IIT-JEE (ADVANCED)

TEST-3 (PA PER-1)

STANDARD ANSWER KEY

Q 1 2 3 4 5 6 7 8 9 10
A BCD AB ACD ABC AB AD ABCD 5 3 2
Q 11 12 13 14 15 16 17 18 19 20
A 3 1 6 1 5 2 A C AD ABD
Q 21 22 23 24 25 26 27 28 29 30
A BCD AB AC BCD ABD 3 3 2 4 0
Q 31 32 33 34 35 36 37 38 39 40
A 4 3 3 3 A B AC AC BC AD
Q 41 42 43 44 45 46 47 48 49 50
A CD BCD ABD 1 1 5 4 8 4 2
Q 51 52 53 54
A 3 2 C D
(1) (BCD).
The flow of heat will always be in the direction of the temperature gradient from higher to lower
temperature. Hence Q1 in rod AB, Q2 in rod BC will both be in clockwise sense while Q 3 in CA will
be in anti-clockwise sense. Also, we have if L is the length of each rod and A its area of cross section,

Hence,

Also,

(2) (AB).
(A) Rate at which heat is radiated from the body = Qr J/s = eAT14
= 0.55 × 5.67 × 10–8 × 1.5 × (323)4 J/s = 509 W
(B) Rate at which heat radiation is absorbed by the body
= Qa J/s = eAT24 = 0.55 × 5.67 × 10–8 × 1.5 × (295)4 J/s = 354 W
(3) (ACD). Since, e = a = 0.2 (Since, a = (1 – r – t) = 0.2 for the body B)
E = (100) (0.2) = 20 W/m2
Power emitted = e.A = 20 × 10 = 200 Watt
(4) (ABC). TVa–1 = const.
a – 1 = 1/2 ; a = 3/2

C = CV – 2R
As V increases, temperature decreases hence internal energy decreases.
(5) (AB). PV = constant = c

. Also,

(6) (AD). Radiating power P = 4r2 . T4 P  r2

 = cooling rate R 

(7) (ABCD). Let us find of the gas mixture which is given by , where n stands for

mass in moles.
Since oxygen is diatomic

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 For argon , since argon is monatomic.

Hence, 

Simplifying  = 1.55
= 15.2 J mol–1 K–1

Cp =  Cv = 1.55 × 15.2 = 23.56 J mol–1 K–1

(8) 5.

12 = 7 + 7

(9) 3.

(10) 2. P =  A e (30004 – 3004) = 2 kW.

(11) 3. 1, 1  steel rod
2, 2  Brass rod
As difference in lengths is constant
 1 = 2
 11T = 22T
 11 = 22 ..... (1)
Also, 1 – 2 =  ..... (2)
From (1) and (2)

and

Sum = = 300 cm = 3 m

(12) 1. For an adiabatic change in case of a monatomic gas, TV–1 = constant.

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 In this case x itself is ( – 1) and  = 5/3 giving the value of x.
(13) 6. Let initial pressure, volume, temperature be P0, V0, T0 indicated by state A in P-V diagram.
The gas is then isochorically taken to state B (2P0, V0, 2T0) and then taken from state B to state C
(2P0, 2V0, 4T0) isobarically.
P
2T 0 4T 0
2P 0
B C

P0 T0
A
V
V0 2V 0
Total heat absorbed by 1 mole of gas
Q = Cv (2T0 – T0) + Cp (4T0 – 2T0)

=
Total change in temperature from state A to C is Q = 3T0

 Molar heat capacity =

(14) 1. The rate of heat loss by a thin hollow sphere of thickness x, mean radius r and made of density  is
given by

  is independent of radius.

Hence, rate of cooling is same for both spheres.

1 : a = 1 : 1 a = 1
(15) 5. A gas is suddenly expanded so it is an adiabatic expansion i.e. PV = constant
or
Given : V2 = 3V1, Cv = 2R
 CP = 2R + R = 3R

or

(16) 2.

P2 = 2P1
(17) (A). i : isochoric, ii : isothermal, iii : isobaric
iv : Compression process (Temp. decreases)
(18) (C).

