SDFSDFD
SDFSDFD
Warning
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P273 Avoid release to the environment.
P280 Wear protective gloves and eye protection/face protection.
P391 Collect spillage.
Hazard components for labelling
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Glycerol, propoxylated, esters with acrylic acid
hexamethylene diacrylate
Ethoxylated trimethylolpropane triacrylate
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Supplemental hazard information
not applicable
2.3. Other hazards
This product does not contain a substance that has endocrine disrupting properties with respect to humans as no
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
4.2. Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
alcohol resistant foam, carbon dioxide fire blanket, Powder, spray mist, (water)
Unsuitable extinguishing media
strong water jet
5.2. Special hazards arising from the substance or mixture
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device. Cool closed containers that are near the source of the fire. Do
not allow water used to extinguish fire to enter drains, ground or waterways.
Additional information
No data available
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see section 13). Clean using cleansing
agents. Do not use solvents.
6.4. Reference to other sections
Observe protective provisions (see section 7 and 8).
SECTION 7: Handling and storage
Persons with a history of skin sensitisation problems should not be employed in any process in which this product is used.
7.1. Precautions for safe handling
Advices on safe handling
Use only in well-ventilated areas. Keep away from heat sources, sparks and open flames. Avoid contact with skin, eyes and
clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using
do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure - no
pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal
protection and safety regulations.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks.
Hints on joint storage
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Protect
from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
only for authorised persons. Store carefully closed containers upright to prevent any leaks. Keep only in the original
container.
7.3. Specific end use(s)
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
DNEL:
hexamethylene diacrylate
Index No. 607-109-00-8 / EC No. 235-921-9 / CAS No. 13048-33-4
DNEL long-term dermal (systemic), Workers: 2,77 mg/kg
DNEL long-term inhalative (systemic), Workers: 24,5 mg/m³
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
DNEL long-term dermal (systemic), Workers: 1,7 mg/kg
DNEL long-term inhalative (systemic), Workers: 2,35 mg/m³
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
DNEL long-term dermal (systemic), Workers: 33 mg/kg
DNEL long-term inhalative (systemic), Workers: 1,17 mg/m³
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
DNEL long-term dermal (systemic), Workers: 2,1 mg/kg
DNEL long-term inhalative (systemic), Workers: 7,4 mg/m³
Methyl 2-benzoylbenzoate
EC No. 210-112-3 / CAS No. 606-28-0
DNEL long-term dermal (systemic), Workers: 1,46 mg/kg
DNEL long-term inhalative (systemic), Workers: 0,37 mg/m³
PNEC:
hexamethylene diacrylate
Index No. 607-109-00-8 / EC No. 235-921-9 / CAS No. 13048-33-4
PNEC aquatic, freshwater: 0,007 mg/L
PNEC aquatic, marine water: 0,001 mg/L
PNEC sediment, freshwater: 0,0493 mg/kg
PNEC sediment, marine water: 0,049 mg/kg
PNEC, soil: 0,094 mg/kg
PNEC sewage treatment plant (STP): 2,7 mg/L
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
PNEC aquatic, freshwater: 0,005 mg/L
PNEC aquatic, marine water: 0,0005 mg/L
PNEC aquatic, intermittent release: 0,046 mg/L
PNEC sediment, freshwater: 0,487 mg/kg
PNEC sediment, marine water: 0,049 mg/kg
PNEC, soil: 0,095 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
PNEC aquatic, freshwater: 0,025 mg/L
PNEC aquatic, marine water: 0,003 mg/L
PNEC sediment, freshwater: 8,96 mg/kg
PNEC sediment, marine water: 0,896 mg/kg
PNEC, soil: 1,78 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
PNEC aquatic, freshwater: 0,0057 mg/L
PNEC aquatic, marine water: 0,0006 mg/L
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
Viscosity at 20 °C: 80 s 4 mm
Method: 3 DIN EN ISO 2431
Solubility(ies):
Water solubility at 20 °C: insoluble
Partition coefficient: n-octanol/water: see section 12
Vapour pressure at 20 °C: not determined
Density and/or relative density:
Density at 20 °C: 1,10 g/cm³
Relative vapour density: not determined
particle characteristics: not applicable
9.2. Other information
solvent content:
Organic solvents: 0,0 weight-%
Solvent separation test: < 3 weight-% (ADR/RID)
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
section 7.
