Safety data sheet

This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,

without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: Epokoat Vernice Epossidica parte B
Other means of identification:
Non-applicable
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: High performance coatings
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet:
Diasen S.r.l.
Zona Ind.le Berbentina, 5
60041 Sassoferrato (AN) - Marche - Italia
Phone: +39 0732 9718 - Fax: +39 0732 971899
diasen@diasen.com
https://www.diasen.com
1.4 Emergency telephone number: Poison Centre - Ospedale di Niguarda - Milan - Tel. +39/02/66101029
Diasen S.r.l - Tel: +39-07329718 - (office hours)

SECTION 2: HAZARDS IDENTIFICATION **

2.1 Classification of the substance or mixture:
CLP Regulation (EC) No 1272/2008:
Classification of this product has been carried out in accordance with CLP Regulation (EC) No 1272/2008.
Acute Tox. 4: Acute toxicity, Category 4, H302+H332
Aquatic Acute 1: Hazardous to the aquatic environment, acute hazard, Category 1, H400
Aquatic Chronic 1: Hazardous to the aquatic environment, long-term hazard, Category 1, H410
Eye Dam. 1: Serious eye damage, Category 1, H318
Repr. 2: Reproductive toxicity, Category 2, H361fd
Skin Corr. 1B: Skin corrosion, Category 1B, H314
Skin Sens. 1A: Sensitisation, skin, Category 1A, H317
2.2 Label elements:
CLP Regulation (EC) No 1272/2008:
Danger

Hazard statements:
Acute Tox. 4: H302+H332 - Harmful if swallowed or if inhaled.
Aquatic Chronic 1: H410 - Very toxic to aquatic life with long lasting effects.
Repr. 2: H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child.
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage.
Skin Sens. 1A: H317 - May cause an allergic skin reaction.
Precautionary statements:
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P501: Dispose of contents/container according to the separated collection system used in your municipality.
Supplementary information:

** Changes with regards to the previous version

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(Replaced 1)
 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 2: HAZARDS IDENTIFICATION ** (continued)

Contains 3-aminomethyl-3,5,5-trimethylcyclohexylamine.
Substances that contribute to the classification
4,4´-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, reaction products with m-
phenylenebis(methylamine); 4-nonylphenol, branched; benzyl alcohol; 2-piperazin-1-ylethylamine
UFI: RG40-80DX-T00Y-2M4D
2.3 Other hazards:
Product does not meet PBT/vPvB criteria
The product contains substances with endocrine-disrupting properties: 4-nonylphenol, branched
** Changes with regards to the previous version

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substance:
Non-applicable
3.2 Mixture:
Chemical description: Aqueous emulsion
Components:
In accordance with Annex II of Regulation (EC) No 1907/2006 (point 3), the product contains:
Identification Chemical name/Classification Concentration
CAS: 113930-69-1 4,4´-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3- Self-classified
EC: 500-302-7 epoxypropane, reaction products with m-phenylenebis(methylamine)⁽¹⁾
Index: Non-applicable
25 - <50 %
REACH: 01-2119965162-39- Aquatic Chronic 2: H411; Eye Dam. 1: H318; Skin Corr. 1B: H314; Skin Sens. 1:
Regulation 1272/2008
XXXX H317 - Danger

CAS: 84852-15-3 4-nonylphenol, branched⁽¹⁾ ATP CLP00

EC: 284-325-5
25 - <50 %
Index: 601-053-00-8 Acute Tox. 4: H302; Aquatic Acute 1: H400; Aquatic Chronic 1: H410; Repr. 2:
REACH: 01-2119510715-45- Regulation 1272/2008 H361fd; Skin Corr. 1B: H314 - Danger
XXXX
CAS: 100-51-6 benzyl alcohol⁽¹⁾ ATP CLP00
EC: 202-859-9
10 - <25 %
Index: 603-057-00-5
Regulation 1272/2008 Acute Tox. 4: H302+H332 - Warning
REACH: 01-2119492630-38-
XXXX
CAS: 140-31-8 2-piperazin-1-ylethylamine⁽¹⁾ ATP CLP00
EC: 205-411-0
2,5 - <10 %
Index: 612-105-00-4 Acute Tox. 4: H302+H312; Aquatic Chronic 3: H412; Skin Corr. 1B: H314; Skin Sens. 1:
REACH: 01-2119471486-30- Regulation 1272/2008 H317 - Danger
XXXX
CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine⁽¹⁾ ATP ATP17
EC: 220-666-8
2,5 - <10 %
Index: 612-067-00-9 Acute Tox. 4: H302; Eye Dam. 1: H318; Skin Corr. 1B: H314; Skin Sens. 1A: H317 -
REACH: 01-2119514687-32- Regulation 1272/2008 Danger
XXXX