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 (i) Initially more heat will enter through section A but the metal will absorb some heat and less heat will
leave from C.
(ii) At steady state heat accumulation is same for all sections

(iii) At steady state or

is inversely proportional to area of cross-section. Hence is maximum at B and minimum at C.
(iv) At steady state heat accumulation = 0
So for any section.
(19) (AD). He has the structure 1s 2. It has a nuclear charge of +2 and the removal of a paired electron from first
orbit will be most difficult. Rare gases with completely filled orbits have highest I.P values.
O–(g) + e–  O2– (g) is endothermic.
The I.P's of S and P (III period elements) are greater than O and N (II period).
(20) (ABD). BeF2 is highly soluble in water due to high solvation energy of Be2+.
Be2C gives methane on hydrolysis. Mg 2C3 gives allylene (methyl acetylene) CH 3–CCH (and not
propene).
Bicarbonates of II group metals are stable in solution only and not in solid state.
(21) (BCD). HgCl2 : Cl – Hg – Cl
(–) (–) (–)
N3– : N = N = N
I
..

I
..

..

I3– : I

All the three. .are linear molecules

Sn

SnCl2 : Cl Cl Angular molecule.

(22) (AB). Ca2+ is much larger in size than Na+. Hence, hydration energy of CaSO4 is smaller than its lattice
energy and so it is only sparingly soluble while due to very small size and extensive hydration of Na +
ion, Na2SO4 is highly soluble.
(23) (AC). Statement (B) is false. Enthalpy of formation of diamond is +1.9 kJ mol–1.
Statement (D) is false. Boron is the hardest element in group 3.
(24) (BCD). Statement (A) is false. Like diamond, boron nitride is a non-conductor as all the electrons are
involved in B–N bonding.
(25) (ABD). Hardness due to calcium bicarbonate is temporary, which can be removed by boiling or adding
Slaked Lime: Ca(OH)2 or Washing Soda: Na2CO3; and several other methods.
In the given sample, [Ca2+] = ½ [HCO3–] = 0.5 mM.
Hardness of water is measured in ppm of CaCO3
= [Ca2+] ×105 = 0.5 × 10–3 × 105 = 50 ppm of CaCO3.
(26) 3. In sheet silicates, 3 oxygen atoms per [SiO4]4– tetrahedral are shared.

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(27) 3. B2H6 + H2O  H3BO3 + H2 
SiH4 + H2O  SiO2 + H2 
(28) 2. At. No. = 16(S)
Next element below this element has atomic number = 16 + 18 = 34
(29) 4. Energy needed to convert 1 mole of sodium(g) to sodium ions = 495 kJ
 Energy needed to convert 3 mole of Na (g) to Na+ ions = 495 × 3 = 1485 kJ
(30) 0. The formulae of Gypsum, Plaster of Paris and Epsom salt are :
CaSO4.2H2O, CaSO4, 0.5H2O and MgSO4.7H2O
(31) 4
(32) 3
(33) 3
(34) 3
(35) (A).
(i) E.N. as O.S.  because attraction of shared pair electron  E.N. difference between E – O  b basic
character  .
Attraction for electrons –  eg H .

Degree of hydration charge on cation  .

(ii) Size  E.N.  ; EN of E – O basic character  but Al2O3 is amphoteric,
– eg H  with size  .
(iii) Acidity of their oxides seems to nearly same so cannot predict their relative strength.
(iv) N has half-filled configuration. So – eg H will be  than C.
(36) (B).
(i) Bi3+ hydrolysis to (BiO)+
(ii) [AIO2]– exists in basic medium, on acidification gives
Al(OH)3.
(iii) Orthosilicate (SiO44–) on heating changes into pyrosilicate Si2O76–.
(iv) Tetraborate ion [B4O72–] on treatment with dil. acid hydrolysis gradually to orthoboric acid.
(37) (AC). (–3, ) lies on x = –3
x
=
y

y= –x M
L y=2
S
R
3x + 4y – 12 = 0

x= –3
(m, 2) lies on y = 2
(–3, ) will be interior point, if  varies between yL and yM·
(m, 2) will be interior point if m varies between xR and xS.
 varies from 3 to 21/4
m varies from –2 to 4/3.

(38) (AC). Centre is (1, –2)

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 Radius =
AB2 = 2 + 2
20 = 22 2 = 10


Equation of OA is

If r = . It corresponds to A
 A is
It lies on the circle.

