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SDFSDFD

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0% found this document useful (0 votes)
71 views11 pages

SDFSDFD

Uploaded by

Aleko Iosava
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)


according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 1 / 11

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Article No. (manufacturer/supplier): U70717
Trade name/designation UV-Coating U70717 HighGloss Dual Effect
UFI: E3D0-Q00G-2006-AX29
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Coating for graphic industry
Uses advised against:
No data available
1.3. Details of the supplier of the safety data sheet
manufacturer
Heidelberger Druckmaschinen AG
Kurfuersten-Anlage 60 Telephone: +49 6221 92 00
69115 Heidelberg - Germany Telefax: +49 6221 92 69 99
Department responsible for information:
Department Consumables
E-mail consumables-msds@heidelberg.com
1.4. Emergency telephone number
Giftinformationszentrum Nord +49 551 19240

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP]
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
Skin Irrit. 2 / H315 Skin corrosion/irritation Causes skin irritation.
Eye Irrit. 2 / H319 Serious eye damage/eye irritation Causes serious eye irritation.
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 2 / H411 Hazardous to the aquatic environment Toxic to aquatic life with long lasting effects.
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms

Warning

Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P273 Avoid release to the environment.
P280 Wear protective gloves and eye protection/face protection.
P391 Collect spillage.
Hazard components for labelling
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Glycerol, propoxylated, esters with acrylic acid
hexamethylene diacrylate
Ethoxylated trimethylolpropane triacrylate
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Supplemental hazard information
not applicable
2.3. Other hazards
This product does not contain a substance that has endocrine disrupting properties with respect to humans as no
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 2 / 11

components meets the criteria.


SECTION 3: Composition/information on ingredients
3.2. Mixtures
Description: Mixture of substances listed below with nonhazardous additions
Hazardous ingredients:
Classification according to Regulation (EC) No 1272/2008 [CLP]
EC No.: REACH No.:
CAS No.: Designation weight-%
Index No.: classification: // Remark
500-130-2 01-2119490020-53-XXXX
55818-57-0 4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, 20 < 25
acrylate
Skin Sens. 1 H317 / Aquatic Chronic 2 H411
235-921-9 01-2119484737-22-XXXX
13048-33-4 hexamethylene diacrylate 20 < 25
607-109-00-8 Skin Irrit. 2 H315 / Eye Irrit. 2 H319 / Skin Sens. 1 H317 / Aquatic Acute 1
H400 (M = 1) / Aquatic Chronic 2 H411
500-066-5 01-2119489900-30-XXXX
28961-43-5 Ethoxylated trimethylolpropane triacrylate 12,5 < 20
Eye Irrit. 2 H319 / Skin Sens. 1B H317 / Aquatic Chronic 3 H412
256-032-2 01-2119484613-34-XXXX
42978-66-5 (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate 5 < 10
607-249-00-X Eye Irrit. 2 H319 / STOT SE 3 H335 / Skin Irrit. 2 H315 / Skin Sens. 1
H317 / Aquatic Chronic 2 H411
Specific concentration limit (SCL): STOT SE 3 H335 >= 10
210-112-3 01-2120103325-72-XXXX
606-28-0 Methyl 2-benzoylbenzoate 2,5 < 5
STOT RE 2 H373 / Aquatic Chronic 2 H411
231-272-0 01-2119472306-39-XXXX
7473-98-5 2-hydroxy-2-methylpropiophenone 1 < 2,5
Acute Tox. 4 H302 / Aquatic Chronic 3 H412
500-114-5 01-2119487948-12-XXXX
52408-84-1 Glycerol, propoxylated, esters with acrylic acid 0,25 < 0,5
Eye Irrit. 2 H319 / Skin Sens. 1 H317
Additional information
Full text of classification: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth,
place in recovery position and seek medical advice.
In case of inhalation
Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial
respiration.
Following skin contact
Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do
not use solvents or thinners. Following skin contact
Conditions to avoid UV-radiation/sunlight
Causes mild skin irritation.
After eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek
medical advice immediately.
Following ingestion
If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm.
Do NOT induce vomiting.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 3 / 11

