Dropper JEE

Advanced
PAPER -1
MRJM/13 Milestone Test-8 Phase-1

DURATION ::180
DURATION Minutes
90 Minutes DATE : 20/10/2024 M. MARKS : 198

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (A) 19. (D) 37. (D)
2. (A) 20. (A) 38. (C)
3. (B) 21. (B) 39. (B)
4. (A) 22. (B) 40. (B)
5. (C) 23. (B) 41. (C)
6. (C) 24. (C) 42. (D)
7. (A, B, C, D) 25. (A, B, C) 43. (B, C)
8. (A, B, C) 26. (A, B, C, D) 44. (B, C, D)
9. (A, C) 27. (A, B, C) 45. (B, C)
10. (A, B) 28. (B, C) 46. (A)
11. (A, B, C) 29. (C, D) 47. (A, B, C, D)
12. (A, B, C) 30. (B, D) 48. (A, C, D)
13. (1.00) 31. (9.00) 49. (2.00)
14. (43.00) 32. (5.00) 50. (8.00)
15. (4.00) 33. (5.25) 51. (2.00)
16. (2.00) 34. (2.52) 52. (25.00)
17. (3.00) 35. (37.31) 53. (4.00)
18. (8.00) 36. (5.00) 54. (3.00)
 PART-I (PHYSICS)
1. (A) I
 = 106
Work Energy-Theorem I0
Watm + Wgas + Wext = K.E. = 0
 I = (10−12 106 ) = 10−6
W W
Wext = −Watm − Wgas 2
= 1 2
m m
nV0
Watm =  P0 dV = − P0V0 (n − 1) and and the power of sound is given by
−V0
P = IS
nV0
Wgas =  PdV = RT ln(n)
V0 = 110−6  2 = 2μW
Thus energy is given by
2. (A) E=P×t
FR = kx1
= 2 10−6  5  60  60 = 36 10−3 J
4x1 = x
8m
 T = 2 5. (C)
k
Given:
3. (B) Mass of wooden block, m = 9 kg
Two opposite charges situated at opposite vertices Density of the block, ρw = 900 kg/m3
forms a dipole and point lies on bisector line of So, volume of wooden material of block,
dipole for one dipole. m 9
Vw = = = 0.01m3 …(1)
w 900

− Kp
E=
x3
Direction of field due to these three dipoles is in a
horizontal plane at distance x from plane of For Case 1 : When swimming pool is empty
hexagon and parallel to it, mutually having angle kx = mg ...(2)
60° with each other. For Case 2 : When swimming pool is filled with
Q( 2a) Qa water
E0 = E + E = 2 E = 2 3
=
4 πε 0 × x πε 0 x3 F = mg + 3kx [F is thrust force]
⇒ F = mg + 3mg [from (2)]
⇒ F = 4mg
Let the volume of the block be V and the density of
the water be p.
⇒ ρgV = 4mg
4m 4  9
⇒V= = 3 = 0.036 m3 …(3)
4. (A)  10
Loudness level is given as So, volume of hollow portion,
 I  ΔV = Total volume – Volume of wooden material
L = 10log  
 I0  = 0.036 – 0.01 = 0.026 m3
Thus, [from (1) and (3)]
Percentage of hollow portion,
I 
10log   = 60 V 0.026
= 100 = 100 = 72%
 I0  V 0.036

[2]
6. (C)
Let equations of two SHM be
x1 = Asint …(i)
x2 = Asin ( t + ) …(ii)

7. (A, B, C, D)
GMm GMm
TE = − =−
2a 6R
GM  4  2GM x = 2x1 + x2 + x3
v1 =  =
3R  2  3R also we have
k x1
2k x3 = k x2 =
2
 x
 x3 =  
 11 
2kx 2k
 FR = 2k x3 = =
11 11m
GM
v2 = Vmax = A
6R
 2mg  mg  mg   11mg 
8 x0 = (2)  + + = 
L= GMm 2 R  k  k  2k   2k 
3
11mg
For radius of curvature at P A=
2GM 2k
m
GMm  11mg  2k
= 3R  Vmax =  
4R 2 r  2k  11m
2 11. (A, B, C)
r =  4R
3 Let temperature
8 k (TC − TB ) = k (TB − TD ) + k (TB − TA )
r= R
3 2k (TD − TA ) + k (TD − TA ) + k (TD − TC ) = 0

