Test - 11 (Ja2) (29 10 2023)

JEE ADVANCED PAPER – 2
CLASS 12th APNI KAKSHA STAR BATCH
Time : 3 Hours Maximum Marks : 180

ANSWER KEY
&
SOLUTION WITH EXPLANATION
Solution Sheet Available Only for 24 Hours

PART – 1 : MATHEMATICS
SECTION - 1 (Maximum Marks : 24)

• This section contains EIGHT (08) questions.
• Each question has FOUR options ONE OR MORE THAN ONE of these four option(s) is (are) correct
answer(s).
Answer to each question will be evaluated according to the following marking scheme.
Full marks : +𝟒 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +𝟑 If all the four options are correct but ONLY three options are chosen and both
of which are correct
Partial Marks : +𝟏 If two or more options are correct but ONLY one option is chosen and it is a
correct option.
Zero Marks : 𝟎 If two or more options is chosen (i.e. the question is unanswered)
Negative Marks : −𝟏 In all other cases
• For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct
answer, then
choosing ONLY (A), (B) and (D) will get +4 marks
choosing ONLY (A) and (B) will get +2 marks
choosing ONLY (A) and (D) will get +2 marks
choosing ONLY (B) and (D) will get +2 marks
choosing ONLY (A) will get +1 mark
choosing ONLY (B) will get +1 mark
choosing ONLY (D) will get +1 mark
choosing no option (i.e., the question is unanswered) will get marks; and choosing any other
combination of options will get -1 mark
cos −1 (cosx), |x| < π

1. If f(x) = { , then correct statement(s) is/are -
πlog π |x|, |x| ≥ π
(A) f(x) is not differentiable at three points. (B) f ′ (π+ ) + f ′ (−π− ) = 0
(C) f ′ (π+ ) = f ′ (−π− ) (D) f ′ (0+ ) + f ′ (0− ) = 0
Ans. (A, B, D)
sin([x3 ]−[x]3 )
2. Given limx→α exists finitely, then the value of α can be (where α ∈ I & [.]denotes
(x−α)3
greatest integer function)

(A) 0 (B) 1 (C) -1 (D) 2
Ans. (A, B)
APNI KAKSHA 1
min{sin−1 x, cos−1 x} ; 0≤x≤1
3. Let f(x) = {
max. {sin−1 x, cos−1 x} ; −1≤x<0
1 1
and f(x) = 2 , f(x) = 4 & f(x) = 2 has
number of solution(s) λ1 , λ2 , λ3 respectively, then

(A) λ1 = 2 (B) λ2 = 1
(C) λ2 = 2 (D) λ3 = 1
Ans. (A, C, D)
4. Let (1 + √2)n = An + Bn √2, where An and Bn are rational numbers and n ∈ N, then the value of
A
limn→∞ Bn is equal to -
n
cos−1 x
(A) limx→1− ( )
√1−x
sinx
(B) limx→0 ( )
x
|cosx−sinx|
(C) limx→π π
4 |x− |
4
sin√2x
(D) (limx→0 )
x
Ans. (A, C, D)
5. Let f be a polynomial function satisfying f(x 2 ) − xf(x) = x 4 (x 2 − 1) ∀ x ∈ R. Then, which of the

following is correct
(A) f is an even function
(B) f is an odd function
f(x)
(C) limx→∞ =1
x3
f(x)
(D) limx→∞ ( x2 − x) exist and is equal to a non-zero quantity
Ans. (B, C)
x 2 − 2x + 3 ; x ∈ (−2,0)
6. Let f(x) = { x 3 − x 2 + 2 ; x ∈ [0,2], then
3 − 2x ; x ∈ (2,6]
(A) f(f(x)) is discontinuous at 4 points.
(B) f(f(x)) is discontinuous at 3 points.
(C) f(f(0)) = −1
(D) f(f(2)) = −9
Ans. (B, D)
APNI KAKSHA 2
7. Let f(x) be a polynomial function satisfying the following conditions
f(x)
limx→∞ |x|3 = 0, limx→∞ (√f(x) − x) = −1 and f(0) = 0 (Note : [k] denotes greatest integer
function less than or equal to k )

