COORDINATION

COMPOUNDS

RAFTAAR 2.0
DAY 5
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 *
TOM. MORNING
PART 2 -> release
recorded
format
-

PLAYLIST ADD

TOM.
* 12M ORGANIC
40-50 MARKS

ss
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
YALGAAR FREE TEST

SERIES

· 3St MARCH -> SOLUTIONS X

NEXT TEST KINETICS *

LECTROCHEMISTRY
=

COORDINATION I

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 NEET 2025
-
--

---

-
----

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
MOLECULAR↑
OR ADDITION COMPOUNDS I

mind
simple
When 2 or more salts are and

crystalised,
addition
then
compounds formed
are

*
Double Salt Y

coordination
compound
* X

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 NICERT
carnalitte
=

I A

Mgna 6420
KC.MgUc.6420
KCl I I -
= -> =

I
Potash Alum (Phitkar(
⑦
K2SOY I Al [OyLz +2420- kSOY Ala [ou), 244CO
= -
-

Mohr
I
salt
*
FesOn+WHSO+640-FesOn(r)SOYbrg
I I

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 SALT
DOUBLE COORDINATION COMPOUND

Stable in solid state but

*
Stable in both solid
*

as
---- -- -
=>

dissociates in state will as state

-> aqueous - aqueous -

-(a.MgC,640(s) - [Fe(rs] (s)

H20 ↓Has
I + 2
a
nxt + EeGNIs]"-
k
Mg STABLE
->

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 SALT
DOUBLE COORDINATION COMPOUNDS
ions
Gives
* the
=
testall
of -
Does not
*
give the test
of
its ions
C. MgC2.6420
L 420
-kyEe(NIs]
I
Test 420
k
+ Le

+2
nx+ +
[FeCNI]" sTAE
Mg test
+ we

ce +ve test Feth Test---ve

the test
CN- Test - -
ve

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

COORDINATION COMPOUNDS
sphere
coordination
-

Kn(Fe(N),7-
number
codination

Ionisation
central Ligand
sphere metal
Mounter
&

von

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

Ionisation Central metal
sphere electron
accept
EMPTY
ORBITALS
-
->

Jovisable part
-
-
↑

lewis
a nd
d-block element
generally
Coordination
sphere
Non-ionisable
-> part Coordination
Number

how pair
VNIMP
->
&

SHERO HEERALAL)
Number
-
of ->

metal
Legands election donors accepted by
-

atom/ion.
-

Lewis at
t

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

* SOME IMPORTANT TERMS

· Homolepticcomplex
->
·
Yy(e(wIs]
type of big
and
Only
one

Heterolepticcomplex
Have more
&
than one
type Co(NS) Mda]
of Ligand
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
2) Homonuclear
complex
one rential atom
Having
kee(wIs] o GNUsInGa]
Metwnuchas compen
central atom
Having
more then one

=(0),co-ancusiuI Soula

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

3) Perfect complex
which coordination does not dissociate
In
sphere 4
kn[e(w)s] [e[wis]
-

- uxT+
STABLE

Cd CN-
Imperfectcomplex X
wordination
In which the dissociates
-
-

x[Cd(cNin] - +
(d(Nl]-
UNSTABLE

1 +
u
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 COORDINATION POLYHEDRON
A ->
To minimise

*
Arrangement of Ligand
around
repulsion
--

rential atom
>

Mch
Linea
M22 L -

L
M23
-
MEL
Trigone
Plane
n -

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 L
- My Titahedral
d
M

↓ 4*n
L

missg.
L
A Man
Pte

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 L
A 428 octanedial
L ↓ L

**
->
- M
A
↓ ↑ h

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

* LIGANDS IMP Y

DAANVEER
electron dono
*

* Lewis Bate
- =>

Neutral,
vely charged, rely charged
*
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 *
DENTICITY
*

