatom (d) 8.214 x 107? J/atom ‘The energy difference between the ground state of an atom and its excited state is 3 x 10" J, What is the wavelength of the photon required for this transition? E ite (a) 6.6 «10m (©) 1.8% 107 m (b) 3x 10% m (a) 6.6 x 107 m A 100 watt bulb emits monochromatic light of wavelength 400 nm. Calculate the number of Photons emitted per second by the bulb. (a) 3x 10% 5! (b) 2x 107? st (© 2% 10%! (d) 1x 107% 5 Mark the incorrect statement regarding the photoelectric effect. (a) “There is no time lag between the striking of light beam and the ejection of electrons from the metal surface. © scanned with Oken ScannerU0 “The muuuber of elections elected is inversely {portional to the intensity of light, (0) Photoclectrle effect is not abserved helow Aveo egengy ete Below W) “Ube Kinetic energy of the ¢ ith inetease tn fre rons Increases squency’ of light used, A certain metal when dread (v= 328 10! 12) emits photoelectrons with twee of KE as did photoelectrons whe the same metal is ireaiated by light (0 = 2.0.x 10!" 12), The vy of the metal is (@) 1.28 10" he () 12% 10 He lated by Tight (b) 8x 10" Ha @) Ax to? te, The spectrum of white light ranging from red to Violet is called a continuous spectrum because (a) different colours are seen as different bands in the spectrum (b) the colours continuously absorb energy to form a spectrum (©) the violet colour merges into blue, blue into green, green into yellow and so on (@) itis continuous band of coloured and white light separating them, Which of the following types of spectrum is best depicted by the given figure? 0 v Prism (a) Atomic absorption spectra (b) Atomic emission spectra (©) Continuous spectra (d) None of these Match the constants given in column I with their values given in column Il and mark the appropriate choi Column (A) Rydberg constant () (A) > (i), (B) > Gv), (> © (A) (0, 8) Git), (©) > (), (D) > (i) (@) (A) > Gv), (B) > (@, (C) > (ii), (D) > (itt) FG Bohr’s Model for Hydrogen Atom 29, 30, 3 32 33. 34, 35. The emission spectrum of hydrogen is found to satisfy the expression for the energy change AL (in fei joules) such that A= 2.18 % 10!" ; jovtes) such that AF = 2.1 (3 Pa where my = bs 2 35. lines corresponds ta P 2,3, serie indy rascher ‘the spectral (a) myo Land ny = 2,3, (b) ny Sand my = 4, 5,6 (©) m= and m= 3,4,5 (d) n and m = 3,4,5 “the ‘tron in Bohr's model of hydrogen atom is pictured as revolving around the nucleus in order for itto (a) emit protons (b) keep from being pulled into the nucleus (©)_keep from being repelled by the nucleus (2) possess energy. Given below are the spectral lines for an atom of hydrogen. Mark the lines which are not correctly matched with the values of nj and 1; Region Lyman Ultraviolet (i) [Balmer | 2 (ii) |Paschen [3 (iv) [Pfond | 4 (@) Gand Gi) (© (i) and tiv) Infrared Infrared Infrared 5.6, (b) (i) and (ii) (2) (and (iv) ‘Whatis the colour corresponding to the wavelength ‘of light emitted when the electron in a hydrogen atom undergoes transition from n = 4 to (@) Blue (b) Red (©) Yellow () Green ‘Which of the following series of lines are the only lines in hydrogen spectrum which appear in the visible region? (a) Lyman (b) Balmer (c)_ Paschen (@) Brackett ‘An electron in excited hydrogen atom falls from fifth energy level to second energy level, In which of the following regions, the spectral line will be observed and is part of which series of the atomic spectrum? @) Visible, Balmer (b)_ Ultraviolet, Lyman (©) Infrared, Paschen (@) Infrared, Brackett “The third line of the Balmer series in the emission spectrum of the hydrogen atom is due to the transition from the © scanned with Oken Scanner36. 