Chemistry Chapter Five Hydrocarbons test

From the beginning of the Chapter to the last aromatic benzene

1. If the energy of breaking the bond(C-H) = 413kj/mol, (C-C) =346 kj/mol, the energy of
breaking all bonds of one mole alkane = 5168 kj/mol, by replacing one hydrogen atom with
one chlorine atom, we obtain …. different isomerism
a. 1 b. 2 c. 3 d. 4
2. The following pair of compounds have no isomers
a. The first two members in the cyclo alkanes series.
b. The first two members in the alkene series.
c. The first two members in the alkyne series.
d. The third and fourth members in the alkane’s series.
3. The presence of a CH₃ group at both ends of the molecule indicates...
a. The molecule can be prepared by dry distillation of anhydrous sodium propanoate.
b. The molecule can be prepared by dripping water onto calcium carbide.
C. The molecule can be prepared by removing water from ethanol.
d. One mole of an alkane molecule contains 8 moles of sigma bonds.
4. The number of sigma bonds between carbon atoms in the following compound is equal
to... CH₃C(CH₃)₂CH₂CH₃
a. The number of methyl and methylene groups in the compound.
b. The number of hydrogen atoms in the compound.
c. The number of methyl groups in the compound.
d. The number of isomers of alkane, its molar mass is 58 grams/mol
5. The gaseous alkanes in S.T. P which has higher density is
a. Alkan is commonly found in gas cylinders in cold areas.
b. Alkane can be obtained by decomposing organic materials under the surface of water.
c. Alkane is produced by catalytic thermal cracking of propane and propene
d. None of the above.
6.According to the following reaction, which expresses the combustion of alkane in air, Z is
Y
equal to …. CxHy + ZO₂→ XCO₂+ 2 H₂O
Y X +Y Y X +Y
a. X + 2 b. 2
c. X + 4 d. 4

7. Which of the following choices is not a property of all alkanes?

a. Less dense than water. b. saturated. c. hydrocarbon. d. Gaseous at room temperature.
8. ….. electron pairs participates in the formation of weak bonds in naphthalene.
a. 4 b. 5 c. 6 d. 7

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9. Sulfuric acid separates from the following compound at:
H-CH₂-CH₂-O-SO₂-OH
a. Add water at room temperature. b. Heating up to 20°C
c. Add NaOH solution. d. None of the above.
10. The yellowish white substance with a high molecular weight that is not affected by
concentrated acids is …...
a. CH₂=CH₂ b. CH≡CH c. d. CH₄
11. Which of the following statements applies to compound X?
CH₂Cl-CH₂Cl + 2KOH→ X + 2KCl + 2H₂O
a. Saturated and an explosive mixture with air.
b. is a chemically active cyclic hydrocarbon.
c. It can be polymerized inside a nickel tube.
d. Its molecular formula has three isomers.
12. By adding three moles of HCI to aromatic benzene, ..... is formed
a. 1, 2,3-Trichlorobenzene b. 1, 3,5-Trichlorobenzene
c. 1,3 5 - Trichloro cyclohexane d. Gamma Hexachlorocyclohexane
13. The gas that is prepared in a laboratory in an impure form and mixed with a gas that has
an unpleasant odor is a gas.........
a. CH₄ b. C₂H₄ c. C₂H₂ d. C₂H₆
14. The IUPAC name most accurate to represent the following compound is...
Cl-CH₂-C₂H₄Cl
a. 1,3 – Dichloropropane b. 1,2-Dichloropropane c. 2,3-Dichloropropane d. (a and c)are correct

15. By adding 1 mole HCI to one mole of CH₂=CCI-CH=CH₂ ….. is formed

a. CH≡C-CH=CH₂ b. CH≡C-CH≡CH c. CH₃-CH₂-CH=CH₂ d. CH₂=CH-CH = CH₂
16. The number of isomers in the molecular formula C₄H₉I is 1
a. 1 b. 2 c. 3 d. 4
17. According to the following reaction: C₂H₅I(aq) + AgOH(aq)→ X(l) + Y(S)
Which of the following choices represents X,Y?
X Y
a flammable Alkane A precipitate not affected by light
b Dihydroxy alcohol Yellowish white precipitate
c Has no isomer Dissolve in diluted HCI
d It burns with a faint flame and does not dissolve in concentrated ammonia solution
mixes with water in all proportions

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18. Which of the following choices represents X,Y?
Pt / ∆ X + 4Y
→

