SAFETY DATA SHEET

according to Regulation (EU) No. 453/2010

__________________________________________________________________

Daltotherm TSW 38-00

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1. Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

Product code Daltotherm TSW 38-00

Synonyms None.

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Industrial uses

Substance/Preparation A component of a polyurethane system.

1.3. Details of the supplier of the safety data sheet

Company/Undertaking PUR-Systems GmbH

Identification Werner-von-Siemens-Str. 22
D-49124 Georgsmarienhütte
Germany
Tel +49 5401 8355 - 0
Fax +49 5401 8355 83
e-mail info@pursystems.de

1.4. Emergency telephone +49 174 975 1711

number +49 173 899 8220

Issuing date 11.11.2013

Version REACH GHS/CLP

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2. Hazards identification
2.1. Classification of the substance or mixture

Classification according to Skin corrosion/irritation, Cat. 2, H315

Regulation (EC) No. 1272/2008 Serious eye damage/eye irritation, Cat. 1, H318
(GHS/CLP) Reproductive toxicity, Cat. 1B (FD), H360
Can become flammable in use.

Classification according to EU R10

Directives 67/548/EEC or Repr. Cat. 2; R60
1999/45/EC

Additional information For the full text of the phrases mentioned in this Section, see
Section 16.
2.2. Label elements

Signal Word Danger

Hazard Statements H315: Causes skin irritation.
H318: Causes serious eye damage.
H360FFDD: May damage fertility. May damage the unborn child.
Precautionary statements P201: Obtain special instructions before use.
P264a: Wash skin thoroughly after handling.
P280c: Wear protective gloves/ eye protection/ face protection.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/
attention.
P310: Immediately call a POISON CENTER or doctor/ physician.
P332+P313: If skin irritation occurs: Get medical advice/ attention.
P405: Store locked up.

Additional advice Can become flammable in use.

GHS product identifier Dimethylpropylphosphonate, CAS-No. 18755-43-6

Labelling according to Directives 67/548/EEC or 1999/45/EC

R-phrase(s) R10: Flammable.

R60: May impair fertility.

S-phrase(s) S16: Keep away from sources of ignition - No smoking.

S45: In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).
S53: Avoid exposure - obtain special instructions before use.
S36/37: Wear suitable protective clothing and gloves.

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Additional advice Contains . May produce an allergic reaction.

Hazardous component(s) which Dimethylpropanphosphonate, CAS-No. 18755-43-6

must be listed on the label

2.3. Other hazards No hazards to be specially mentioned.

3. Composition/information on ingredients
Chemical characterization Mixture.

DSD/DPD
Components CLP Classification Product identifier
Classification
CAS-No.: 13674-84-5
Tris(2-chlor-1- 5% - EC-No.: 237-158-7
Acute Tox. 4 H302 Xn; R-22
methylethyl)phosphat 10% REACH No.: 01-
2119486772-26-0000
Dimethylpropylphosphon 10% - Eye Irrit. 2 H319, Repr. 1B
Xn; R-60
CAS-No.: 18755-43-6
ate 25% H360 (FD) Index-No: 242-555-3
N,N-Bis[3-
Acute Tox. 4 H312, Skin
(dimethylamino)propyl]- 1% - CAS-No.: 33329-35-0
Corr. 1B H314, Eye Dam. 1 C; R-21-34
N',N'-dimethylpropan- 5% EC-No.: 251-459-0
H318
1,3-diamin
N,N-Bis(2- Acute Tox. 3 H301, Acute CAS-No.: 3030-47-5
Dimethylaminoäthyl)Met < 1% Tox. 3 H311, Skin Corr. 1B T,C,Xn; R-22-24-34 EC-No.: 221-201-1
hylamin H314 Index-No: 612-109-00-6
Acute Tox. 4 H312, Skin
Irrit. 2 H315, Skin Sens. 1
Dibutylbis(dodecylthio)st H317, Muta. 2 H341, Repr. T; R-21-38-43-60-61-68- CAS-No.: 1185-81-5
< 1% 1B H360, STOT RE 2 48/25-50/53 Index-No: 214-688-7
annan
H373o, Aquatic Chronic 1
H410
Skin Corr. 1A H314 C; R-35, Notes B
[CSk1A: C ≥ 90 % ¦ CSk1B: [C >= 90 % \ C; R-35 ¦ 10 CAS-No.: 64-18-6
Formic acid < 1% 10 % ≤ C < 90 % ¦ CSk2: 2 % <= C < 90 % \ C; R-34 ¦ EC-No.: 200-579-1
% ≤ C < 10 % ¦ CEy2: 2 % 2 % <= C < 10 % \ Xi; R- Index-No: 607-001-00-0
≤ C < 10 %] , Notes B 36/38]