(A) The number of points of discontinuity of g(x) = [f(x)] in [0,3] is 5
(B) The number of points of non-derivability of h(x) = |f(|x|)| is 3
(C) The number of points of discontinuity of g(x) = [f(x)] in [0,3] is 2
(D) The number of points of non-derivability of h(x) = |f(|x|)| is 1
Ans. (A, B)
8. Let (1 + √5)n = αn + βn √5 where αn and βn are integers, then choose the correct option(s).
α −β
tan−1 ( n+1 n+1 )θ 4
(A) limθ→0 3
=3
sin−1 (βn θ)
α −β
tan−1 ( n+1 n+1 )θ 2
(B) limθ→0 3
=3
sin−1 (βn θ)
α 2 β 2
(C) (2nn ) − 5 (2nn ) = (−1)n
α 2 β 2 n
(D) (2nn ) − 5 (2nn ) = (−1)2
Ans. (A, C)

• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer. If the numerical value has more
than two decimal places truncate/round-off the value to TWO decimal placed.
• Answer to each question will be evaluated according to the following marking scheme:
• Full Marks : +3 If ONLY the correct numerical value is entered
• Zero Marks : 0 In all other cases.
1
9. The probability that value of sin−1 (sinx) + cos −1 (cosy), where x, y ∈ {1,2,3} is an integer is k,
where k is:
Ans. (3)
10. If x = (2 + √3)n , n ∈ N then the value of x − x 2 + x[x], (Where [.] denotes greatest integer
function) is equal to
Ans. (1)
APNI KAKSHA 3
11. P(4,2) is a point on parabola x 2 = 8y. A tangent and a normal are drawn at point P which
1 PN
intersects y-axis at point T & N respectively, then value of 10 (sin(∠PTN)) =
Ans. (0.8)
x
(1−cos(1−cos ))
2
12. If limx→0 is equal to the left-hand derivative of e−|x| at x = ′0′ . Then find the value
2m xn
n−10 m
of ( ).
10
Ans. (7.4)
13. If a⃗ and ⃗b are perpendicular vectors with |a⃗| = 2, |b

⃗ | = 3 and c × a⃗ = ⃗b, then the least value of
|c − a⃗|
Ans. (1.5)
14. If lx + 13y + mz + n = 0 is a plane through intersection of planes 2x + 3y − z + 1 = 0 and

ℓ−n
x + y − 2z + 3 = 0 and is perpendicular to plane 3x − y − 2z = 4, then equals
m
Ans. (4)

• This section contains TWO (02) List -Match sets
• Each List Match set has TWO (02) Multiple Choice Questions.
• Each List Match set has two lists. List I and List II
• List I has Four entries (I), (II),(III) and (IV) and List II has Six entries (P),(Q)(R),(S),(T)and (U)
• Four options are given in each multiple choice question based on List I and List II and only one of these
four options satisfies the condition asked in the multiple choice question.
Full marks : +𝟑 If ONLY the option corresponding to the correct combination is chosen
Zero Marks : 𝟎 If none of the options is chosen (i.e., the question is unanswered)
Negative marks : −𝟏 In all other cases.
Answer the following by appropriately matching the lists based on the information given in the
paragraph
APNI KAKSHA 4
Paragraph – 1
paragraph.
Let L(n, r) denotes the number of ways to select ' r ' objects from ' n ' distinct objects placed in a
row, such that no two of the selected objects were consecutive, and let R (n, r) denotes the
number of ways to select ' r ' objects from ' n ' distinct objects placed on a circle, such that no
two of the selected objects were consecutive.
List-I List-II
(I) R(12,4) + L(8,2) = (P) 81
(II) R(14,5) + L(10,3) = (Q) 9
(III) L(12,4) = (R)124
(IV) L(13,5) = (S) 126
(T) 248
(U) 252
15. Which of the following is correct:
(A) I → (U)
(B) II → (S)
(C) I → (R)
(D) II → (U)
Ans. (D)
16. Which of the following is correct :
(A) III → (R)
(B) IV → (Q)
(C) IV → (S)
(D) III → (U)
Ans. (B)
APNI KAKSHA 5
Paragraph – 2
Let f(x) = max{h(x), ϕ(x), ψ(x)} for 0 ⩽ x ⩽ 1, & f(x + 1) = f(x) ∀x ∈ R. If
g(x) = min{h(x), ϕ(x), ψ(x)}, for 0 ⩽ x ⩽ 1, g(−x) = −g(x) and g(x + 2) = g(x) ∀ x ∈ R,
where h(x) = x 2 , ϕ(x) = (x − 1)2 , ψ(x) = 2x(1 − x)
There are some expressions given in the List I whose values are given in List II below :
List I List II
1 1
f(x+ )− 1
(I) limx→0− 2 2
= (P)
g(x) 12
1
(II) max(min(f(x)), max(g(x))) = (Q) 4
1
(III) The value of 'a' such that equation f(x) = a + g(x) has exactly (R) 2
one solution for x ∈ [−1,1]

