Chemistry Databook W
Chemistry Databook W
Data Book
2024 VCE Examination
Contents pages
1. Electrochemical series 2
2. Chemical relationships 3
3. Physical constants and standard values 4
4. Unit conversions 4
5. Metric prefixes 4
6. Acid‑base indicators 5
7. Colours of selected conjugate redox reagents 5
8. Formulas and charges for selected ions 6
9. Solubility table 8
10. Average bond enthalpies at 25 °C – single bonds 9
11. Average bond enthalpies at 25 °C – multiple bonds 9
12. Energy content of food groups 10
13. Molar enthalpies of combustion 10
14. Heats of combustion of selected blended fuels 11
15. Heats of combustion of selected biofuels 11
16. Periodic table of the elements 12
17. Names of selected elements 14
18. Representations of organic molecules 15
19. Functional group nomenclature in organic chemistry 15
20. 2‑amino acids (α‑amino acids) 16
21. Formulas of selected fatty acids 18
22. Characteristic ranges for infrared absorption 18
13
23. C NMR data 19
1
24. H NMR data 20
25. Representations of selected biomolecules 22
26. Sustainability 22
i. United Nations Sustainable Development Goals 22
ii. Green chemistry principles 23
iii. Types of economies 23
© VCAA 2024
Page 2 of 24VCE Chemistry Data Book
1. Electrochemical series
Standard electrode potential (E 0)
Reaction
in volts at 25 °C
– –
F2(g) + 2e ⇌ 2F (aq) +2.87
+ –
H2O2(aq) + 2H (aq) + 2e ⇌ 2H2O(l) +1.77
– + –
MnO4 (aq) + 8H (aq) + 5e ⇌ Mn (aq) + 4H2O(l) +1.51
2+
+ –
PbO2(s) + 4H (aq) + 2e ⇌ Pb (aq) + 2H2O(l)
2+
+1.47
+ –
(aq) + 14H (aq) + 6e ⇌ 2Cr (aq) + 7H2O(l) +1.36
2– 3+
Cr2O7
– –
Cl2(g) + 2e ⇌ 2Cl (aq) +1.36
+ –
O2(g) + 4H (aq) + 4e ⇌ 2H2O(l) +1.23
– –
Br2(l) + 2e ⇌ 2Br (aq) +1.09
+ –
Ag (aq) + e ⇌ Ag(s) +0.80
–
Fe (aq) + e ⇌ Fe (aq) +0.77
3+ 2+
+ –
O2(g) + 2H (aq) + 2e ⇌ H2O2(aq) +0.68
– –
I2(s) + 2e ⇌ 2I (aq) +0.54
– –
O2(g) + 2H2O(l) + 4e ⇌ 4OH (aq) +0.40
–
Cu (aq) + 2e ⇌ Cu(s) +0.34
2+
–
Sn (aq) + 2e ⇌ Sn (aq) +0.15
4+ 2+
+ –
2H (aq) + 2e ⇌ H2(g) 0.00
–
Pb (aq) + 2e ⇌ Pb(s) – 0.13
2+
–
Sn (aq) + 2e ⇌ Sn(s) – 0.14
2+
–
Ni (aq) + 2e ⇌ Ni(s) – 0.25
2+
–
Co (aq) + 2e ⇌ Co(s) – 0.28
2+
–
Fe (aq) + 2e ⇌ Fe(s) – 0.44
2+
–
Zn (aq) + 2e ⇌ Zn(s) – 0.76
2+
– –
2H2O(l) + 2e ⇌ H2(g) + 2OH (aq) – 0.83
–
Mn (aq) + 2e ⇌ Mn(s) – 1.18
2+
–
Al (aq) + 3e ⇌ Al(s) – 1.66
3+
–
Mg (aq) + 2e ⇌ Mg(s) – 2.37
2+
+ –
Na (aq) + e ⇌ Na(s) – 2.71
–
Ca (aq) + 2e ⇌ Ca(s) – 2.87
2+
+ –
K (aq) + e ⇌ K(s) – 2.93
+ –
Li (aq) + e ⇌ Li(s) – 3.04
VCE Chemistry Data Book Page 3 of 24
2. Chemical relationships
Name Formula
m V
amount of substance (number of moles) n= ; n = cV ; n =
M Vm
E VIt
electrical calibration factor (CF) = =
∆T ∆T
electric charge Q = It
Q
amount of electrons (number of moles) n(e ) =
F
[C ]c [D]d
K
[ A]a [B ]b
equilibrium constant
for the equation
aA + bB + … ⇌ cC + dD + …
Page 4 of 24VCE Chemistry Data Book
4. Unit conversions
0 °C 273 K
5. Metric prefixes
The following prefixes are commonly used within the International System of Units (SI) to modify the
base units and express quantities in multiples or fractions of those units.
