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B.Sc. III Semester Degree Examination, March/April - 2023
CHEMISTRY
Paper No. 3 : Analytical and Organic Chemistry
(NEP)
Time : 2 Hours Maximum Marks : 60
Note : Answer all sections.
SECTION - A
1. Answer the following sub-questions. Each sub-question carries one mark. 10x1=10
(a) Define wave number and give its unit. 1
(b) Write the principle of paper chromatography. 1
(c) What is spectrophotometer ? 1
(d) What is Rf value ? 1
(e) State the Nernst distribution law. 1
(f) What are carbocations ? 1
(g) What is Van Deemters equation ? 1
(h) Define enantiomers and give an example. 1
(i) What is carbon ion ? 1
(j) What is geometrical isomerism ? 1
SECTION - B
Answer any four of the following questions, each question carries five marks.
4x5=20
2. Explain calibration graph. 5
3. Discuss the Instrumentation of nephelometry. 5
4. Briefly discuss the applications of Ion-exchange chromatography. 5
5. How does the delocalization of carbonium ion leads to Dienone phenol
rearrangement ? Explain with a suitable example. 5
6. Define mesocompound and give any two examples. 5
7. Write a note on thin layer chromatography. 5
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SECTION - C
Answer any three of the following questions, each question carries ten marks.
3x10=30
8. (a) Derive Beer’s-lambert law. 6
(b) Give any four limitations of Beer’s law. 4
9. (a) Write any five differences between nephelometry and turbidimetry. 6
(b) What are factors affecting on column efficiency ? Explain. 4
10. (a) Define chromatography. Give any four principles of Thin layer chromatography. 6
(b) Discuss the solvent extraction procedure with a suitable example. 4
11. (a) How does free radicals stabilized by (i) Inductive effect (ii) Resonance effect. 6
(b) Discuss the effect of catalyst on reaction mechanism ? 4
12. (a) What are resolution ? Explain the diastereomeric method of seperation of 6
enantiomers from its racemic mixture.
(b) Check the order of priority and assign the R/S configuration of the following. 4
(i) 2-Hydroxybutane
(ii) 2-Amino Propanoic acid
(iii) 2-Bromo-2-Deutoriumethane
(iv) 1-Bromo-1-Chloroethane
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