Diesel MSDS English
Diesel MSDS English
2 DIESEL FUEL
 Revision Date: 28 Nov 2017
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PRODUCT
     Product Name:     NO. 2 DIESEL FUEL
     Product Description:   Hydrocarbons and Additives
     Product Code:      123455-22,    123455-29,      152017-00
     Intended Use:    Diesel engine fuel, Heating Oil
COMPANY IDENTIFICATION
     Supplier:                  EXXON MOBIL CORPORATION
                                 22777 Springwoods Village Parkway
                                Spring, TX 77389       USA
        24 Hour Health Emergency                                 609-737-4411
         Transportation Emergency Phone                          800-424-9300 or 703-527-3887 CHEMTREC
         Product Technical Information                           800-662-4525
         MSDS Internet Address                                   www.exxon.com, www.mobil.com
This material is hazardous according to regulatory guidelines (see (M)SDS Section 15).
CLASSIFICATION:
LABEL:
Pictogram:
Hazard Statements:
H226: Flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H315: Causes skin
irritation. H332: Harmful if inhaled. H351: Suspected of causing cancer. H373: May cause damage to organs
 Product Name:        NO. 2 DIESEL FUEL
 Revision Date: 28 Nov 2017
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through prolonged or repeated exposure. Bone marrow, Liver, Thymus
Precautionary Statements:
P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children.
P103: Read label before use.P201: Obtain special instructions before use. P202: Do not handle until all safety
precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. -- No
smoking. P233: Keep container tightly closed. P240: Ground / bond container and receiving equipment. P241:
Use explosion-proof electrical, ventilating, and lighting equipment. P242: Use only non-sparking tools. P243:
Take precautionary measures against static discharge. P260: Do not breathe mist / vapours. P264: Wash skin
thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the
environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.P301 + P310: IF
SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with
plenty of soap and water. P304 + P340: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. P308 + P313: IF exposed or concerned: Get medical advice/ attention. P312: Call a POISON
CENTER or doctor/physician if you feel unwell. P331: Do NOT induce vomiting. P332 + P313: If skin irritation
occurs: Get medical advice/ attention. P362 + P364: Take off contaminated clothing and wash it before reuse.
P370 + P378: In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish. P391:
Collect spillage.P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.P501: Dispose
of contents and container in accordance with local regulations.
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200.
HEALTH HAZARDS
      May cause central nervous system depression. High-pressure injection under skin may cause serious
     damage. Under conditions of poor personal hygiene and prolonged repeated contact, some polycyclic
     aromatic compounds (PACs) have been suspected as a cause of skin cancer in humans. May be irritating to
     the eyes, nose, throat, and lungs.
ENVIRONMENTAL HAZARDS
      Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
NOTE:     This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
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* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and
exact percentage (concentration) of composition may have been withheld.        Specific chemical identity and exact
percentage composition will be provided to health professionals, employees, or designated representatives in
accordance with applicable provisions of paragraph (i).
INHALATION
      Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
      adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
      immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
      mouth-to-mouth resuscitation.
SKIN CONTACT
      Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by
      washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself
      or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard
      contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of
      the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately
      by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
      minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
      of injury.
EYE CONTACT
      Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
      Seek immediate medical attention.      Do not induce vomiting.
NOTE TO PHYSICIAN
      If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
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EXTINGUISHING MEDIA
      Appropriate Extinguishing Media:        Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
      flames.
FIRE FIGHTING
       Fire Fighting Instructions: Flammable. Evacuate area. Prevent runoff from fire control or dilution from
       entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and
       in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed
       surfaces and to protect personnel.
        Unusual Fire Hazards: Vapors are flammable and heavier than air. Vapors may travel across the ground
        and reach remote ignition sources causing a flashback fire danger. Hazardous material. Firefighters should
        consider protective equipment indicated in Section 8.
