Atomic Structure QUICK LOOK Structure of Atom Lie ‘Average kinetic energy = 3 mu ‘The specific charge (e/m) of proton is 9.5810" Cig Mass of | mole proton =Nxm, = 6,023s10? «1.673« 10 Pkg 1.0076 +10 kg = 1.0076 ‘The radius of proton = 1.5310 em, ‘The volume of proton y =1.50«10-%em! The charge on positive rays is usually +1 butt may have + 2, #3 values. circumference of orbit wavelength Number of waves in an orbit = 2( mur) b fort Number of revolution f an electron per second in the 1 orbit speed of electron __u, circumference 2, ‘The wavelength of an electron accelerated by a potential difference V can be given by Fora gas molecule, A= Where, k is Boltzmann’s constant. Bohr Model: (For hydrogen like atoms): The quantum theory to atomic model was first of all applied by Bohr. Bohr ‘quantised angular momentum of electron. The consequence of it was that all the quantities radius, velocity, linear momentum, ‘angular momentum and energy were quantised. Bob's theory is applicable only to atoms containing one electron only eg, He.He “Li ete. Here ¢ = elementary charge,r =radius of orbit, m= mass of electron, v = speed of electron, f= Planck's constant, n = integer = principal quantum number. m1 Ze? = Conditions of circular orbit rd, * Condition of transition : hv =E, ~E , + Radius of a orbit: 5, According to Bohr’s theory, radius of n™ obit, cen" ‘The radius of first Bohr orbit is 053A + Speed of electron inn ® onbit: v, where © = speed of light The velocity of electron in first Bohr orbit is 2 22010'm/s a7 © Kinde energy: B, = —L.22 tm * Potential energy: U= + Total ene tal energy: B= 1 + Total energy of electron, Foe For hydrogen atom in lowest orbit (n =1).E=~13.6eV + The total ener orbits, but kinetic energy decreases. In free state (out of atom), electron can have any energy (Continuous state). Increases as the electron reaches in higher56 ‘The energy ABs released when electron jumps from higher orbit to lower orbit. The corresponding wavelength of 12375 5 AE, ‘When electron jumps from higher to lower orbit, photon emitted and the atom recoils. The momentum of recoiled emitted radiation is 2 atom is equal to the momentum of photon Le, py = Sommerfeld introduced the idea of elliptical orbits. For principal quantum number n, there are n orbits, out of ‘which (a 1) are elliptical while on is circular Energy Spectrum: Fornt orbit B, =2 8 =-136. R=dket a2 ak=3 Figure: 81 Where, R=—™ Bech Rydberg constant Frequency of emitted radiatioy ref = 4] Wave number For wavelength (4) of emitted radiation: SEE Main and Advanced Chapter-wise Solved Papers: Chemist ‘The Wave Funetions for Hydrogen ‘According to quantum mechanics, the atom has no sharply defined boundary as suggested by the Bohr theory. The probability distribution in figure a suggests that the charge of the electron can be modeled as being extended throughout a region of space, commonly referred to as an electron cloud. ‘The darkest portion of the distribution appears at corresponding to the most probable value of r for the electron. Pu » 6 = 00529 am ‘ » igure: 82 ‘The next-simplest wave function for the hydrogen atom is the ‘one corresponding to the 2s state (1 wave funetion for this sta yi Pep os os oa as ol \ 02 on 00 ‘Again notice that ys,depends only on r and is spherically symmetric. The energy corresponding to this state is E, =~(13.606/4)eV = 3.401eV. The plot for the 2s states has two peaks. These models were against the Heisenberg ‘uncertainty principle. The principle states that itis impossible 10 determine momentum and position of a sub-atomic particle precisely and simultaneously. wool or mavacs|]Atomic Structure Ea inty in momentum; Ax is uncertainty in position along one axis; Au is uncertainty in velocity along same axis, [As the mass of particle increases the uncertainty values ‘decrease and thus, uncertainty principle and de-Broglie concept loses its significance in case of large objects. Uncertainty principle is also valid for a conjugate pair of variable which are to be measured simultaneously. Some other simultaneous measurements