X Y
a Hydrocarbon derivative Gas
b Hydrocarbon Solid
c Organic liquid compound Inorganic gas
d Unsaturated oxidizing agent
19. Substance (X) is expressed in the following reaction 3CCl₄ + 2SbF₃→3X + 2SbCl₃
a. safe anathematic b. dangerous anathematic c. detergent. d. Freon.
20. A student suggested formulas for some compounds. Which of These formulas are
incorrect
a. CH₃-Zn-I b. ZnCl₃ c. C₃H₇-Mg-I d. Cu₂Cl₂
21. The six atoms in aromatic benzene are completely equivalent and connected to each
other by bonds
a. all strong and difficult to break b. all weak and easy to break
c. Sigma and Bi d. double and triple
22.The following table includes a group of aromatic organic compounds
Melting point Boiling point
a -25.2 ⁰C 144.4 ⁰C
b 5.5 ⁰C 80 ⁰C
c -95.1 ⁰C 110.6 ⁰C
d 67.2 ⁰C 177 ⁰C
The compounds are …

23. A cylinder containing (X) moles of different organic gases, alkane, alkane, and alkane, for
its complete combustion, 20 moles of oxygen gas are required, so the combustion of each gas
separately produces 4 moles of water vapor, Which of the following choices is correct
X Alkane Alkene Alkyne
a. 10mol C3H8 C2H4 C2H6
b. 4mol C2H6 C3H6 C2H2
c. 6mol CH4 C3H6 C3H4
d. 8mol CH4 C2H4 C2H2

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24. By reducing the following compound with hydrogen, then removing water, then
hydrogenation, respectively, we obtain……… CH3-CH(CH3)-CHO
a. Alkane its molar mass of 58 b. Alkane is liquid at room temperature
c. Alkene its molar mass of 42 d. Alkane polymerizes and gives P.P
25. In the following chart A →1 B →2 C →3 CnH2n+2
The correct choice that expresses the materials of the reactions and processes occurring is ....
1 2 3 A B C
a. Hydrogenation Thermal Catalytic cracking Hydration Alkene Alkane Alkene
b. Hydration oxidation neutralization C2H2 C2H5OH R-ONa
c. oxidation neutralization Dry distillation R-CHO CH3COOH CH3COONa
d. Reduction oxidation Dry distillation RCOOH R-CHO R-H
26. A, B are two saturated aliphatic compounds. The number of carbon atoms of A is n and
the number of carbon atoms of B is 2n. By catalytic reforming of compound B, we obtain an
aromatic compound its molar mass of 78g. Which of the following statements is correct?
a. By catalytic thermal cracking of B, butane and butene produced
b. The molecular formula of B has only four isomers
c. The number of sigma bonds per mole of A= 10 mol
d. By polymerizing A, produce P.P
27. The following reaction takes place in two steps: adding water first and then oxidizing the
product from adding water
HC≡CH+H₂O+(O)→ X
The substance used to complete the reaction is ….and the reaction product is ….. .
The substance Reaction product
a. HgSO4 Ethylene glycol
b. KMnO4 Ethylene glycol
c. H₂SO4 Ethanol
d. KMnO4 Acetic acid
28.One grams of mixture of (pentane, 2-pentene ) reacts with 0.12g of bromine. Assuming
that the entire reaction is an addition reaction (not a substitution reaction), the percentage of
pentane in the mixture is equal to(C=12) (H=1) (Br = 80)
a. 40.33% b. 80.5% c. 5.25% d. 94.75%
29. The correct choice expressing the reaction of a mole of Zn with a mole of an organic
compound is...

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30. The molecular formula of methyl anthracene is...
a. C14H13 b. C15 H12 c. C15H13 d. C16H15
31. By reacting the compound C6H10 (A) with Br₂ …. is formed
a. C4H9-C2H5Br b. c. C6H10Br d.(b, c) are correct
32. The Baeyer reaction can be performed for all of the following compounds except...
a. symmetric Alkane b. asymmetric Alkene c. cyclo alkane d. cyclo alkene
33. Which of the following options is correct according to the following reaction?

X Y
a. Methane Sodium carbonate
b. CnH2n-2 It reacts with HCI and a gas is released
c. CnH2n-7 Its solution with magnesium sulphate solution gives a white precipitate
d. Naphthalene white precipitate that reacts with H2SO4
34. In the following two charts the correct choice is...

35. Which of the following options is correct according to the reaction?

X Carbon atom 1 Carbon atom2

a. 1 - Fluoropropane Carrying an electrical charge +Ϭ Carrying an electrical charge -Ϭ
b. 2- Fluoropropane Carrying an electrical charge -Ϭ Carrying an electrical charge +Ϭ
c. 2- Fluoropropane Carrying an electrical charge +Ϭ Carrying an electrical charge --Ϭ
d. Floride isopropyl Carrying an electrical charge -Ϭ Carrying an electrical charge +Ϭ
36. Orthochloromethylbenzene produced from...
a. Catalytic reformation of normal heptane and then halogenation of the product.
b. Reduction of phenol and then halogenation of the product.
c. Polymerization of ethene, then performing the Friedel-Krafts reaction for the product.
d. alkylation of toluene
37. The number of methane molecules present in 32g of it is equal to (Avogadro's number N A)
a. NA b. 2 NA c. 3 NA d. 0.5 NA

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38. One of the following compounds is affected by hot platinum to produce a cyclic
compound:

39. The following two compounds are similar in…..

a. empirical formula b. Molar mass c. Molecular formula d. All of the previous.

