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Hydrocarbons

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HYDROCARBONS

PHYSICAL PROPERTZES ALKANESs AUENES ALIKYNES


General Fomula CnH2n+2 CrHDn CoHn-2
Moleauar formula-CAH8

Bond type Sirgle bonds Dauble bands At least one triple bond

Polarity Non-pola Polar Pdar

Intermolecular forces Weak Moderate van der Waals forces Strong van der Waals forces

States of matter C-C Gases C-C. Gases


Uquids Uquds
C>18 Solds Co18 Solid C>18 Solids

Appearance Colourlesss, odourless EheneCoburless faint smell Colourless, odourless


Sweet gas

Solublity Insoluble in water, soluble in non-polar norganic


Insoluble
so sohotSoluble
in water in insoluble in water, soluble in oganic
sovents olvents

Boilng Point Proporional to molecular weight due to Increases with increase in number MPBP and density lngeases with
increased van der Waals farces wth of carbons increase in number of carbons
molecula size Every increase in CH2 gp, BP
increases by 20-30K

Efect of branching on BP Branching dereases BP. Sraight-chain alkenes have higher


n-pentane>lso>Neo BP than branched isomers

Even vs Odd cartbon count Alkanes with even number d carbons


have higher BP

Reactvity reactvity order of alkanes with halogens Higher than alkanes due to pi Higher than alkanes and alkenes due
Rate M replacerment of alkanes bonds, which are oasly attacked to triple bonds
by electrophles
3 > 2> 1

Fluorinaion lodination Fluorinaßon is too violent to control,


iodination is very siow and reversble
can proceed with HiOY HNO3

Aternate names
Paraffins Acetylenes
Olefins(ol forning)

Hybridisaton of C atom sp3 spZ

Bond Parameters ETHYNE

Angle H-CH 1166" HCC- 180

Length CEC <C-C <CC 120 pm < 133 pm


C-C. 134 pm
< 154 pm

823 kJ/mol > 681kJ/mob 348


KJ/mol
CC> 681 kJ
Energy HCaCH Two sp hybridised orbitals,
CCo bond, 2 C-H a bonds, and 2
CCn bonds

Structure d bonds

Examples of 1st member Methane - CH4 CH2 Methenenot stable


1st stable mbes
c2H4 Ethylenel Acetylene,
simplest

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