1st प्री बोर्ड परीक्षा / 1st PRE-BOARD EXAMINATION – 2024-25 कक्षा / CLASS: बारहवीीं / XII अधिकतम अंक / Maximum marks = 70 विषय / SUB: रसायन ववज्ञान / CHEMISTRY समय / Time: 3 घींटे / 3 hours
Instructions: Read the following instructions carefully and follow them : (i) This question paper contains 33 questions. All questions are compulsory. (ii) This question paper is divided into five sections Section A, B, C, D and E. (iii) Section A questions number 1 to 16 are multiple choice type questions. Each carrying 1 mark. (iv) Section B questions number 17 to 21 are very short answer type questions each carrying 2 marks . (v) Section C questions number 22 to 28 are short answer type questions. Each question carries 3 marks. (vi) Section D questions number 29 and 30 are case-based questions. Each question carries 4 marks. (vii) Section E questions number 31 to 33 are long answer type questions. Each carrying 5 marks. (viii) There is no overall choice given in the question paper. However, an internal choice has been provided in few questions in all the sections except Section A. (ix) Use of log tables & calculators are not allowed.
Section A 1. What is the most basic aromatic amine’s common name? a) Benzenamine b) Benzylamine c) Aniline d) Aminobenzene 2. According to the Arrhenius equation k=Ae−Ea/RT what does Ea represent? a) The rate constant b) The activation energy c) The reaction temperature d) The concentration of reactants 3. When acetamide is converted to methylamine, what is the name of the reaction? a) Friedel-Craft’s reaction b) Hofmann reaction c) Hoffmann bromamide degradation reaction d) Hinsberg’s reaction 4. The rate constant of a first-order reaction depends on: a) The temperature b) The concentration of catalyst c) The concentration of products d) None of the above 5. Which of the following is a strong electrolyte? a) CH₃COOH b) HCl c) NH₃ d) C₆H₁₂O₆
Page 1 of 7 6. The complex ion [Ni(CO)₄]²⁻has: a) A tetrahedral geometry b) An octahedral geometry c) A square planar geometry d) A linear geometry 7. For a second-order reaction with respect to A, if the concentration of A is doubled, the rate of reaction will: a) Double b) Increase fourfold c) Decrease by half d) Remain the same 8. Which of the following compounds is formed when benzyl alcohol is oxidised with KMnO₄? a) CO₂ and H₂O b) Benzoic acid c) Benzaldehyde d) Benzophenone
9. The oxidation state of Cr in Cr2O72⁻ & CrO42- is ?
a) +3, +5 b) +5, +7 c) +6, +6 d) -1, +6 10. A disaccharide is formed when two monosaccharides are bonded together by a bond which is named as: a) Glycosidic b) Peptide c) Ionic d) Phosphodiester 11. Which mechanism is followed in nucleophilic substitution reactions? a) SN1 b) SN2 c) E1 d) Both SN1 and SN2 In the following questions, a statement of assertion (A), followed by a statement of reason (R), is given. Choose the correct answer out of the following choices: (a) Assertion and reason both are true; reason is correct explanation of assertion. (b) Assertion and reason both are true but reason is not the correct explanation of assertion. (c) Assertion is true; reason is false. (d) Assertion is false; reason is true. 12. Assertion (A): Linkage isomerism arises in coordination compounds containing ambidentate ligands. Reason (R): Ambidentate ligands have two different donor atoms. 13. Assertion: In case of phenol, bromination takes place even in absence of Lewis acid whereas bromination of benzene takes place in presence of Lewis acid like FeBr₃. Reason: –OH group attached to benzene ring is highly deactivating. 14. Assertion: CHCl₃ is stored in dark bottles. Reason: CHCl₃ is oxidised in presence of light. 15. Assertion: Cuprous ion (Cu⁺) has no unpaired electrons while cupric ion (Cu²⁺) has. Reason: Cuprous ion (Cu⁺) is colourless whereas cupric ion (Cu²⁺) is blue in aqueous solution. 16. Assertion: Vitamin C cannot be stored in our body. Reason: Vitamin C is water-soluble vitamin and is excreted from the body in urine.
Page 2 of 7 Section B 17. On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation from Raoult’s law is shown by the resulting solution? What change in temperature would you observe after mixing liquids X and Y? OR a 1.00 molal aqueous solution of trichloroacetic acid (CCl₃COOH), heated to its boiling point, has a boiling point of 100.18°C. Determine the van’t Hoff factor for trichloroacetic acid (Kb for water = 0.512 K kg mol⁻¹). 18. Magnetic moment of [MnCl4]2− is 5.92 BM. Explain why? 19. The chemistry of corrosion of iron is essentially an electrochemical phenomenon; explain the reactions occurring during the corrosion of iron in the atmosphere. 20. Draw other resonance structures related to the following structure and find out whether the functional group present in the molecule is ortho, para directing or meta directing.
