Cereal Technology (1) Notes
Cereal Technology (1) Notes
Cereal science is a study concerned with all technical aspects of cereals. It studies nature of the
cereal and the changes that occur naturally and as a result of handling and processes. It is
meant to study nature of cereals and changes that occur naturally.
TYPES OF CEREALS
Cereals are rich in vitamins, minerals, carbohydrates, fats and oils and proteins especially if
taken as whole grains but when refined by removal of the bran and germ, the remaining
endosperm is mostly carbohydrates and lacks other nutrients.
STRUCTURE OF A CEREAL
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--Endosperm is the main part of the grain and mainly composed of starch (CARBOHYDRATES)
-Bran is composed of fibre, omega three fatty acids, vitamins and dietry minerals
-Whole grain cereal is a rich source of many vitamins, minerals and phytochemicals
-A typical cereal food is low in saturated fatty acids but is a rich source of polyunsaturated fats
including omega 3 linoleic acid, cholesterol free both soluble and insoluble fibre ,resistant
starch, source of carbohydrates, proteins, B complex, vitamins, minerals e.g iron, magnesium,
copper, phosphorus, zinc and good source of antioxidants and phytochemicals which help lower
blood cholesterol level.
PHYOCHEMICALS
b. Phytic acid- reduces diabetes and protect against colon cancer cells
MILLING PROCESS
a. wet milling
b. dry milling
DRY MILLING
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The cereal is cleaned and water is added to increase moisture content in a process called
tempering
The cereal tempers for approximately 1-3 hours allowing moisture to spread throughout the
grains
The moisture allows the grain to toughen for easy removal of bran and the germ
The germ is removed early to prevent the oil from mixing with the products
The coarsely ground material is sieved to completely remove any more of the germ and bran
then it is subjected to roller mills and particle size separation equipment.
WET MILLING
The cereal is cleaned and then soaked for 24-36 hours in warm water with sulphur dioxide
added
The grain absorbs the sulphur dioxide and swells. Native enzymes break down the kernel [bran]
The softened grain is then coarsely ground to free the germ from the endosperm,the germs are
then dried and pressed to extract oil
The ran particles are separated from the endosperm,the gluten is filtered and dried.The starch
is washed,vaccum filtered and dried.
The starch and oil are the most valuable products from wet milling.
   a.   The cereal grains should have a built body with a husks that are unshrinkled
   b.   Grains shouldn’t have holes
   c.   The cereals shouldn’t have foreign materials e.g stones,insect faeces etc
   d.   The cereal microbiological quality should be known to have low microbial count
   e.   Stored cereals should have a moisture content of low than 11%
   f.   The cereals should be found singly and caked
   g.   The cereal body should not have any dust
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WET MILLING
Differs in dry milling because it is a macesation process in which both chemical changes occur in
constituents of maize leading to separation and dissociation of the products.
-Drying temperature does not exceed 54 degrees Celsius because higher temperatures caused
some changes in cells preventing effective separation
2.steeping
-grain soaked in water for a period of between 28-48 hours at 50 degrees Celsius
-it is carried out in very huge tanks.Which with stand high acidic conditions.
Conditions of steeping
Grains absorb moisture to become soft,soluble solids leach out of the grain e.g proteins,simple
sugars etc
Steep water will be rich in soluble solids forming the steep liquor
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Presence of lactic acid bacteria thrive well in steep water and produces acids which interact and
affect the amino acids
Why ph is important
Actual uptake of water takes about 6 hours,other physical-chemical changes take place after
wards.
The reactions are ph dependant hence should be maintained at 3.9-4.1 to ensure presence of
sulphite ions and bisulphite ions to affect protein molecules in terms of hydrolysis.
The reaction causes the protein molecule to open up by breaking some linkages thus causing
release of amino acids which change the ph to counter the action produced by lactic acid
bacteria.
Change in temperature
If temperature is above 50 degrees Celsius lactic acid bacteria dies but if the temeratures are
below 40 degrees Celsius there is a likelihood of growth of yeast and other microbes to cause
fermentation to produce alcohol from the steeped maize.