37. 38, 39. 40, al. 42, 43, (a) fourth Bohr orbit to the first Bohr orbit (b) fifth Bohr orbit to the second Bohr orb (c)_ sixth Bohr orbit to the third Bohr orbit (a) seventh Bohr orbit to the third Bohr orbit. ‘The frequency of radiation absorbed or emitted when transition occurs between two stationary states with energies Ej (lower) and Ey (higher) is given by stationary state can be expressed as 1, Based on this expression an electron can move only in those orbits for which its angular momentum is (a) equal ton ; (b) integral multiple of Re (6) multiple of n (4) equal to only. ee ase According to Bohr’ theory, theangular momentum of an electron in 5" orbit is 10h 25h 1h h ot ot oS @ ‘The radius of the stationary state which is also called Bohr radius is given by the expression Tq = Wo Where the value of ay is () 52.9 pm (b) 5.29 pm (©) 529 pm (@) 0.529 pm If the radius of first Bohr orbit is x pm, then the radius of the third orbit would be (@) (3x) pm (6) (6x x) pm e) (fx) pm ‘The longest wavelength doublet absorption tran- sition is observed at 589 and 589.6 nm. Energy difference between two excited states is (2) 331x107 kj} (b) 3.31 x 1077 (©) 2.98 x 107] (@) 3.0.x 107" ky Bohr's theory can also be applied to the ions like (a) He" (b) Lit (©) Be’* (A) all of these. Identify the incorrect statement, ‘The findings from the Bohr model for H-atom are (a) angular momentum of the electron is expressed. (a) x3) pm he integral multiy = 2 integral mupls of {b) the first Bohr radius is 0.529 A AM 46. (c) the energy of the n' level, B, is Proportions} wot ° (a) the spacing between ad with increase in ‘n! it levels increases According to Bohr’ theory, the electronic energy of H-atom in Bohs orbit is given by 21.7910" x2 2 2577 J 21.8x . Which of the following is not correctly matched? 47. (a) Energy associated with Bohr’s orbit, 2.181078 J x Z* " (b) Energy gap between two orbits, s-a(h-4) (c)_ Kinetic energy of the ejected electron, Iro= hy +homv® (a) Energy of one mole of photons, ay, ¢ ‘What is the trend of energy of Bohr's ot (a)_ Energy of the orbit increases as we move away from the nucleus. (b) Energy of the orbit decreases as we move away from the nucleus. (c) Energy remains same as we move away from the nucleus. (@) Energy of Bohr’ orbit cannot be calculated. What does the negative electronic energy (negative sign for all values of energy) for hydrogen atom ‘means? (a) The energy ofan electron in the atom is lower than the energy of a free electron at rest which is taken as zero. When the electron is fre from the influence of nucleus it has a negative value which becomes more negative, When the electron is attracted by the nucleus the energy is absorbed which means. negative value. Energy is released by hydrogen atom in ground state. (b) (©) @ © scanned with Oken ScanneraM, 19. 50. |. Splitting of spectral Ue energy ofthe election tna hydrogen atom has | 86. 8 negtive slg for all posse atbits heeatwe (1) when the electron Is attracted! by the nucle ‘nul is present in orbit, the energy fs emitted ann Hts energy ts lowered (6) when the electron fs attracted by the micleus and Is present in orbit, theenerpy tsabsorbed | and Its energy is Increased | (6) when the electron Is repelled by the nucleus, theenergy released and is enengyIslawered | (a) none af these, ‘The radius of hydrogen atom tn ground state is | 58. 0.59 A, What will be the radius of sLP! In the | round state? | (a) 1.06 A (b) 0.265 A | (©) 01764 (@) 053.4 Which one is not in agreement with Bohr's model of the atom? (a) Line spectra of hydrogen atom (b) Pauli exclusion principle (c). Planck's theory (a) Helsenberg’s uncertainty principle es under the influence of | magnetic field is called | (a). Stark effect (b) Zeeman effect (c)_ photoclectric effect (dl) screening effect. Which of the following statements is false? (a) Photon has momentum as well as wavelength. 