dsasadass

Revision: 03
Date: Apr/18

I. Product and Company Identification

Product Name: TapeGlass

Supplier: TechnoFink – 21625 Rhodes Rd, Spring-TX, 77388, USA
Supplier Phone Number: 346-331-6200
Emergency Phone Number: 800-535-5053
Product Description: Fiberglass cloth impregnated with water activated resin.
Product Use: Intended to repair pipes or for corrosion control.
Chemical Name or Synonym: N/A

II. Hazards Identification

Classification of the substance or mixture

Acute toxicity oral – Category 4
Acute toxicity/dermal – Category 4
Sensitization/respiratory – Category 1
Acute toxicity/inhalation – Category 4
Skin corrosion/irritation – Category 2
Eye damage/eye irritation – Category 2A
Sensitization/skin – Category 1
Specific Target Organ Toxicity (SE) – Category 3

GHS07 GHS08

Hazard Statements:
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful in inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation

Signal Word: DANGER!

Precautionary Statement:
P264 Wash thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P262 Do not get in eyes, on skin, or on clothing.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing

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National Fire Protection Association Hazard Ratings – NFPA(R):

Health Hazard: 2
Flammability: 1
Reactivity: 0

III. Composition/ Information on Ingredients

Component CAS # % Composition

Fiberglass Cloth (textile grade) 65997-17-3 65 - 70
Diphenylmethane diisocyanate (MDI), containing Methylene Bisphenyl isocyanate
26447-40-5 10 - 25
(CAS 101-68-8)
Diphenylmethane diisocyanate (homopolymer) 39310-05-9 3-8
Textured polyester filament yarn N/A <5
Surface sizing N/A < 1.4

IV. First Aid Measures

First Aid Measures for Accidental:

Eye Exposure: Flush with copious amount of water. Preferably lukewarm, for at least 15 minutes, holding eyelids open at all times. Refer
individual to a physician or ophthalmologist for immediate follow up.
Skin Exposure: Remove contaminated clothing. Wash affected skin thoroughly with soap and water. Wash contaminated clothing
thoroughly before reuse. Get under safety shower after removing clothing. Seek medical attention if irritation develops after area is
washed.
Inhalation: Move to an area free from risk of further exposure. Administer oxygen as needed. Obtain medical attention. Asthmatic –type
symptoms may develop and may be immediate or delayed up to several hours. Consult physician should this development occur.
Ingestion: Do not induce vomiting. Give one to two cups of milk or water to drink. Do not give anything by mouth to an unconscious
person, consult a physician.
Most important symptoms/effects, acute and delayed:
Acute Inhalation: MDI/ vapors or mist at concentrations above the TLV can irritate (burning sensation) the mucous membranes in the
respiratory tract (nose, throat, and lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced
lung function (breathing obstruction). Persons with a preexisting, nonspecific bronchial hyperactivity can respond to concentrations below
the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm and
pulmonary edema (fluid in lungs). These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like symptoms
(e.g., fever, and chills) has also been reported. These symptoms can be delayed up to several hours after exposure.
Acute Eye: Liquid, aerosols or vapor are irritating and can cause tearing, reddening and swelling. If left untreated, corneal damage can
occur and injury is slow to heal. Damage, however is usually reversible.
Acute Skin contact: Isocyanates react with skin protein and moisture and can cause irritation which may include the following symptoms:
reddening, swelling, rash, scaling or blistering. Cured material is difficult to remove.
Acute ingestion: Irritation and corrosive action can occur in the mouth, stomach tissue and digestive tract. Symptoms can include: sore
throat, abdominal pain, nausea, vomiting and diarrhea.
Over-exposure signs/symptoms: Overexposure to isocyanates has also been reported to cause lung damage, (including decrease in
lung function) which may be permanent. Sensitization can either be temporary or permanent. Asthma, other respiratory disorders
(bronchitis, emphysema, bronchial hyperactivity), skin allergies, eczema.
Notes to Physician: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Workplace
vapors have produced reversible corneal epithelial edema impairing vision. This compound is a known skin and pulmonary sensitizer.
Treat symptomatically for contact dermatitis or thermal burns, if burned treat as a thermal burn.

