CHEMISTRY

(SCIENCE PAPER – 2)
Maximum Marks: 80

Time allowed: Two hours

Answers to this Paper must be written on the paper provided separately.

You will not be allowed to write during first 15 minutes.

This time is to be spent in reading the question paper.

The time given at the head of this Paper is the time allowed for writing the answers.

Section A is compulsory. Attempt any four questions from Section B.

The intended marks for questions or parts of questions are given in brackets [ ].

SECTION A (40 Marks)

(Attempt all questions from this Section.)

Question 1

Choose the correct answers to the questions from the given options. [15]

(Do not copy the questions, write the correct answers only.)

(i) An element in period 3, whose electron affinity is zero:

(a) Neon

(b) Sulphur

(c) Sodium

(d) Argon

(ii) An element with the largest atomic radius among the following is:

(a) Carbon

(b) Nitrogen

(c) Lithium

(d) Beryllium
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 (iii) The compound that is not an ore of aluminium:

(a) Cryolite

(b) Corundum

(c) Fluorspar

(d) Bauxite

(iv) The vapour density of CH3OH is ___________. (At. Wt. C=12, H=1, O=16)

(a) 32

(b) 18

(c) 16

(d) 34

(v) Which of the following reactions takes place at the anode during the electroplating
of an article with silver?

(a) Ag – 1e-  Ag1+

(b) Ag + 1e-  Ag1-

(c) Ag – 1e-  Ag

(d) None of the above

(vi) The metallic hydroxide which forms a deep inky blue solution with excess
ammonium hydroxide solution is:

(a) Fe(OH)2

(b) Cu(OH)2

(c) Ca(OH)2

(d) Fe(OH)3

(vii) An example of a cyclic organic compound is:

(a) Propene

(b) Pentene

(c) Butene

(d) Benzene

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 (viii) In the laboratory preparation, HCl gas is dried by passing through:

(a) dilute nitric acid

(b) concentrated sulphuric acid

(c) dilute sulphuric acid

(d) acidified water

(ix) The nitrate which on thermal decomposition leaves behind a residue which is yellow
when hot and white when cold:

(a) Lead nitrate

(b) Ammonium nitrate

(c) Copper nitrate

(d) Zinc nitrate

(x) The salt formed when concentrated sulphuric acid reacts with KNO3 above 200⁰C:

(a) K2SO4

(b) K2SO3

(c) KHSO4

(d) KHSO3

(xi) The property exhibited by concentrated sulphuric acid when it is used to prepare
hydrogen chloride gas from potassium chloride:

(a) Dehydrating property

(b) Drying property

(c) Oxidizing property

(d) Non-volatile acid property

(xii) The hydrocarbon formed when sodium propanoate and soda lime are heated together:

(a) Methane

(b) Ethane

(c) Ethene

(d) Propane

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 (xiii) The acid which does not form acid salt by a basic radical:

(a) H2CO3

(b) H3PO4

(c) H2SO4

(d) CH3COOH

(xiv) The general formula of hydrocarbons with single covalent bonds is:

(a) CnH2n+2

(b) CnH2n

(c) CnH2n–2

(d) CnH2n–6
(xv) The indicator which changes to pink colour in an alkaline solution is:

(a) Blue Litmus

(b) Methyl Orange

(c) Red Litmus

(d) Phenolphthalein

Question 2

(i) Match the Column A with Column B: [5]

Column A Column B

(a) Sodium Chloride 1. has two shared pair of electrons

(b) Methane 2. has high melting and boiling points

(c) Hydrogen chloride gas 3. a greenhouse gas

(d) Oxidation reaction 4. has low melting and boiling points

(e) Water 5. Zn – 2e–  Zn2+

6. S + 2e–  S2–

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 (ii) The following sketch illustrates the process of conversion of Alumina to Aluminium: [5]

Study the diagram and answer the following:

(a) Name the constituent of the electrolyte mixture which has a divalent metal in it.

(b) Name the powdered substance ‘X’ sprinkled on the surface of the electrolyte
mixture. Coke

(c) What is the name of the process? Hall Heroults

(d) Write the reactions taking place at the electrodes ‘Y’ (anode) and ‘Z’ (cathode)
respectively. O2- - 2e --> O x 2 Al 3+ + 3e- --> Al
--> O2

(iii) Fill in the blanks with the choices given in the brackets: [5]

(a) Metals are good _________. [oxidizing agents / reducing agents]

(b) Non-polar covalent compounds are __________ [good / bad] conductors of

heat and electricity.