8. (A, B, C)
Pressure difference will accelerate the fluid. 12. (A, B, C)
2u y 2  10
T= = = 2s
9. (A, C) g 10
We have
u 2y (10)2
 3R   5R  H= = = 5m
(4)   ( 400 − Tmix ) = 2   (Tmix − 300 ) 2g 20
 2   2 
 2400 R + 1500 R = 11RT 1 1  qE  2
R= a xT 2 =  T
3900 2 2 m 
 Tmix = K
11 1  10−3  104  2
=   (2)
 mix =
CPmix
=
n1Cp1 + n2Cp2 2  2 
CVmix n1CV1 + n2Cv2
= 10 m
7 5
2 R + 4 R
= 2 2 = 34 13. (1.00)
5 3
2  R + 4  R 22  r 22 
PB − PA =  
 2 
2 2
 
10. (A, B) r 2 2
If block is at a distance of x from its mean position, =
2
we have
[3]
 1  YA 
U =   (I ) 2 (Y, I & ΔI are same for both)
14. (43.00) 2 I 
U A
 B = B =2
U A AA

17. (3.00)
v = v0 − gt0
2g
 =  t0 =
d  = (dm)( x sin ) ( x cos )
2 R
v0 − gt0 = 2gt0
 M   x sin 2  2 MgL
2
 =   dx     = sin 
 L   2  2 18. (8.00)
Ny = mg Ve
Given, V0 =
m2 L sin  2
Nx = 1 1
2  GM  2 1  2GM  2
  =  
R+h 2 R 
15. (4.00)
h=R
2GM1m −2GM 2 m 1 2
− + mv = 0 GMm 1 2 GMm
d d 2 − = mv −
( R + h) 2 R
4G ( M1 + M 2 )
v= 1 2 GMm GMm GMm
d or, mv = − =
2 R 2R 2R
GM
16. (2.00) v= = gR
Elastic potential energy, R
= [10  6.4  106 ]1/2 = 8 km/s

PART-II (CHEMISTRY)
19. (D)
Highest electron density is at the nucleus thus A is (A) O
1s and B is 2s (because 2s has 1 node).
oxolane
(B) 2-(3-oxobutyl)cyclohexan-1-one
20. (A)
(D) 3-ethyl-1, 1-dimethylcyclohexane
(A) Li—Mg diagonal relationship
(B)  Na — K  25. (A, B, C)
(C)  Ca — Mg  same group (B) Alkenes: Always planar.
(D)  B — Al  (C) Allenes (Cumulated dienes)
Thus, (A) Atoms get out of plane when there are even number
of (=) bonds.
21. (B) However, in option (C), there is a plane on which
Structure with the highest bond order and the there are all atoms i.e.,
shortest bond length (NN)

22. (B) And in option (D).

Refer theory.

23. (B)
Phenol and alcohol are functional isomers 26. (A, B, C, D)
24. (C) Refer theory.

[4]
27. (A, B, C)
Ionisation energy is not related to atomic mass. 32. (5.00)

28. (B, C)
SF4 → sp3d; SCl2 → sp3; SO24− → sp3, H2S →
drago molecule

29. (C, D)

(A) (B)

(C) (D)

30. (B, D) So total number of isomers obtained are 5.

(A) Does not show tautomerism.
(B) 33. (5.25)
Since, position is measured within 1 mm = 0.001 m
h 6.6 10 −34  7
p = =
4x 4  22 10 −3
(C)
= 5.25 10−32 kg ms−1.

34. (2.52)
(D) Using Pauling’s scale:
1
C −  H = 0.208 E C − H − (E C – C + E H − H )
2
1
C = 2.05 + 0.208 98.8 − (83.1 + 104.2)
2
C = 2.05 + 0.208 5.15
31. (9.00)
= 2.05 + 0.208 × 2.27 = 2.52

35. (37.31)
%ionic character = 16(A − B ) + 3.5(A − B )2
= 16 × 1.7 + 3.5 × (1.7)2
= 37.315

36. (5.00)
i. Acid (–COOH), ii. Keto (>=0),

iii. Aldehyde iv. Alcohol (–OH)

v. Phenol
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 PART-III (MATHEMATICS)
37. (D) 39. (B)
y Given, f  ( x ) = − f ( x )
We have cos −1 x − cos−1 =
2  g ( x ) = − f ( x ) and f  ( x ) = g ( x ) …(i)
 y 
 x = cos  cos −1 +  
2
 x    x 
2
 2  Now, F ( x ) =  f   + g 
  2    2 
 y  y
= cos  cos −1  cos  − sin  cos −1  sin    x   x  1
 2  2  F ( x) = 2 f   . f   .
  2   2  2
y y2   x   x  1
= cos  − 1 − sin  +2  g    .g   . = 0 [using Eq.(i)]
2 4
  2   2  2
 2 x = y cos  − sin  4 − y 2 F ( x ) is a constant  F (10) = F ( 5) = 5

 2 x − y cos  = − sin  4 − y 2 40. (B)