for angular momentum —(w) and angle (0), for energy (E) and time (0), we can have swaos i apart i Note + Boh's model assumes te existence of wll defined cris in which both te positon and momentum of he tectons tre known exaly, On the other hind, Heisenberg concluded tha poston nd momentum of any ub atom particle cano! be valine precisely nd snltaneouly, + The mcensily prccple has negligible effec for inaroscopi patil, For example, he uncertain n Neloiy of an electon and cricket alse 0.15) ‘are in order of 1 A, then uncertainty in velocity obtained Heisenberg principle areS.8x10ins “and rom 3.51s10*ims “ respectively. Thus, uncertainty in velocity of cricket ball is definitely negligible. ‘Heisenberg uncertainty principle can be best understood ‘with the help of an example, To observe an electron we can illuminate it with light or electromagnetic radiation having ‘wavelength smaller than the dimensions or an electron. But 1 ww (0a! change the energy of electron when it strikes on electron. No doubt we can evaluate the position of electron but we would know very little about the velocity of electron after collision, "If Aw along X-axis and Avalong Y-axis is predicted. Heisenberg uncertainty principle is not vali. photon of such light having high e ) woud The wavelength of any particle showing dual nature of wave an y particle proposed by de-Broglie sé = "is independent of the nature of charge (i.., +e or -ve or neutral). collection of orbitals with the same value of mis called an electron shell, e.g, all the orbitals with n = 3 are said to be {in 3" shell. One or more orbitals with same values of 1 and 1 is called a sub-shell. Each sub-shell is designated by a number (the value of 7m) and a letter (spd or f corresponding to the values of 2), .g., all the orbitals with = Band [= | are collectively referred as 3 p-orbitals and are said to be in 3p-sub-shel An orbital may also be represented as y, form =4,1=2, m/=0, ie. dd-orbital. ‘The three quantum numbers (n, J, m,) derived from quantum, ‘mechanical concept also have classical analogue but the two quantum mechanical spin states have no classical analogue. ‘The plane and point at which zero electron density exists (ie., y=0)is known as nodal plane or nodal point , e.g, the probability of find electron between Is and 2 s-orbitals ‘or between two lobes of p-orbitals is zero, ‘An orbital with quantum number 2 and / possesses : Angular or non-spherical nodes Radial or spherical nodes = n — ‘Thus, total nodes in an orbital =n ——1+/=n-1 For one electron systems (an atom or an ion) the energy of ‘orbital depends only on the number of nodes, i.e, on n and which means not on fof m. I therefore, in H-atom or He” energy levels of orbitals ina shell are same, i.e, energy level of 3 =3p=M. As r approaches zero, the wave function vanishes forall “orbitals except the s-orbitals, thus, only an electron in 1 s- frbital can penetrate the nucleus, fe, have a finite probability of being found right at the nucleus, Actually these rules were framed to explain the experimental facts. For example Pd was found diamagnetic and thus its configuration was written as 4d" and not 4s*.4p* 4, 5s Write configuration of atoms up to atomie number 57 and note the exceptions. No new rule is needed for them. Some notable exceptions in writing eleetronic configurations are: ND: [Krad Ss‘, Ru: [Ke}1d'5s' «Rh: [KrHa Ss ! Pa: [Kr]4a" Pt: Ke af “sds * Au: [Xe] 4" 5d"%6s! “The outer shell electrons are often referred to as valence electrons. The electrons in the inner shells are called core electrons.8 ‘The energy of atomic orbitals for H-atom or He"is (asthe * energy depends on the value of n): p <38= 3p=3d< ds= p= dd = Af * The energy of orbitals other than H-atom depends upon n + | value and varies as: 152s <2p <3s <3p Cu + Cu However, 2CuJ., is more stable than Cul, because. vis strongest reducing agent among halides and thus, Cul, shows redox change as 2Cul, Cu J 41, Whereas, CuCl, is more stable than Cu, . Compton Effect: Compion allowed the monochromatic A-rays to fall on lighter elements