MATERIAL SAFETY DATA SHEET

The Valvoline Company Page 001

Date Prepared: 07/22/03
Date Printed: 10/02/06
MSDS No: 505.0393450-001.001

PL HIGH MILEAGE MOTOR OIL 10W30

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Material Identity
Product Name: PL HIGH MILEAGE MOTOR OIL 10W30
SAP Material No: NP75305

General or Generic ID: PRIVATE LABEL HIGH MILEAGE MOTOR OIL 10W30

Company Telephone Numbers

The Valvoline Company Emergency: 1-800-274-5263
P.O. Box 14000
Lexington, KY 40512 Information: 1-859-357-7206

2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient(s) CAS Number % (by weight)

-------------------------------------------- ------------- -------------

ALIPHATIC PETROLEUM DISTILLATES 64742-65-0 79.0- 89.0

DETERGENT/DISPERSANT ADDITIVE 6.0- 16.0

VISCOSITY INDEX IMPROVER 1.0- 9.0

ZINC COMPOUNDS 1.0- 6.0

ALKYLATED PHENOL 26998-80-1 1.0- 6.0

3. HAZARDS IDENTIFICATION

Potential Health Effects

Eye
Can cause eye irritation.

Skin

Prolonged or repeated contact may dry and crack the skin. Additional symptoms of skin contact
may include: acne, Passage of this material into the body through the skin is possible, but it is
unlikely that this would result in harmful effects during safe handling and use

Swallowing

Swallowing this material is not likely to be harmful.

Inhalation

It is possible to breathe this material under certain conditions of handling and use (for
example, during heating, spraying, or stirring). Breathing small amounts of this material during
normal handling is not likely to cause harmful effects.

Symptoms of Exposure

Signs and symptoms of exposure to this material through breathing, swallowing, and/or
passage of the material through the skin may include: stomach or intestinal upset (nausea,
vomiting, diarrhea) irritation (nose, throat, airways).

Target Organ Effects

No data

Developmental Information

There are no data available for assessing risk to the fetus from maternal exposure to this
material.

Cancer Information
This material is not listed as a carcinogen by the International Agency for Research on Cancer,
the National Toxicology Program, or the Occupational Safety and Health Administration. Used
motor oil has been shown to cause skin cancer in laboratory animals continually exposed by
repeated applications. Avoid prolonged or repeated skin contact.

Other Health Effects

No data

Primary Route(s) of Entry

Inhalation, Skin contact, Eye contact, Ingestion.

4. FIRST AID MEASURES

Eyes

If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently
with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek
medical attention.

Skin
Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist,
seek medical attention. Launder clothing before reuse.

Swallowing
First aid is not normally required. If symptoms develop, seek medical attention.

Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If symptoms
persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm
and quiet; seek immediate medical attention.

Note to Physicians
 Acute aspiration of large amounts of oil-laden material may produce a serious aspiration
pneumonia. Patients who aspirate these oils should be followed for the development of long-term
sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic
inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis.
Symptoms are often subtle and radiological changes appear worse than clinical abnormalities.
Occasionally, persistent cough, irritation of the
upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur.
Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause
pulmonary abnormalities. Preexisting disorders of the following organs (or
organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma-
like conditions).

5. FIRE FIGHTING MEASURES

Flash Point
228.0 F (108.8 C)
Explosive Limit
No data
Autoignition Temperature
No data
Hazardous Products of Combustion
May form: carbon dioxide and carbon monoxide, nitrogen oxides,
sulfur oxides, various hydrocarbons.

Fire and Explosion Hazards

Never use welding or cutting torch on or near drum (even empty) because product (even just
residue) can ignite explosively.

Extinguishing Media
Regular foam, carbon dioxide, dry chemical.

Fire Fighting Instructions

Water or foam may cause frothing which can be violent and possibly endanger the life of the
firefighter. Water may be used to keep fire-exposed containers cool until fire is out. Wear a self-
contained breathing apparatus with a full face piece operated in the positive pressure demand
mode with appropriate turn-out gear and chemical resistant personal protective equipment. Refer
to the personal protective equipment section of this MSDS.

NFPA Rating

Health - 2, Flammability - 1, Reactivity - 0

6. ACCIDENTAL RELEASE MEASURES

Small Spill

Absorb liquid on vermiculite, floor absorbent or other absorbent material.