> No.
of a donated by ligand
MONODENTATE - Donates 12P
-

BIDENTATE
-
-
11
2LP

TRI
->
-> ③a
TETRA - ④ 2D
PENTA ->
⑧LD
5

HEXA - ⑩P
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 MONODENTATE
A AMBIDENTATE--
Y
has Donor site, but can donate
which a
from
site
one
only;
CN= NC NO2 ONO
y eq
SCN- NCS
o

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

A
FLEXIDENTALE-NE
Ligands
=
which can
vary denticity soz-
Coz2
-

Bidentate "
· Io

sOy O

Morodintate I -o
/
O - MONO

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 Ligands
* Monodentate donates -
ALP

NEUTRAL

M wa-ethylene
=

NEUTRAL

-420- aqua Nas-oi-Hydroxylamine

00 ⑧o

NHz- ammine DONOR ATOM Less

M
-
-

CO
--
->
carbonyl
--

NO ->
nitrosys
PPh3
O

-
->
plunge phosphine
⑮T-
-N Pyridine a

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

ANIONIC
0
ido 8
-

Ordo
.
④.
ANIONIC >
-

>

Halido
3
Nitrido
-

x --> N ->

F- ->
fluorido M42- Amido
a chloido
-

->
2-
NH imido
Be- bromide -

I -> Jodida N3-- Azido -

or--
hydronido CN--Ganido or
Ganido-c
2-
02 Peronido
NC--Iolyanido cyanida
N
-
or -

AMBI
Or superoxido DENTATE

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

NO2--> Nitrito -M

ONO--> Nitrito -
O

SOg--> sulphito Flexidetate

SOY-- sulphelo
-

2-
CO3 -> carbanato

SCN--thiocyanato-s
NCS--thiocyanato
- N

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

CATIONIC
BROWN RING TEST
->
Nitrosonium
[Fe(M205 I
NOT ->

NO son-
-
-

⑧
Tz-NH2- Hydrazium
d
-

↓
NOzt-> Nitronium + 10 1
+

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 2LP
* BIDENTATE-> Donates
-
-

Ethere-1.2-Diamine Elhylene
Diamone
-
⑰)
or

CH2-CH2 CHELATING
I

wr,
· aNa
GIGANA

CHELATING
M LIGAND
-

(On)2-
2 - -

2) Ocalato Cou
0 O

o - - -8
DONOR ATOM -- ve CHARGE
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

3)
Cycrato (gly) &08
11

42-CH,-c- o
) Dig glyomato
Dimethyl
i
CHz-c
=

4n
=

Mz
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

NOTWA
Scarlet red

*
Ang firms ->
a
conquerwith
init
Nilding a
P- 4.00..-0
membered
Grings
I
15
Mz -
C N
=

⑥ N c =
-

M3
y I 6 membered
15
inges
a
+2
⑤
NI
d
.
-
*
A
N
Mz
=
C N
= -

My
-

1 ⑧ I
active
↑

Oftically
*
O.Jeo-
Square y
0
*
-

Plane
&

- H-Bonding
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

3) Tridentate
donates SLP
- (DienI
Triamine
Dulhylene
M2-CH2-CH2-N-CHI-CH **2
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 4) Tetadinate
a p
donates

(Trien) Triethylene
Tetramine

&O 00

M4-CH,--MI-in-c,-LNGC-My-N e
⑧O

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

5) Penta dentate donates 52P
CHZC00-Actate
-

3 -

Ton
EDTA

Ethylene
- -
Diamine
Triacluto
->

W3C00 -M3100
I
M
/N-CH2-CH2
-

H cc00-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

6) tendentst -> donates GND Y
EDTAY-

Diamine Tete actoto

Ethylene
C3100-
I
-M3200
N
N CH2-CHz
-
-

/
-, 200-
C1,00

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

A CHELATING LIGANDS
M :
NH3

Ligands form rig;

·
which

Dentity, 2

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 *
I
⑦ Coordination
Number 8-