4.2. Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
alcohol resistant foam, carbon dioxide fire blanket, Powder, spray mist, (water)
Unsuitable extinguishing media
strong water jet
5.2. Special hazards arising from the substance or mixture
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device. Cool closed containers that are near the source of the fire. Do
not allow water used to extinguish fire to enter drains, ground or waterways.
Additional information
No data available
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see section 13). Clean using cleansing
agents. Do not use solvents.
6.4. Reference to other sections
Observe protective provisions (see section 7 and 8).
SECTION 7: Handling and storage
Persons with a history of skin sensitisation problems should not be employed in any process in which this product is used.
7.1. Precautions for safe handling
Advices on safe handling
Use only in well-ventilated areas. Keep away from heat sources, sparks and open flames. Avoid contact with skin, eyes and
clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using
do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure - no
pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal
protection and safety regulations.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks.
Hints on joint storage
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Protect
from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
only for authorised persons. Store carefully closed containers upright to prevent any leaks. Keep only in the original
container.
7.3. Specific end use(s)
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 4 / 11

Observe technical data sheet.


SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limit values
not applicable

DNEL:
hexamethylene diacrylate
Index No. 607-109-00-8 / EC No. 235-921-9 / CAS No. 13048-33-4
DNEL long-term dermal (systemic), Workers: 2,77 mg/kg
DNEL long-term inhalative (systemic), Workers: 24,5 mg/m³
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
DNEL long-term dermal (systemic), Workers: 1,7 mg/kg
DNEL long-term inhalative (systemic), Workers: 2,35 mg/m³
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
DNEL long-term dermal (systemic), Workers: 33 mg/kg
DNEL long-term inhalative (systemic), Workers: 1,17 mg/m³
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
DNEL long-term dermal (systemic), Workers: 2,1 mg/kg
DNEL long-term inhalative (systemic), Workers: 7,4 mg/m³
Methyl 2-benzoylbenzoate
EC No. 210-112-3 / CAS No. 606-28-0
DNEL long-term dermal (systemic), Workers: 1,46 mg/kg
DNEL long-term inhalative (systemic), Workers: 0,37 mg/m³
PNEC:
hexamethylene diacrylate
Index No. 607-109-00-8 / EC No. 235-921-9 / CAS No. 13048-33-4
PNEC aquatic, freshwater: 0,007 mg/L
PNEC aquatic, marine water: 0,001 mg/L
PNEC sediment, freshwater: 0,0493 mg/kg
PNEC sediment, marine water: 0,049 mg/kg
PNEC, soil: 0,094 mg/kg
PNEC sewage treatment plant (STP): 2,7 mg/L
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
PNEC aquatic, freshwater: 0,005 mg/L
PNEC aquatic, marine water: 0,0005 mg/L
PNEC aquatic, intermittent release: 0,046 mg/L
PNEC sediment, freshwater: 0,487 mg/kg
PNEC sediment, marine water: 0,049 mg/kg
PNEC, soil: 0,095 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
PNEC aquatic, freshwater: 0,025 mg/L
PNEC aquatic, marine water: 0,003 mg/L
PNEC sediment, freshwater: 8,96 mg/kg
PNEC sediment, marine water: 0,896 mg/kg
PNEC, soil: 1,78 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
PNEC aquatic, freshwater: 0,0057 mg/L
PNEC aquatic, marine water: 0,0006 mg/L
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 5 / 11

PNEC sediment, freshwater: 0,078 mg/kg


PNEC sediment, marine water: 0,0078 mg/kg
PNEC, soil: 0,0122 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
Methyl 2-benzoylbenzoate
EC No. 210-112-3 / CAS No. 606-28-0
PNEC aquatic, freshwater: 9,16 µg/L
PNEC aquatic, marine water: 0,916 µg/L
PNEC aquatic, intermittent release: 91,6 µg/L
PNEC sediment, freshwater: 0,219 mg/kg
PNEC sediment, marine water: 0,022 mg/kg
PNEC, soil: 0,041 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
8.2. Exposure controls
Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and
solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.
Personal protection equipment
Respiratory protection
If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection
must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection
apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number.
This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter
(i.e. type A1 according to standard EN 14387) is used.
Hand protection
For prolonged or repeated handling the following glove material must be used: Nitrile rubber, NR
Thickness of the glove material: > 0,56 mm; Breakthrough time: > 480 min.
Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove
manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended
glove articles EN ISO 374
Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
Eye/face protection
Wear closely fitting protective glasses in case of splashes.
Body protection
Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.
Protective measures
After contact clean skin thoroughly with water and soap or use appropriate cleanser.
Environmental exposure controls
Do not allow to enter into surface water or drains. See section 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Physical state: Liquid