Large Spill

Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper
authorities as required, that a spill has occurred. Notify the proper authorities as required that a
spill has occurred. Persons not wearing protective equipment should be excluded from area of
spill until clean-up has been completed.
7. HANDLING AND STORAGE

Handling
Containers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must
be observed. All five gallon pails and larger metal containers including tank cars and tank trucks
should be grounded and/or bonded when material is transferred. Precautions during use: avoid
prolonged or frequently repeated skin contact with this
material. Skin contact can be minimized by wearing impervious protective gloves. As with all
products of this nature, good personal hygiene is essential. Hands and other exposed areas should
be washed thoroughly with soap and water after contact, especially before eating and/or smoking.
Regular laundering of contaminated clothing is essential to reduce indirect skin contact with this
material.

Storage
Do not store near extreme heat, open flame, or sources of ignition.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Eye Protection

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA
regulations also permit other type safety glasses. Consult your safety representative.

Skin Protection

Wear impervious gloves (consult your safety equipment supplier). To prevent repeated or
prolonged skin contact, wear impervious clothing and boots.

Respiratory Protections

If workplace exposure limit(s) of product or any component is exceeded (See Exposure

Guidelines), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper
environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative
pressure type) under specified conditions (consult your industrial hygienist). Engineering or
administrative controls should be implemented to reduce exposure.

Engineering Controls

Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure
below TLV(s).

Exposure Guidelines

Component

ALIPHATIC PETROLEUM DISTILLATES (64742-65-0)

OSHA VPEL 5.000 mg/m3 - TWA

ACGIH TLV 5.000 mg/m3 - TWA

DETERGENT/DISPERSANT ADDITIVE
No exposure limits established
VISCOSITY INDEX IMPROVER
No exposure limits established

ZINC COMPOUNDS
No exposure limits established

ALKYLATED PHENOL (26998-80-1)

No exposure limits established

9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point
(for component) > 425.0 F (218.3 C)

Vapor Pressure
(for product) .000

Specific Vapor Density

No data

Specific Gravity
.872 @ 60.00 F

Liquid Density
7.260 lbs/gal @ 60.00 F

7.260 lbs/gal @ 60.00 F

Percent Volatiles (Including Water)

No data

Evaporation Rate
No data

Appearance
CLEAR, DRY, & BRIGHT

State
LIQUID

Physical Form
No data

Color
AMBER
Odor
No data

pH
No data

Viscosity
10.8 cst @ 100 C
10. STABILITY AND REACTIVITY

Hazardous Polymerization
Product will not undergo hazardous polymerization.

Hazardous Decomposition
May form: alcohols, aldehydes, carbon dioxide and carbon monoxide hydrogen sulfide, various
hydrocarbons.

Chemical Stability
Stable.

Incompatibility
Avoid contact with: acids, alkalies, chlorine, halogens, strong oxidizing agents.

11. TOXICOLOGICAL INFORMATION

No data

12. ECOLOGICAL INFORMATION

No data

13. DISPOSAL CONSIDERATION

Waste Management Information

Dispose of in accordance with all applicable local, state and federal regulations.

14. TRANSPORT INFORMATION

DOT Information - 49 CFR 172.101

DOT Description:
Not Regulated

Container/Mode:
CASES/SURFACE - NO EXCEPTIONS

NOS Component:
None

RQ (Reportable Quantity) - 49 CFR 172.101

Not applicable

15. REGULATORY INFORMATION

US Federal Regulations

TSCA (Toxic Substances Control Act) Status

TSCA (UNITED STATES) The intentional ingredients of this product are listed.

CERCLA RQ - 40 CFR 302.4

None
 SARA 302 Components - 40 CFR 355 Appendix A
None

Section 311/312 Hazard Class - 40 CFR 370.2

Immediate(X) Delayed( ) Fire( ) Reactive( ) Sudden Release of Pressure( )

SARA 313 Components - 40 CFR 372.65

Section 313 Component(s) CAS Number

ZINC COMPOUNDS

International Regulations
Inventory Status
AICS (AUSTRALIA) The intentional ingredients of this product are listed.
DSL (CANADA) The intentional ingredients of this product are listed.
ECL (SOUTH KOREA) The intentional ingredients of this product are listed.
EINECS (EUROPE) This material or a component requires notification before sale or
importation.
ENCS (JAPAN) the intentional ingredients of this product are listed.
PICCS (PHILIPPINES) The intentional ingredients of this product are listed.

State and Local Regulations

California Proposition 65
None

16. OTHER INFORMATION

The information accumulated herein is believed to be accurate but is not warranted to be

whether originating with the company or not. Recipients are advised to confirm in advance of
need that the information is current, applicable, and suitable to their
circumstances.