21 4
(iv) ∫20 g(x)dx = (S) 9
(T) 1
(U) 2
17. Which of the following is the only CORRECT combination ?
(A) (II), (Q)
(B) (I), (T)
(C) (I), (R)
(D) (II), (S)
Ans. (D)
18. Which of the following is the only CORRECT combination ?
(A) (III), (R)
(B) (IV), (U)
(C) (III), (Q)
(D) (IV), (T)
Ans. (C)
APNI KAKSHA 6
PART – 2 : PHYSICS

answer(s).
correct option.
answer, then
19. A point source of light S is placed on the axis of a lens of focal length 20 cm as shown. A screen
is placed normal to the axis of lens at a distance x from it. Treat all rays as paraxial :
(A) As x is increased from zero intensity continuously decreases

(B) As x is increased from zero intensity first increases then decreases
(C) Intensity at centre of screen for x = 90 cm and x = 110 cm is same
(D) Radius of bright circle obtained on screen is equal to 1 cm for x = 200 cm
Ans. (B,C,D)
1 1 1 1 1 1 1 1 1 1
Sol. − u = f ⇒ v − (−25) = 20 ⇒ v = 20 − 25 = 100 ⇒ V = 100 cm
v
from O to I intensity increases and then decreases at x = 90 cm

and 110 cm intensity is same
(d) Radius at x = 200 cm is equal to radius of lens.
APNI KAKSHA 7
20. A plano-convex lens (μ = 1.5 ) of focal length 20 cm has its plane side silvered :
(A) The radius of curvature of its curved surface is half that of a surface of equi-convex lens of
focal length 20 cm made of same material.
(B) An object placed at 15 cm on the axis on the convex side gives rise to an image at a distance
of 30 cm from it.
(C) An object placed at a distance of 20 cm on the axis on the convex side gives rise to an image
at 40 cm from it.
(D) It acts as a convex mirror.
Ans. (A,B)
1 (μ−1) 1 R
Sol. = = 20 ⇒ 20 = (μ−1) …(i)
F R
1 2
If equiconvex lens of f = 20 then 20 = (μ − 1) R
From eq. (i) and (ii) we conclude

∴ R = 40(μ − 1) … (ii)
So (a) is correct.
After silvering :
Feq = −10 cm (combination will behave like a concave mirror)
[b] u = −15
1 1 1 1 1 1
+ = ⇒ − =−
v μ Feq. v 15 10
1 1 1
= − ⇒ v = −30 cm
v 15 10
So (b) is correct.
[c] u = −20
v = −20
So (c) is wrong
Alternative:
For planoconvex
1 1 1
= (μ − 1) ( − )
f R1 R 2
R1 = ∞R 2 = R
r = 20(μ − 1)
1 1 1
For equiconvex = (μ − 1) ( + )
20 R R
R = 40(μ − 1)
APNI KAKSHA 8
21. A particle is moving along a circle with a constant speed u, as shown in figure. M is a plane
mirror, then:
(A) relative velocity of image with respect to object becomes zero twice in one revolution
(B) path of image with respect to object is circle
(C) path of image with respect to object is straight line
(D) speed of image with respect to object when particle is at P is 2usin θ
Ans. (A,C,D)
Sol. (a)
Relative speed = 2usin θ (perpendicular to mirror)
(b) Relative speed = 0 ⇒ θ = 0, 180∘ since relative velocity is perpendicular to the mirror.
(c) ∴ path will be to and fro along a straight line perpendicular to the mirror.
22. A fish, F in the pond, is at a depth of 0.8 m from water surface and is moving vertically upwards
with velocity 2 ms −1 . At the same instant, a bird B is at a height of 6 m from water surface and
is moving downwards with velocity 3 ms −1 . At this instant both are on the same vertical lines
as shown in the figure. Which of the following statement(s) is(are) correct?
(A) Height of B, observed by F (from itself) is equal to 8.00 m

