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Fdocuments - in - Api 571 Part 5

The document discusses cooling water corrosion including the description of damage, affected materials, critical factors, affected units, and appearance of damage. Cooling water corrosion can cause various types of damage such as general corrosion, pitting corrosion, microbiologically influenced corrosion, and stress corrosion cracking in heat exchangers and cooling towers.

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0% found this document useful (0 votes)
46 views21 pages

Fdocuments - in - Api 571 Part 5

The document discusses cooling water corrosion including the description of damage, affected materials, critical factors, affected units, and appearance of damage. Cooling water corrosion can cause various types of damage such as general corrosion, pitting corrosion, microbiologically influenced corrosion, and stress corrosion cracking in heat exchangers and cooling towers.

Uploaded by

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API510/570-Exam

Figure 4-74 – Close-up of Tee CUI of a Tee in Figure


4-73 after insulation removal.
API510/570-Exam

Figure 4-75 – CUI of a 30 inch CS Butadiene line showing highly localized corrosion
which could only be found by stripping the entire line. Note the 0.25 in (6.5 mm)
diameter hole at arrow
API510/570-Exam

Figure 4-76 – CUI of nozzle on a bottom head.


API510/570-Exam

Figure 4-77 – CUI of nozzle on a top head.


API510/570-Exam

Figure 4-78 – CUI of vessel wall. Note leak at arrow.


API510/570-Exam

Figure 4-79 – CUI at attachment supports and vessel head.


API510/570-Exam

Figure 4-80 – CUI of CS level bridle.


API510/570-Exam

保温层下腐蚀学习重点:
1. 温度: 操作温度
2. 受影响材料:碳钢,低合金钢,奥氏体不锈钢,双相不锈钢,
3. 损伤原理: 潮湿腐蚀(碳钢,低合金钢)/氯化物应力腐蚀开裂(奥氏体不锈钢/双
相不锈钢).
4. 关键因素: 易感温度(碳钢 -10oF~350oF) / (奥氏体不锈钢 140oF~400oF), 损
坏保温层,保温层突漏点(T点,垂直高点,阀门突漏点)
5. 预防/缓解:表面处理和适当的涂料应用,低氯绝缘应使用在300系列不锈钢,
6. API 510/570 考试学习项.
API510-Exam

4.3.4 Cooling Water Corrosion 冷却水的腐蚀


4.3.4.1 Description of Damage
General or localized corrosion of carbon steels and other metals caused
by dissolved salts, gases, organic compounds or microbiological activity.
溶解的盐, 气体, 有机化合物的, 或微生物的活动引起的均匀与局部腐蚀.

4.3.4.2 Affected Materials


Carbon steel, all grades of stainless steel, copper, aluminum, titanium and
nickel base alloys.
API510-Exam

4.3.4.3 Critical Factors


a) Cooling water corrosion and fouling are closely related and should be
considered together. Fluid temperature, type of water (fresh, brackish, salt
water) and the type of cooling system (once-through, open circulating,
closed circulating), oxygen content, and fluid velocities are critical factors.
b) Increasing cooling water outlet temperatures and or process side inlet
temperatures tend to increase corrosion rates as well as fouling tendency.
c) Increasing oxygen content tends to increase carbon steel corrosion rates.
d) If the process side temperature is above 140 F (60 C), a scaling potential
° °

exists with fresh water and becomes more likely as process temperatures
increase and as cooling water inlet temperatures rise. Brackish and salt
water outlet temperatures above about 115 F (46 C) may cause serious
° °

scaling.
e) Fouling may occur from mineral deposits (hardness), silt, suspended
organic materials, corrosion products, mill scale, marine and
microbiological growth.
API510-Exam

f) Velocities should be high enough to minimize fouling and drop out of


deposits but not so high as to cause erosion. Velocity limits depend on the
tube material and water quality.
g) Low velocities can promote increased corrosion. Velocities below about 3
fps (1 m/s) are likely to result in fouling, sedimentation and increased
corrosion in fresh and brackish water systems. Accelerated corrosion can
also result from dead spots or stagnant areas if cooling water is used on the
shell side of condensers/coolers rather than the preferred tube side.
h) 300 Series SS can suffer pitting corrosion, crevice corrosion and SCC in
fresh, brackish and salt water systems.
API510-Exam

i) Copper/zinc alloys can suffer dezincification in fresh, brackish and salt


water systems. The copper/zinc alloys can suffer SCC if any ammonia or
ammonium compounds are present in the water or on the process side.
j) ERW carbon steel may suffer severe weld and/or heated affected zone
corrosion in fresh and/or brackish water.
k) When connected to a more anodic material, titanium may suffer severe
hydriding embrittlement. Generally, the problem occurs at temperatures
above 180 F (82 C) but can occur at lower temperatures.
° °
API510-Exam

Copper/zinc alloys can suffer dezincification


API510-Exam

4.3.4.4 Affected Units or Equipment


Cooling water corrosion is a concern with water-cooled heat exchangers and
cooling towers in all applications across all industries.
4.3.4.5 Appearance or Morphology of Damage
a) Cooling water corrosion can result in many different forms of damage
including general corrosion, pitting corrosion (Figure 4-81), MIC, stress
corrosion cracking and fouling.
b) General or uniform corrosion of carbon steel occurs when dissolved
oxygen is present.
c) Localized corrosion may result from under-deposit corrosion, crevice
corrosion or microbiological corrosion.
d) Deposits or crevices can lead to under-deposit or crevice corrosion of any
of the affected materials.
API510-Exam

e) Wavy or smooth corrosion at nozzle inlets/outlets and tube inlets may be


due to flow induced corrosion, erosion or abrasion.
f) Corrosion at ERW weld areas will appear as grooving along the weld fusion
lines.
g) Metallurgical analysis of tube samples may be required to confirm the
mode of failure.
API510-Exam

Crevice corrosion
API510-Exam

Crevice corrosion
API510-Exam

microbiological corrosion / MIC


API510-Exam

microbiological corrosion / MIC


API510-Exam

microbiological corrosion / MIC

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