No.
of
up
accepted by mutil atom li
[No.
CM
ofhigardxDeutnity
=

Oxidation
Number

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

Ks[Fe(NI] ((wrsIn4282]
emono
&

3(+ 1) 6( 1) 0
3
=
-

4(0) 2(0)
x
+
+
+

x +
+ =

x +3
=

(N 6x1 6=
=
(N (4x1) + 2x1)
=

6
=

e So Cenla Bra]c NiColy

&

x 2(0)
+
2)
+ -
1) (
+ -
1) 0
=

x 4(0)
+
0
=

i
⑱3
(N 4x1
=

4
=

(N (2x2) (x1)
=
+

D
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 Number) I
I EAN
(Effective Atomic

EAM=Atomic -
ON+ 2 CN

Number

EAN 26 3 2(s)
Ys(e(w10]
+
-

- 35
(M = 6 x 1 0
=
CN =

3(+ 1) x
+
+
6( -

1) 0
=

⑰3 ON

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 E
* SIDGWICK AAN RULE (kr)38
next nearest
*
If
EAN is
equal
to number
atomic
of
is stable.
noble
gas
then that
complex
metal
carbonyls I
*
Applicable mainly for
Mn(2015
I NiCO)y I CM 5 =

(N 4
=

ON 0 =

ON 0
=

EAN 25 -
0 2(5)
+

2(4)
=

EAN 28 0 +
-

=35 unstable
=

=36 Stable
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

A IUPAC NOMENCLATURE

Name
*
--
of
cation is
-
written first and then
-
anion
-

oflegard is
⑧

in name
wrleng complex
⑧
-

* Whell -
- . ->
-- - &

alphabatical order.
E & ~

first
written in
> -

*
Prefines di,
-
tri etc.
->
are
--
used.

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 of ligands already
YOWA: have words like
If
- names
- -

like
di, bi, tri, tetra,
-
-
then use
special words

tetrakes used
bis, this, are
-- -

CH2-CH2
en
enja Bi
-
1 I

NM2 NM2

Diamine
thylene
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
*
Naming of central atom
cationic
Mital If complexis

or Neutral
- complex
>
If is
Anoni
↑

G Chromium - Chromate

Manganese- Manganale
>

Mn

Fe Iron Ferrate

Co Cobalt Cobattate

Ni Nickel Nickelote
C
coffer Caprale
--

zn Zinc Zincate

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

*
Naming of central atom
is Cationis
Mital If complex
or Neutral
If complex is
Anionic

Pd Palladium Palladate
Pt Platinum Platinate

Ag Silver
Argentate
An Gold Aurate

rig Mercury Merculate

Ti Titanium Titanate

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

Ovidation
*

Number
-> of metal justafter
is written
-

in numbers
the
naming of central metal roman
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 counter Ton Counter on
*
t

is [ENIs]
Nahi
Number
specify
W
cation
Anion
Karenge;
(I
potassium
henacyanido ferrate
[Ws)] us ANION
not
a
-ligand
CATION

Hexaammine nickel (I) clouds

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

ECwI]3-Y
ANION

Menacyanide ferrate (III) ion

egation (ptaisI 24*+ [Pt4,]

-

Al D

Hexa chlorida (in)

platinate
Acid

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 SOME
A IMPORTANT COMPOUNDS

FERROCENE
c atoms
Hefti c i t y No. of
* -

involved in :
donation Sandwich
Fe(y5-2545)a -

Fe
compounds
a)
eta :

1 I:yofentanye
⑦

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

G(n"-C4)2
*

--

12 I ⑧

-- Sandwich
Csto-Beugen G
compounds
->

--

II
It
-

CHI

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

Zisse's
*
--
k(Pt,
set (un)] ihyum
-

-
C

Pt
awar
=
Cr 2
y

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 I Co, NHz, U
# WERNER THEORY