Squaring, we get
4 x2 + y 2 cos2  −4 xy cos  = 4sin 2  − y 2 sin 2 

 4 x2 − 4 xy cos  + y 2 = 4sin 2 

38. (C)
x − ai
We have Ai = = −1, i = 1, 2,, n and
− ( x − ai )

a1  a2  ...  an−1  an From figure refracted ray makes an angle of 15

Let x be in the left neighbourhood of am . Then with positive direction of x -axis and passes
through the point (1, 0). Its equation is
x − ai  0 for i = m, m + 1,, n and x − ai  0 for
( y − 0) = tan ( 45 + 30)( x − 1)
i = 1, 2,, m − 1 . Therefore,
x − ai
( )
or y = 2 + 3 ( x − 1)
Ai = = −1 for i = m, m + 1,, n and
− ( x − ai )
41. (C)
x − ai
Ai = = 1 for i = 1,2,, m − 1 The intersection of y − x + 1 = 0 and y + x + 5 = 0
x − ai
is ( −2, −3) . Put x = X − 2, y = Y − 3
Similarly, if x is in the right neighbourhood of am,
dY Y − X
then x − ai  0 for i = m + 1,, n and x − ai  0 The given equation reduces to =
dX Y + X
for i = 1, 2,, m Putting Y = vX , we get
x − ai dv v2 + 1
 Ai = = −1 for i = m + 1,, n and X =−
− ( x − ai ) dX v +1
x − ai  v 1  dX
Ai = = 1 for i = 1, 2,, m  − 2 − 2  dv = X
x − ai  v +1 v +1

Now, lim ( A1 A2  An ) = ( −1)

−
n−m+1
and
1
2
( )
 − log v 2 + 1 − 2 tan −1 v = log X + constant
x→am

lim ( A1 A2  An ) = ( −1)
n−m ( ) Y
 log Y 2 + X 2 + 2 tan −1 = constant
X
+
x→am

Hence, lim ( A1 A2  An ) does not exist ( 2 2

)
 log ( y + 3) + ( x + 2 ) + 2 tan −1
y+3
x+2
=C
x→am
42. (D) 1
  +1
Curve tracing : y = x + sin x 1 + x 2 dx 2 1
 2I =  = x dx , put x − =y
dy
= 1 + cos x  0 x 0 1+ x 4 1
0 +x 2 x
dx x2
 
d2y dy  1 −1 y  
= − sin x = 0 when x = n, n  Z
Also
dx 2
 2I =  y 2 + 2 =  2 tan 2  = 2
− −
Hence, x = n are points of inflection, where

curve changes its concavity I =
2 2
Also for x  ( 0, ) ,sin x  0  x + sin x  x ,
And for x  ( , 2) ,sin x  0  x + sin x  x 44. (B, C, D)
From these information, we can plot the graph of x 2 + cos 2 x
y = f ( x ) and its inverse I = cosec 2 xdx
x +1
2

x + 1 + cos 2 x − 1
2
= cosec 2 xdx
x2 + 1
 sin 2 x 
=  1 − 2 2
 cosec xdx
 +
 x 1 
 1 
=   cosec 2 x − 2  dx
 x +1
= − cot x − tan −1 x + C

Required area = 4A , where = − cot x + cot −1 x − + C
2
 
A=
0
( x + sin x ) dx −  0xdx = − cot x + cot −1 x + C

=  sin xdx = 2 square units 45. (B, C)
0
f ( x ) = x3 − x 2 + 100 x + 2002
f  ( x ) = 3 x 2 − 2 x + 100  0 x  R
43. (B, C)

 f ( x ) is increasing (strictly)
dx
I= (1)
0 1+ x
4
 1   1 
 2 f  f  
x +1 − x 2
 2000   2001 
= dx
0 1 + x4 Also, f ( x − 1)  f ( x − 2) as x − 1  x − 2 for  x
 
x2 1 − x2
= dx +  dx = I1 + I 2 46. (A)
0 1+ 0 1+
4
x x4
sin −1 (1 −  x ) cos −1 (1 −  x )
1 We have f ( x ) =
 2
−1 2 x (1 −  x )
I2 =  x dx
1  lim f ( x ) = lim f ( 0 + h )
0
2
+ x2 x→0+ h→0
x
1 sin −1 (1 − 0 + h) cos −1 (1 − 0 + h)
Put x + =y = lim
x h→0 20 + h (1 − 0 + h)