such as carbon and noticed that scattered X-rays have wavelength larger than incident X-rays In other words: Ascot > Aas ae OF Exctnxen > Basta ‘This phenomenon of increase in wavelength of X-r scattering from the surface of light element is known as ‘Compton effect. The scattering of X-rays is due to interaction of photons (X-rays) and electrons and thus, supports quantum theory of light and illustrates uncertainty principle. Furthermore X-rays deflected by larger angles show a loss of larger energy. ss after X-rays = Xray] | Coltimator Incident slecton Bromstralong Blatcity ‘Seateed Photographic Fin Inelastic Seaterd Electron Figure: 84 SEE Main and Advanced Chapter-wise Solved Papers: Chemist ‘About X-ray photon he Energy of X-ray photon = hy Momentum of X-ay photon = Rest mass X-ray photon = 0 Ah eA Dynamic mass of X-ray photon Duane-Hunt Rule: inimum wavelength of continuous X- he wv ray spectrum 2, ‘Maximum frequency limit of continuous X-rays spectrum ov Aun Moseley’s Law: Frequency of v of characteristic X-ray spectrum Vv = a(Z—a) Where, @ and oF are constants for given radiation, Bragg’s Law: ‘The directions of maximum of X-ray. 4iffracted form crystal 2dsin @=n An =1,2,3,..) Intensity of X-rays transmitted through a thickness dof the le (k= a constant fora substance) Where, material = Crd’, wave length, thickness, C constant, atomic number. X-ray continuum ration (remsstahing) Characteristic Keays || ry roma. [Sen D204 6 ws Oe Wavelength (an) 7 oe 08 10 ‘Wavelength (am) Figure: 85 Xerays of wavelength TA-I00A. Wave-length of X-ays is ofthe same order as fare electromagnetic waves spacing between erystal atoms, hence X-rays may be used for study of crystal structure,Atomic Structure 9 * Bromsstrahlung or Continuous X-rays are caused due to deceleration of bombarding electrons in the electric field of heavy speetrum has a short nucleus, Continuous elng ini Rend fr = 25 opto ity + Characteristie X-ray is produced due to jumping of electrons form higher to lower vacant shells in atoms of heavy substances. Screening constant, for K., = radiation of all elements. * Keelectrons: They are very close to nucleus: play an important role in the production of characteristic X-ray spectrum. Atoi numbers and are never fractional. je Number: Atomic number and mass number are whole + Number of Neutrons = Mass no. ~ Atomic no, INo. of p x its mass + no. of neutrons its ‘mass + No. of e" x its mass} ‘= Mass loss duc to binding energy. Neglecting small masses of * e* and assuming proton and neutron of nearly | amu each, one can have atomic mass = ‘mass number. + Atomic mass 1 Relative atomic mass: The weiive atomic mass of an elements the mis of a tom of the element eave ‘one-twelfths the mass of one (C"?) carbon atom where mass istakens [2m Atomic mass: The average isotope mass Average tomie mass A= 2A% Dra 9% of isotope x Relative atomic mas of isotope 4% of MxRelave omic mis of Isotope + 100 Note * Both atomic mass and molecular mass are just ratios and hhave no units. Accurate determination of atomic masses and their relative abundance of the isotopes was determined using Aston's ‘mass spectrometer. = Actual masses of atoms are not equal to the sum of the ‘masses ofp, n and e present init. Aufbau Principles: The electronic configuration is written on the basis of the electrons in a poly electronic atom are filled ‘one by one in order of increasing energy level. eg. |H: Is iscorect 2s! is wrong. Because, energy level of 1s < 28 ‘Hund’s Rules subshells) it is preferred to assign electrons to empty orbitals, rather than pair them in a particular subshell, because the former arrangement leads to lower energy level. In filling a group or orbitals of equal energy (or ‘Same spin of ‘unpaired electrons in sub-sub shell also gives rise to lower energy level eg, .N:For 2p" TATA] sseorest TATA] J is wrong (statement a) TTA T 1] is wrong satement >) (a 41) rule: The subshell with lower values of (n + 1) possesses: lower energy level and should be filled frst. eg, 6K: Is?,287.2p *3s 3p Sd ' is wrong Is',25"2p £38 