Maize is coarsely ground with aim of releasing the germ from the rest of the grain
For effective milling maize is suspended in water, fed into the mill,brokened or opened to
release the germ and further procedures follow
Once grains are opened some starch is added into the mixture to adjust the density of the
ground material so that the germ floats while rest of the grain sinks
For complete separation the material passes through several cyclones normally four of them for
efficient separation of the germ
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Recovered germ is washed and dried to be used for oil extraction
Endosperm which is still suspended in water is coarsely filtered and the recovered endosperm is
re-suspended in fresh water
Recovered water is then evaporated to recovered starch which might have found its way to the
germ
Separation of endosperm
Materials that come out of the hydrocyclones contain protein,starch and fibre.These are then
passed through an entoleter mill
The machine operates on impact system which grinds the material into fine particles
The protein separation is easy because they are lighterbthan the starch,just like in cream
separation is effected by use of high speed continuous centrifuges.This can separate upto
70%pure protein but it is not good enough because the protein is still in the starch
Protein recovered are used as animal feeds while starch is dried and used for other purposes
It can be washed dried and sold as modified corn starch or simly as corn flour or treated to
produce modified starches
DRY MILLING
OBJECTIVES
Sequence of milling
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       Hydrostatics and colour separation
   b. Conditioning –loosening and toughening the germ allowing their separation from
      endosperm so that it cannot break
   c. Degerming –it is done in three ways
       Beall degerminator
       Roller mills and sifters
       Impact machines
   d. Drying and cooling
      Degerminated stock is dried to 15% dry of rotary steam tube at temperatures of 60-70
      degrees Celsius
      Immediately after temperatures are obtained, it is cooled
   e. Grinding
      Dried stock is sifted
      Separated material is fed into the middle
      Large and medium materials enter the first pair of break rollers while the fine enters the
      second and the third
      Milling is done on roller mills that are flattened on the surface such that there are 16
      pairs of rollers in a typical mill
      Breakrow is incharge of the release of endosperm from the bran and remaining
      germ.Also produce large sized particles
      Sifters sift, purify and clarify the material in stock contained in the rollers which result to
      grits
      These products are further dried to achieve 12-24% moisture content
      The materials are then packed
       a.   Flaking grits
       b.   Coarse grits
       c.   Fine grits
       d.   Granulated mills
       e.   Corn or maize flour
WHEAT MILLING
   1. Species
       Triticum vulgare-breads
       Triticum durum-paster
       Triticum compactum-bread
   2. Growing season
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       Winter wheat-planted in autumn and harvested in summer
       Spring wheat –planted on winter harvested on summer
   3. Protein content
      Strong/soft/weak wheat depends on the nutritional content
   4. Country
       Canadian wheat-has high protein content
       UK wheat- has low protein content
   5. Milling characteristics
      Hardness of endosperm and the ease of endosperm to break
Objectives
       1.    Cleaning
            Wash the grains
            Dry-scoring by putting grains in cylinders which has removing beaters
            Screening for size and shape separation
            Aspiration
            Colour separation
       2. Conditioning
          Adjusting moisture content so as the endosperm and germ can easily be removed
       3. Blending
          Ratio of mixing determined by the type of flour intended to be made
       4. Milling
          Divided into break rolls and reducing roll.
          Break roll involves separation of endosperm from germ and bran
          Made up of 4 pairs of rollers that have the following
        Grooved surfaces
        Grooved flutting
        A pair of movers
          Reduction section has 6-7 pairs of rollers and a gap between them
          It moves faster than the break rolls,done in a way that starch granules are not
          damaged. The milling system is gradual,the semolinas enter to the rollers first while
          the middlings enter to the third and fourth rollers
          Materials go to the purified section with a combination of seedings and air filtration
          to remove all the fine particles of bran which could be passed
          At the end ,the amount of grisks which go into the mill should be equal to flour and
          animal feed collected
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           Fflour should have atleast 12% moisture content
FLOUR TREATMENT
After milling process flour is obtained and It is said to have poor baking qualities with following
effects on bread
But on storage of flour these qualities have been found to improve particularly when stored to
3 months;associated with atmosphere oxidation etc
   1. Bleaching
      Removes the dull colour in wheat containing yellow pigment which have 95%
      xantrophils bringing out the dull colour in flour. Naturally the pigments are oxidized but
      takes long .bleaching agents are used to accelerate the process.
      Examples
       Benzoyl peroxide- bleaches at rate of 20-30 ppm mixed together with starch before
         used
       Chlorine gas-used to treat flour meant for cake making but not for bread because it
         has effects on the yeast. Used at rate of 1000-1200 ppm
       Acetone peroxide- acts as a bleaching and improving agents at a rate of 446 ppm
   2. Improvers
      Used to treat flour to modify baking qualities
      Improved flour will differ from freshly milled flour in that
       Improved flour has better baking qualities
       Exhibits increased tolerance of dough to fermentation condition
       Increase in volume in bread baked using improved flour
       Improved flour produces fine cramp texture
           Types of improvers
          Potassium bromate/glutex-dosage is 10-20 ppm. And oxidising agent acting after
           flour is mixed with water
           Increases elasticity while reduces extensibility. Extensibility of gluten is same as
           extensibility of potassium bromate
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         Ascorbic acid- it is an oxidizing agent. Important in mechanical dough process. It is
          first converted to dehydroascorbic acid which has improving characteristics.its
          dosage is 75ppm
         Azodicarbonamide- oxidizing agent which is very active effects are realized after 2.5
          minutes of mixing with water. Not a bleaching agent but improves whiteness of
          product.dosage is 20-30ppm
         L –cysteine-reducing agent,used in conjuction with an oxidizing agent mainly
          ascorbic acid. Used in dough making of activated dough development. Used in form
          of l-cysteine monochloride. It eliminates long process of fermentation. Dosage is
          75ppm
   a. Test baked
      Performed on flour depending on purpose of the flour and product e.g cake,chapati etc.
