Revision Mock Test-21

Pattern : JEE-Advanced
Batch : XII | Test Date : 21.04.2024

MATHEMATICS
1 BC 2 BCD 3 ABCD 4 B 5 C 6 B

7 C 8 10 9 3 10 13 11 24 12 8

13 5 14 C 15 D 16 A 17 B

PHYSICS
18 ABC 19 ABCD 20 BC 21 C 22 A 23 B

24 D 25 5 26 4 27 8 28 3 29 8

30 4 31 A 32 B 33 A 34 B

CHEMISTRY

35 BC 36 CD 37 AD 38 C 39 A 40 B

41 B 42 7 43 6 44 9 45 5 46 3

47 4 48 A 49 B 50 C 51 D
 SOLUTIONS
MATHEMATICS
1. 
det  A2  2 I   0  det A  2 I det A  2 I  0   

As A contains rational entries, det A  2 I  det A    
2I  0
So characteristics equation of A is A  2 I 2  0
2

A2 n  2n I 2 , A2 n1  2n A & A  2.

2 2 2
2. As sum of coefficients of x , y and z is zero so the planes are perpendicular
1
Clearly x  y  z satisfies the equation. So l  m  n 
.
3
yz z2 y2
3. If OA  x, OB  y , OC  z. pq .  2 &   2 .
y z
2 2 y z
4. P  0   0  a0  0
Now a1 x  a2 x  .....  x a1  a2 x  ..... 1 So a1 1.
2

5. Maximum value of A is 398.

1
6. a2  2 so an  2  n  2. an2  an21  2
an21
1 1
As an  2 so  1
an2 4
Hence 2  an  an1  3
2 2

putting n  2,3,...,75 and adding 148  a75  1  222

2

144  149  a75

2
 223  225 So 12  a75  15
7. Sum (required) =
12

  i  112  i   12  0  1  ......  11  1  2  3  .....  12   870

i 1
8. Note that the left-hand side of the equation can be written as
x  x 2  2m  1  m  x 2  2m  1  x 2  2m  1  5

Then,  x  m  1 x  2m  1  5
2

Now, if the equation has an integer root, we have
 x  m  1, x 2
 2m  1  1,5  ,  1, 5  ,  5,1 ,  5, 1
We have four cases,
(i) x  m  1  1 and x  2m  1  5.
2

Then, x  2m  1  2  x  m  1  7.
2
 Hence, x  2 x  4  0, which has no integer roots.
2

(ii) x  m  1  1and x  2m  1  5. Then, x  2 x  10  0, which has no real

2 2

roots.
(iii) x  m  1  5 and x  2m  1  1. Then x  2 x  8  0, which gives
2 2

x  2, 4 and , m  2,8 respectively.

(iv) x  m  1  5 and x  2m  1  1. Then x  2 x  14  0, which has no real
2 2

roots.
9. a  2, b  6, c  3, d  4
13
10. sin 1  sin 2 x  cos 4 x  
14
3 3
cos 1  sin 2 x  cos 4 x  
14
We split into cases on the integer k   x  y  . Note that x  y  k but
2 2
11.
1 1
x 2  y 2   x  y   k 2 and x 2  y 2  1, which forces k  2.
2

2 2
If k  0, the region defined by 0  x  y  1 and x  y  0 is the diameter from
2 2

 2 2  2 2
 ,  to   ,  , which has length 2.
 2 2   2 2 
If k  1, the region 1  x  y  2 and x  y  1 consists of two segments, which is
2 2

the chord on x  y  2 minus the chord on x  y  1. The former has length

2 2 2 2

2 2
 2  2
 
2
2 2    6, and the latter has length 2 1  
2
  2. So the total
 2   2 
length here is 6  2.
If k  2, the region 2  x  y  3 and x  y  1 is the chord on x  y  3, which
2 2 2 2

 3    2   2.
2 2
has length 2

Our final answer is 2   6  2   2  4  6  2.

  n    n 
12. H  n   5  1  2  3  ....      52 1  2  3  ....   2    .... so. On. ([.] G.I.F)
 5   5  
n2
Using sandwich theorem, we can show lim  8.
n H  n 

ac
13. The given condition is equivalent to b  .
1  ac
a  tan  , b  tan  , c  tan  ,
  
where tan   tan     and  ,  ,     ,  , so we have
 2 2
2 2 3 2 2 3
A 2  2  2   
a  1 b  1 c  1 tan 2   1 tan 2      1 tan 2   1
 2cos 2   2cos 2      3cos 2 
  2cos 2   1   2cos 2      1  3cos 2 
 cos   cos  2  2   3cos 2   2sin  2    sin   3cos 2 
Let x  sin  . Then we have
2
 1  10 10
A  2 x  3 1  x   3 x  2 x  3  3  x     .
2 2

