Product Name: MAL Hydraulic AW-320 MAL PAKISTAN LTD
Effective Date: 15 October 2010
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MATERIAL SAFETY DATA SHEET
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1. PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME: MAL Hydraulic AW 320
Product Description: Base Oil and Additives
Intended Use: Anti wear Hydraulic Oil
COMPANY IDENTIFICATION
Supplier: MAL PAKISTAN LTD
J1, J2 LIEDA Hub
Balochistan Pakistan
MSDS Requests UAN 111-840-840
Product Technical Information UAN 111-840-840
MSDS Internet Address http://www.mobil.com.pk
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2. COMPOSITION/INFORMATION ON INGREDIENTS
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CHEMICAL NAMES AND SYNONYMS: BASE OIL AND ADDITIVES
See Section 8 for exposure limits (if applicable).
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3. HAZARDS IDENTIFICATION
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Under normal conditions of use, this product is not considered hazardous
according to regulatory guidelines (See section 15).
EMERGENCY OVERVIEW: Dark Amber Liquid. Note: Pressurized mists may form
a flammable mixture. DOT ERG No. : NA
POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this
product does not pose a risk to health. Excessive exposure may result
in eye, skin or respiratory irritation.
For further health effects/toxicological data, see Section 11.
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4. FIRST AID MEASURES
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EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a
physician.
Product Name: MAL Hydraulic AW-320
Effective Date: 15 October 2010
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SKIN CONTACT: Wash contact areas with soap and water. Remove and clean
oil soaked clothing daily and wash affected area. INJECTION INJURY
WARNING: If product is injected into or under the skin, or into any
part of the body, regardless of the appearance of the wound or its
size, the individual should be evaluated immediately by a physician
as a surgical emergency. Even though initial symptoms from high
pressure injection may be minimal or absent, early surgical
treatment within the first few hours may significantly reduce the
ultimate extent of injury.
INHALATION: Not expected to be a problem. However, if respiratory
irritation, dizziness, nausea, or unconsciousness occurs due to
excessive vapor or mist exposure, seek immediate medical assistance.
If breathing has stopped, assist ventilation with a mechanical
device or mouth-to-mouth resuscitation.
INGESTION: Not expected to be a problem. Seek medical attention if
discomfort occurs. Do not induce vomiting.
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5. FIRE-FIGHTING MEASURES
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EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog.
SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use
water to keep fire exposed containers cool. Water spray may be used
to flush spills away from exposure. Prevent runoff from fire
control or dilution from entering streams, sewers, or drinking water
supply.
SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters
must use self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Note: Pressurized mists may form a
flammable mixture.
COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides,
aldehydes and other decomposition products, in the case of
incomplete combustion.
Flash Point C(F): > 200 oC (ASTM D-92).
Flammable Limits (approx.% vol.in air) - LEL: 0.9%, UEL: 7.0%
NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0
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6. ACCIDENTAL RELEASE MEASURES
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NOTIFICATION PROCEDURES: Report spills/releases as required to
appropriate authorities.
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED:
LAND SPILL: Shut off source taking normal safety precautions.
Take measures to minimize the effects on ground water. Recover by
pumping or contain spilled material with sand or other suitable
absorbent and remove mechanically into containers. If necessary,
dispose of adsorbed residues as directed in Section 13.
WATER SPILL: Confine the spill immediately with booms. Warn other
ships in the vicinity. Notify port and other relevant authorities.
Remove from the surface by skimming or with suitable absorbents. If
permitted by regulatory authorities the use of suitable dispersants
should be considered where recommended in local oil spill
procedures.
ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water
sources or low lying areas; advise the relevant authorities if it
Product Name: MAL Hydraulic AW-320
Effective Date: 15 October 2010
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has, or if it contaminates soil/vegetation.
PERSONAL PRECAUTIONS: See Section 8
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7. HANDLING AND STORAGE
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HANDLING: High pressure injection under the skin may occur due to the
rupture of pressurized lines. Always seek medical attention. No
special precautions are necessary beyond normal good hygiene
practices. See Section 8 for additional personal protection advice
when handling this product.
STORAGE: Keep containers closed when not in use. Do not store in open or
unlabelled containers. Store away from strong oxidizing agents and
combustible materials. Do not store near heat, sparks, flame or
strong oxidants.
SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip
hazard.
EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/or
vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME,
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean
container since residue is difficult to remove. Empty drums should
be completely drained, properly bunged and promptly returned to a
drum reconditioner. All containers should be disposed of in an
environmentally safe manner and in accordance with governmental
regulations.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
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OCCUPATIONAL EXPOSURE LIMITS:
When mists/aerosols can occur, the following are recommended: 5 mg/m3
(as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist)
- ACGIH Short Term Exposure Limit (STEL), 5 mg/m3 (as oil mist) - OSHA
Permissible Exposure Limit (PEL)
VENTILATION: If mists are generated, use adequate ventilation, local
exhaust or enclosures to control below exposure limits.
RESPIRATORY PROTECTION: If mists are generated, and/or when ventilation
is not adequate, wear approved respirator.
EYE PROTECTION: If eye contact is likely, safety glasses with side
shields or chemical type goggles should be worn.
SKIN PROTECTION: Not normally required. When splashing or liquid contact
can occur frequently, wear oil resistant gloves and/or other
protective clothing. Good personal hygiene practices should always
be followed.
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9. PHYSICAL AND CHEMICAL PROPERTIES
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Typical physical properties are given below. Consult Product Data Sheet
for specific details.
Product Name: MAL Hydraulic AW-320
Effective Date: 15 October 2010
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APPEARANCE: Liquid
COLOR: Dark Amber
ODOR: Mild
ODOR THRESHOLD-ppm: NE
pH: NA
BOILING POINT C(F): > NE
MELTING POINT C(F): NA
FLASH POINT C(F): > 220 (ASTM D-92)
FLAMMABILITY (solids): NE
AUTO FLAMMABILITY C(F): NA
EXPLOSIVE PROPERTIES: NA
OXIDIZING PROPERTIES: NA
VAPOR PRESSURE-mmHg 20 C: NE
VAPOR DENSITY: > NE
EVAPORATION RATE: NE
RELATIVE DENSITY, 15/4 C: 0.88-0.91
SOLUBILITY IN WATER: Negligible
PARTITION COEFFICIENT: > NE
VISCOSITY AT 40 C, cSt: > 288
VISCOSITY AT 100 C, cSt: > 23.5
POUR POINT C(F): -3
FREEZING POINT C(F): NE
VOLATILE ORGANIC COMPOUND: NE
DMSO EXTRACT, IP-346 (WT.%): <3, for mineral oil only
NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES
FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE
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10. STABILITY AND REACTIVITY
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STABILITY (THERMAL, LIGHT, ETC.): Stable.
CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient
temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
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11. TOXICOLOGICAL DATA
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---ACUTE TOXICOLOGY---
ORAL TOXICITY (RATS): Practically non-toxic (LD50: between 2000 to 5000
mg/kg). ---Based on testing of similar products and/or the
components.
DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than
2000 mg/kg). ---Based on testing of similar products and/or the
components.
INHALATION TOXICITY (RATS): No data available.
EYE IRRITATION : Week to moderate. ---Based on testing of similar products
and/or the components.
SKIN IRRITATION : Prolonged contact with skin may cause dermatitis.
---Based on testing of similar products and/or the components.
OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not
performed with this product, a variety of mineral and synthetic
oils, such as those in this product, have been tested. These
Product Name: MAL Hydraulic AW-320
Effective Date: 15 October 2010
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samples had virtually no effect other than a nonspecific
inflammatory response in the lung to the aerosolized mineral oil.
The presence of additives in other tested formulations (in
approximately the same amounts as in the present formulation) did
not alter the observed effects.
---REPRODUCTIVE TOXICOLOGY (SUMMARY)---
No teratogenic effects would be expected from dermal exposure, based on
laboratory developmental toxicity studies of major components in
this formulation and/or materials of similar composition.
---CHRONIC TOXICOLOGY (SUMMARY)---
Repeated and/or prolonged exposure may cause irritation to the skin, eyes
or respiratory tract. Overexposure to oil mist may result in oil
droplet deposition and/or granuloma formation. For mineral base
oils: Base oils in this product are severely solvent refined and/or
severely hydrotreated. Chronic mouse skin painting studies of
severely treated oils showed no evidence of carcinogenic effects.