      done in the mill before flour goes to the market. Carried out in a standardized condition
      that are conducive for the particular product
   b. Protein test
      Used to estimate amount of protein. Done by estimating nitrogen content by use of
      kjeldhal method of protein determination, on average,100g of gluten contain 17.5 g of
      nitrogen.calculation of gluten content of flour is done by multiplying nitrogen content by
      9.7 which is a factor
       Done by estimating Nitrogen content
       Gluten wash-done by taking known dough amount washed in running tap water
          until the wash water remains clear while constantly rubbing dough between fingers
          The remaining whey is taken to be glutened. It is not accurate in determining levels
          of protein in four but it is a quick way of protein test
          Other tests include;
       Ash content
       Moisture content
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          Damage to starch content
          Water absorption test
RICE
RICE PRODUCTS
Rice can be made by quick cooking or almost instant in terms of preparation time,done by pre-
cooking to gelatinize starch then dry under conditions that will give the rice an expanded
internal structure and quick preparation of water during subsequent preparation
          Spices
          Salt
          Rice flour
Types of rice
   b. Porched rice
      Prepared by throwing rice into sand heated at high temperature in an iron pan.
      On stirring rice begins to crack and swells. It is the separated from sand through serving.
      It is crisp product with a greyish to brilliant white colour.
      Sold as salted or unsaulted
   c. Puffed rice
      Made by taking paddy rice [soaked in water to increase moisture to 20%] moist paddy is
      puffed by subjecting to sudden heat treatment for 250-270 degrees celsius this causes
      the mask to split off and the rice to be puffed
      Used in snack foods and breakfast cereals
   d. Rice flakes
      Produced largely in india. The paddy is soaked in hot water of between 70-80 degrees
      celsius for 20 minutes. Hot water is drained off,the soaked paddy is roasted in a pan at
      about 250-300 degrees celsius until the grains have stopped puffing
      Roasted paddy is immediately subjected to flaking by use of iron rollers. The rice flakes
      are pre-cooked products and can readily be reconstituted by cooking in warm water for
      20 minutes to prepare snacks.
   e. Rice starch
      Small granules embedded in a protein matrix to separate starch granules from proteins
      broken rice is stipped for 24 hours in sometimes 0.3% sodium hydroxide,this process
      removes gluten protein
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       Used as thickening agent and preparation of simple sugars
The reason for limited shelf life of flour is the fatty acids of the germ,which react from moment
they are exposed to oxygen. Heat processed flour where the germ is first separated from the
endosperm and bran then processed with steam,dry or microwave and blended into flour
again.
   a. Graham
   b. Whose inventor
   c. Sylvester graham
BREAD MAKING
Requirements
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   -    The gas can be carbon dioxide. The flour rises due to gas forcing its way out of the
        dough.
Qualities of bread
These depend on quality of ingredients used and specifically wheat flour used including partly
the baking process.
Time taken for optimum gluten development [fermentation time cycle also affects quality]
Ingredients
   a. Wheat flour- forms bulk of product,source of protein for forming of structure gives
      starch and sugars.
   b. Yeast –used to convert fermentable sugars to carbon dioxide and alcohol carbon dioxide
      is responsible for aerating dough while alcohol brings out the flavor of product
      fermentation stops during baking
   c. Water –dissolving flour and other products,influences consistency of dough and controls
      dough final temperature i.e 27 degrees celsius for reaction to take place
   d. Salt-used for flavouring,accelerating flavor of other ingredient i.e sweetness of sugar by
      its contrasting taste. Helps in controlling activity of yeast hence rate of fermentation.
      If put a lot dough cracks.
      Strengthening gluten network
      Modifies crust colour of bread to get golden brown colour.
      Provides mild preservation
   e. Other ingredients
       Fat –impacts richness and tenderness of the product due to lubrication. Improves
           eating quality and influences flavor. Lubricates gluten strands to assist in volume
           increase. Acts as and emulsifier bringing in ability of product to hold water than
           would be if the fat is not present
       Sugar – sweetens product improves tenderness as it holds more water. Influences
           the colour since the golden brown colour is due to caremalization
       Milk- enrich product because of presence of minerals. Presence of protein in milk
           strengthens gluten network hence increases fermentation tolerance of dough.