⁽¹⁾ Substances presenting a health or environmental hazard which meet criteria laid down in Regulation (EU) No. 2020/878

To obtain more information on the hazards of the substances consult sections 11, 12 and 16.
Other information:
Identification M-factor
4-nonylphenol, branched Acute 10
CAS: 84852-15-3 EC: 284-325-5 Chronic 10

Identification Specific concentration limit

3-aminomethyl-3,5,5-trimethylcyclohexylamine
CAS: 2855-13-2 % (w/w) >=0,001: Skin Sens. 1A - H317
EC: 220-666-8
Acute toxicity estimate for the substance in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or as determined in accordance
with Annex I to that Regulation:

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(Replaced 1)
 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continued)

Identification Acute toxicity Genus

benzyl alcohol LD50 oral 500 mg/kg (ATEi) Rat
CAS: 100-51-6 LD50 dermal Non-applicable
EC: 202-859-9 LC50 inhalation 11 mg/L (ATEi)
2-piperazin-1-ylethylamine LD50 oral 500 mg/kg (ATEi)
CAS: 140-31-8 LD50 dermal 1100 mg/kg (ATEi)
EC: 205-411-0 LC50 inhalation Non-applicable
4-nonylphenol, branched LD50 oral 1412 mg/kg (ATEi) Rat
CAS: 84852-15-3 LD50 dermal Non-applicable
EC: 284-325-5 LC50 inhalation Non-applicable
3-aminomethyl-3,5,5-trimethylcyclohexylamine LD50 oral 1030 mg/kg (ATEi) Rat
CAS: 2855-13-2 LD50 dermal Non-applicable
EC: 220-666-8 LC50 inhalation Non-applicable

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
Request medical assistance immediately, showing the SDS of this product.
By inhalation:
Remove the person affected from the area of exposure, provide with fresh air and keep at rest. In serious cases such as
cardiorespiratory failure, artificial resuscitation techniques will be necessary (mouth to mouth resuscitation, cardiac massage,
oxygen supply, etc.) requiring immediate medical assistance.
By skin contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water
and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this
could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will
increase the risk of infection.
By eye contact:
Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes.
If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, in which case this could
cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the
product.
By ingestion/aspiration:
Request immediate medical assistance, showing the SDS of this product. Do not induce vomiting, because its expulsion from the
stomach can be hazardous to the mucus of the main digestive tract, and also risk damage to the respiratory system through
inhalation. Rinse out the mouth and throat, as they may have been affected during ingestion. In the case of loss of
consciousness do not administer anything orally unless supervised by a doctor. Keep the person affected at rest.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:
Suitable extinguishing media:
Product is non-flammable under normal conditions of storage, handling and use. In the case of combustion as a result of
improper handling, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems.
Unsuitable extinguishing media:
Non-applicable

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(Replaced 1)
 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 5: FIREFIGHTING MEASURES (continued)