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V. Fire Fighting Measures

Extinguishing Media: Use cold water spray to cool fire-exposed containers to minimize the risk rupture. Carbon dioxide, foam, dry
chemical. Water spray for large fires. During a fire, smoke may contain the original material in addition to unidentified toxic and/or irritating
compounds. Product reacts with water. Reaction may produce heat and/or gases. Reaction may be violent. Container may rupture from
gas generation in a fire situation. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.
Dense smoke is produced when product burns.
Special Fire Fighting Procedures: During a fire, MDI vapors and other irritating, highly toxic gases may be generated by thermal
decomposition or combustion. At temperatures greater than 400°F, polymeric MDI can polymerize and decompose which can cause
pressure build-up in closed containers. Explosive rupture is possible. Therefore, use cold water to cool fire-exposed containers.
Special Protective Equipment for Fire-fighters: Full emergency equipment with self-contained breathing apparatus and full protective
clothing should be worn by firefighters. Wear positive pressure self-contained breathing apparatus (SCBA) and protective fire fighting
clothing (includes helmet, coat, pants, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is
likely, change to full chemical resistant clothing with SCBA. This will not provide sufficient fire protection, consider fighting fire from a
remote location.
Unusual Fire and Explosion Hazards: During a fire, smoke may contain the original material in addition to unidentified toxic and/or
irritating compounds. Product reacts with water. Reaction may produce heat and/or gases. Reaction may be violent. Container may
rupture from gas generation in a fire situation. Violent steam generation or eruption may occur upon application of direct water stream
to hot liquids. Dense smoke is produced when product burns.
Hazardous Decomposition Materials (Under Fire Conditions): Combustion produces carbon monoxide, oxides of nitrogen, and traces
of HCN, MDI vapors or aerosols.

VI. Accidental Release Measures

Personal Precautions, Protective Equipment and Emergency Procedures: No action shall be taken involving any personal risk or
without suitable training. Keep people at a distance and stay upwind. Evacuate surrounding areas. Do not touch or walk through spilled
material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
Cleanup and Disposal of Spill: Decontaminate floor with decontamination solution letting stand for at least 15 minutes. Absorb with
liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to
item 13. Ensure adequate ventilation.

VII. Handling and Storage

Precautions for safe handling: Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination is
suspected. Avoid contact with skin and eyes. Do not breathe aerosols or vapors. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Ensure good
ventilation/exhaustion at the workplace.
Conditions for safe storage including any incompatibilities: Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Storage at temperature between 64 0F
and 86 0F. Keep away from humidity and water. Keep container tightly closed and sealed until ready for use.

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VIII. Exposure Controls / Personal Protection

Exposure limits
Component ACGIH NIOSH OSHA-PELs
4,4'-methylenediphenyl diisocyanate 0.02 ppm Ceiling (STEL)
0.005 ppm (TWA) ND
(101-68-8) 0.2 mg/m3 Ceiling(STEL)
Fibrous glass dust 5 mg/m3 (inhalable) ND 5 mg/m3 (respirable)

Appropriate Engineering Controls: Local exhaust should be used to maintain levels below the TLV whenever MDI is processed, heated
or spray applied. Standard reference sources regarding industrial ventilation (i.e., ACGIH Industrial Ventilation) should be consulted for
guidance about adequate ventilation.
Personal Protective Equipment:
Respiratory Protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use respiratory protective device that is independent of circulating air.
Eye / Face Protection: Wear appropriate safety glasses with side shields or chemical goggles as described by OSHA’s eye and face
protection regulations in 29CFR 1910.133 or European Standard EN166.
Skin Protection: The glove material has to be impermeable and resistant to the product. Cover as much of the exposed area as possible,
with protective clothing.

IX. Physical and Chemical Properties

Physical Appearance: Fiberglass cloth coated with viscous resin.

Odor: Pungent
Odor Threshold: ND
pH: ND
Melting Point Range: NA
Boiling point: ND
Flash Point: 370°F (188°C)
Evaporation rate: ND
Method Used: Pensky-Martens Closed Cup
Flammability Limits (vol/vol%): Lower: N/A Upper: N/A
Vapor Pressure: ND
Vapor Density: ND
Relative Density: ND
Specific Gravity: 2.5 (glass) 1.23 (resin)
Water Solubility: Not soluble. Reacts with water to liberate CO2 gases. Dangerous reactions can occur in large
masses producing toxic gases, hazardous runaway polymerization, and excessive heat caused by
exothermic reaction.SS
Partition coefficient (n-octanol/water): ND.
Auto-ignition Temperature: Product is not self-igniting
Decomposition Temperature: ND
Viscosity: ND

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X. Stability and Reactivity

Reactivity: No specific test data related to reactivity available for this product or its ingredients.
Chemical Stability: Stable under standard use and storage conditions.
Possibility of Hazardous reactions: No dangerous reactions known. Hazardous polymerization can occur. Polymerization can be
catalyzed by water and strong bases.
Conditions to Avoid: Avoid temperatures above 105F (41°C). Avoid temperatures below 75F (24°C). Can react with itself at
temperatures above 320°F (160°C). Product can decompose at elevated temperatures. Generation of gas during decomposition can
cause pressure in closed systems. Pressure build up can be rapid. Avoid moisture. Material reacts with water, releasing carbon dioxide,
which can cause pressure build up and rupture of closed containers. Elevated temperatures accelerate this reaction.
Incompatible Materials / Chemicals: Avoid contact with acids, water, alcohols, amines, ammonia, bases, moist air, and strong oxidizers.
Avoid contact with metals such as aluminum, brass, copper, galvanized metals, tin, zinc. Avoid contact with moist organic absorbants.
Reaction with water will generate carbon dioxide and heat. Avoid contact with polyols and other Isocyanates.
Hazardous Decomposition Products: Hazardous combustion products may include but are not limited to: nitrogen oxides, isocyanates,
Hydrogen cyanide, carbon monoxide, and carbon dioxide.