59, (b) Splitting of spectral lines in electrical field is called Stark effect. (c) Frequency of emitted radiation from a black. body goes from a lower wavelength to higher wavelength as the temperature increases, (a) Rydberg constant has unit of energy. 60. [89 Towards Quantum Mechanical Model 5h, of the Atom i |. ‘The de Broglie wavelength associated with a ball ‘of mass 200 g and moving at a speed of 5 metres/ hour, is of the order of (ht = 6.625 x 107] ) is @) 10% m (b) 10° m 61. (©) 10% m @ 10m A body of mass 10 g is moving with a velocity of 100 m s', The wavelength associated with itis (2) 6626 x 10°7 mb) 6.626 x 10" m (o) 6626 x 10m — (d) 6.626 x 10 m 62. “The wavelength of an electron moving with velocity of 10’ ms” is (@) 727 x10 m —(b) 355x107 m l (©) 825x104m — (a) 105 x 10" m What will be the wavelength ofan electron moving \ of velocity of light? with th of velocity of light (a) 24310! m (by 243 10° m (©) 0.243 m (d) 2.43 x 10° m Ifthe velocity of an electron in Bolu’ first orbit is 2,19 x 10% ms, what will be the de Broglie ‘wavelength assoclated with it? (a) 219 10% Mm (b) 4.38% 10° m (©) 332%10"%m — (d) 3.3210" m Match the column [ with column 11 and mark the appropriate choice. Column 1 Column I 2 (A) [Uncertainty of an object (i) 2220" | | hb ofan orbit (i) |Z, (B) |Bohr’s (©) Angular momentum of ) phe | aneleetron |__| mv (D) fee Broglie wavelength | (iv) |n ¢ (a) (A) > Gil), (B) > Gv), (C) > (, (D) > Gi) ) (A) > Gi), B) > @, (©) Ww), (D) > (ii) (2) (A) > iv), (B) > (ii), (C) > @, (D) > Gi) (@ (A>, B)> Gi), (©) (iv), D) > If uncertainty principle is applied to an object of ‘mass | milligram, the uncertainty value of velocity and position will be (@) 02x10 ms! (b) 052 x 108 m (©) 052 x 10% m? st (d) 2 107m? s ‘What will be the uncertainty in velocity ofa bullet with a mass of 10 g whose position is known with £001 mm? (a) 5.275 x 10 ms (b) 5.275 x 10° ms (©) 5.275 x 10° ms" (@) 5.275 x 10 mst ‘What will be the mass of a patticle if uncertainty in its position is 10°* m and velocity is 5.26 x 10° ms"'? (a) 0.01 kg (b) 0.1 kg (©) 1kg @) 10kg What will be the uncertainty in velocity of an electron when the uncertainty in its position is 1000 A? (a) 5.79 x10? ms (2) 5.79x10' ms (b) 5.79 x 108 mst (@) 5.79 10° ms © scanned with Oken Scanner48, ‘The energy of the electron in a hydrogen atom has a negative sign for all possible orbits because (a)_when the electron is attracted by the nucleus and is present in orbit n, the energy is emitted and its energy is lowered (b) when the electron is attracted by the nucleus andis present in orbit n, the energy is absorbed and its energy is increased. o) pies the electron is repelled by the nucleus, the energy is releas n ue egy i wed and its energy is lowered 49. The radius of hydrogen atom in ground state is 0.53 A. What will be the radius of jLi?* in the ground state? @) 1.06A (b) 0.265 A () 0.1764 (a) 053 A 50, Which one is not in agreement with Boht’s model of the atom? (a) Line spectra of hydrogen atom (b) Pauli exclusion principle (©) Planck's theory (¢) Heisenberg’s uncertainty principle 51. Splitting of spectral lines under the influence of magnetic field is called (a) Stark effect (b) Zeeman effect (c) photoelectric effect (d) screening effect. . Which of the following statements is false? (a) Photon has momentum as well as wavelength. (b) Splitting of spectral lines in electrical field is called Stark