10.3. Possibility of hazardous reactions
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
10.4. Conditions to avoid
This preparation contains material instable under the following conditions: Heat, strong ultraviolet radiation. An exotherm
polymerization of the product may thereby be caused. Avoid unintended contact with it. Hazardous decomposition byproducts
may form with exposure to high temperatures.
10.5. Incompatible materials
not applicable
10.6. Hazardous decomposition products
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
hexamethylene diacrylate
oral, LD50, Rat: > 5000 mg/kg
dermal, LD50, Rabbit: 3600 mg/kg
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
oral, LD50, Rat: > 2000 mg/kg
dermal, LD50, Rabbit: > 2000 mg/kg
Ethoxylated trimethylolpropane triacrylate
oral, LD50, Rat: > 2000 mg/kg
dermal, LD50, Rabbit: > 13200 mg/kg
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
oral, LD50, Rat: > 2000 mg/kg
Method: OECD 401
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
EU legislation
Directive 2010/75/EU on industrial emissions [Industrial Emissions Directive]
VOC-value (in g/L): 0,399
National regulations
Restrictions of occupation
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juveniles according to the 'juvenile work protection guideline' (94/33/EC).
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Full text of classification in section 3:
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 2 / H411 Hazardous to the aquatic environment Toxic to aquatic life with long lasting effects.
Skin Irrit. 2 / H315 Skin corrosion/irritation Causes skin irritation.
Eye Irrit. 2 / H319 Serious eye damage/eye irritation Causes serious eye irritation.
Aquatic Acute 1 / H400 Hazardous to the aquatic environment Very toxic to aquatic organisms.
Skin Sens. 1B / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 3 / H412 Hazardous to the aquatic environment Harmful to aquatic life with long lasting effects.
STOT SE 3 / H335 STOT-single exposure May cause respiratory irritation.
STOT RE 2 / H373 STOT-repeated exposure May cause damage to organs (or state all
organs affected, if known) through prolonged or
repeated exposure (state route of exposure if it
is conclusively proven that no other routes of
exposure cause the hazard).
Acute Tox. 4 / H302 Acute toxicity (oral) Harmful if swallowed.
Classification procedure
Classification for mixtures and used evaluation method according to regulation (EC) No 1272/2008 [CLP]
Skin Irrit. 2 Skin corrosion/irritation Calculation method.
Eye Irrit. 2 Serious eye damage/eye irritation Calculation method.
Skin Sens. 1 Respiratory or skin sensitisation Calculation method.
Aquatic Chronic 2 Hazardous to the aquatic environment Calculation method.
Abbreviations and acronyms
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
OEL Occupational Exposure Limit Value
BLV Biological Limit Value
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging
CMR Carcinogenic, Mutagenic and Reprotoxic
DIN German Institute for Standardization / German industrial standard
DNEL Derived No-Effect Level
EAKV European Waste Catalogue Directive
EC Effective Concentration
EC European Community
EN European Standard
IATA-DGR International Air Transport Association – Dangerous Goods Regulations
IBC Code International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk
ICAO-TI International Civil Aviation Organization Technical Instructions for the Safe Transport of Dangerous
Goods by Air
IMDG Code International Maritime Code for Dangerous Goods
ISO International Organization for Standardization
LC Lethal Concentration
LD Lethal Dose
MARPOL Maritime Pollution: The International Convention for the Prevention of Pollution from Ships
OECD Organisation for Economic Cooperation and Development
PBT persistent, bioaccumulative, toxic
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
UN United Nations
VOC Volatile Organic Compounds
vPvB very persistent and very bioaccumulative
Further information
Classification according to Regulation (EC) No 1272/2008 [CLP]
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations.Without written approval, the product must not be used for purposes different from those mentioned in section
1.It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and
regulations.The details in this safety data sheet describe the safety requirements of our product and are not to be regarded
as guaranteed attributes of the product.