5/22/2024
Module 6: Additional
Aqueous Equilibria
CH 117
University of Alabama at Birmingham
Dr. Corey Burns
Calculate the pH at after the addition of each mL of 0.100 M pH
quantity of 0.100 M NaOH to a 100.00 mL NaOH
sample of 0.100 M HCl. 0.00
20.00
50.00
90.00
99.00
99.50
100.00
100.50
101.00
110.00
120.00
1
5/22/2024
Weak Acid Titrated with a Strong Base
Strategy for calculating the pH
• Dissociate the strong base
NaOH(aq) Na+(aq) + OH−(aq)
Na+ will be a spectator ion
• Set up a table for reaction of OH− and HA
• In table, use up either OH− or HA (use up the limiting
reagent)
• If OH− is limiting or at equivalence point, calculate
pH from equilibrium concentrations
• If HA is limiting, calculate pH from [OH−] in excess
© UAB. All Rights Reserved.
Question 1 (5 minutes)
• Write Ksp expressions for the following compounds.
• Lead (II) nitrate
• Cobalt (II) phosphate
• AgCl
• VCO3
2
5/22/2024
Question 1 Work
• Write Ksp expressions for the following compounds.
• Lead (II) nitrate
• Cobalt (II) phosphate
• AgCl
• VCO3
Question 2 (16.5 minutes)
• Calculate the mass & molar solubility of the following compounds given their Ksp.
• AgBr (Ksp = 5.0*10-13)
• PbCrO4 (Ksp = 2.8*10-13)
• Sn(OH)2 (Ksp = 1.4*10-28)
3
5/22/2024
Question 2 Work
• Calculate the mass & molar solubility of the following compounds given their Ksp.
• AgBr (Ksp = 5.0*10-13)
• PbCrO4 (Ksp = 2.8*10-13)
• Sn(OH)2 (Ksp = 1.4*10-28)
Question 3 (9 minutes)
• Calculate the molar solubility of lead (II) fluoride (Ksp = 3.6*10-8) in the
following solutions.
• Pure water
• 0.050 M sodium fluoride
4
5/22/2024
Question 3 Work
• Calculate the molar solubility of lead (II) fluoride (Ksp = 3.6*10-8) in the
following solutions.
• Pure water
• 0.050 M sodium fluoride
Question 4 (9 minutes)
• Will a precipitate form when 20.00 mL of 0.010 M AgNO3 is mixed with 10.00 mL
of 0.015 M NaIO3? The Ksp of AgIO3 is 3.17*10-8.
10
5
5/22/2024
Question 4 Work
• Will a precipitate form when 20.00 mL of 0.010 M AgNO3 is mixed with 10.00 mL
of 0.015 M NaIO3? The Ksp of AgIO3 is 3.17*10-8.
11
Question 5 (8 minutes)
• Will Co(OH)2 (Ksp = 1.3*10-15) precipitate from a 0.020 M solution of Co(NO3)2 if
the solution’s pH is 8.5?
12
6
5/22/2024
Question 5 Work
• Will Co(OH)2 (Ksp = 1.3*10-15) precipitate from a 0.020 M solution of Co(NO3)2 if
the solution’s pH is 8.5?
13
Reflection Questions
• Make a list of individual skills necessary to solve problems that will be on your
Module 6 Quiz. Make a strategy on how to practice these skills.
14