5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and,
consequently, can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained breathing apparatus
(SCBA). Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance
with Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for products susceptible to
combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an
aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
For non-emergency personnel:
Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be
used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have
protection.
For emergency responders:
Wear protective equipment. Keep unprotected persons away. See section 8.
6.2 Environmental precautions:
Avoid at all cost any type of spillage into an aqueous medium. Contain the product absorbed appropriately in hermetically sealed
containers. Notify the relevant authority in case of exposure to the general public or the environment.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
A.- General precautions for safe use
Comply with the current legislation concerning the prevention of industrial risks with regards manually handling weights.
Maintain order, cleanliness and dispose of using safe methods (section 6).
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, handling and use. It is recommended to transfer at slow speeds
to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on
conditions and materials that should be avoided.
C.- Technical recommendations on general occupational hygiene
PREGNANT WOMEN SHOULD NOT BE EXPOSED TO THIS PRODUCT. Transfer in designated areas that comply with the
necessary safety conditions (emergency showers and eyewash stations in close proximity), using personal protection
equipment, especially on the hands and face (See section 8). Limit manual transfers to small amounts only. Do not eat or
drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
Due to the danger of this product for the environment it is recommended to use it within an area containing contamination
control barriers in case of spillage, as well as having absorbent material in close proximity.
7.2 Conditions for safe storage, including any incompatibilities:

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(Replaced 1)
 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 7: HANDLING AND STORAGE (continued)

A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximum Temp.: 30 ºC
Maximum time: 6 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the workplace (European OEL, not country-specific
legislation):
There are no applicable occupational exposure limits for the substances contained in the product
DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

4,4´-Isopropylidenediphenol, oligomeric reaction products
with 1-chloro-2,3-epoxypropane, reaction products with m- Oral Non-applicable Non-applicable Non-applicable Non-applicable
phenylenebis(methylamine)
CAS: 113930-69-1 Dermal Non-applicable Non-applicable 0,14 mg/kg Non-applicable
EC: 500-302-7 Inhalation Non-applicable Non-applicable 0,493 mg/m³ Non-applicable
4-nonylphenol, branched Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 84852-15-3 Dermal 15 mg/kg Non-applicable 7,5 mg/kg Non-applicable
EC: 284-325-5 Inhalation 1 mg/m³ Non-applicable 0,5 mg/m³ Non-applicable
benzyl alcohol Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 100-51-6 Dermal 40 mg/kg Non-applicable 8 mg/kg Non-applicable
EC: 202-859-9 Inhalation 110 mg/m³ Non-applicable 22 mg/m³ Non-applicable
2-piperazin-1-ylethylamine Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 140-31-8 Dermal Non-applicable Non-applicable 3,33 mg/kg Non-applicable
EC: 205-411-0 Inhalation 10,6 mg/m³ 80 mg/m³ 10,6 mg/m³ 0,015 mg/m³
3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 2855-13-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 220-666-8 Inhalation Non-applicable Non-applicable Non-applicable 0,073 mg/m³

DNEL (General population):

Short exposure Long exposure

Identification Systemic Local Systemic Local

4,4´-Isopropylidenediphenol, oligomeric reaction products
with 1-chloro-2,3-epoxypropane, reaction products with m- Oral Non-applicable Non-applicable 0,05 mg/kg Non-applicable
phenylenebis(methylamine)
CAS: 113930-69-1 Dermal Non-applicable Non-applicable 0,05 mg/kg Non-applicable
EC: 500-302-7 Inhalation Non-applicable Non-applicable 0,074 mg/m³ Non-applicable
4-nonylphenol, branched Oral 0,4 mg/kg Non-applicable 0,08 mg/kg Non-applicable
CAS: 84852-15-3 Dermal 7,6 mg/kg Non-applicable 3,8 mg/kg Non-applicable
EC: 284-325-5 Inhalation 0,8 mg/m³ Non-applicable 0,4 mg/m³ Non-applicable
benzyl alcohol Oral 20 mg/kg Non-applicable 4 mg/kg Non-applicable
CAS: 100-51-6 Dermal 20 mg/kg Non-applicable 4 mg/kg Non-applicable
EC: 202-859-9 Inhalation 27 mg/m³ Non-applicable 5,4 mg/m³ Non-applicable

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

Short exposure Long exposure

Identification Systemic Local Systemic Local

3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral Non-applicable Non-applicable 0,526 mg/kg Non-applicable
CAS: 2855-13-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 220-666-8 Inhalation Non-applicable Non-applicable Non-applicable Non-applicable