 3 3 3
1
Equality holds if any only if sin  2     1 and sin   , from which we deduce
3
 2 2
 a, b, c    , 2,  .
 2 4 
Use  2a    3b   12ab  c  0
2 2 2
14.
  2a  3b  c  2a  3b  c   0
15. Conceptual
x2
f t   t f  x2   x2  2 x2 f ' x2   2 x2
16. (P) lim
x1   x  1
1
2
dt  lim
x1 1

 lim
2x  f  x   x   lim f  x   x
2 2 2 2
 2 x2 f ' x2   2 x 2
=4
x 1 2  x  1 x 1 1
n
 4 1
 
n n
(Q) lim 1  n 4  lim 1  
n n
 2 
  41/ n 1   1  41/ n 1  
lim  n  lim   1
n 2   n  2  1/ n   .n 4
e e 
e
2  2

2x
(R) f  x   lim tan 1  nx   x; x  0
n 
 n 1  1
lim  f  x   1  lim  x  1  1 (S) lim   r   lim 1  r   0.
x 0 x 0 n
 r 1 2  n  2 
17. (A) 2 sinx, sin 2x & 2 cosx are in A.P., hence sin 2x = sin x + cos x
Now, let sin x  cos x  t , then sin 2 x  t  1, then the above equation gives
2

1 5
t 2  t  1  0 or t  sin x  cos x 
2
 c   c
(B) Let C be the sides angles, then angles will be  , , 
3 3 3 3 3
 c    
 
 c  c  , hence angles are , ,
3 3 2 6 3 2
a b c a b c
Now     
   1 3 2
sin sin sin
6 2 2
  
Hence angles are , ,
6 3 2
a b c a b c
Now    
   1 3 2
sin sin sin
6 2 2
(C) Let AB  a, BC  3 a, CA  3a & AD  3 3 a
a 2  27 a 2  BD 2 a 2  9a 2  BD 2
Now cos A  cos C  0   0
3 3 a2 3 3 a2
BD
BD 2  20a 2   20  2 5
AB
2a 2 c 2 8a 2 c 2
 a  c  2
2
(D) a  c  2b & b  2
2

a  c2 a  c2
 a  c
2

  a  c   2ac  a  c   8a c  0
2 2 2 2
 2,4
ac
a
But gives a  c, hence taking – 2 a 2  4ac  c 2  0   3  2.
c
 
PHYSICS
  
18. a0   2 giˆ  gjˆ  FB  V  a0  g   2 Vg  iˆ  ˆj 
  
Fnet  FB  mg  2 Vg  iˆ  ˆj   0Vgjˆ
 2 ˆ ˆ   
anet  g  i  j   gjˆ arelative  anet  a0
0
T
19. Most probable velocity Vmp 
M
T T
From graph, V1  V2  1  2
M1 M 2
1
20. Applying Bernaullis theorem from the frame of car. Pin  0  Pout   v 2
2
Again  Pin  Pout    0.4     1.6  t
2

1 2 1 1.25  40  40  0.16
  v  0.16  4  107  1.6t   t t  2.5  m
2 2 1.60  4  107
3g r sin  4 4l
21. aQ  aP  g sin   r 
l  3 9
   
22.  
aB  a A    rB , A   rB , A
2
 5 j  4 i  3 j  12i  16 j 

aB along y-axis should be zero.
4
 11  3  0     rad / s 2
3
80
aB   4  12  i   i m / s 2
3
 MR 2
23. dT||   dm  r sin  T  TA 
2
1  cos 
2 2