PRIMARY -> OvidationNumber

**
-
VALENCY

SECONDARY VALENCY
*

-> coordination
number

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 Co
*
-> (N 6
=

M43- Bahar Nahi

Targa
*

Co(N43], Us
* *

Co(NH315 C5 Co(NuglnGs
*

Kors(o] as [0(NMs),U] da [Co(NUs)aUa] c

+34- +
Go(us),] Cowrs)sc] +a [Co(NuslaCa] ce

IONS 2
IONS= 4 IONS 3
=
=

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 ->
> IONS
Find order van't Factor?
of Hoff
-
&

ab > c > d
a) Co (43), 43- [ongIs] us IONS 4
=

b) Co (435Gy ->(CNs),n] d2 IONS= 3

x) co(W43) nUs -
(o(s)n42]U IONS 2
=

d) CONUS)sCs-> (wis,37" zons =

0

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

How
many
moles
of Age are
found
when
*

reacts with?
AgNOz
Co(H315 C3
Me
(wrsl- a]
unEng Age

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 VALENCE BOND THEORY
Y (N 4
=

A
S3-> TETRAHEDRAL

Hybridisation
-

->

dsp2-
-

SO. LANER
aometry -

Magnetic behavious (M 6
=

->

Sp3d- OCTAMEDRAL
(n+a)
Magnet Moment
-> (=
BM

Colour
d's- OCTAHEDRAL-a
of compen
->

Para coloured
Dia-Colowless

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

STRONG
*
FIELD LIGAND
(SFL)-PainingHogi
* Donor atom
-
=
Carbon or
Nitrogen if required

WEAK
*
FIELD LIGAND
(WEL) ->
No
Paining
* Dond
--
atom anygen
or
Halogen

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

icculaTysde
CN-
regard
* CM 4
=

SFL-Painigv
~
oblats I

e reguard --

*I II In I I
3d us up
After Ligand
DIAMAGNETIL
Nith [Ar] Sdo us" dsG2 sq. Plane;

M 0
= conos
LESS
44/*d/41- ~
vul
3d 41 YP
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 GoBenIe(N-
ene
& Ligand
WFL - No
Paint
* 1*1*14 I I
3d 41 YP
and
After big sp'-tetrahedral
Paramagneti
* Cat 3
[Ar] 3d" us" ->

n4
Coloured
=
=52) Buy
M n(n
+
* 1*1*14 v ~ IVM
M E4 BM
=

3d 41 YP
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 GoCwngls]
CN=6 NNzeSFL
& ·

Parry
W

LOW SPIN
Cats CAr] 3d' us"* COMPLEX

* 1*1*14 I I I 11 I
3d 41 YP Yd
abitat
After Ligand
Inner
dsp3-OAUEDRAL complex
Diamagnetic
↑ I (0108 41518 111 I
Colorless 3d 41 YP Yd
M 0
=

n0
=

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 decreases
how
spin If of urfaind
* no

remains
of urfaind
I
spin If
no.
high
*

same
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 NCERT
NOTWA

Pt and Pd with
foun
CN 4
*
always
=

-
-
- O

square
Plane
complex aspective of legard
2

I [tau]
-

Plane
Sq.
->

2t

⑦[d(n(n) ->
sg. Plane

A ovulate
with
in behoves as

SFL
I

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 WVNIMD

CRYSTAL FIELD -

THEORY

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

POINTS 8 -
Y
-
--

is
A Intraction
w M and L
electrostatic;
Point
Aniouic
*
regards charges
-
- -

beards-Dipole
&

Nutal
-
⑧

Central metal d-orbitals Nose

*

orbitals
-
degeneracy; -
-

Degenuateorbitals
degenuate having gy
some
5

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 11 I I orbitet
degenuate
5

Axial Now Axial

duydz day dyz d22

It M

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

CRYSTAL FIELD SPLITTING ENERGY CN 6Y
=

octabdial
-

ligands
-

In octahedral
*
-
complex, approach
central metal towards
--

ai
arbitals
--

A ·: Axial
M26 y
Le Le Idx2y: d24
&

L ↓ bx
fall more
repulsion;
Le
L L
Z

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 E
↑

Do=Cystal splittingEnergy Field

Enugy
- diye Axial

e
BARI CENTER
I 11 I
---jonytsoad
degenuate orbi y-z
. . . . .