3p ‘ds * is comect. of 4s=440=4, of 3d=342 ‘Thus, 4s should be filled frst. If (a +1) is same for two subshells, the one with lower values ‘fn possess lower energy should be filled first. Is!,2s2p *3s 3p As tp | is wrong, Is! 25°2p%3s"3p".3d4s? is comect. of 4p of 3d ‘Thus, 3d should be filled first nof 3d 3 b. Paschen, > 3 Lyman, 0 Balmer, 20> 2 FF) The de Broglie wavelength (%) associated with a photoelectron varies with the frequency (¥) ofthe incident radiation as, [vp is threshold frequency -|JEE Main 2019] l Wo a doe bre —— o9 L L che de ww 23, What is the work function of the metal if the light of wavelength 4000 A generates photoelectrons of velocity 6x 10° ms" from it? (Mass of electron =9 x10 kg Velocity of light = 3 x 10" ms" Planck's constant = 6.626 10 Js Charge of electron = 1.6 10°" JeV") [JEE Main 2019] a.09eV e21eV b.40eVv a3.16eV 24, The upper stratosphere consisting of the ozone layer protects us from the sun's radiation that falls in the wavelength region of: [JE Main 2019] 600-750 nm b.08-1.5nm ©. 400-550 nm 4200-315 nm 25. If the de Broglie wavelength of the electron inn Bohr “orbit in a hydrogenie atom is equal t0 1.5 xa(ag is Bohr radius), then the value of n/zis: [JE Main 2019] a.10 b.0.75 «040 4.1.50 26. The number of orbitals associated with quantum number L a=5.m, [JEE Main P-1 2020] als b.25 au n. Gen rHome=Ry \ | Select the correct options regarding this formula for Balmer series. [JEE Main P-1 2020] ayn (B) lonization energy of H atom can be calculated from above formula © Bogan form: = 3. (D) If 2, decreases then spectrum lines will converse. aAB BCD cA&C ABCD2», 30. 31. 32, 33. 34 36. Determine Bobr's radius of Li™ (Bohr’s radius of H-atom = a) jon for n [JEE Main P-1 2020) an ye 4 3 a. a 1 3 9 Determine wavelength of electron in 4* Bohr's orbit? [JEE Main P-1 2020] a. dra, b. 2na, ©. Bray ‘The elecwonic configuration of bivalent Europium and trivalent cerium respectively is: [JEE Main P-1 2020] (Atomic Number: Xe = 54, Ce = 58, Eu = 63) a. [Xe}4f" [Xel4f" b. [Xe}4"° 6s", [Xe}st" €.[Xel41"6s", [Xel4f'd!6s" d. [Xe]4t”, [Xe]4'Sd6s" ‘The number of subshells associated with and 2 quantum numbers is: [JEE Main P-11 2020) a6 bs 4 2 ‘The atomic number of the element unnilennium is [JEE Main P-I1 2020] b. 109 4.102 ‘Consider the hypothetical situation where the azimuthal quantum umber, 1, takes values 0, 1, 2, where n is the principal quantum number. Then, the element with atomic number: |JEE Main P-11 2020} nel, 4. 6 has a 2p-valence subshell bb. 9s the first alkali metal €. isthe first noble gas, 4.13 has a half-filled valence subshell The region in the lectromagnetic spectrum where the ‘Balmer series lines appear is: [JEE Main P-L1 2020) a. Infrared b. Microwave e. Ultraviolet d. Visible ‘The shortest wavelength of H atom in the Lyman series is| ‘he The longest wavelength in the Balmer series of He’ is: [JEE Main P-1I 2020] ony 36, Shy a2 aS Ss oO 5 In the sixth period, the orbitals that are filled are: JEE Main P-11 2020] a. 65, Sf, 64, 6p bi. Gs, Sd, SE, 6p €.68, 6p, 6d, 6F 4.68, 4f, 5d, 6p 2. Given 37. 38. 39. 40. aL, SEE Main and Advanced Chapter-wise Solved Papers: Chemist ‘The correct electronie configuration and spin-only ‘magnetic moment (BM) of Ga" (Z=64), respectively, are: [JEE Main P-11 2020] b. [Xe] 5f” and 8.9 4. [Xe] 4f7 and 8.9 a. [Xe] 5” and 7.9 e. [Xe] 5f” and 8.9 ‘The correct statement about probability density (except at| infinite distance from nucleus) is: [JEE Main P-1I 2020] a. It can be zero for Is orbital bi. It can never be zero for 2s orbital ¢.It can be negative for 2p orbital 4. It can be zero for 3p orbital P is the probability of finding the Is electron of hydrogen atom in a spherical shell of infinitesimal thickness, dr, at a distance from the nucleus. The volume of this shell is 4ze°dr. The qualitative sketch of the dependence of P on ris [JEE Main P11 2020] a? ba? o 7 ° ol ary o 7 ° 7 ‘The correct statement(s) regarding the binary transition ‘metal carbonyl compounds is(are) (Atomic numbers Ni=28) [JEE Main P-11 2020] a. Total number of valence shell electrons at metal centre in Fe(CO), or Ni(CO), is 16 bb. These are predominantly low spin in nature € Metal-carbon bond strengthens when the oxidation state of the metal is lowered 4. The carbonyl C-O bond weakens when the oxidation state ofthe metal is increased For He+ the electron is in orbit with energy equal to SAV. The azimuthal quantum number for that orbit is 2 and magnetic quantum number is 0. Then which of the following ivare correct. [EE Main P-11 2020] a. The subshell is 4d, ». The number of angular nodes in it is 2. ¢. The numbers of radial nodes init i 3. 