24. Given 10 VSD = 9 MSD

1MSD
Least count =  0.1 mm
10
As '0' of V.S. lies before '0' of M.S.
Zero error = –[10 – 6] L.C.
= – 4 × 0.01 cm = –0.04 cm
 Reading = 4.1 cm + 2 × LC
= 4.1 cm + 2 × 0.01 cm = 4.12 cm
True diameter = Reading – Zero error = 4.12 – (–0.04) cm = 4.16 cm
ml 2 2k k  2
25.       l      
 5k 
12  12 4 m
 /2  2  1   2  R g
26. f  2    1   2  Rg  sin  d   2  1   2  R g  a  4
0  2 R 

d v2
27. 2T sin  dN   Rd (  is linear mass density of belt)
2 R
 Td  dN   v 2 d
  
  
2 2 2
 so total normal force   dN cos   T cos d  v  cos d
2

  
2 2 2
 N  8 newton

 
28. Since    , the upper block will move faster than the middle block and hence
4 2
force of friction on upper block is towards left
 g
 f  mg  aA  leftward
4 4
3 1
 3m  mg   mg
f ' . g aB  4 4   g leftwards
2 2 m
2
g 3 3L 1  3  L
a A/ B   g   g    g t 2 t   3s
4 4 8 2 4  g
29. Acceleration of particle with respect box is along perpendicular to inclined plane
vmin  g cos37  AB  CD  AC   8  2  3  3  8m / s
30. A system of pullies is massless,  net 0  0

T1 R  T3  3R   T2  2 R   0
T1  3T3  2T2 ____________ 1
8mg  T1  8m  R 
T1  8m  g  R  _________  2 
Similarly,
T3  2m  g  3R  _________  3 
T2  m  g  2 R  _________  4 
Substituting (2), (3), (4) in (1)
8m  g  R   6m  g  3R   2m  g  2 R 
12 g 120
12 g  30 R  R    4 ms 2
30 30
1 VdT 3dV dT
31.  P  tan    3   
T TdV V T
3
ln V  ln T  C  TV  constant
3

This is polytropic process with x  1  3  x  2

 25 
2 
nR 50
W T1  T2    3   1   J
x 1 3 9
 25 
2 
 Q  U  nCV T  5 3  1  25 J
 
  1
3 
  R  QP  nCP T   2  
5R  25 125
T  5  1  J
 2  3 3
 S  U  25 J for any polytropic co-efficient i.e., for any value of ' '.
3a 2
32.  P t  s
2V 3
3V
V  3
 Q  0   rel  2 
x a 2
V  3V
 R  t   rel 
x 2x
d 3V  1  dx  3V  3V  3 3
    2    2 
.  0 
dt 2  x  dt  2 x  2  4

 S  x  a  t  a    
3V 3V a 5a
2 2  4V  8
1 1  3x  3  5a 
2
25 3
A   b  h    x     
2 2  2  4  8  256
m
33. A) If 1  0  m1  0
m2
v
Then v2 f  0 and v1 f  v1i  1i  1
v1 f
m
When 1    m1  
m2
v
Then v2 f  2v1i and v1 f  v1i  1 f  1  Correct graph is (B)
v1i
B) From above discussion, the answer is – 1
m1 v
C) When  , 2 f  2
m2 v1i
v2 f m1
D)  0 if m2 is massive  when 0
v1i m2
v2 f m1
 2 if m2 is light  when is large
v1i m2
U  4  x  1  x  2  i 
2 2
34.
 dU
 4  2  x  1 x  2   2  x  1  x  2  
2 2

dx  
dU
Or,  8  x  1 x  2   x  2  x  1  8  x  1 x  2  2 x  3
dx
dU
Force on the particle is F    8  x  1 x  2  2 x  3  ii 
dx
dU
Force (i.e., ) is zero at x  1, 2,1.5m. These are positions of equilibrium. Nature of
dx
d 2U
the equilibrium can be ascertained by finding or just by plotting the graph of U
dx 2
versus x.

A) From (ii), the force on the particle is negative at x  1m. If it is released at

x  1m, it will move in the negative x direction.
B) If the particle is released at x  1m, it will remain in unstable equilibrium.
C) Force F  8  x  1 x  2  2 x  3
When the particle is displaced x from its equilibrium position at x  1.5 m (so that its
co-ordinate is 1.5  x ), the force on it is
F  8 1.5  x  11.5  x  2  3  2x  3
 8  0.5  x  x  0.5  2x 
 8  x 2  0.52   2x   16x  x 2  0.52 
If x  0.5, then x  0.5  0.5
2 2 2


Or, F  16x 0.5
2
  4x
 ma  4x  a  4x m  1kg 
 Motion is SHM and   4  2
D) It is same as (C)
 CHEMISTRY
35. Ionic product of D2O 1.35  10 15
 is less than ordinary water 1 10 14