Ard-0.
t aas-....
. . . .

"'s
..... Now axial
(In
presence ligand( 1 I dz*g
↓

I 1 I I
day ayz
orbital
degestate
-

5
(In absence
Ligand)
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
A HOW TO CALCULATE
CFSE

CFSE= (R x0.610) -
(yx-0.410) + up

ein
x ->
No.o eg
e-in
y
- No.
of &
tag
Mo. Pau
n e

of
PC
Pairing engy
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 I
SFL WEL
a
I
eq I
eg
↑11/1
0 Pai
tagego tagego
↑I tag ↑1 I tag
10 (0x0.610)
= + (14-0.410) +OP

Do = =
0.410

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 I
2 SFL WEL
d
I
eq
↑ 1811 1
Pai
tagegi Egegol eg
0 ↑ 181 tag ↑141
-
tag
CFSE (x0.610)
=
+ (2x-6.410) or
+

CFSE =
=
0.0 10

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 I
SFL WEL
a
I
eq I
eg
↑

0
I141
Pai
1
tag ego tagego
* 1** tag * 1* * tag
-

(x0.610)
=

- (3x-0.410) to Pan

CFSE=-
1.210;

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 lower I
Always
*

I PairingEnugy
(P) energy prefered
is

· DoT PSFL

Preferred l
Paining ogi
· Do P WFL

Prefined
-
PainingNahilagi
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 paigge
No
pairing

I
SFL WFL
an
I
eq *I
eg
* I /*/*1 tag "eg. tageg"
o pair
*** tag I4 14
I

·Pair
*
①Pain
tag
CFSE =
(0x0.610) CFSE =
(1X0.610) +
(4x -0.410)
+
(3x-0.410) + OP
+
(- 0)P -

=
0.6A0
CFSE= -1.610+ P

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 I
SFL WFL
as
I
eq ↓ In
eg
I /4/4/*
tagbego equ
↑

Di
tag
/Nd/ tag It i
Spai
*
tag
Opai
CFSE (0x0.110) +
=
(x0.610)
CFSE=

(5x -0.410) or
-(3X
+ =
0.4

(2-01D
CFSE=-2D0+ 2P CFSE 0
=

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 I
SFL WFL
ab
I
eq & Is
eg
MNM*/* tageg" tag"g
Pai
↑/**d tag I I tag
*

3 Dai
·Pai
CFSE=(0x0.610)
CFSE(2x0.610) t
=

+34D e
(4x 0.410)
- +
I
CFSE=- 2.410+2P I-P-o
RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 I
SFL WEL
d
I
eq I
eg
111 I

1 I tag 11 tag

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

↑
d'de ds do da de same
for
WIL and SEL

Sh
d5 d dT-diff for
and
d" WIL

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
* FACTORS AFFECTING CFSE8-

[FeC20)s][FeCOLs ]
2
↑ OXIDATION NUMBER
CFSE LON

2) GEOMETRY Otabechel Tithediah

CN 6
= CN 4
=

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

3) LIGAND

CFSE:- SFL WFL

4) Transition
metal series

CFSE: - 3d < 4d <5d

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
A COLOUR COMPOOND
OF

eg
[FiChaoo] it3 [Ar]3d"
voilet
↑
tag
d-d tansition
COMPLIMENTARY
Indab -
dab
en
-

COLOR ~Ba
R. Y
⑧
>
dem

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 CFSE FOR TETRAHEDRAh
E
* In Tetrahedral
complex, aigard approach
central atom in bw asis
i " Now anialaibital

(day dyzdzn)
A
-

&

<
7
face repulsion
more

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 At= CFSE Tetrahedral
a
of

Enugy
BARI CENTER
---
-- -

I 11 I...--
e5degreate orbitets
offer and presence
&

of Legand)
111 I
orbitets
degreate
5

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

NOTWA

there is no
In Tetrahedral
complex,
*

gavery (irrespectiveof bgard)

- ↑

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

A ISOMERISM
Same molecular
formula but
diff
*

physical and chemical

property.