        Hazardous Combustion Products:          Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke,
        Fume, Sulfur oxides
FLAMMABILITY PROPERTIES
     Flash Point [Method]: >38°C (100°F) [ASTM D-93]
     Flammable Limits (Approximate volume % in air): LEL: 0.6                   UEL: 7.0
     Autoignition Temperature: >200°C (392°F)
NOTIFICATION PROCEDURES
      In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
      regulations. US regulations require reporting releases of this material to the environment which exceed the
      applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
      National Response Center can be reached at (800)424-8802.
PROTECTIVE MEASURES
     Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
     required due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the
     Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for
     advice on the minimum requirements for personal protective equipment. Additional protective measures may be
     necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
        For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic
        vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used depending on
        the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an
        oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant
        to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water-
        resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact
        with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body
        suit of chemical resistant, antistatic material is recommended.
 Product Name:       NO. 2 DIESEL FUEL
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SPILL MANAGEMENT
       Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak
       if you can do it without risk. All equipment used when handling the product must be grounded. Do not touch
       or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapor
       suppressing foam may be used to reduce vapors. Use clean non-sparking tools to collect absorbed material.
       Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large
       Spills: Water spray may reduce vapor; but may not prevent ignition in closed spaces.
        Water Spill: Stop leak if you can do it without risk. Eliminate sources of ignition. Warn other shipping. If
        the Flash Point exceeds the Ambient Temperature by 10 degrees C or more, use containment booms and
        remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point
        does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and
        allow material to evaporate. Seek the advice of a specialist before using dispersants.
        Water spill and land spill recommendations are based on the most likely spill scenario for this material;
        however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
        and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
        consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
      Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
      sewers, basements or confined areas.
HANDLING
     Avoid all personal contact. Do not siphon by mouth. Do not use as a cleaning solvent or other non-motor fuel
     uses. For use as a motor fuel only. It is dangerous and/or unlawful to put fuel into unapproved containers.
     Do not fill container while it is in or on a vehicle. Static electricity may ignite vapors and cause fire. Place
     container on ground when filling and keep nozzle in contact with container. Do not use electronic devices
     (including but not limited to cellular phones, computers, calculators, pagers or other electronic devices, etc.) in
     or around any fueling operation or storage area unless the devices are certified intrinsically safe by an approved
     national testing agency and to the safety standards required by national and/or local laws and regulations.
     Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause
     an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and
     grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for
     guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions
     Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended
     Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance
     of hazards due to static electricity).
        Static Accumulator:        This material is a static accumulator. A liquid is typically considered a nonconductive,
        static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a
        semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive
        or semiconductive, the precautions are the same. A number of factors, for example liquid temperature,
        presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.
STORAGE
     The type of container used to store the material may affect static accumulation and dissipation. Keep
     container closed. Handle containers with care. Open slowly in order to control possible pressure release.
     Store in a cool, well-ventilated area. Storage containers should be grounded and bonded. Fixed storage
 Product Name:        NO. 2 DIESEL FUEL
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        containers, transfer containers and associated equipment should be grounded and bonded to prevent
        accumulation of static charge. Keep away from incompatible materials.
Biological limits
ENGINEERING CONTROLS
        The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
        Control measures to consider:
                 Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION
        Personal protective equipment selections vary based on potential exposure conditions such as applications,
        handling practices, concentration and ventilation. Information on the selection of protective equipment for use
        with this material, as provided below, is based upon intended, normal usage.
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                 Half-face filter respirator
        For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
        Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
        gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
        Hand Protection: Any specific glove information provided is based on published literature and glove
        manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
        Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
        conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
        include:
                  Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style
                 gloves.
Eye Protection: If contact with material is likely, chemical goggles are recommended.
        Skin and Body Protection:        Any specific clothing information provided is based on published literature or
        manufacturer data. The types of clothing to be considered for this material include:
                Chemical/oil resistant clothing is recommended.
        Specific Hygiene Measures:       Always observe good personal hygiene measures, such as washing after
        handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and
        protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be
        cleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS
       Comply with applicable environmental regulations limiting discharge to air, water and
      soil. Protect the environment by applying appropriate control measures to prevent or limit
      emissions.
Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.
GENERAL INFORMATION
     Physical State:    Liquid
     Color:   Clear (May Be Dyed)
     Odor:    Petroleum/Solvent
     Odor Threshold:    N/D
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         Vapor Pressure:       0.067 kPa (0.5 mm Hg) at 20 °C
         Evaporation Rate (n-butyl acetate = 1):     N/D
         pH:    N/A
         Log Pow (n-Octanol/Water Partition Coefficient):       > 3.5
         Solubility in Water: Negligible
         Viscosity:    1.7 cSt (1.7 mm2/sec) at 40 °C - 4.1 cSt (4.1 mm2/sec) at 40 °C
         Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
     Freezing Point:   N/D
     Melting Point:  N/A
     Pour Point:     < -6°C            (21°F)
CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.
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for material.
Skin Sensitization: Data available.          Not expected to be a skin sensitizer. Based on test data for
                                             structurally similar materials. Test(s) equivalent or similar to OECD
                                             Guideline 406
Aspiration: Data available.                  May be fatal if swallowed and enters airways. Based on physico-
                                             chemical properties of the material.
Germ Cell Mutagenicity: Data available.      Not expected to be a germ cell mutagen. Based on test data for
                                             structurally similar materials. Test(s) equivalent or similar to OECD
                                             Guideline 471 475
Carcinogenicity: Data available.             Caused cancer in laboratory animals, but the relevance to humans
                                             is uncertain. Based on test data for structurally similar materials.
                                             Test(s) equivalent or similar to OECD Guideline 451
Reproductive Toxicity: Data available.       Not expected to be a reproductive toxicant. Test(s) equivalent or
                                             similar to OECD Guideline 414
Lactation: No end point data for material.   Not expected to cause harm to breast-fed children.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data for       Not expected to cause organ damage from a single exposure.
material.
Repeated Exposure: Data available.           Concentrated, prolonged or deliberate exposure may cause organ
                                             damage. Based on test data for structurally similar materials.
                                             Test(s) equivalent or similar to OECD Guideline 410 413
OTHER INFORMATION
          For the product itself:
                Target Organs Repeated Exposure: Bone marrow, Liver, Thymus
Vapor concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may
cause headaches and dizziness, are anesthetic and may have other central nervous system effects.
   Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or
pulmonary edema.
Diesel fuel: Caused cancer in animal tests. Caused mutations in vitro. Repeated dermal exposures to high
concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at
maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and
some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung
changes/infiltration/accumulation, and reduction in lung function.
   Diesel exhaust fumes: Carcinogenic in animal tests. Inhalation exposures to exhaust for 2 years in test animals
resulted in lung tumors and lymphoma. Extract of particulate produced skin tumors in test animals. Caused mutations
in vitro.
Contains:
NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia,
and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans
is uncertain.
   ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is
 Product Name:       NO. 2 DIESEL FUEL
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uncertain.
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
           Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
     environment.
MOBILITY
              More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to
        sediment and wastewater solids.
              High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the
        land. Expected to partition to sediment and wastewater solids.
ECOLOGICAL DATA
Ecotoxicity
 Test                          Duration        Organism Type            Test Results
Aquatic - Acute Toxicity       48 hour(s)      Daphnia magna            EL50 1 - 1000 mg/l: data for similar
                                                                       materials
Aquatic - Acute Toxicity       96 hour(s)      Fish                     LL50 1 - 100 mg/l: data for similar
                                                                       materials
Aquatic - Acute Toxicity       72 hour(s)      Pseudokirchneriella      EL50 1 - 100 mg/l: data for similar
                                              subcapitata              materials
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Aquatic - Chronic Toxicity     72 hour(s)      Pseudokirchneriella      NOELR 1 - 10 mg/l: data for similar
                                              subcapitata              materials
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
        Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
      incineration at very high temperatures to prevent formation of undesirable combustion products.
 Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue
and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should
be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be
taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
LAND (DOT)
      Proper Shipping Name: DIESEL FUEL
      Hazard Class & Division: COMBUSTIBLE LIQUID
      ID Number: NA1993
      Packing Group: III
      Marine Pollutant:  Yes
      ERG Number:       128
      Label(s):    NONE
      Transport Document Name:  NA1993, DIESEL FUEL, COMBUSTIBLE LIQUID, PG III, MARINE
      POLLUTANT
        Footnote: The flash point of this material is greater than 100 F. Regulatory classification of this material
        varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable
        liquid. This material is not regulated under 49 CFR in a container of 119 gallon capacity or less when
        transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically
        listed as a hazardous substance.
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LAND (TDG)
      Proper Shipping Name: GAS OIL
      Hazard Class & Division: 3
      UN Number: 1202
      Packing Group: III
SEA (IMDG)
       Proper Shipping Name: GAS OIL
       Hazard Class & Division: 3
       EMS Number: F-E, S-E
       UN Number: 1202
       Packing Group: III
       Marine Pollutant:  Yes
       Label(s):   3
       Transport Document Name:    UN1202, GAS OIL, 3, PG III, (>38°C c.c.), MARINE POLLUTANT
AIR (IATA)
       Proper Shipping Name: GAS OIL
       Hazard Class & Division: 3
       UN Number: 1202
       Packing Group: III
       Label(s) / Mark(s): 3
       Transport Document Name:   UN1202, GAS OIL, 3, PG III
OSHA HAZARD COMMUNICATION STANDARD:                   This material is considered hazardous in accordance with OSHA
HazCom 2012, 29 CFR 1910.1200.
Listed or exempt from listing/notification on the following chemical inventories:        AICS, DSL, IECSC, KECI,
PICCS, TSCA
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302
CERCLA:       This material is not subject to any special reporting under the requirements of the Comprehensive
Environmental Response, Compensation and Liability Act (CERCLA). Contact local authorities to determine if other
reporting requirements apply.
SARA (311/312) REPORTABLE GHS HAZARD CLASSES: Acute Toxicity (any route of exposure), Aspiration
Hazard, Carcinogenicity, Flammable (gases, aerosols, liquids, or solids), Skin Corrosion or Irritation, Specific
Target Organ toxicity (single or repeated exposure)
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       WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov. Chemicals known to the State of
California to cause cancer, birth defects, or other reproductive harm are created by the combustion of this product.
This warning is given to comply with California Health and Safety Code 25249.6 and does not constitute an admission
or a waiver of rights.
KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H225: Highly flammable liquid and vapor; Flammable Liquid, Cat 2
H226: Flammable liquid and vapor; Flammable Liquid, Cat 3
H302: Harmful if swallowed; Acute Tox Oral, Cat 4
H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1
H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
H332: Harmful if inhaled; Acute Tox Inh, Cat 4
H351: Suspected of causing cancer; GHS Carcinogenicity, Cat 2
H373: May cause damage to organs through prolonged or repeated exposure; Target Organ, Repeated, Cat 2
H400: Very toxic to aquatic life; Acute Env Tox, Cat 1
H401: Toxic to aquatic life; Acute Env Tox, Cat 2
H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1
H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3
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Section 16: HCode Key information was modified.
Section 16: Standard phrases for California Proposition 65 information was modified.
THIS MSDS COVERS THE FOLLOWING MATERIALS: DIESEL EFFICIENT | DIESEL NO. 2 | ESSO DIESEL
FUEL | EXXON DIESEL FUEL | EXXON SYNERGY DIESEL EFFICIENT | LOW SULFUR DIESEL |
MARINE DIESEL FUEL | MOBIL DIESEL EFFICIENT | MOBIL DIESEL FUEL | MOBIL SYNERGY DIESEL
EFFICIENT | ULTRA LOW SULFUR DIESEL | WINTERIZED DIESEL FUEL
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affiliates in which they directly or indirectly hold any interest.
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