Colour: colourless
Odour: characteristic
Odour threshold: No data available
Melting point/freezing point: not applicable
Initial boiling point and boiling range: not applicable
Flammability: not determined
Lower and upper explosion limit:
Lower explosion limit: No data available
Upper explosion limit: No data available
Flash point: > 100 °C
Method: DIN 53213
Auto-ignition temperature: not determined
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 6 / 11

Decomposition temperature: not determined

pH at 20 °C: not applicable


Kinematic viscosity (40°C): not determined

Viscosity at 20 °C: 80 s 4 mm
Method: 3 DIN EN ISO 2431
Solubility(ies):
Water solubility at 20 °C: insoluble
Partition coefficient: n-octanol/water: see section 12
Vapour pressure at 20 °C: not determined
Density and/or relative density:
Density at 20 °C: 1,10 g/cm³
Relative vapour density: not determined
particle characteristics: not applicable
9.2. Other information
solvent content:
Organic solvents: 0,0 weight-%
Solvent separation test: < 3 weight-% (ADR/RID)
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
section 7.
10.3. Possibility of hazardous reactions
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
10.4. Conditions to avoid
This preparation contains material instable under the following conditions: Heat, strong ultraviolet radiation. An exotherm
polymerization of the product may thereby be caused. Avoid unintended contact with it. Hazardous decomposition byproducts
may form with exposure to high temperatures.
10.5. Incompatible materials
not applicable
10.6. Hazardous decomposition products
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
hexamethylene diacrylate
oral, LD50, Rat: > 5000 mg/kg
dermal, LD50, Rabbit: 3600 mg/kg
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
oral, LD50, Rat: > 2000 mg/kg
dermal, LD50, Rabbit: > 2000 mg/kg
Ethoxylated trimethylolpropane triacrylate
oral, LD50, Rat: > 2000 mg/kg
dermal, LD50, Rabbit: > 13200 mg/kg
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
oral, LD50, Rat: > 2000 mg/kg
Method: OECD 401
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 7 / 11

dermal, LD50, Rat: > 2000 mg/kg


Glycerol, propoxylated, esters with acrylic acid
oral, LD50, Rat: > 2000 mg/kg
Method: OECD 401
dermal, LD50, Rabbit: > 2000 mg/kg
Method: OECD 402
Methyl 2-benzoylbenzoate
oral, LD50, Rat: 2000 mg/kg
dermal, LD50, Rat: > 2000 mg/kg
Skin corrosion/irritation; Serious eye damage/eye irritation
Causes skin irritation.
Causes serious eye irritation.
Respiratory or skin sensitisation
May cause an allergic skin reaction.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Based on available data, the classification criteria are not met.
STOT-single exposure; STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Practical experience/human evidence
The fractions of acrylic resin in the preparation have an irritant effect. Prolonged or repeated contact with the preparation can
lead to irritations of mucous membranes and of skin such as redness, formation of blebs, dermatitis, etc.. Cases of allergic
skin reactions have been observed. Liquid splashes can lead to irritations of the eyes. Inhaling of drolets in the air or aerosols
may lead to irritations of the respiratory tract . Ingestion may cause nausea, weakness and affect the central nervous system.
Overall assessment on CMR properties
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.
11.2. Information on other hazards
Endocrine disrupting properties
This product does not contain a substance that has endocrine disrupting properties with respect to humans as no
components meets the criteria.
SECTION 12: Ecological information
Classification according to Regulation (EC) No 1272/2008 [CLP]
Do not allow to enter into surface water or drains.
12.1. Toxicity
hexamethylene diacrylate
Fish toxicity, LC50, Oryzias latipes (Ricefish): 0,38 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 2,7 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Desmodesmus subspicatus: 1,5 mg/L (72 h)
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Fish toxicity, LC50, Leuciscus idus (golden orfe) 4,6 - 10 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: 89 mg/L (48 h)
Algae toxicity, ErC50, Desmodesmus subspicatus: 69,5 mg/L (72 h)
Ethoxylated trimethylolpropane triacrylate
Fish toxicity, LC50, Danio rerio (zebrafish): 1,95 mg/L (96 h)
Method: OECD 203
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 70,7 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Desmodesmus subspicatus: 2,2 mg/L (72 h)
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Fish toxicity, LC50, Danio rerio (zebrafish): > 100 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: > 100 mg/L (48 h)
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