6. Acid‑base indicators
Colour change from lower
Name pH range
pH to higher pH in range
dichromate ion, 3+
2− orange chromium(III) ion, Cr green
Cr2O7
brown in −
iodine, I2 iodide ion, I colourless
aqueous solutions
3+ 2+
iron(III) ion, Fe yellow/brown iron(II) ion, Fe pale green
Cations
1+ 2+ 3+
Anions
1− 2− 3−
− monohydrogen 2−
chlorite ClO2 HPO4
phosphate
− 2−
cyanide CN oxide O
dihydrogen − 2−
H2PO4 peroxide O2
phosphate
− 2−
ethanoate CH3COO sulfate SO4
− 2−
fluoride F sulfide S
hydrogen − 2−
HCO3 sulfite SO3
carbonate
− 2−
hydrogen sulfate HSO4 thiosulfate S2O3
−
hydrogen sulfide HS
−
hydrogen sulfite HSO3
−
hydroxide OH
−
hypochlorite ClO
−
iodide I
−
nitrate NO3
−
nitrite NO2
−
perchlorate ClO4
−
permanganate MnO4
Page 8 of 24VCE Chemistry Data Book
9. Solubility table
sodium
potassium
nitrate
ethanoate
bromide, chloride, iodide Most are soluble. lead(II), silver, CuBr2 , CuI2
ΔH (kJ mol−1)
C H O N Br Cl F I
C=C 614
C≡C 839
C=N 615
C≡N 890
C=O 804
O=O 498
N=N 470
N≡N 945
Page 10 of 24VCE Chemistry Data Book
protein 17
carbohydrate 16
Molar enthalpy of
Fuel Formula
combustion (kJ mol–1)
Heat of Heat of
Fuel State combustion combustion
(kJ g–1) (kJ mL–1)
diesel liquid 45 37
kerosene liquid 46 37
petrol liquid 45 34
Heat of combustion
Fuel State
(kJ g−1 )
biodiesel liquid Approx 37
bioethanol liquid 29.7
14–24
This depends on its methane content,
biogas gas which can vary from 45% to 75% methane
by volume, depending on its source. The
other main constituent is CO2 , which does
not burn.
Page 12 of 24VCE Chemistry Data Book
1 2.2
H
1.0
hydrogen
2
He
4.0
helium
96 1.3 97 1.3 98 1.3 99 1.3 100 1.3 101 1.3 102 1.3 103 1.3
Cm Bk Cf Es Fm Md No Lr
(247) (247) (251) (252) (257) (258) (259) (262)
curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
Formula Representation
H H H O
structural formula H C C C C
H H H O H
semi‑structural
CH3CH2CH2COOH or CH3(CH2)2COOH
(condensed) formula
O O
skeletal structure H or
O OH
Class of Functional
Prefix Suffix
compound group name
hydroxy/
alcohol hydroxy‑ ‑ol
hydroxyl
‘halo’ bromo-
(i.e. bromo, chloro-
halogen –
chloro, fluoro, fluoro-
iodo) iodo-
Page 16 of 24VCE Chemistry Data Book
CH3
alanine Ala
H2N CH COOH
NH
H2N CH COOH
H2N CH COOH
CH2 COOH
aspartic acid Asp
H2N CH COOH
CH2 SH
cysteine Cys
H2N CH COOH
H2N CH COOH
CH3 CH CH3
H 2N CH COOH
CH2
phenylalanine Phe
H2N CH COOH
COOH
HN
proline Pro
CH2 OH
serine Ser
H2N CH COOH
CH3 CH OH
threonine Thr
H 2N CH COOH
HN
H2N CH COOH
CH2 OH
tyrosine Tyr
H2N CH COOH
CH3 CH CH3
valine Val
H2N CH COOH
Page 18 of 24VCE Chemistry Data Book
13
23. C NMR data
C shift values relative to TMS = 0
13
Typical
These can differ slightly in different solvents.
R–CH3 8–25
R–CH2–R 20– 45
R3–CH 40–60
R4–C 36– 45
R–CH2–X 15–80
R–CH2–OH 50–90
R2C=CR2 110–150
RCOOH 160–185
R
C O 165–175
RO
R
C O 165–185
H 2N
R
C O 190–200
H
R2C O 205–220
Page 20 of 24VCE Chemistry Data Book
1
24. H NMR data
Typical proton shift values relative to TMS = 0
These can differ slightly in different solvents. The shift refers to the proton environment that
is indicated in bold letters in the formula.
R–CH3 0.9–1.0
R–CH2–R 1.3–1.4
RCH=CH–CH3 1.6–1.9
R3–CH 1.5
O O
CH3 C or CH3 C 2.0
OR NHR
R CH3
C 2.1–2.7
O
O
R C 3.2
NHCH2R
O C CH3 2.3
O
R C 3.7– 4.8
OCH2R
1–6
(varies considerably
R–O–H
under different
conditions)
R–NH2 1–5
RHC=CHR 4.5–7.0
VCE Chemistry Data Book Page 21 of 24
OH 4.0–12.0
H 6.9–9.0
O
R C 6.0–8.0
NH2
O
R C 9.4 –10.0
H
O
R C 9.0–13.0
O H
Page 22 of 24VCE Chemistry Data Book
H
CH2OH
H C OH
O
H H
H C OH H
OH H
H C OH HO OH
H H OH
glycerol α-D-glucose
CH2OH
O
OH
O
OH
O
CH2OH CH2OH CH2OH
CH2OH CH2 CH2OH
O O O
O O O
OH OH OH
OH OH OH
O O O O
O O O O
OH OH OH
n OH OH OH
26. Sustainability
i. United Nations Sustainable Development Goals
The following nine goals are relevant to VCE Chemistry:
• Goal 2: Zero hunger
• Goal 6: Clean water and sanitation
• Goal 7: Affordable and clean energy
• Goal 9: Industry, innovation and infrastructure
• Goal 11: Sustainable cities and communities
• Goal 12: Responsible consumption and production
• Goal 13: Climate action
• Goal 14: Life below water
• Goal 15: Life on land
VCE Chemistry Data Book Page 23 of 24
Natural
Take Make Distribute Use Dispose
resources
Circular
Natural
resources Take
Recycle
Make
Compost
Re-Make
Enrich
Sort
Distribute
Transfer
Use
Re-Use
Repair