PNEC:
Identification
4,4´-Isopropylidenediphenol, oligomeric reaction products
with 1-chloro-2,3-epoxypropane, reaction products with m- STP 8,889 mg/L Fresh water 0,001 mg/L
phenylenebis(methylamine)
CAS: 113930-69-1 Soil 923000 mg/kg Marine water 0 mg/L
EC: 500-302-7 Intermittent 0,015 mg/L Sediment (Fresh water) 4610000 mg/kg
Oral 0,00333 g/kg Sediment (Marine water) 461000 mg/kg
4-nonylphenol, branched STP 9,5 mg/L Fresh water 0,001 mg/L
CAS: 84852-15-3 Soil 2,3 mg/kg Marine water 0,001 mg/L
EC: 284-325-5 Intermittent 0 mg/L Sediment (Fresh water) 4,62 mg/kg
Oral 0,00236 g/kg Sediment (Marine water) 1,23 mg/kg
benzyl alcohol STP 39 mg/L Fresh water 1 mg/L
CAS: 100-51-6 Soil 0,456 mg/kg Marine water 0,1 mg/L
EC: 202-859-9 Intermittent 2,3 mg/L Sediment (Fresh water) 5,27 mg/kg
Oral Non-applicable Sediment (Marine water) 0,527 mg/kg
2-piperazin-1-ylethylamine STP 250 mg/L Fresh water 0,058 mg/L
CAS: 140-31-8 Soil 1 mg/kg Marine water 0,006 mg/L
EC: 205-411-0 Intermittent 0,58 mg/L Sediment (Fresh water) 215 mg/kg
Oral Non-applicable Sediment (Marine water) 21,5 mg/kg
3-aminomethyl-3,5,5-trimethylcyclohexylamine STP 3,18 mg/L Fresh water 0,06 mg/L
CAS: 2855-13-2 Soil 1,121 mg/kg Marine water 0,006 mg/L
EC: 220-666-8 Intermittent 0,23 mg/L Sediment (Fresh water) 5,784 mg/kg
Oral Non-applicable Sediment (Marine water) 0,578 mg/kg
8.2 Exposure controls:
A.- Individual protection measures, such as personal protective equipment
As a preventative measure it is recommended to use basic Personal Protective Equipment, with the corresponding <<CE
marking>> in accordance with Regulation (EU) 2016/425. For more information on Personal Protective Equipment (storage,
use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more
information see subsection 7.1. All information contained herein is a recommendation which needs some specification from
the labour risk prevention services as it is not known whether the company has additional measures at its disposal.
B.- Respiratory protection
The use of protection equipment will be necessary if a mist forms or if the occupational exposure limits are exceeded.
C.- Specific protection for the hands
Non-applicable
D.- Eye and face protection
Non-applicable
E.- Body protection
Non-applicable
F.- Additional emergency measures
It is not necessary to take additional emergency measures.

Environmental exposure controls:

In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental
spillage of both the product and its container. For additional information see subsection 7.1.D
Volatile organic compounds:

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

With regard to Directive 2010/75/EU, this product has the following characteristics:
V.O.C. (Supply): 0 % weight
V.O.C. density at 20 ºC: 0 kg/m³ (0 g/L)
Average carbon number: Non-applicable
Average molecular weight: Non-applicable

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:
For complete information see the product datasheet.
Appearance:
Physical state at 20 ºC: Liquid
Appearance: Not available
Colour: Light yellow
Odour: Not available
Odour threshold: Non-applicable *
Volatility:
Boiling point at atmospheric pressure: Non-applicable *
Vapour pressure at 20 ºC: Non-applicable *
Vapour pressure at 50 ºC: Non-applicable *
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: 1047 kg/m³
Relative density at 20 ºC: 1,047
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility properties: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Flammability (solid, gas): Non-applicable *
Autoignition temperature: 372 ºC
Lower flammability limit: Non-applicable *
Upper flammability limit: Non-applicable *
Particle characteristics:
Median equivalent diameter: Non-applicable
*Not relevant due to the nature of the product, not providing information property of its hazards.