D – O bond is stronger than O – H bond so ionization of D2O is less than H 2O

The pD value of neutral D2O is 7.43 so if D2O has pD 7.2 which is less than 7.43, D2O
is acidic. For neutral H 2O pH  7 but for D2O is 7.43
36. I & II are aromatic.
Basic order IV > III > II > I
37. Addition of Br2 on an alkene is a trans-addition. Q1 is a binary mixture and is optically
inactive due to external compensation. Note that the alkene P formed
 MeCH  CHEt  is an unsymmetrical alkene and hence anti addition of Br2 upon it
will not yield meso-product.
38. – 186 and – 104 are less than – 100°C. So they exist as liquids 60and 10 are greater than
– 100. So they vapourse and do not exist as liquids.
39. C60 soluble in benzene. The remaining statements are incorrect
2a a
40. In version temperature Ti  , Boyle’s temperature TB   Ti  2  TB
Rb Rb
8a 2a
Critical temperature TC  , Inversion temperature Ti 
27 Rb Rb
Critical temperature is less than Inversion temperature
Inversion tempature more than critical temperature and Inversion temperature.
41. G  H  TS
G  U  PV  TS
G  U  PV  V P  T S  S T
From the first and second laws,
T S  U  PV
 G  V P  S T
G
G  H T
T
OR
 G 
G  H T  
 T  P
H G 1  G 
 2  2   
T T T  T  P
  G / T  
 
 T  P
  G / T  
H  T 2   ]
 T  P
42.  Be  CH  3  ,  BeH 2 n ,  AlH 3  n , Al 2  CH 3  6 , B2 H 6 , Be  BH 4  2 and Al  BH 4 3 contain 3c-2e bonding
n

 BeCl 2 n , Al 2 Cl6 contain 3c-4e bonding

43. O 2 , O22 , O2 , O3 ions hydrolyse in water liberating oxygen converting into hydroxide
3 2 4
ions N gives NH 3 , C2 gives C2 H 2 , C3 gives propyne by reacing with water.
F  , Cl  , OH  , SO42 and NO3 ions exists in water as hydrated ions
K P1 4P1 4  1 1
44.     K P2  9K p1
K P2 P2 36 9

45. Given  2  30.4 107 cm 1  108.5 107 cm


let excited state of He be n2 . it comes from n2 to n1 and then n1 to 1 to emit two
1 1 1  1 1 1 
successive photon  R H .z 2  2   7
 109678  4  2  2  n1 = 2
2  1 n1 2  30.4  10  1 n1 
1 1 1 1 1 1
Now  R H z2  2  2  7
 109678  4  2  2 
1  2 n2  108.5 10  2 n2 
n 2  5 thus excited state for He is 5th orbit.
46.
x is CH3 CH2Cl

Cl2/hv

Cl2/FeCl3

CH3 CH3

Cl
+

Cl
47. Each aromatic ring can have three resonating forms.
48.
49. Mixture I:
End point with phenolphthalein (disappearance of pink colour ) corresponds to the
neutralisation of NaOH and half- neutralisation of Na2CO3 .
NaOH  HCl  NaCl  H 2O
Na2CO3  HCl  NaHCO3  NaCl
End point with Methyl orange (Appearance of Red colour ) corresponds to the
neutralisation of NaOH and Na2CO3 .
NaOH  HCl  NaCl  H 2O
Na2CO3  2 HCl  2 NaCl  CO2  H 2O
Volume of HCl required for neutralisation of Na2CO3
 = 2  x  w
1 2  x  w 
Normality of Na2CO3 =
100
2  x  w   10 2

Molarity of Na2CO3 =  x  w 102

Volume of HCl req. for neutralisation of NaOH
 w   x  w
=  2w  x  ml

Hence, molarity of NaOH =

 2w  x  1
100
=  2w  x  102 M
Mixture II :
End point with phenolphthalein corresponds to half- neutralisation of Na2CO3 as
Na2CO3  HCl  NaHCO3  NaCl
Volume of HCl req. for complete neutralisation of Na2CO3 = ‘2y’ ml
1 2y
 Molarity of Na2CO3  
2 100
= y 102
End point with Methyl orange corresponds to neutralisation of NaHCO3
Hence, volume required for neutralisation of NaHCO3 present initially =  z  2 y  ml
 Molarity of NaHCO3 =
 z  2y
100
=  z  2 y  10 2

50. Conceptual
51. Conceptual