           Increases nutritional level of bread.
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           Eggs- used to increase nutritional content and bring varieties of product
           Soy and malt flour- increases protein richness and flavor
           Acetic acid- used as a preservative and adds flavor. It acts by smashing micro
            organisms
Dough development
Involves protein part of flour where gluten network is developed and capable of holding gases.
Produced to aerate dough so as to achieve required volume and shape of product. Wheat flour
has two proteins : glutenin and gliadin.the two join to form gluten
Development of gluten involves uncoiling of protein molecule and the amine molecule to form
a vast network of gluten due to disulphide bonds. The coils are held together by the disulphide
bonds
Uncoiling of the protein molecule therefore comes as a result of cutting of these bonds by use
of chemicals or mechanically during mixing processes
As mixing continues different protein molecules are brought together and new bonds are
formed linking molecules together
If the dough is overmixed or allowed to remain without being used,the newly formed bonds
break up and reverse back to original stage resulting to stickiness and lack of elasticity of the
dough.
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Disadvantages of mechanical way
Procedure
   3. Bulk fermentation
      Development of dough which takes long. There are two ways that it is done:-
      a. Mixing ingredient together
         Done by using a low speed mixer and allow it to stand for about 2-3 hours for
         ripening. When dough is initially mixed it is sticky and difficult to work on,as time
         goes it becomes less sticky,lighter and more easily worked on. Has ‘good
         fermentation tolerance’. Which means the persistence to attain optimum condition
         of ripeness.
         Bread baked from such a dough become better until maximum condition of ripeness
         is achieved. If process of ripeness is allowed beyond optimum,dough detoriates and
         becomes sticky ,more rubbery and hard to work on. An optimum condition dough is
         said to be ripe,if it persists for a certain period,the type of flour used to make the
         dough is said to have a good fermentation tolerance. Weak flour have low and
         strong wheat have high fermentation tolerance
      b. Sponge and dough method
         Sponge is made by:-
       Take yeast,mix with quarter of flour and water to make a semi-solid mixture. Allow
         to stand [sponge] to ferment for 2 hours. Remaining flour and other ingredients are
         added to dough. Water is then added to correct the constistency. Rest the dough for
         30-60 minutes before processing starts.
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   a. Less amount of yeast used
   b. Good quality bread
Disadvantages
PASTA PRODUCTS
   a. Macaroni
   - Cereal product processed from wheat flour by milling of durum type of wheat. This type
      gives the semolina with brightness and yellowness that is essential in pasta products.
   - They are usually of different types but the difference is mainly on the shape and
      moulding of these products macaroni
       Hallow tubular [different diameters]
          Smooth rods of different diameters of spaghetti and vermicelli. Tubular and
          corrugated surfaces instead of smooth of different thickness
       Flat ribbon types of different thickness. Any other fancy types e.g butterfly shaped
            All of these are made from the same ingredients by same process but they are
            merely presented in different ways. Basic ingredients is semolina and water
            processing.
            There are four stages involved:-
Procedure
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    i.    Over bake the proofed dough at 230-250 degrees celsius for 23-27 minutes and remove
          when golden brown
    j.    De-pan,cool at room temperature 2-3 hours before slicing and/or packing for dispatch
CAKE MAKING
A good recipe is an accurate record of weight of raw materials that are necessary for the
formula/recipe is correctly balanced. A good quality cake will be produced provided that the
correct manufacturing. Procedure is,adapted and packaging and baking of the cake.
A good cake is the one that shows in fault either in appearance or when being consumed.
Quality of cake varies but if the formula is well balanced them a good cake [in quality] will be
produced.
Understanding of the formula balance therefore is of great importance to the baker,with this
knowledge he cannot only perfect his formula but also recognize the faults called by incorrect
balance of raw materials and also take the corrective ensures.
Faults in cakes
M fault
X fault
Cake has been removed from the oven and has started cooling. The excess milk or water mostly
causes the x faults because while the cake is in the oven. The cake therefore fall on the middle
and also on the side because the structures are weak.
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Occur when two strong and flour is used became when strong flour is processed gluten is
formed which tends to resist the expansion during baking. Because the expansion cant’t be
maintained,a violent crack opens the crust.
Also caused by use of too hot oven or dry oven- a crust tends to form very quickly before the
expansion is complete. If the batter is over mixed there could be firm structure that resist
expansion
Insuffient volume
Caused by use of insuffient liquid or milk. Due to excess fat and weakens the structure to
reduce the gas. Capacity, so there is minimal retained co2
Cure
   e. Milk
      Dissolving other ingredients
   f. Baking powder
      Used for aeraton,providing the co2 into the cake
      Sodium hydrogen carbonate is commonly used
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