For the full text of the phrases mentioned in this Section, see Section 16.
Hazardous impurities None known.

4. First aid measures

4.1. Description of first aid measures

Inhalation Move to fresh air in case of accidental inhalation of vapours.

Skin contact Wash off immediately with plenty of water. Remove contaminated
clothes and shoes. Consult a physician for severe cases.

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Eye contact Rinse immediately with plenty of water, also under the eyelids, for
at least 15 minutes. Protect unharmed eye. Consult an
ophthalmologist.

Ingestion Rinse the mouth thoroughly with water. Consult a physician if

necessary. Prevent vomiting if possible.

4.2. Most important symptoms Causes severe burns.

and effects, both acute and
delayed

4.3. Indication of any immediate None known.

medical attention and special
treatment needed

5. Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Use dry chemical, CO2, water spray or alcohol foam.

Extinguishing media which must High volume water jet.

not be used for safety reasons

5.2. Special hazards arising from During a fire, smoke may contain the original material in addition to
the substance or mixture unidentified toxic and/or irritating compounds. In the event of fire the
following can be released: COx, NOx, SiOx, POx, HX. Collect
contaminated fire extinguishing water separately. This must not be
discharged into drains.

5.3. Advice for firefighters

Special protective equipment for Standard procedure for chemical fires. In case of fire and/or
firefighters explosion do not breathe fumes. Wear self contained breathing
apparatus for fire fighting if necessary.

Specific methods Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Advice for non-emergency Use personal protective equipment. Avoid contact with skin and
personnel eyes.

Advice for emergency Use personal protective equipment. Avoid contact with skin and
responders eyes.

6.2. Environmental precautions Prevent product from entering surface water or sewage.

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6.3. Methods and material for Soak up with inert absorbent material (e.g. sand, silica gel, acid
containment and cleaning up binder, universal binder, sawdust).

6.4. Reference to other sections See chapter 8 and 13.

7. Handling and storage

7.1. Precautions for safe Handle in accordance with good industrial hygiene and safety
handling practice. Wear personal protective equipment. Ingestion, exposure
to skin and eyes and inhalation of any generated vapours should be
avoided.

7.2. Conditions for safe storage, The product is hygroscopic. Keep container tightly closed. Store at
including any incompatibilities room temperature in the original container. Keep away from food
and drink.

7.3. Specific end use(s) No information available.

8. Exposure controls/personal protection

8.1. Control parameters

Exposure limit(s) No data is available on the product itself.

Formic acid (CAS 64-18-6)

EU - Occupational Exposure 5 ppm TWA
(2006/15/EC) - Second List of 9 mg/m3 TWA
Indicative Occupational Exposure
Limit Values - TWAs
Ireland - Occupational Exposure 5 ppm TWA
Limits - TWAs 9 mg/m3 TWA
United Kingdom - Workplace 15 ppm STEL (calculated)
Exposure Limits (WELs) - STELs 28.8 mg/m3 STEL (calculated)
United Kingdom - Workplace 5 ppm TWA
Exposure Limits (WELs) - TWAs 9.6 mg/m3 TWA

8.2. Exposure controls

Occupational exposure controls General industrial hygiene practice. Ensure adequate ventilation,
especially in confined areas.