4. The nuclear charge experienced in n = 4 is 2e less than that in n= 1, where eis electronic charge.‘Atomie Structure a2, 46. Ifthe Thompson model of the atom was correct, then the result of Rutherford's gold foil experiment would have Been: 47, According to Boht’s theory, Ea a. All ofthe a-particles pass through the gold foil without decrease in speed. [JEE Main P-I 2021] . a-Particles are deflected over a wide range of angles. ¢.Allla-particles get bounced back by 180° d. -Particles pass through the gold foil deflected by small angles and with reduced speed. Consider the following pairs of electrons [JEE Main P-1 2022] @@ n=3 my =Lm, Gi) n=3,1-2.m, “Lm, ()@ n=3, Gi) n=3.1=2.m, =4m , = (0) @ n=4,1=2,m, 2m , Gi) n=3,1-2.m , 2m , ‘The pairs of electron present in degenerate orbital is/are: a.Only (a) b.Only(b) €. Only (b) de (b) and (c) ‘The energy of one mole of photons of radiation of ‘wavelength 300 nm is [JEE Main P-1 2022] (Given: h = 6.63 « 10 Js, NA = 6.02 10 mol x 10*ms*) a, 235 I mol! b. 3251 molt €. 399kI mol! 4. 435 kI mol"! Given below are the quantum numiers for 4 electrons. m,=+1/2 [JEE Main P-11 2022] 0=1om = 1m =4172 ‘The correct order of increasing energy is: aD1 48. Match the entries in Column I withthe correctly related quantum number(s) in Column TL [SEE 2008 P-1 Column 1 Column (A) Orbital angular momentum 1. Principal quantum of the electron in a number hydrogenlike atomic orbital (B)A_hydrogen-like one 2, Azimuthal electron wave function quantum number obeying Pauli principle (©) Shape, orientation of hydrogen- like atomic orbitals (D)Probability density of electron at the nucleus in hydrogen-like atom AAS 1B 12,350 1,4: D-+ 12 b.A2; Bo 4, C+ 1,2,3;D+1,2,3 6 AS 3B 13,652; D5 1234 GA 1,3, BF 123.4; C2; D> 123 size and 3. Magnetic quantum number 4, Electron spin ‘quantum number For Question No. 49 t0 51 ‘The information are given in the three columns of the following table. ‘The wave function, yq, m/s a mathematical function whose value depends upon spherical polar coordinates of the electron ‘and characterised by the quantum numbers n, and m ¢. Here, ‘ris distance from nucleus, @is co-lattude and @ is azimuth, In the mathematical functions given in the Table is atomic number and a) is Bohr radius, [WEE Adv. 2017 P-1]os SEE Main and Advanced Chapter-wise Solved Papers: Chemist Column t Column tt (@) 1s orbital @ Vaca, 2 IF (2 | y ‘| io > )2s orbital (il) One radial (B) Probability node density at releus «<4, (11H 2p, orbital GY, ry, (©) Probabitity 2 density is 2) maximum — at - a, nucleus axe (IV) 3d2orbital —iv)ay-plane is (D) Energy needed 4 nodal plane to excite electron fiom n= 2 state ton=4 stateis 7 2 ‘energy needed 10 excite electron times the from n=2 state ton=6 state 49. For He* ion, the only incorrect combination is: a @O b.d GiB) 2) 4.) (ii) (©) 50, For the given orbital in Column I, the only correct ‘combination for any hydrogen-like species is: a. (i) (D) bay iv (ID Git) (A) a. a (a) 51. For hydrogen atom, the only correct combination is: a.) @ (A) b.() (iv) B) MOO 4.) For Question No. 52 to 53 Match the Columns: HEE Adv. 2019 P11] Column 1 (Column I (A) Radius Lent (B) Angular momentum — 2, (©) Kinetic energy 3c? (D) Potential energy dean! erg 52, Which of the following is correct? avo bAs2 ASS @A53 83. Which of the following is correct? a.Do4 boo eC>2 4D33 Statement/Assertion and Reason ‘54. Given below are two statements: Statement I: Rutherford’s gold foil experiment cannot explain the line spectrum of hydrogen atom, Statement Il: Bolu’s model of hydrogen atom contradicts Heisenberg’s uncertainty principle. In the light of the above statements, choose the most appropriate answer from the options given below: a, Statement 1 is false but statement Il is wue, D, Statement Lis true but statement Is false. ¢. Both statement I and statement IT are false. 