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued)

9.2 Other information:
Information with regard to physical hazard classes:
Explosive properties: Non-applicable *
Oxidising properties: Non-applicable *
Corrosive to metals: Non-applicable *
Heat of combustion: Non-applicable *
Aerosols-total percentage (by mass) of flammable Non-applicable *
components:
Other safety characteristics:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7 from
Safety Data Sheet.
10.2 Chemical stability:
Chemically stable under the indicated conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

10.5 Incompatible materials:

Acids Water Oxidising materials Combustible materials Others
Avoid strong acids Not applicable Precaution Not applicable Avoid alkalis or strong bases

10.6 Hazardous decomposition products:

Contains substances which require external energy for spontaneous decomposition. Form explosive peroxides when distilled,
evaporated or otherwise concentrated.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008:

The experimental information related to the toxicological properties of the product itself is not available

Dangerous health implications:

In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits,
adverse effects on health may result, depending on the means of exposure:
A- Ingestion (acute effect):

- Acute toxicity: The consumption of a considerable dose can cause irritation in the throat, abdominal pain, nausea and
vomiting.
- Corrosivity/Irritability: Corrosive product, if it is swallowed causes burns destroying the tissues. For more information about
secondary effects from skin contact see section 2.
B- Inhalation (acute effect):

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 11: TOXICOLOGICAL INFORMATION (continued)

- Acute toxicity : Exposure in high concentration can interfere with the central nervous system causing headache, dizziness,
vertigo, nausea, vomiting, confusion, and in serious cases, loss of consciousness.
- Corrosivity/Irritability: Prolonged inhalation of the product is corrosive to mucous membranes and the upper respiratory
tract
C- Contact with the skin and the eyes (acute effect):

- Contact with the skin: Above all, skin contact may occur as fabrics of all thicknesses can be destroyed, resulting in burns.
For more information on the secondary effects see section 2.
- Contact with the eyes: Produces serious eye damage after contact.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified
as hazardous for the effects mentioned. For more information see section 3.
IARC: Non-applicable
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous for this effect. For more information see section 3.
- Reproductive toxicity: Suspected of damaging fertility. Suspected of damaging the unborn child.
E- Sensitizing effects:

- Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous with sensitising effects. For more information see section 3.
- Skin: Prolonged contact with the skin can result in episodes of allergic contact dermatitis.
F- Specific target organ toxicity (STOT) - single exposure:

Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for
this effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:

- Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as
it does not contain substances classified as hazardous for this effect. For more information see section 3.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous for this effect. For more information see section 3.
H- Aspiration hazard:

Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for
this effect. For more information see section 3.
Other information:

Non-applicable

Specific toxicology information on the substances:

Identification Acute toxicity Genus

benzyl alcohol LD50 oral 500 mg/kg (ATEi) Rat
CAS: 100-51-6 LD50 dermal 2500 mg/kg
EC: 202-859-9 LC50 inhalation 11 mg/L (ATEi)
2-piperazin-1-ylethylamine LD50 oral 500 mg/kg (ATEi)
CAS: 140-31-8 LD50 dermal 1100 mg/kg (ATEi)
EC: 205-411-0 LC50 inhalation Non-applicable
4-nonylphenol, branched LD50 oral 1412 mg/kg (ATEi) Rat
CAS: 84852-15-3 LD50 dermal Non-applicable
EC: 284-325-5 LC50 inhalation Non-applicable
3-aminomethyl-3,5,5-trimethylcyclohexylamine LD50 oral 1030 mg/kg (ATEi) Rat
CAS: 2855-13-2 LD50 dermal Non-applicable
EC: 220-666-8 LC50 inhalation Non-applicable
11.2 Information on other hazards:
Endocrine disrupting properties
Endocrine-disrupting properties: The product does not meet the criteria.
Other information

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This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 11: TOXICOLOGICAL INFORMATION (continued)