21. Give the structure of the following compounds:
Section C 22. The cell in which the following reaction occurs: 2Fe3+(aq) + 2I−(aq) → I2(s) + 2Fe2+(aq) has cell Eocell=0.236V. Calculate the standard Gibbs energy for this cell reaction (Given: 1F = 96,500 C mol−1). 23. When chromite ore (A), is fused with sodium carbonate in free excess air, and the product is dissolved in water, a yellow solution of compound (B) is obtained. After treatment with sulfuric acid, compound (C), can be crystallised from this yellow solution; when compound C treated with KCl it gives orange crystals compound D; identify A to D and explain reactions. 24. Arrange the following in decreasing order of their acidic strength and give reasons for your answer: ● CH₃CH₂OH ● CH₃COOH ● ClCH₂COOH ● FCH₂COOH ● C₆H₅CH₂COOH OR What product(s) will be formed on reacting propanal with 2-methyl propanal in presence NaOH? Write name for the reaction also.
Page 3 of 7 25. Differentiate clearly giving examples: a) Monosaccharide & Polysaccharide b) Peptide & Glycoside linkage c) Nucleoside & Nucleotide 26. Which of the following haloalkane reacts with aqueous KOH most easily? Explain why? (i) 1-Bromobutane (ii) 2-Bromobutane (iii) 2-Bromo-2-methylpropane (iv) 2-Chlorobutane 27. What is the Cell Potential of the electrochemical cell in which the cell reaction is:
Pb2+ + Cd → Pb + Cd2+? Given that Eocell = 0.277 volts, temperature = 25oC, [Cd2+] = 0.02 M, and [Pb2+] = 0.2 M ? 28.Explain why: a) Allyl chloride is hydrolysed more readily than n-propyl chloride? b) Traces moisture should be avoided during use Grignard reagent? c) Despite being polar alkyl halides are insoluble in water?
SECTION D 29.Read passage below and answer following questions: The half-life of a reaction is the time required for the concentration of reactant to decrease by half, i.e., For first order reaction, t[1/2]=0.693/K, this means t[1/2] is independent of initial concentration. Figure on the right shows that typical variation of concentration of reactant exhibiting first order kinetics. It may be noted that though the major portion of the first order kinetics may be over in a finite time, but the reaction will never cease as the concentration of reactant will be zero only at infinite time.
Choose most appropriate answers:
(i) A first order reaction has rate constant k=3.01x10−3s. How long will it take to decompose half reactant? (a) 2.303 s (b) 23.03 s (c) 230.3 s (d) 2303 s (ii) The rate constant for a first order reaction is 7.0x 10-4 s-1. If the initial concentration of reactant is 0.080 M, what is the half-life of reaction? (a) 990 s (b) 99.2 s (c) 12375 s (d) 10.10 x 10-4 s (iii) For the half-life period of a first order reaction, which one of the following statements is generally false? (a) It is independent of initial concentration. (b) It is independent of temperature. (c) It decreases with the introduction of a catalyst (d) None of these
Page 4 of 7 (iv) The rate of a first order reaction is 0.04 mol L-1 s-1 at 10 minutes and 0.03 mol L-1 s-1 at 20 minutes after initiation. The half-life of the reaction is –
(a) 4.408 min
(b) 44.086 min (c) 24.086 min (d) 2.408 min OR Write expression for rate constant for the first order reaction derived by integrated rate law method.
30. When the mixture contains the three amine salts (1°, 2° and 3°) along with quaternary salt, it is distilled with KOH solution. The three amines distil, leaving the quaternary salt unchanged in the solution. Then the mixture of amines is separated by fractional distillation, Hinsberg’s method and Hoffmann's method
The following questions are multiple choice questions. Choose the most appropriate answer:
Write the acid base equation between aniline & HCl
SECTION E 31. a) Using valence bond theory, explain the following in relation to the complexes given below:(any one) [Mn(CN)6]3-, [Co(NH3)6]3+, (i) Type of hybridisation. (ii) Inner or outer orbital complex. (iii) Magnetic behaviour. b)Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl and Write down the formula of : Tetraamineaquachloridocobalt(III) chloride OR a) Using crystal field theory, draw an energy level diagram, write electronic configuration of the central metal atom/ion in the following: [CoF6]3-, [Co(H2O)6]2+, [Co(CN)6]3- b) Write the ionic equations for the reaction of acidified KMnO4 with (i)H2S and (ii)FeSO4
32. a) Write the equations involved in the following reactions:
(i) Wolff-Kishner reduction (ii) Rosenmund reduction iii)HVZ Reaction. b) How would you obtain acetophenone from phenol & phenol from benzene ?
Page 6 of 7 OR a) Give the structure and IUPAC name of the product formed when propanone is reacted with methyl magnesium bromide followed by hydrolysis. And explain why Carboxylic acids do not give characteristic reactions of carbonyl group. b) Complete the following reaction equations :
33. a) Define azeotropes. What type of azeotrope is formed by positive deviation from Raoult’s law? Given an example. b)100 mg of a protein is dissolved in just enough water to make 10.0 mL of solution. If this solution has an osmotic pressure of 13.3 mm Hg at 25°C, what is the molar mass of the protein? (R = 0.0821 L atm mol-1 K-1 and 760 mm Hg = 1 atm.) OR a) A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further 18 g of water is added to this solution. The new vapour pressure becomes 2.9 kPa at 298 K. Calculate (i) the molecular mass of solute and (ii) vapour pressure of water at 298 K. b) Explain why: (i) Soft drink bottles are sealed under high pressure. (ii) Oxygen used by divers is diluted with helium.