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 STRUCTURAL ISOMERISM

1) HYDRATE ISOMERISM: -

Water molecules act as both

ligands and walk
of
crystalisation
⑦ [40)s] 4s (4,0=U] U2· 420

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

2) ISOMERISM
LINKAGE

AMBIDENTATE
* LIGAND

(CWM35Now]" [CNMs150No]
3
-
-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

IONISATION
3)
ISOMERISM
ions
Different
* counter are
present;

⑨ Cr (20)4 Ua] Be CrdncBrIc

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

4) ISOMERISM
COORDINATION

should be
Both
ratin and anion
complex
*

Ligand or central
atom
gets exchanged;
*

[Co(n)s] [GCs]

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 DONOR ATOM
SAME
STEREO
ISOMERISM AA
Bidentate
4I >Based on distance symmetrial
regard
01 > Based on POSICOS DONOR ATOM

A unsymmetrictBidetet
DIFF

M- metal
O

ABC DEF
Monodentate agand
Ligand

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

CN 4
=

TETRAHEDRAL

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

CN 4=

Plauer
Square
*

No OI

MAY MASB

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

MAzBa MABC

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

MABCD MAA)2

MAB2

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

CN 6
=
GEOMETRICAL ISOMERISM

Octahedral MAS
*

-
-

MAgB
*

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

MAuBz
**

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

MASB3
*

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

OPTICAL ISOMERISM
MAua
Case
--
8 -
Monodentate
Ligand MA5B
=Total
diff.
Monodentate
Ligand
xx 3
always optically
active
MAaBaca
Except MAYBC
MAuB
x3 =

MAzBaC

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 Cate 2 %- Bidentat
-

X rings, optically
-

TRICK :- Total 2
scie

except trans-[M (nTB2]

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

M(A)3 cis-(coona 42]
cis-(MAA)a B1)
MB)3

37
trans-(co(a0n) Uc)
[Cocen)s]
trans-(MEA) BC7

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247
 Anticancer
cis-plate
*

t (rsla 4n]
is

Wilkinson
calalyst hydrogenation
-

[Re(PPh3]sI -
alkene
of

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 dissociation
constant
Stabilly
and

M15
① M h
+

ya ko= ans
② MG + 2
-
M42 Ya (x2]
=

[M2][h]

③ Mas Ys=M]
[M22] [2]

3h3]ere
M +

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 B kxk2
=
XK3

stability constant

Higher
value
the
of
B More
=
is
stable
complex.
A

dissociation
constant-

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 *
I BONDING IN METAL CARBONYS 8-

# -
C
⑥

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 orbital
empty
in
carlongs
donates
fair
* so

of
Metal
forming BOND;
orbitst
Metal back donates
*
electron
pain
in
unpty
of
CO
forming a
Bown;

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

EFFECT SYNERGIC
OF BONDING

Blw
* metal and Carbon

BOY=> BE4 2) BLA

Blw carbon and

oxygen
*

BOH=) BEL=> BLA

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

 metal
Mov the-ve
charge on
*

is
Move
synergic Bonding

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

highest
I
2-0

I
Boud
length? -

) (Mncols] 2) GCoss]

3) [COL,]- 4) Pata
Nahi

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247

strongest
I

I
C-O Bond is
present in

①[Cols] 2) [e(075]

3) [C010] 4) He He Ha

RAFTAAR 25 days = 25 chapters t.me/neetpreparationadda247