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Atoms - DPP 01 (Of Lec 02) - (Parishram 2.0 2023)

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Parishram 2.0
Atoms DPP-01

1. When an α-particle of mass m moving with velocity v 5. Angular momentum of an electron in the hydrogen
bombards on a heavy nucleus of charge Ze, its 3h
atom is . Here h is Plank's constant. The Kinetic
distance of closest approach from the nucleus depends 2
on m as Energy of this electron is
1 1 (1) 4.53 eV (2) 1.51 eV
(1) (2) (3) 3.4 eV (4) 6.8 eV
m m2
1 6. The ratio of the speed of the electron in the first Bohr
(3) m (4)
m orbit of hydrogen atom and the speed of light is equal
to (where e, h and c have their usual meanings)
2. According to Bohr's theory of the hydrogen atom, the (1) 2hc/e2 (2) e2 c/2h
2
(3) e h/2c (4) e2 /2𝜀0 hc
speed vn of the electron in a stationary orbit is related
to the principal quantum number n as (C is a 7. According to Bohr’s model, the ratio of atomic radius
constant): of the First Orbit in Hydrogen Atom to that of Second
C C Orbit of Li2+ is
(1) vn = 2 (2) vn =
n n (1) 3/2 (2) 2/3
(3) 4/3 (4) 3/4
(3) vn = Cn (4) vn = Cn2
8. If the radius of the first orbit of hydrogen atom is
3. The shortest wavelength in Balmer's series for 5.29 × 10–11 m, the radius of the second orbit will be
Hydrogen atom is ... and this is obtained by (1) 21.16 × 10–11 metre
1 1 1 (2) 15.87 × 10–11 metre
substituting ... in Balmer's formula = R ( − )
𝜆 4 𝑛2 (3) 10.58 × 10–11 metre
(1) 656.3 nm, n = 3 (2) 486.1 nm, n = 4 (4) 2.64 × 10–11 metre
(3) 410.2 nm, n = 5 (4) 364.6 nm, n =
9. An electron in Bohr’s hydrogen atom has angular
2ℎ
4. As an electron makes a transition from an excited momentum . The energy of the electron is
𝜋
state to the ground state of a hydrogen like atom/ion (1) – 3.4 eV (2) – 0.64 eV
(3) – 0.85 eV (4) – 10.25 eV

10. Which of the curves may represent the speed of the


electron in a hydrogen atom as a function of the
principal quantum number n?

(1) Kinetic energy, potential energy and total energy


decreases
(2) Kinetic energy decreases, potential energy
increases but total energy remains same
(1) I (2) II
(3) Kinetic energy and total energy decrease but
(3) III (4) IV
potential energy increases
(4) Its kinetic energy increases but potential energy
and total energy decrease
2

Answer Key
1. (4) 6. (4)
2. (2) 7. (4)
3. (4) 8. (1)
4. (4) 9. (3)
5. (2) 10. (3)
3

Hints and Solutions


1. (4)
1 k (2e)(Ze) 6. (4)
NV 2 = n=1
2 r2
Z=1
2. (2) 2ke2 e2 V
Ve = = = e
v=
Z
 (2.2 106
m
) n 20 hc c
n sec
Z 7. (4)
v
n o
Z = 1 for hydrogen Atom r1 = 0.53 A
1 z=1
For hydrogen atom v 
n 22
r2 = (0.53)
3
3. (4) z=3
Shortest wavelength means highest energy.
r1 1 3
Movement   orbit to 2nd orbit. = =
r2 4 / 3 4
4. (4)
Conceptual 8. (1)

5. (2) 9. (3)
3h
Angular momentum = n = 3
2 10. (3)
z
Z
Now, v =  (2.2 106
m
) v
n sec n
1 m
=  (2.2 106 )
3 sec
(n = 3 in this problem)
1
Kinetic energy = mv 2
2
1 1 m
= (9.110−31 Kg )  (  2.2 106 )2
2 3 s
2.45 10−19
= 2.45  10–19 J = eV
1.6 10−19
= 1.53 eV

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