4. Both statement [and statement If are true. Paragraph Paragraph for Question No. 55 to 57 The hydrogenclike species Lis ina spherically symmetric state $,with one radial node. Upon absorbing light the ion ‘undergoes transition toa state S». The state S » has one radial node and its energy i equal to the ground state energy of the hydrogen atom, [JE 2010 P-1] 585. The state Sis: als bids 2p 3s ‘56. Enetgy of the state S,in units of the hydrogen atom ground state energy is: 8.0.75 b. 1.50 6.225 4.4.50 ‘87. The orbital angular momentum quantum number of the state S, is a0 bi 2 a3 Integer and Subjective $8, The maximum number of electrons that can have principal quantum number, 8=3. and spin quantum umber, m, [JE 2011 Pt]‘Atomic Structure os 59. The work function (g) of some metals is listed below, Eg (as indicated in the figure) in kI mol ~', for d = dy at ‘The number of metals which will show photoelectric Which the electron-electron repulsion and the mucleus- effect when light of 300 nm wavelength falls on the metal nucleus repulsion energies are absent? As reference, the is JE 2011 P-t] potential energy of H atom is taken as zero when its Meal [o[N[K-[M CTR [RW election and the nucleus are infinitely fr apart. wens [24 [23 [aa] a7] as] a] a os 8 Use Avogadro constant as 6,023 < 10 mol [JEE Adv. 2020 60. The work function of sodium metal is 4.41 < 10° J.1F photons of wavelength 300 nm are incident on the metal, the kinetics energy of the ejected electrons will be (i= 6.63 « 10 Js; €= 3 « 108 mvs) 107", [JEE 2011 P-t] 61, The atomic masses of He and Ne are 4 and 20 a.m.u respectively. The value of the de Broglie wavelength of | He gas at ~73°C is “M" times that of the de Broglie wavelength of Ne at 727°C, Mis: JEE Adv. 2013 P-1] Internuclea distance (d) —> 62. In an atom, the total number of electrons having quantum 67. ‘The Mass of Li * is 8.33 times mass of proton Li" and 1 proton are accelerated through same potential difference. smambera= 4m | = andm, * Then ratio of debroglie's wavelength of Li ™ to proton is (EE Adv. 2014 Pt] xx 10" Find x EE Main P-t 2021] 63. Not considering the electronic spin, the degeneracy of the 68, Consider a helium (He) atom that absorbs photon of second excited state (n = 3) of Hatom is 9, while the ‘rvlenit $90-mm. The change nthe velocty tn em degeneracy ofthe second excited state of H” is ©") of He atom after the photon absorption is__, HIER Adv. 2015 PT] (Assume: Momentum is conserved when photon is absorbed. 64, (a) Calculate velocity of electron in first Bohr orbit of Use: Planck constant = 6.6 10 Js, Avogadro number hydrogen atom (Given r=a5) =6 x 10" mot, Molar mass of He = 4 g mot!) (b) Find de-Broglie wavelength of the electron in first Lyre Ady. 2021 Bohr orbit. (© Find the orbital angular momentum of 2p orbital in 69, When the excited electron of a H atom from n= 5 drops terms of h/ 2x units WEE Adv. 2015 P-1] to the ground state, the maximum number of emission lines observed are __is. [JEE Main P-11 2022], The 1°, 2"! and the 3% ionization enthalpies I,, 13 and Is, of four atoms with atomic numbers n.n+1, n+2.andn+3. 79, The minimum uncertainty in the speed of an electron in ‘where n < 10, are tabulated below. What is the value of n? [JEE Adv. 2020 PII] an one dimensional region of length 2a (Where ay = Bohr radius 52.9 pm) is__km s"', JIEE Main P-II 2022] Ate number |__Tortaon Eathaipy Comm) _ (Given: Mass of electron = 9.1 10" kg, = ar an = Planck's constant h = 6,63 10" Js) aT RT SE wie nea 196 62 w0 aed 7 TST TS Or figure below is the plot of potential energy versus ‘internuclear distance (d) of H2 molecule in the electronic round state, What is the vale ofthe net potential energy