Non-applicable

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the eco-toxicological properties of the product itself is not available
Very toxic to aquatic life with long lasting effects.
12.1 Toxicity:
Acute toxicity:
Identification Concentration Species Genus
4,4´-Isopropylidenediphenol, oligomeric reaction products with 1-
chloro-2,3-epoxypropane, reaction products with m-phenylenebis LC50 >1 - 10 mg/L (96 h) Fish
(methylamine)
CAS: 113930-69-1 EC50 >1 - 10 mg/L (48 h) Crustacean
EC: 500-302-7 EC50 >1 - 10 mg/L (72 h) Algae
4-nonylphenol, branched LC50 0,05 mg/L (96 h) Acipenser oxyrhynchus Fish
CAS: 84852-15-3 EC50 0,14 mg/L (48 h) Daphnia magna Crustacean
EC: 284-325-5 EC50 1,3 mg/L (72 h) Scenedesmus subspicatus Algae
benzyl alcohol LC50 646 mg/L (48 h) Leuciscus idus Fish
CAS: 100-51-6 EC50 400 mg/L (24 h) Daphnia magna Crustacean
EC: 202-859-9 EC50 79 mg/L (3 h) Scenedesmus subspicatus Algae
2-piperazin-1-ylethylamine LC50 2190 mg/L (96 h) Pimephales promelas Fish
CAS: 140-31-8 EC50 58 mg/L (48 h) Daphnia magna Crustacean
EC: 205-411-0 EC50 1000 mg/L (72 h) Pseudokirchneriella subcapitata Algae
3-aminomethyl-3,5,5-trimethylcyclohexylamine LC50 110 mg/L (96 h) Leuciscus idus Fish
CAS: 2855-13-2 EC50 388 mg/L (48 h) N/A Crustacean
EC: 220-666-8 EC50 Non-applicable

Chronic toxicity:
Identification Concentration Species Genus
4-nonylphenol, branched NOEC 0,006 mg/L Oncorhynchus mykiss Fish
CAS: 84852-15-3 EC: 284-325-5 NOEC 0,024 mg/L Daphnia magna Crustacean
benzyl alcohol NOEC 48,897 mg/L N/A Fish
CAS: 100-51-6 EC: 202-859-9 NOEC 51 mg/L Daphnia magna Crustacean
3-aminomethyl-3,5,5-trimethylcyclohexylamine NOEC Non-applicable
CAS: 2855-13-2 EC: 220-666-8 NOEC 3 mg/L Daphnia magna Crustacean
12.2 Persistence and degradability:
Substance-specific information:
Identification Degradability Biodegradability
benzyl alcohol BOD5 Non-applicable Concentration 100 mg/L
CAS: 100-51-6 COD Non-applicable Period 14 days
EC: 202-859-9 BOD5/COD Non-applicable % Biodegradable 94 %
2-piperazin-1-ylethylamine BOD5 Non-applicable Concentration 30 mg/L
CAS: 140-31-8 COD Non-applicable Period 28 days
EC: 205-411-0 BOD5/COD Non-applicable % Biodegradable 0%
3-aminomethyl-3,5,5-trimethylcyclohexylamine BOD5 Non-applicable Concentration 7 mg/L
CAS: 2855-13-2 COD Non-applicable Period 28 days
EC: 220-666-8 BOD5/COD Non-applicable % Biodegradable 8%
12.3 Bioaccumulative potential:
Substance-specific information:

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This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 12: ECOLOGICAL INFORMATION (continued)