Personal protection equipment

Respiratory protection In case of insufficient ventilation, wear suitable respiratory

equipment.

Hand protection The selected protective gloves have to satisfy the specifications of
EU Directive 89/689/EEC and the standard EN 374 derived from it.

Eye protection Safety glasses with side-shields. Avoid contact with eyes.

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Skin and body protection Long sleeved clothing. Remove and wash contaminated clothing
before re-use.

Thermal hazards No special measures required.

Environmental exposure controls Dispose of waste product or used containers according to local
regulations. Prevent product from entering surface water or
sewage.

9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form Liquid.
Colour colorless to yellowish
Odour Characteristic.
Odour Threshold not determined
pH: not applicable
Melting point/range: < 0 °C
Boiling point/range: not determined
Flash point: not applicable

Evaporation Rate: not determined

Flammability: not applicable
Explosion limits: not determined
Vapour pressure: not determined
Vapor density: not determined
Relative density: 1,17 g/cm³(25°C)
Water solubility: partly soluble
Partition coefficient (n- not determined
octanol/water):
Autoignition temperature: not determined
Decomposition temperature: not determined
Viscosity: 275 mPas (25°C)
Combustion/explosion hazards: not determined
Oxidizing properties: None

9.2. Other information

General Product Characteristics No information available.

10. Stability and reactivity

10.1. Reactivity Reagiert mit Isocyanat.

10.2. Chemical stability No decomposition if used as directed.

10.3. Possibility of hazardous No if used as directed.

reactions

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10.4. Conditions to avoid Burning produces obnoxious and toxic fumes.

10.5. Incompatible materials ferrous metals, alloys and galvanized surfaces

10.6. Hazardous decomposition None under normal use. In the event of fire the following can be
products released: COx, NOx, SiOx, POx, HX.

11. Toxicological information

11.1. Information on toxicological effects

Acute toxicity 2-Propanol, 1-chloro-, phosphate (3:1) (CAS 13674-84-5)

Dermal LD50 Rabbit = 1230 mg/kg (IUCLID)
Dermal LD50 Rat > 5000 mg/kg (IUCLID)
Inhalation LC50 Rat = 5 mg/L 4 h (IUCLID)
Inhalation LC50 Rat > 17.8 mg/L 1 h (IUCLID)
Oral LD50 Rat = 500 mg/kg (IUCLID)
Formic acid (CAS 64-18-6)
Inhalation LC50 Rat = 15 g/m3 15 min (NLM_CIP)
Oral LD50 Rat = 730 mg/kg (IUCLID)

Skin corrosion/irritation Causes skin irritation.

Serious eye damage/eye Serious eye damage/eye irritation

irritation

Respiratory / Skin Sensitisation None known.

Carcinogenicity Carcinogenicity classification not possible from current data.

Germ cell mutagenicity Classification not possible from current data.

Reproductive toxicity Classification not possible from current data.

Specific target organ toxicity No data available.

(single exposure)

Specific target organ toxicity No data available.

(repeated exposure)

Aspiration hazard No data available.

Human experience This product has no known adverse effect on human health.

12. Ecological information

12.1. Toxicity No data is available on the product itself.

2-Propanol, 1-chloro-, phosphate (3:1) (CAS 13674-84-5)

Ecotoxicity - Freshwater Fish - 96 h LC50 Brachydanio rerio: 56.2 mg/L [static]
Acute Toxicity Data 96 h LC50 Leuciscus idus: 180 mg/L [static]
96 h LC50 Pimephales promelas: 98 mg/L [static]