−1 sin −1 (1 − h ) cos −1 (1 − h )
 I2 =  dy = 0 = lim
 y −2
2
h→0 2h (1 − h )
  2
I =
dx
=
x dx
( 2) sin −1 (1 − h ) cos−1 (1 − h )
= lim lim
0 1+ 0 1+
4 4
x x h→0 (1 − h ) 2h h→0
Adding equations (1) and (2), we get In second limit put 1 − h = cos 
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 sin −1 (1 − h ) cos −1 ( cos  ) 49. (2.00)
= lim lim Let cos −1 x = a  a   0, 
h →0 (1 − h ) →0 2 (1 − cos  )
and sin −1 y = b  b   − / 2,  / 2
= lim
sin (1 − h ) lim
−1

(   0) p2
h→0 (1 − h ) →0 2sin (  / 2) We have a + b 2 =
4
…(i)

= sin −1 1 1 =  / 2 4
and ab 2 = …(ii)
16
47. (A, B, C, D)
Since b2  0, 2 / 4 , we get
A, B, C, D are false  
2 
a + b  0,  +  / 4 
2
48. (A, C, D)  
p2 2
So, from Eq. (i) we get 0  +
4 4
4
i.e., 0  p  + 1

Since p  Z , so p = 0, 1 or 2
Substituting the value of b 2 from Eq. (i) in Eq. (ii),
We know that area bounded by y = sin x and we get
 p2  2
x -axis for x 0,  is 2 sq. units a − a =
 4  16
Then area bounded by y = sin x and y = sin 2 x is  
4 sq. units for x 0, 2  16a − 4 p 2 a + 4 = 0
2

...(iii)
Then for x 0,10 , the area bounded is 20 sq. Since a  R  D  0
units i.e.,16 p 2 4 − 644  0  p 2  4
 p2  p=2
Substituting p = 2 in Eq. (iii), we get
16a 2 − 82 a + 4 = 0

( ) 2
2
 4a − 2 =0 a= = cos −1 x
4
2
 x = cos
4
From Eq. (ii), we get
The area bounded by y = sin x and y = sin x for
2 2 4 
x 0, 2 is 4 sq. units b =  b =  = sin −1 y  y = 1
4 16 2
Then for x0, 20 , the area bounded is 40 sq.
units
50. (8.00)
dy
+ 2t y = t 2
dt
2
I.F. = et
2 2 2
 Solution is y  et =  t 2et dt =  tet dt
2
t2 et 1 2
ye = t  −  et dt + C
2 2
The area bounded by y = sin x and y = sin3 x for 2
t 2 et 2
x  [0, 2] is 4 sq. units y = − e −t  dt + Ce−t
Then for x  [0, 10], the area bounded is 20 sq. 2 2
2
units et
Similarly, the area bounded by y = sin x and 
y 1 1
lim = − lim 22 =
y = sin 4 x for x 0,10 is 20 sq. units t → t 2 t → tet 2

[8]
51. (2.00) 12y – 24 = –x – 1
We have x + 12y = 23 …(ii)
n
n2 − 1 On solving eq (i) and (ii), we get
L = lim  −47 121
n→
n=2 n2 = ,=
19 57
n
n −1 n n +1 Now, 9 – 6 + 60 = 25
= lim
n→
 
n=2 n n=2 n
53. (4.00)
 1 2 3 n − 1  3 4 5 n +1
= lim        Here, f ( x ) = x3 + x 2 f  (1) + xf '' ( 2 ) + f ''' ( 3)
n →  2 3 4 n  2 3 4 n 
1 n +1 1 Put f  (1) = a, f  ( 2) = b, f  ( 3) = c (1)
= lim  =
n→ n 2 2  f ( x ) = x3 + ax 2 + bx + c

52. (25.00)  f  ( x ) = 3x 2 + 2ax + b, or

Orthocentre is a point where the perpendicular drawn f  (1) = 3 + 2a + b (2)
from the vertices to the opposite sides of the triangle  f '' ( x ) = 6 x + 2a, or
interest each other.
f '' ( 2) = 12 + 2a (3)
 f ''' ( x ) = 6, or
f ''' ( 3) = 6 (4)
From(1) and(4), c = 6
From(1),(2) and (3), we have a = −5, b = 2
 f ( x ) = x3 − 5 x 2 + 2 x + 6
f  ( x ) = 3 x 2 − 10 x + 2
AD ⊥ BC and BE ⊥ AC
 Slope of AD  Slope of BC = –1 54. (3.00)
Also, slope of BE  Slope of AC = –1 A, B, C are the 3 critical points of y = f ( x )
5−2 3
Here, slope of BC = =
4 − ( −7) 5
5 − (−7)
Slope of AC = = 12
4−3
−5
Altitude of BC: y + 7 = ( x − 3)
3 At B, it has vertical tangent, hence non-
3y + 21 = –5x + 15 differentiable
5x + 3y + 6 = 0 …(i) At A , it is non-differentiable
−1
Altitude of AC: y − 2 = ( x + 1) dy
At C , = 0
12 dx

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