40. Compound has no isomers is …...
a. Dry cleaning compound. b. safe anesthetics c. chloroform d. butane.
41. By dry distillation of a salt CH₃-C(CH₃)₂COONa ….. is produced
a. The second member of gaseous alkanes b. branched Alkene is
c. Molecularly similar to butane d. Butane.
42. In the following reaction X represents ….
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X+ 2 O₂ →5CO₂ + 5H₂O
a. cyclo pentane b. naphthalene c. Methyl pentane d. aromatic benzene
43. Which of the following properties increases with thermal catalytic cracking of an alkane in
which the number of carbon atoms does not exceed 8 atoms?
a. boiling temperature b. Volatility c. molar mass d. Viscosity
44. The substance that plays an important role in the manufacture of industrial detergents is:
a. NaOH b. AgBr c. MgSO₄ d. HCI
45. By adding an industrial detergent to water, the surface tension of water …… and the
ability of water to wet clothes...(Selection from right to left)
a. decreases, decreases b. increases, increases c. decrease, don't change
d. decreases, increases
46. In the next reaction CH3-CH=CH-CH₃ + HCI→
a. Chlorine is added to either end of the double bond
b. Chlorine is added to the carbon chain end of the compound
c. An unsaturated alkyl halide is formed
d. Addition is done according to Markonnikov's rule

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47. By adding a mole of hydrogen gas to aromatic benzene, (A) is formed, by adding a mole of Cl₂ to
A, B is formed, and by adding F₂ to B produce C, which of the following choices is correct
A B C
a. C6H8 5,6-Dichlorocyclohexene A hexasubstituted derivative of benzene
b. C6H10 Gamixane Chlorofluoro aromatic benzene
c. C6H8 1,2 Dichloro-2hexene 1,2-Difluoro3,4-dichlorocyclohexene
d. C6H8 3,4- Dichloro-1-cyclohexene 1,2-dichloro-3,4-difluorocyclohexane
48. The following reaction is called ....... and the type of reaction is .......and the name of the
resulting organic compound is ........ According to IUPAC system,

reaction name Type of reaction Name of the resulting organic compound

a. Friedel - Kraft addition Isopropyl benzene
b. Friedel - Kraft replacement 2-methyl-2-phenylpropane
c. Friedel - Kraft Substitution Phenyltrimethylmethane
d. Markonnikov Catalytic hydration Isopropyl benzene
49. The organic compound resulting from the following reaction isomerizes with...

a. Methylcycloheptane b. cyclo octane c. Diethylcyclobutane d. All of the pervious

50. The polymer resulting from the addition reaction similar its forming monomer in … and
differs in …
Similarity Difference
a. Molecular formula Structural formula
b. Molar mass Density
c. Molecular formula Empirical formula
d. Empirical formula Molecular formula

51. A suitable monomer for addition polymerization is...

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52. Alkane A, the sum of its atoms and bonds, is 15. One mole of chlorine gas was added to it
under the suitable conditions, producing an organic compound, B, and by burning B in the air,
C produced. Which of the following arrangements is correct?

53. ln the following reaction C2H6 + Cl2 UV

→
Z+ HCl so Z is
a. hydrocarbon b. has isomers c. CnH2n+1X d. safe anesthetics
54. By reacting the following compound CH≡C-CH(CH3)-CH₂CI with a mole of chlorine, it
produces...
a. 1,3,4-Trichloro-2-methylbutane b. 1,2,4-Trichloro--3-methyl-1-butene
c. 1, 3,4-Trichloropentane d. 3-Methyl-1,2,4-trichlorobutene
55. The molecular formula C6H4BrNO2 has a different aromatic structural formula.
a. 2 b. 3 c.4 d. 5
56. Which of the following choices is correct?
Suitable the conditions

57. By oxidizing the isomer of vinyl alcohol and reacting the product with sodium hydroxide,
A is formed. Which of the following choices is correct?
a. Dry distillation of salt A produces an alkane containing two carbon atoms
b. A is C2H5COONa
c. Solution A is basic, affecting litmus paper
d. By passing A into a nickel tube heated to the point of redness, it formed with aromatic
benzene

58. Ethanol and dimethyl ether are similar in...

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a. number of covalent bonds b. Structural formula c. boiling point d. melting point

59. Adding one mole of HCI to one mole of

…… is formed

a. Aromatic hydrocarbon b. aliphatic hydrocarbon

c. 1-chloro-1-methylcyclohexane d. 1-chloro-2-methylcyclohexane
60. The number of atoms (X) and the number of sigma bonds between atoms is equal to
a. x b. x+1 c. x-1 d. x-2