effect. (c) Frequency of emitted radiation from a black body goes from a lower wavelength to higher wavelength as the temperature increases. (a) Rydberg constant has unit of energy. [3 Towards Quantum Mechanical Model of the Atom 53. ‘The de Broglie wavelength associated with a ball cof mass 200 g and moving at a speed of 5 metres/ hour, is of the order of (H = 6.625 x 107 J) is @) 10m (b) 107° m (© 10% m @ 10m 54. A body of mass 10 g is moving with a velocity of 100 m s“!, The wavelength associated with it is (a) 6626 x 107m — (b) 6.626 x 10" m (©) 6626 x 10m — (4) 6.626 x 10°" m 55. The wavelength ofan electron moving with velocity of 107 ms tis @) 7.27 x10 m (©) 8.25 x 10m (b) 3.55 x10" m (d) 1.05 x 107 m 56. What will be the wavelength of an electron moving with i. th of velocity of light? (@) 24310" m — (b) 243 x 10 m (©) 0.243 m (d) 2.43 x 10% m 57. Ifthe velocity of an electron in Bohr's first orbit is 2.19 x 10° ms, what will be the de Broglie ‘wavelength associated with it? (a) 219 10%m (6) 438. 10% m (©) 332x107! m — (d) 3.32 x 10" m 58. Match the column f with column Il and mark the appropriate choice. Column It 29%nt { [Column i (A) Uncertainty of an object | (i) {B) Bohr’s radius of an orbit (ii) G lAngular momentum of | Gi) [an electron me (v) ee Broglie wavelength bh Go) me {@) (A) > (ii) (B) > Gi), (C) > @, (D) > Gi) (b) (A) > Gi, B)> (, (©) Go), D) > (HD) () (A) > (iv), (B) > (iti), (C) > (0, (D) > Gi) @ (A) 0.8) @, © > WW) (D) > Gi 59, If uncertainty principle is applied to an object of, ‘mass | milligram, the uncertainty value of velocity and position will be (a) 02x 104% m?s* (b) 0.52 x 10 ms (©) 052 x 107 m? 5 (d) 2x 107% m? 60. What will be the uncertainty in velocity of a bullet with a mass of 10 g whose position is known with £001 mm? (a) 5275x 10% mst (b) 5.275 x 107 ms? (©) 5.275 x 10° m (@) 5.275 x10 ms 61. What will be the mass of a particle if uncertainty in its position is 10° m and velocity is 5.26 x 107 ms"? (a) 0.01 kg (b) O.1 kg (©) 1kg (2) 10 kg What will be the uncertainty in velocity of an electron when the uncertainty in its position is 1000 A? (a) 5.79 x 10? ms (©) 5.79 x 10! ms 62, (b) 5.79 x 10° m st (@) 5.79 x10" mst © scanned with Oken Scannerok, Table tena ball hiya maw 10 and a speed of 72. 100, mvs, We apeed can he mewaured within accuracy of 10%, what will be the uncertahnly bn apeed and position respectively? n (a) 10 av/aee, doen (b) (0 mfwe, 5.27 10" (e) OE anface, 8 10 “One (dl) None of these BY Quantum Mechani Atom 4. ‘Whe probability af findingont an electron ata point within an atom ts proportional to the he (a) square of the orbital wave function he, yw? (b) orbital wave finetion hes Wp (c) Hamiltonian operator he HT (1). prineipal quanti number Le, 9 75. 65. ‘Two electrons present In M shell will differ In {a)_ principal quantum number (b)_ azimuthal quantum number (©) magnetic quantum number (a) spit quantum number. 66, What is the lowest value of 1 that allows g orbital to exist? @o6 7 wd as | 7% 67. Mow many orbitals and electrons are associated with ne Az (a) 32, 64 (b) 16,32 (ce) 4,16 (Wd) 8,16 | 68. An electron is in one of the 3d-orbil | 9, tie possible values of n, {and ny for this () 183,16 0,m=0 | (b) 13,2 Ly mys 1, 0,41 () ne 3te am sore (Wd) ne 3t m 1,0, 41, +2, 43 69, What are the possible values of 1 Fand my for an atomic orbital 4f? 78. (a) n= Ato 0,1, 2, 2, 1,0, +1, 42 (b) n= 4, P= 3, mm 10,41, 42, 43 (c) n= 4 t= 2m 1,0, 41,42, 43 G) ne Ate 01 mys 1,0, 41 2, 70. ae Deseribe the orbital with following quantum numb QW n=3la2 Gi) n=4,1 () (3p, GAP (b) dh Gi) ad i (©) @ 3h Gi) af (a) (i) 3d, Gi) af How many electrons in an atom have the