; ; tan  = 2

; tan ( + ) = 1 ; tan  = –1/3

Equation of OA is x + 3y = 0
Other slope is 3.
 Equation of the other line is 3x – y = 0
 Equation of OA can be taken either as x + 3y = 0 or 3x – y = 0
(39) (BC). (8 sin  + 7 cos )2 + (7 sin  – 8 cos )2 = 82 (cos2  + sin2 ) + 72 (cos2  + sin2 )
= 82 + 72 (7 sin  – 8 cos )2 = 82 + 72 – (8 sin  + 7 cos )2 = 82 + 72 – 82 = 72
 7 sin  – 8 cos  = ± 7

(40) (AD).

i.e., 4R abc  r (b + c) (c + a) (a + b)
(41) (CD).

i.e.,

By hypothesis,



i.e., –ab < a2 + b2 – c2 < ab

(a + b)2 > c2 + ab and (a – b)2 < c2 – ab

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(42) (BCD). Equation of family of circles passing through two given points
A (0, 1) and B (0, 9) is s + L = 0
(x– 0) (x – 0) + (y – 1) (y – 9) + (x) = 0
 x2 + y2 –10y + 9 + (x) = 0 ... (1)
It touches x-axis  g = C 2

 Required circles are x2 + y2 + 6x –10y + 9=0 and x2 + y2 – 6x – 10y + 9 = 0

 (B), (C) and (D) are correct.
(43) (ABD). (sin2x + cos2x)3 – 3 sin2x cos2x (sin2x + cos2x) >

 1 – 3 sin2x cos2x >

 > 3 sin2x cos2x

 1 – 2 sin2 2x > 0 cos 4x > 0

 4x  4x  , n Z

(44) 1.

 IA.IB.IC = 64R3 sin2 sin2 sin2

= 8R3 sin A sin B sin C

(45) 1. The determinantal equation becomes

(sin x – cos x)2 (sin x + 2 cos x) = 0
sin x + 2 cos x = 0 tan x = –2



 sin x = cos x x = /4

 The number of solution is one.

(46) 5. Using Sine law,

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  ...(1)

Again

= 4 cos  cos 2 = 4 cos  (1 – 2 sin2)

Hence, b = 35. So,

(47) 4. x2 – 3y2 – 2xy + 8y – 4 (x – 3y + 2) (x + y – 2)

(0 , 0 ) (2 , 0 )
(– 5 , – 1 )

From diagram slope (–1, 1/5)

a = –1, b = 1/5
a+ =4
(48) 8.
Equation of line BC, 4x – 3y + 3 = 0 A
We known that image orthocentre about BC lies on circumcircle
N
So, HM = 2HT = 2 × (1,2 )
H
P
(2,3)

B T C
Equation of line HA = (y – 2) = – (x – 1) = 3x + 4y – 11 = 0
4 x – 3y + 3 = 0 M

HNP is right angles so,

So, radius

(49) 4. tan 9° + cot 9° – (tan 27° + cot 27°)

=

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(50) 2.

= 2 (1 + sin x) + 2 | sin x | = 2 + 2 sin x – 2 sin x = 2

(51) 3. Let (, 3 – ) be any point on x + y = 3
 equation of chord of contact is x + (3 – ) y = 9
i.e., (x – y) + 3y – 9 = 0
 The chord passes through the point (3, 3) for all values of .
(52) 2. Equation of circle is x2 + y2 + 2gx +2fy + c = 0
(1, t) 1 + t2 + 2g + 2ft + c = 0
(t, t) t2 + t2 + 2gt + 2ft + c = 0
(t, 1)  1 + t2 + 2gt + 2f + c = 0
Subtract 1 + 2g – t2 – 2gt = 0
 1 – t2 + 2g(1 – t) = 0
 (1 – t)(1 + t + 2g) = 0 t = 1
 one point (t, t) passes through (1, 1)
(53) (C).

(i) =3

(ii) N =

 5 + log2 N = 5 + log2 =3

(iii) 6 cos x + 8 sin x = 2 + 1

i.e.


Number of integral values of  is 10.
(iv) Least value of 3sin2 + 4 cos2 is 3.
(54) (D).
(i) Centre and radius of the circle
x2 + y2 + 14x – 4y + 28 = 0 are (–7, 2), 5 respectively
Centre and radius of the circle x2 + y2 – 14x + 4y – 28 = 0 are (7, –2), 9
 Length of direct common tangent =
(ii) The line is mx – y + 2 – m = 0

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 which is true for all real values of m

(iii) i.e.,
 For y = 0, we have x2 + 2 = r2
 If r is rational and r2 > 2, then there are 2 points on the circle which have rational co-ordinates.
Further if there are three point, then circumcentre of the triangle fromed by these three point has
rational co-ordinates, which is not so.
 Maximum number of points is 2.
(D) Let (h, k) be the centre, then | h | = | k | and | h + k – 4 | =
Case - 1 : If h = k, then | 2h – 4 | = | h | i.e. 2h – 4 = ±
It gives two different values of (h, k)
Case 2 : If h = – k, then i.e.
It a gain gives two different points (h, k) thus there are 4 different circles.

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