(c) Higher the pH value of a solution, the more __________ [acidic / alkaline] it
is.

(d) __________, [Silver chloride / Lead chloride] is a white precipitate that is

soluble in excess of Ammonium hydroxide solution.

(e) Conversion of ethene to ethane is an example of __________. [hydration /

hydrogenation]

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 (iv) State the terms / process for the following: [5]

(a) The energy released when an atom in the gaseous state accepts an electron to
form an anion. Electron Affinity

(b) Tendency of an element to form chains of identical atoms. Catenation

(c) The name of the process by which Ammonia is manufactured on a large scale. Haber Process

(d) A type of salt formed by partial replacement of hydroxyl radicals with an acid
radical. Basic Salt

(e) The ratio of the mass of a certain volume of gas to the same volume of
hydrogen measured under the same conditions of temperature and pressure. Vapour Density

(v) (a) Give the structural formula of the following organic compounds: [5]

1. 2-chlorobutane

2. Methanal

3. But-2-yne

(b) Give the IUPAC name of the following organic compounds:

1. 2.

Ethanoic Acid But-2-ol

SECTION B (40 Marks)

(Attempt any four questions from this Section.)

Question 3

(i) Identify the cation in each of the following cases: [2]

(a) Ammonium hydroxide solution when added to Solution B gives a white

precipitate which does not dissolve in excess of ammonium hydroxide
solution. Pb2+

(b) Sodium hydroxide solution when added to Solution C gives a white precipitate
which is insoluble in excess of sodium hydroxide solution. Ca 2+

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 (ii) Fill in the blanks by choosing the correct answer from the brackets: [2]

(a) During electrolysis, the compound _________ in its molten state liberates
reddish brown fumes at the anode. [NaCl / PbBr2]

(b) The ion which could be discharged most readily during electrolysis is
__________. [Fe2+ / Cu2+]

(iii) Arrange the following as per the instruction given in the brackets: [3]

(a) Al, K, Mg, Ca (decreasing order of its reactivity)

(b) N, Be, O, C (increasing order of non-metallic character) O < N < C < Be

(c) P, Si, F, Be (decreasing order of valence electrons) P > Si > F > Be

(iv) Complete and balance the following equations: [3]

(a) NH4Cl + Ca(OH)2  NH4OH + CaCl2

(b) CuSO4 + NH4OH  Cu (OH)2 + (NH4)2SO4

(c) Cu + Conc. HNO3  CuO + H2O + NO2

Question 4

(i) State a relevant reason for the following: [2]

(a) Hydrogen chloride gas cannot be dried over quick lime. It reacts with Quick Lime

(b) Ammonia gas is not collected over water. It is highly soluble in water

(ii) Identify the alloy in each case from the given composition: [2]

(a) aluminium, magnesium, manganese, copper Duralumin

(b) iron, nickel, chromium, carbon Stainless Steel

(iii) Solve the following numerical problem. [3]

Ethane burns in oxygen according to the chemical equation:

2C2H6 + 7O2  4CO2 + 6H2O

If 80 ml of ethane is burnt in 300 ml of oxygen, find the composition of the resultant

gaseous mixture when measured at room temperature.

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 (iv) The following questions are pertaining to the laboratory preparation of Ammonia [3]
gas from Magnesium nitride:

(a) Write a balanced chemical equation for its preparation. Mg3N2 + 6H2O --> 3Mg (OH)2 + 2NH3

(b) Why is this method seldom used? Nitrides Are Expensive

(c) How do you identify the gas formed? Dense white fumes with HCL

Question 5

(i) Write one use of the following alloys: [2]

(a) Bronze It is used in statues, coins, medals, etc

(b) Fuse metal Soldering

(ii) Draw the electron dot structure for the following: [2]

(a) Ammonium ion

(b) A molecule of nitrogen

[At. No.: N =7, H = 1]

(iii) Give a balanced chemical equation for the following conversions with conditions: [3]

(a) Ethene from ethanol C2H5OH + NaCl (Alcoholic) --> C2H4 + NaOH + HCl

(b) Ethyne from calcium carbide CaC2 + H2O --> CaO + C2H2

(c) Monochloromethane from methane C2H6 + Cl2 --> C2H5Cl + HCl

(iv) Study the following observations and name the anions present in each of the reactions. [3]