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Method: OECD 202


Algae toxicity, ErC50, Selenastrum capricornutum: 105 mg/L (72 h)
Method: OECD 201
Glycerol, propoxylated, esters with acrylic acid
Fish toxicity, LC50, Danio rerio (zebrafish): 5,74 mg/L (96 h)
Method: OECD 203
Daphnia toxicity, EC50, Daphnia magna: 91,4 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Desmodesmus subspicatus: 12,2 mg/L (72 h)
Methyl 2-benzoylbenzoate
Fish toxicity, LC50, Danio rerio (zebrafish): 9,16 mg/L (96 h)
Method: OECD 203
Daphnia toxicity, EC50, Daphnia magna: 26,8 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Desmodesmus subspicatus: 29,7 mg/L (72 h)
Method: OECD 201
Long-term Ecotoxicity
Toxic to aquatic life with long lasting effects.
hexamethylene diacrylate
Fish toxicity, NOEC, Oryzias latipes (Ricefish): 0,072 mg/L (39 d)
Daphnia toxicity, NOEC, Daphnia magna (Big water flea): 0,14 mg/L (21 d)
Algae toxicity, NOEC, Desmodesmus subspicatus: 0,5 mg/L (72 h)
Ethoxylated trimethylolpropane triacrylate
Algae toxicity, EC10, Desmodesmus subspicatus.: 0,323 (72 h)
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Fish toxicity, NOEC, Pimephales promelas (fathead minnow): 0,25 mg/L (33 d)
Daphnia toxicity, NOEC, Daphnia magna: 0,51 mg/L (21 d)
12.2. Persistence and degradability
hexamethylene diacrylate
Biodegradation, OECD 310: 60 - 70 % [mass] (28 d); Evaluation: Readily biodegradable (according to OECD criteria).
12.3. Bioaccumulative potential
hexamethylene diacrylate
Partition coefficient: n-octanol/water: 2,81
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Partition coefficient: n-octanol/water: 2,77
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Partition coefficient: n-octanol/water: 1,6 - 3,8
Method: OECD 117
Glycerol, propoxylated, esters with acrylic acid
Partition coefficient: n-octanol/water: 2,52
Method: OECD 107
Methyl 2-benzoylbenzoate
Partition coefficient: n-octanol/water: 2,6
Bioconcentration factor (BCF)
Toxicological data are not available.
12.4. Mobility in soil
Toxicological data are not available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Endocrine disrupting properties
No information available.
12.7. Other adverse effects
No information available.
SECTION 13: Disposal considerations
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

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13.1. Waste treatment methods


Appropriate disposal / Product
Recommendation
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste
disposal according to directive 2008/98/EC, covering waste and dangerous waste.
List of proposed waste codes/waste designations in accordance with EWC
080111* waste paint and varnish containing organic solvents or
other dangerous substances
*Hazardous waste according to Directive 2008/98/EC (waste framework directive).
Appropriate disposal / Package
Recommendation
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste.
SECTION 14: Transport information
14.1. UN number or ID number
UN 3082
14.2. UN proper shipping name
Land transport (ADR/RID): Environmentally hazardous substance, liquid, n.o.s.
(4,4'-(1-methylethylidene)bisphenol, polymer with (chlorometh yl)oxirane,
acrylate)
Sea transport (IMDG): ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(4,4'-(1-methylethylidene)bisphenol, polymer with (chlorometh yl)oxirane,
acrylate)
Air transport (ICAO-TI / IATA-DGR): Environmentally hazardous substance, liquid, n.o.s.
(4,4'-(1-methylethylidene)bisphenol, polymer with (chlorometh yl)oxirane,
acrylate)
14.3. Transport hazard class(es)
9
14.4. Packing group
III
14.5. Environmental hazards
Land transport (ADR/RID) UMWELTGEFÄHRDEND
Marine pollutant p / 4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane,
acrylate
14.6. Special precautions for user
Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in
case of an accident or leakage.
Advices on safe handling: see parts 6 - 8
Further information