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 96 h LC50 Poecilia reticulata: 30 mg/L [static]
Ecotoxicity - Water Flea - Acute 48 h EC50 Daphnia magna: 63 mg/L
Toxicity Data
Ecotoxicity - Freshwater Algae - 72 h EC50 Desmodesmus subspicatus: 45 mg/L
Acute Toxicity Data 96 h EC50 Pseudokirchneriella subcapitata: 4 mg/L
Formic acid (CAS 64-18-6)
Ecotoxicity - Freshwater Fish - 24 h LC50 Lepomis macrochirus: 175 mg/L [static]
Acute Toxicity Data
Ecotoxicity - Water Flea - Acute 48 h EC50 Daphnia magna: 120 mg/L
Toxicity Data 48 h EC50 Daphnia magna: 138 - 165.6 mg/L [Static]
Ecotoxicity - Freshwater Algae - 96 h EC50 Desmodesmus subspicatus: 25 mg/L
Acute Toxicity Data 72 h EC50 Desmodesmus subspicatus: 26.9 mg/L

12.2. Persistence and No data is available on the product itself. Expected to be

degradability biodegradable.

12.3. Bioaccumulative potential No data is available on the product itself. Bioaccumulation is

unlikely.

12.4. Mobility in soil No data available.

12.5. Results of PBT and vPvB No information available.

assessment

12.6. Other adverse effects No information available.

13. Disposal considerations

13.1. Waste treatment methods

Waste from residues / unused Dispose of in accordance with local regulations.

products

Contaminated packaging Dispose of as unused product.

14. Transport information

ADR/RID Not required.

IMDG Not required.

IATA Not required.

Further Information Not classified as dangerous in the meaning of transport regulations.

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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Regulatory Information The product contains organic halogens.

2-Propanol, 1-chloro-, phosphate (3:1) (CAS 13674-84-5)

EU - REACH (1907/2006) - List of Present
Registered Substances
N-[2-(Dimethylamino)ethyl]-N,N'.N'-trimethyl-1,2-ethanediamine (CAS 3030-47-5)
EU - Seveso III Directive 50 tonne
(2012/18/EU) - Qualifying
Quantities of Dangerous
Substances - Lower-Tier
Requirements
EU - Seveso III Directive 200 tonne
(2012/18/EU) - Qualifying
Quantities of Dangerous
Substances - Higher-Tier
Requirements
Stannane, dibutylbis(dodecylthio)- (CAS 1185-81-5)
EU - REACH (1907/2006) - List of Present
Registered Substances
Formic acid (CAS 64-18-6)
EU - Biocides (1451/2007) - Present
Existing Active Substances
EU - REACH (1907/2006) - Article Present
15(1) - Substances Regarded as
Being Registered - Plant Health
Products
EU - REACH (1907/2006) - List of Present
Registered Substances

15.2. Chemical safety A Chemical Safety Assessment is not required for this substance
assessment when it is used in the specified applications.

16. Other information

Key or legend to abbreviations None.
and acronyms

Full text of phrases referred to H301: Toxic if swallowed.

under sections 2 and 3 H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H319: Causes serious eye irritation.
H341: Suspected of causing genetic defects.
H360: May damage fertility or the unborn child.
H360F: May damage fertility.
H360FD: May damage fertility. May damage the unborn child.
H360FFDD: May damage fertility. May damage the unborn child.
H373oral: May cause damage to organs through prolonged or
repeated exposure if swallowed.
H410: Very toxic to aquatic life with long lasting effects.

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 R10: Flammable.
R21: Harmful in contact with skin.
R22: Harmful if swallowed.
R24: Toxic in contact with skin.
R34: Causes burns.
R38: Irritating to skin.
R43: May cause sensitisation by skin contact.
R48/25: Toxic: danger of serious damage to health by prolonged
exposure if swallowed.
R50/53: Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R60: May impair fertility.
R61: May cause harm to unborn child.
R68: Possible risk of irreversible effects.

Further information Take notice of the directions of use on the label.

Disclaimer The information provided in this Safety Data Sheet is correct to the
best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance
for safe handling, use, processing, storage, transportation, disposal
and release. It is not to be considered a warranty or quality
specification. The information relates only to the specific material
designated and may not be valid for such material used in
combination with any other materials or in any process, unless
specified in the text. This safety datasheet only contains information
relating to safety and does not replace any product information or
product specification.

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