These results are confirmed on a continuing basis using various
screening methods such as Modified Ames Test, IP-346, and/or other
analytical methods. For synthetic base oils: The base oils in this
product have been tested in the Ames assay and other tests of
mutagenicity with negative results. These base oils are not
expected to be carcinogenic with chronic dermal exposures.
---SENSITIZATION (SUMMARY)---
Not expected to be sensitizing based on tests of similar type of products.
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12. ECOLOGICAL INFORMATION
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ENVIRONMENTAL FATE AND EFFECTS:
In the absence of specific environmental data for this product, this
assessment is based on information for representative products.
ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates that
adverse effects to aquatic organisms are not expected from this
product.
MOBILITY: When released into the environment, adsorption to sediment and
soil will be the predominant behavior.
PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently
biodegradable.
BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very
low water solubility of this product, therefore bioavailability to
aquatic organisms is minimal.
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13. DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL: Product is suitable for burning in an enclosed,
Product Name: MAL Hydraulic AW-320
Effective Date: 15 October 2010
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controlled burner for fuel value. Such burning may be limited
pursuant to the Resource Conservation and Recovery Act. In
addition, the product is suitable for processing by an approved
recycling facility or can be disposed of at an appropriate
government waste disposal facility. Use of these methods is subject
to user compliance with applicable laws and regulations and
consideration of product characteristics at time of disposal.
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14. TRANSPORT INFORMATION
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USA DOT: NOT REGULATED BY USA DOT.
RID/ADR: NOT REGULATED BY RID/ADR.
IMO: NOT REGULATED BY IMO.
IATA: NOT REGULATED BY IATA.
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15. REGULATORY INFORMATION
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US OSHA HAZARD COMMUNICATION STANDARD: When used for its intended
purposes, this product is not classified as hazardous in accordance
with OSHA 29 CFR 1910.1200.
EU Labeling: Product is not dangerous as defined by the European Union
Dangerous Substances/Preparations Directives. EU labeling not
required.
The following product ingredients are cited on the lists below:
Data collected similar type of products.
CHEMICAL NAME CAS NUMBER LIST CITATIONS *
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ZINC (ELEMENTAL ANALYSIS) Confidential NA
ZINC DITHIOPHOSPHATE Confidential NA
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16. OTHER INFORMATION
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USE: HYDRAULIC OIL
NOTE:
Health studies have shown that many hydrocarbons pose potential human
health risks which may vary from person to person. Information provided
on this MSDS reflects intended use. This product should not be used for
Product Name: MAL Hydraulic AW-320
Effective Date: 15 October 2010
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other applications. In any case, the following advice should be
considered:
INDUSTRIAL LABEL
Under normal conditions of intended use, this product does not pose a
risk to health. Excessive exposure may result in eye, skin or
respiratory irritation. Always observe good hygiene measures. First
Aid: Wash skin with soap and water. Flush eyes with water. If
overcome by fumes or vapor, remove to fresh air. If ingested do not
induce vomiting. If symptoms persist seek medical assistance. Read
and understand the MSDS before using this product.
Information given herein is offered in good faith as accurate, but
without guarantee. Conditions of use and suitability of the product for
particular uses are beyond our control; all risks of use of the product
are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL
WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE
USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a
recommendation for uses which infringe valid patents or as extending
license under valid patents. Appropriate warnings and safe handling
procedures should be provided to handlers and users. Alteration of this
document is strictly prohibited. Except to the extent required by law,
republication or retransmission of this document, in whole or in part, is
not permitted. MAL Pakistan Ltd and its affiliated companies
assume no responsibility for accuracy of information unless the document
is the most current available from an official MAL Pakistan distribution
system. MAL Pakistan Ltd and its affiliated companies neither
represent nor warrant that the format, content or product formulas
contained in this document comply with the laws of any other country
except the Pakistan.
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The information and recommendations contained herein are, to the best of MAL Pakistan Ltd knowledge and
belief, accurate and reliable as of the date issued. You can contact MAL Pakistan Ltd to insure that this
document is the most current available from MAL Pakistan Ltd. The information and recommendations are
offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product
is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper
health, safety and other necessary information is included with and/or on the container. Appropriate warnings
and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly
prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in
part, is not permitted. The term, "MAL Pakistan Ltd" is used for convenience, and may include any one or more
of MAL Pakistan Ltd companies, MAL Pakistan Ltd, or any affiliates in which they directly or indirectly hold any
interest.