following, quantum numbers? | ne dymye 12 @) 2°) 1 ©) 8 (@) 16 lection are wsseciated with the giv we Sand bot How many set of qu nun (a) 2 hh le) 6 (d) 10 An orbital bs described with the help of a wave ible for an electron, there are many atomic orbitals, When atom i field the possible number of orientations for an orbital of Since many wave function function, Are ps placed Ina mag azimuthal quanti number 3 is (a) three (h) two (0) five (d) seven, What will be the orbital angular momentum of an electron in 2s-orbitalt (a) Zero (c) Two (b) One (d) ‘three ‘Iwo values of spin quantum numbers he. +1/2and 1/2 represent (a) upand down spin of the electrons respectively (b) two quantum mechanical spin states which refer lo the orientation of spin of the electron (c) anti-clockwise and clockwise spin of the electrons respectively, (d)_ none of these ‘The region where probability density function reduces to zero is called (a) probability density region (b) nodal surfaces (©) orientation surfaces (d)_ wave function, ‘Though the five d-orbitals are degenerate, the first four d-orbitals are similar to each other in shape whereas the fifth d-orbital is different from others. ‘What is the name of the fifth orbital? (a) deny (b) de fo) dhe () dy. ‘The 3d-orbitals having electron density in all the three axes is () Sd (b) 3d. (c) Ibe (d) 3 Observe the given boundary surface diagrams of two orbitals Land [and choose the correct option. ~ol2 Noli” yt | Ne Ke ve 1 " @) Ledy ju Medyy OD Tides Hedy: © ted, U-d, @ Ted, Hed © scanned with Oken Scanner80. si. 82. 83. 85. 86, ‘The number of radial nodes and ang. orbital can be represented as (a) (= 2) radial nodes + angular node = (1 1) total nodes (n= 1) radial nodes + 1 angular node = (n= 1) total nodes (n= 3) radial nodes + 2 angular nodes 7 = (n= 1-1) total nodes e (n~ 3) radial nodes + 2 angular nodes = (n ~ 1) total nodes nades for (b) ©) @) Few statements are given regarding nodes in the orbitals, Mark the statement which is not correct {a)_ Incase of p.- orbital, xy plane isa nodal plane. (b) ns - orbital has (1 + 1) nodes. (c)_ The number of angular nodes is given by J (a) The total number of nodes is given by (1 ~ 1) i.e. sum of ! angular nodes and (1 ~ I = 1) radial nodes. i 88, Which of the following is not a correct statement regarding the energies of orbitals? (a) ‘The lower the value of (n + 1) for an orbital, lower is its energy. Electrons in the same subshell have equal energy. Energy of s-orbital is lower than the p-orbital and that of p-orbital is lower than the d-orbital. | Iftwo orbitals have same value for (v1 +1), the | 99, orbital with higher value of » will have lower | energy. | Few electrons have following quantum numbers, () 4 (i) m=4,!=0 (iii) m= 3, (iv) m= 3,P=1 ‘Arrange them in the order of increasing energy from lowest to highest. (a) Giv) < Gi) < Gill) < @ () Gi) < @v) << (©) Gi) < Gil) < i) < Gv) (@) (iii) < @ < Gv) < Gi) | ital when 89. (b) © (dd) a1. ‘An electron can enter into the orbi (@)_ value of mis minimum (b) value of fis minimum (6) value of (n + 1) is minimum (a) value of (1 + m) is minimum. How many orbitals in total are associated with 4" energy level? wr 1b) 2 Effective nuclear charge (Zeq) for a atom is defined as (a) shielding of the outermost shell electrons from the nucleus by the innermost shell 92. 7 a ucleus of an () 16 clectrons nnced by electron (b) the net positive charge exper from the nucleus (6). theattractive force experienced by the nucleus from electron (a) screening, of positive charge on nucleus by innermost shell electrons. “The orbital diagram in which the Aufbau principle is violated is ae oe c (ru) [fr {| (ny [ttt] » tut [4] a 1 co [t| [tft [t] @ [ry Which of the sequences given below shows the correct increasing order of energy? (a) 3s 3p, 48, 4p, 3d, 5s, 5p. Ad (b) 3s, 3p, 3d, 4s, 4p, 4d, 5s, 5p (o). 