Land transport (ADR/RID)


Tunnel restriction code -

in packages <= 5 litres Kein Gut der Klasse 9


Sea transport (IMDG)
EmS-No. F-A, S-F
in packages <= 5 litres not restricted 2.10.2.7
Air transport (ICAO-TI / IATA-DGR)
in packages <= 5 litres Not Restricted, as per Special Provision A197
14.7. Maritime transport in bulk according to IMO instruments
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 10 / 11

EU legislation
Directive 2010/75/EU on industrial emissions [Industrial Emissions Directive]
VOC-value (in g/L): 0,399
National regulations
Restrictions of occupation
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juveniles according to the 'juvenile work protection guideline' (94/33/EC).
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Full text of classification in section 3:
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 2 / H411 Hazardous to the aquatic environment Toxic to aquatic life with long lasting effects.
Skin Irrit. 2 / H315 Skin corrosion/irritation Causes skin irritation.
Eye Irrit. 2 / H319 Serious eye damage/eye irritation Causes serious eye irritation.
Aquatic Acute 1 / H400 Hazardous to the aquatic environment Very toxic to aquatic organisms.
Skin Sens. 1B / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 3 / H412 Hazardous to the aquatic environment Harmful to aquatic life with long lasting effects.
STOT SE 3 / H335 STOT-single exposure May cause respiratory irritation.
STOT RE 2 / H373 STOT-repeated exposure May cause damage to organs (or state all
organs affected, if known) through prolonged or
repeated exposure (state route of exposure if it
is conclusively proven that no other routes of
exposure cause the hazard).
Acute Tox. 4 / H302 Acute toxicity (oral) Harmful if swallowed.
Classification procedure
Classification for mixtures and used evaluation method according to regulation (EC) No 1272/2008 [CLP]
Skin Irrit. 2 Skin corrosion/irritation Calculation method.
Eye Irrit. 2 Serious eye damage/eye irritation Calculation method.
Skin Sens. 1 Respiratory or skin sensitisation Calculation method.
Aquatic Chronic 2 Hazardous to the aquatic environment Calculation method.
Abbreviations and acronyms
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
OEL Occupational Exposure Limit Value
BLV Biological Limit Value
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging
CMR Carcinogenic, Mutagenic and Reprotoxic
DIN German Institute for Standardization / German industrial standard
DNEL Derived No-Effect Level
EAKV European Waste Catalogue Directive
EC Effective Concentration
EC European Community
EN European Standard
IATA-DGR International Air Transport Association – Dangerous Goods Regulations
IBC Code International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk
ICAO-TI International Civil Aviation Organization Technical Instructions for the Safe Transport of Dangerous
Goods by Air
IMDG Code International Maritime Code for Dangerous Goods
ISO International Organization for Standardization
LC Lethal Concentration
LD Lethal Dose
MARPOL Maritime Pollution: The International Convention for the Prevention of Pollution from Ships
OECD Organisation for Economic Cooperation and Development
PBT persistent, bioaccumulative, toxic
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: U70717 UV-Coating U70717 HighGloss Dual Effect


Print date: 07.05.2024 423290 GE
Version: 21.0 Issue date: 01.02.2024 Page 11 / 11

UN United Nations
VOC Volatile Organic Compounds
vPvB very persistent and very bioaccumulative
Further information
Classification according to Regulation (EC) No 1272/2008 [CLP]

The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations.Without written approval, the product must not be used for purposes different from those mentioned in section
1.It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and
regulations.The details in this safety data sheet describe the safety requirements of our product and are not to be regarded
as guaranteed attributes of the product.

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