(a) When a crystalline solid ‘P’ is warmed with concentrated H2SO4 and copper
turnings a reddish brown gas is released. NO3-

(b) When few drops of dilute sulphuric acid is added to Salt ‘R’ and heated, a
colourless gas is released which turns moist lead acetate paper silvery black. S2-

(c) When few drops of barium nitrate solution is added to the salt solution ‘Q’, a
white precipitate is formed which is insoluble in HCl. SO4-

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 Question 6

(i) Define / State: [2]

(a) Electronegativity Energy required to accept electron outermost shell isolated gaseous state

(b) Gay-Lussac’s Law of combining volumes All gases combine in a whole number ratio of volumes in stp

(ii) The Empirical formula of an organic compound is CHCl2. [2]

If its relative molecular mass is 168, what is its molecular formula?

[At. Wt. C = 12, H = 1, Cl = 35.5]

(iii) Choose the substances given in the box below to answer the following questions: [3]

Iron Magnesium sulphite Zinc Sodium sulphide

Lead Ferric chloride Copper Ferrous sulphate

(a) The metal that will not produce hydrogen gas when reacted with dilute acids. Ferric Chloride

(b) The compound that will produce sulphur dioxide gas when reacted with dilute
HCl. Magnesium Sulphite

Ferrous Sulphate
(c) The solution of this compound produces dirty green precipitate with NaOH.

(iv) State one relevant observation for each of the following: [3]

(a) To the copper nitrate solution, initially few drops of sodium hydroxide solution
is added and then added in excess. Pale blue precipitate, insoluble in excess

(b) Burning of ammonia in excess of oxygen. Greenish Yellow Flame

(c) Dry ammonia gas is passed over heated PbO. Silvery Grey Residue

Question 7

(i) Name the following: [2]

(a) Organic compounds with same molecular formula but different structural
formula. Isomers

(b) Group of organic compounds where the successive members follow a regular
structural pattern, successive compounds differ by a ‘CH2’ group. Homologous Series

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 (ii) Give reason for the following: [2]

(a) Ionisation potential decreases down a group. Nuclear Charge Increases, Atomic Size Increases

(b) Ionic compounds do not conduct electricity in solid state. Strong electrostatic forces exist between
them and no free ions, these forces are
weakened in molten/aqueous state
(iii) Calculate: [3]

(a) The percentage of phosphorus in the fertilizer super phosphate Ca(H2PO4)2

correct to 1 decimal point. [At. Wt. H=1, P=31, O=16, Ca=40]

(b) Write the empirical formula of C8H18. C4H9

(iv) Answer the following questions with reference to electrorefining of copper: [3]

(a) What is the anode made of? Impure Copper

(b) What do you observe at the cathode? Reddish Brown Deposit

(c) Write the reaction taking place at the cathode. Cu 2+ + 2e --> Cu

Question 8

(i) Arrange the following according to the instructions given in brackets: [2]

(a) C2H2, C3H6, CH4, C2H4 (In the increasing order of the molecular weight) CH4 < C2H2 < C2H4 < C3H6

(b) Cu2+, Na+, Zn2+, Ag+ (The order of Preferential discharge at the cathode) Na < Zn < Cu < Ag

(ii) Differentiate between the following pairs based on the criteria given in the brackets: [2]

Sulphuric Acid Forms (a) Cane sugar and hydrated copper sulphate [using concentrated H2SO4] Cane sugar gives a black
An Acid Salt, HCL Forms puffy mass of carbon while
Normal Salt CuSO4 gives a reddish brown
(b) Sulphuric acid and hydrochloric acid [type of salts formed] residue or smth

(iii) Convert the following reactions into a balanced chemical equation: [3]

(a) Ammonia to nitric oxide using oxygen and platinum catalyst. NH3 + 2O2 -Pt (450 - 500C) -> NO3 + H2O

(b) Sodium hydroxide to sodium sulphate using sulphuric acid. 2NaOH + H2SO4 ---> Na2SO4 + 2H2O

FeS + 2HCL --> FeCl2 + H2S

(c) Ferrous sulphide to hydrogen sulphide using hydrochloric acid.

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 (iv) Choose the answer from the list which fits in the description: [3]

[CCl4, PbO, NaCl, CuO, NH4Cl]

(a) A compound which undergoes thermal dissociation. NH4Cl

(b) An amphoteric oxide. PbO

(c) A compound which is a non-electrolyte. CCL4

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