3s, 3p, 4s, 3d, 4p, 55, Ad, Sp (d) 3s, 3p, 45, 4p, 5, 3d, 4d, Sp Which of the following configurations does not follow Hund’s rule of maximum multiplicity? (a) 1s? 28 2p® 3? 3p? (b) “1s? 25? 2p® 35? 3p® 45? 3d? (c)_ 1s? 25? 2p® 35? 3p® 4s! 3d? (a) 1s? 2s? ap® 3s? 3p8 3d 4s? Read the following statements and mark the incorrect statement. (a) No two electrons in an atom can have all the four quantum mumbers same. (b) All the orbitals in a subshell are first occupied singly with parallel spins. (©) ‘Theouterclectronic configuration of chromium atom is 3d" 4s. (@) Lyman series of hydrogen spectrum lies in ultraviolet region, What is the electronic configuration of (a) 1s? 28? 2p° (b) 1s? 2s? 2p* (co) 1s? 28? 2p (d)_ 1s? 2s? 2p* Which atom (X) is indicated by the following configuration? X— [Ne] 357 3p” (@) Nitrogen (b) Chlorine (c) Phosphorus (a) Sulphur Which of the following configurations represents the most electronegative element? (a) 1s? 2s? 2p8 3s! (b) 1s? 2s? 2p* (o)_ 1s? 28? 2p8 38? 3p* (d) 1s? 2s? ap" ion? © scanned with Oken Scanner94 95. 96. Which of the following configurations represents ble gas? o W : 2p? as? 3p® 3d ae aps ad" 55? (b) 1s? 2st ap' 36? 3p 3a! 4? ag 52 (©) 18826 pt 36 ap 3a 4 ap Al? 52 5p (d)_ 1s? 2s? ap’ 3s? 3p® 3d! 4? ap® ad! 58° 5p Match the column 1 with column I and mark the appropriate choice, Column ID | (No. of unpaired electrons) Column 1) (Atom) &) (4) G), 6) 3.0, (©) > Gi, (0) Gy (b) (A) (0, (B) — Gi), (©) > Gi), (D) > Gv) () (A) > (iii), (B) > (i), (C) > (iv), (D) = (ii) () (A) > WB) > Gi), ©) (9, (D) > Git) Which of the following quantum numbers are correct for the outermost electron of sodium atom? (a) n=4, (b) n=3,1 =0,m=0,5 Is 41/2 12 98. 99, (c) (dn -1,s=-1/2 ‘The configuration of the valence orbit: clement with atomic number 22 is (a) 3d? 4s! (b) 4s? 3° (c) 4s' ap! (d) 3d? 4s! 4p! ‘Three elements ‘X; ‘Y’and ‘2’ have atomic numbers 18, 19 and 20 respectively. How many electrons are Present in the M shells of these elements? (a) 8,9, 10 (b) 8, 10, 13 © 8,88 (d) 89,12 What is the atomic number of an element which has 3d° as its outermost configuration? (@) 12 (b) 32) 26 (d) 24 fal of an 100.Study the orbital diagrams of two atoms ‘X and “Y. Which subshell will be more stable and why? aH omit TAT] x 7, exchange energy is maximum, sos stability ¥, exchange energy is maximum, so is stability. %, exchange energy is minimum, so stability i maximum, ¥, exchange energy is minimum, so stability is maximum. V (a) (b) © (a) © scanned with Oken ScannerMCQs Corner L @ 16. (c) 31. (©) 46. (a) 61. (a) 76. (b) 91. (a) 2 17. 32. 47. 62. 77. 92, (a) ~~ (b) . (a) ~ (a) (a) + (b) - (c) 3. 18. 33. 48. 63. 78. 93. (a) @) (b) (a) (b) (b) 1) 4. 19. 34, 49, 64, 79. 94, (a) (@) @) (©) (a) (b) (©) 5. 20. 35. 50. 65. 80. 95. (b) (c) (b) @d) () @) ©) NCERT Exemplar Problems lL (©) 2. (b) 3. @) 4. () 5. (a) 6. (b) 21. (d) 36. (d) 51. (b) 66. (d) 81. (b) 96. (b) 6. (d) 7 (a) 22. (d) 37. (b) 52. (c) 67. (b) 82. (d) 97. (b) 7 © 8 (0) 23. (©) 38. (d) 53. (d) 68. (c) 83. (a) 98. (c) 8 (©) 9. (b) 24. (b) 39. (a) 54. (b) 69. (b) 84. (c) 99. (©) 9% (a) (ANSWER KEY ) 10. (b) 25. (b) 40. (d) 55. (a) 70. (d) 85. (c) 100.(a) 10. (c) 1. (b) 12. 26. (c) 27. Al. (b) 42. 56. (a) 57. 71. (d) 72. 86. (b) 87. 11. (b) 12. (b) 13. (b) 28. (d) 43. (c) 58. (c) 73. (c) 88. @ 13. (d) 14. (b) 15. (c) (d) 29. (b) 30. (d) (d) 44. (b) 45. (d) (b) 59. (c) 60. (4) (a) 74. (a) 75. (b) (c) 89. (d) 90. (c) (b) © scanned with Oken Scanner