XI. Toxicological Information

For 26447-40-5 Diphenylmethane diisocyanate (MDI) containing Methylene bisphenyl isocyanate (CAS No: 10168-8):
Oral LD50 (rats): >1000 mg/kg
Dermal LD50 (rabbits): >2000 mg/kg
Primary irritant effect:
On the skin: Irritant to skin and mucous membranes.
On the eye: Irritating effect.
Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact.
Symptoms:
Inhalation: MDI/ vapors or mist at concentrations above the TLV can irritate the mucous membranes in the respiratory tract causing
runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function.
Eye Contact: Liquid, aerosols or vapor are irritating and can cause tearing, reddening and swelling. If left untreated, corneal damage
can occur and injury is slow to heal. Damage, however is usually reversible.
Skin Contact: Isocyanates react with skin protein and moisture and can cause irritation which may include the following symptoms:
reddening, swelling, rash, scaling or blistering. Cured material is difficult to remove.
Ingestion: Irritation and corrosive action can occur in the mouth, stomach tissue and digestive tract. Symptoms can include: sore throat,
abdominal pain, nausea, vomiting and diarrhea.
Chronic Health Effects
Mutagenicity (Effects on genetic material): Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in-vitro
studies; other in-vitro studies were negative. Animal genetic toxicity studies were predominantly negative.
Other information (about experimental toxicology):
Cancer Information: Lung tumors have been observed in laboratory animals exposed to aerosol droplets of MDI/Polymeric MDI (6mg/m3)
for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to
protect against these effects reported for MDI.
Teratology (Birth Defects): In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high
doses which were toxic to the mother.
Reproductive Effects: Contains component(s) which have been shown to interfere with reproduction in animal studies. The component(s)
is/are triethyl phosphate. The dose required to produce such effects are highly unlikely with the use of this product.
Numerical measures of toxicity: No specific data

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Delayed and immediate effects and also chronic effects from short and long term exposure:
Short term exposure: No specific data.
Long term exposure: No specific data
Carcinogenic Categories:
IARC (International Agency for Research on Cancer)
Titanium dioxide (13463-67-7) 2B
Benzoyl chloride (98-88-4) 2A
NTP (National Toxicology Program): None of the ingredients is listed.

XII. Ecological Information

Ecotoxicity: Based largely or completely on information for MDI and polymeric MDI: the measured ecotoxicity is that of the hydrolyzed
product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on
an acute basis (LC50 or EC50 >100 mg/l in the most sensitive species tested). The LC50 in earthworm Eisenia foetida is >1000 mg/kg.
Aquatic toxicity: No further relevant information available.
Persistence and degradability: Based largely or completely on information for MDI and polymeric MDI: in the aquatic and
terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the
atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related
diisocyanates.
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
Other adverse effects: No further relevant information available.

XIII. Disposal Considerations

Waste treatment methods: Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging: Dispose of in accordance to all local, state, and/or national legislation.

XIV. Transport Information

UN Number (DOT, ADR, ADN, IMDG, IATA): Not Applicable

UN Proper Shipping Name (DOT, ADR, ADN, IMDG, IATA): Not Applicable
Transport Hazard Class (DOT, ADR, ADN, IMDG, IATA): Not Applicable
Packing Group (DOT, ADR, MDG, IATA): Not Applicable
Environmental Hazard: No
Transport in Bulk: Not Applicable
Transport/Additional Information
DOT: Not Regulated
ADR: Not Regulated
IMDG: Not Regulated
IATA: Not Regulated

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XV. Regulatory Information

SARA Regulations:
Section 355: None of the ingredients is listed
TSCA (Toxic Substance Control Act): All components of this product are on US Inventory or exempt. Glass fiber does not meet the
classification for a “dangerous substance” according to 67/548/EEC. Glass fiber is considered to be an article as defined in section
710.2 (F) of the U.S. TSCA and, as such, is exempt from section 8(a), 710.2 (f) and 704.5 (a).
Proposition 65: None of the ingredients is listed
EPA: None of the ingredients is listed

XVI. Other Information

Key Legend Information:

N/A – Not Applicable
ND – Not Determined
ACGIH – American Conference of Governmental Industrial Hygienists
OSHA – Occupational Safety and Health Administration
PEL – Permissible Exposure Limit
NIOSH – National Institute for Occupational Safety and Health

The information contained herein is based on the data available to us and is believed to be accurate. The data is offered in
good faith as typical values and not as product specification. The information in this data sheet was compiled from information
supplied by NRI Neptune Research as the vendors of the components of this compound. TechnoFink makes no warranty either
expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. The recommended
industrial hygiene and safe handling procedures are believed to be genuinely applicable. However, each user should review
these recommendations in the specific context of the intended use and determine whether they are appropriate. TechnoFink
assumes no responsibility for injury from the use of the product described herein. The information is intended only to assist in
the safe handling of this material.

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