Identification Bioaccumulation potential

4-nonylphenol, branched BCF 231
CAS: 84852-15-3 Pow Log 5.4
EC: 284-325-5 Potential High
benzyl alcohol BCF 0.3
CAS: 100-51-6 Pow Log 1.1
EC: 202-859-9 Potential Low
12.4 Mobility in soil:
Identification Absorption/desorption Volatility
4-nonylphenol, branched Koc 22000 Henry 11,02 Pa·m³/mol
CAS: 84852-15-3 Conclusion Immobile Dry soil Yes
EC: 284-325-5 Surface tension Non-applicable Moist soil Yes
benzyl alcohol Koc Non-applicable Henry Non-applicable
CAS: 100-51-6 Conclusion Non-applicable Dry soil Non-applicable
EC: 202-859-9 Surface tension 3,679E-2 N/m (25 ºC) Moist soil Non-applicable
2-piperazin-1-ylethylamine Koc 37000 Henry Non-applicable
CAS: 140-31-8 Conclusion Immobile Dry soil Non-applicable
EC: 205-411-0 Surface tension 4,001E-2 N/m (25 ºC) Moist soil Non-applicable
3-aminomethyl-3,5,5-trimethylcyclohexylamine Koc 928 Henry 4,46E-4 Pa·m³/mol
CAS: 2855-13-2 Conclusion Low Dry soil No
EC: 220-666-8 Surface tension Non-applicable Moist soil No
12.5 Results of PBT and vPvB assessment:
Product does not meet PBT/vPvB criteria
12.6 Endocrine disrupting properties:
Contains 4-nonylphenol, branched. A substance shall be considered as having endocrine-disrupting properties that may cause
adverse effects on non-target organisms if: (a) it shows an adverse effect in non-target organisms, which is a change in the
morphology, physiology, growth, development, reproduction or life span of an organism, system or (sub)population that results in
an impairment of functional capacity, an impairment of the capacity to compensate for additional stress or an increase in
susceptibility to other influences
(b) it has an endocrine mode of action, i.e. it alters the function(s) of the endocrine system
(c) the adverse effect is a consequence of the endocrine mode of action.
12.7 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Waste class (Regulation (EU) No
Code Description
1357/2014)
08 01 11* waste paint and varnish containing organic solvents or other hazardous substances Hazardous

Type of waste (Regulation (EU) No 1357/2014):

HP14 Ecotoxic, HP6 Acute Toxicity, HP10 Toxic for reproduction, HP13 Sensitising, HP8 Corrosive
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex
2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has been in direct contact with
the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-hazardous residue.
Waste should not be disposed of to drains. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) No 1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 14: TRANSPORT INFORMATION **

Transport of dangerous goods by land:
With regard to ADR 2023 and RID 2023:
14.1 UN number or ID number: UN3066
14.2 UN proper shipping name: PAINT
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: II
14.5 Environmental hazards: Yes
14.6 Special precautions for user
Special regulations: 163, 367
Tunnel restriction code: E
Physico-Chemical properties: see section 9
Limited quantities: 1L
14.7 Maritime transport in bulk Non-applicable
according to IMO
instruments:
Transport of dangerous goods by sea:
With regard to IMDG 40-20:
14.1 UN number or ID number: UN3066
14.2 UN proper shipping name: PAINT
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: II
14.5 Marine pollutant: Yes
14.6 Special precautions for user
Special regulations: 367, 163
EmS Codes: F-A, S-B
Physico-Chemical properties: see section 9
Limited quantities: 1L
Segregation group: Non-applicable
14.7 Maritime transport in bulk Non-applicable
according to IMO
instruments:
Transport of dangerous goods by air:
With regard to IATA/ICAO 2023:
14.1 UN number or ID number: UN3066
14.2 UN proper shipping name: PAINT
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: II
14.5 Environmental hazards: Yes
14.6 Special precautions for user
Physico-Chemical properties: see section 9
14.7 Maritime transport in bulk Non-applicable
according to IMO
instruments:

** Changes with regards to the previous version

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 15: REGULATORY INFORMATION (continued)

Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): 4-nonylphenol, branched
Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable
Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable
Article 95, REGULATION (EU) No 528/2012: Non-applicable
REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Contains 4-nonylphenol,
branched
Seveso III:
Lower-tier Upper-tier
Section Description
requirements requirements
E1 ENVIRONMENTAL HAZARDS 100 200
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII REACH,
etc ….):
Contains more than 0.1 % of 4-nonylphenol, branched by weight. Shall not be placed on the market, or used, as substances or in
mixtures in concentrations equal to or greater than 0,1 % by weight for the following purposes:
(1) industrial and institutional cleaning except:
— controlled closed dry cleaning systems where the washing liquid is recycled or incinerated,
— cleaning systems with special treatment where the washing liquid is recycled or incinerated.
(2) domestic cleaning;
(3) textiles and leather processing except:
— processing with no release into waste water,
— systems with special treatment where the process water is pre-treated to remove the organic fraction completely prior to
biological waste water treatment (degreasing of sheepskin);
(4) emulsifier in agricultural teat dips;
(5) metal working except:
uses in controlled closed systems where the washing liquid is recycled or incinerated;
(6) manufacturing of pulp and paper;
(7) cosmetic products;
(8) other personal care products except:
spermicides;
(9) co-formulants in pesticides and biocides. However national authorisations for pesticides or biocidal products containing
nonylphenol ethoxylates as co-formulant, granted before 17 July 2003, shall not be affected by this restriction until their date of
expiry.
Shall not be used in:
—ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental lamps
and ashtrays,
—tricks and jokes,
—games for one or more participants, or any article intended to be used as such, even with ornamental aspects.
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk
assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this
product.
Other legislation:
The product could be affected by sectorial legislation
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION **

Legislation related to safety data sheets:
The SDS shall be supplied in an official language of the country where the product is placed on the market. This safety data sheet
has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation (EC) No 1907/2006
(COMMISSION REGULATION (EU) 2020/878).
Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks.:

** Changes with regards to the previous version

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

SECTION 16: OTHER INFORMATION ** (continued)

COMMISSION REGULATION (EU) 2020/878
CLP Regulation (EC) No 1272/2008 (SECTION 2, SECTION 16):
· Hazard statements
TRANSPORT INFORMATION (SECTION 14):
· UN number
· Packing group
Texts of the legislative phrases mentioned in section 2:
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H317: May cause an allergic skin reaction.
H410: Very toxic to aquatic life with long lasting effects.
H400: Very toxic to aquatic life.
H361fd: Suspected of damaging fertility. Suspected of damaging the unborn child.
H302+H332: Harmful if swallowed or if inhaled.
Texts of the legislative phrases mentioned in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the
individual components which appear in section 3
CLP Regulation (EC) No 1272/2008:
Acute Tox. 4: H302 - Harmful if swallowed.
Acute Tox. 4: H302+H312 - Harmful if swallowed or in contact with skin.
Acute Tox. 4: H302+H332 - Harmful if swallowed or if inhaled.
Aquatic Acute 1: H400 - Very toxic to aquatic life.
Aquatic Chronic 1: H410 - Very toxic to aquatic life with long lasting effects.
Aquatic Chronic 2: H411 - Toxic to aquatic life with long lasting effects.
Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects.
Eye Dam. 1: H318 - Causes serious eye damage.
Repr. 2: H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child.
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage.
Skin Sens. 1: H317 - May cause an allergic skin reaction.
Skin Sens. 1A: H317 - May cause an allergic skin reaction.
Classification procedure:
Skin Corr. 1B: Calculation method
Eye Dam. 1: Calculation method
Skin Sens. 1A: Calculation method
Aquatic Chronic 1: Calculation method
Aquatic Acute 1: Calculation method
Repr. 2: Calculation method
Acute Tox. 4: Calculation method
Advice related to training:
Training is recommended in order to prevent industrial risks for staff using this product and to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://echa.europa.eu
http://eur-lex.europa.eu
Abbreviations and acronyms:
ADR: European agreement concerning the international carriage of dangerous goods by road
IMDG: International maritime dangerous goods code
IATA: International Air Transport Association
ICAO: International Civil Aviation Organisation
COD: Chemical Oxygen Demand
BOD5: 5day biochemical oxygen demand
BCF: Bioconcentration factor
LD50: Lethal Dose 50
LC50: Lethal Concentration 50
EC50: Effective concentration 50
LogPOW: Octanolwater partition coefficient
Koc: Partition coefficient of organic carbon
UFI: unique formula identifier
IARC: International Agency for Research on Cancer
** Changes with regards to the previous version
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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878,
without any country-specific legislation

Epokoat Vernice Epossidica parte B

Printing: 07/12/2023 Date of compilation: 25/11/2021 Revised: 09/05/2023 Version: 2 (Replaced 1)

The information contained in this safety data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy. This
information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of
this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the
manipulation, storage, use and disposal of chemical products. The information on this safety data sheet only refers to this product, which should not be used for needs other than those specified.

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