(B) Depth of F, observed by B (from itself) is equal to 6.60 m
(C) Velocity of B, observed by F (relative to itself) is equal to 5.00 ms −1
(D) Velocity of F, observed by B (relative to itself) if equal to 4.50 ms −1
APNI KAKSHA 9
Ans. (B,D)
Sol.
y dx 1 dy
If observer is in air then d1 = (x + ) and v1 = +
μ dt μ dt
μdx dy
If observer is in water d2 = μx + y and v2 = +
dt dt
23. Which of the following statements is/are correct about the refraction of light from a plane
surface when light ray is incident in denser medium ? [ C is critical angle]
π
(A) The maximum angle of deviation during refraction is 2 − C, it will be at angle of incidence is C
(B) The maximum angle of deviation for all angle of incidences is π − 2C, when angle of
incidence is slightly greater than C
(C) If angle of incidence is less than C then deviation increases if angle of incidence is also
increased
(D) If angle of incidence is greater than C then angle of deviation decreases if angle of incidence
is increased
Ans. (A,B,C,D)
Sol.
24. A certain mirror placed at the origin has î as the normal vector to its reflecting surface. The
mirror begins to translate with a velocity î + ĵ + k̂ at t = 0, at the same time an object which
was initially at î + ĵ starts moving with a velocity (î + ĵ)m/s. Now choose the correct options.
(A) Initial position of the image will be −î + ĵ
(B) The velocity of the image will be î + ĵ
(C) The velocity of the image relative to the object will be zero
(D) The velocity of the image relative to the mirror will be −k̂.
Ans. (A,B,C,D)]
APNI KAKSHA 10
Sol. Motion of mirror perpendicular to its area normal will not made any difference to the velocity
of its image.
25. Light wave enters from medium 1 to medium 2 . Its velocity in 2nd medium is double from 1st .
For total internal reflection the angle of incidence must be greater than
(A) 30∘
(B) 60∘
(C) 45∘
(D) 90∘
Ans. (A)
μ2 v 1 μ
Sol. = v1 = 2 ⇒ μ1 = 2(μ1 > μ2 )
μ1 2 2
For total internal reflection

1 μ1
2 μ1 = ⇒
sin C μ2
1
=
sin C
1
⇒2= ⇒ C = 30∘
sin C
So, for total (Internal reflection angle of incidence must be greater than 30∘ .
26. Glass has refractive index μ with respect to air and the critical angle for a ray of light going from
glass to air is θ. If a ray of light is incident from air on the glass with angle of incidence θ, the
corresponding angle of refraction is
1
(A) sin−1 ( μ)
√
(B) 90 ∘
1
(C) sin−1 (μ2 )
1
(D) sin−1 (μ)
Ans. (C)
1 1
Sol. α μg = sin θ ⇒ μ = sin θ ….(i)
sin i sin θ sin θ
Now from Snell's law, μ = sin r = ⇒ sin r = ….(ii)
sin r μ
From equations (i) and (ii)

1 −1
1
sin r = ⇒ r = sin ( )
μ2 μ2
APNI KAKSHA 11

27. The convex surface of a thin concavo-convex lens of glass of refractive index 1.5 has a radius of
curvature 20 cm. The concave surface has a radius of curvature 60 cm. The convex side is
silvered and placed on a horizontal surface.
At what distance (in metre) should a pin be placed on the optic axis such that its image is
formed at the same place? Calculate your answer in cm.
Ans. (15)
Sol. This silvered concavo-convex lens behaves like a mirror whose focal length can be calculated by
the formula
1 2 1
= +
f f1 f2
f1 = focal length of concave surface.
f2 = focal length of concave mirror
1 2 1 4
∴ = + =−
f −30 −10 30
∴ f = −7.5 cm
1 1 1 1 1 1
Using mirror formula f = v + u ⇒ −7.5 = −x + −x ⇒ x = 15 cm
APNI KAKSHA 12
28. Light is incident at an angle α on one planar end of a transparent cylindrical rod of refractive
index μ. Determine the least value of μ so that the light entering the rod does not emerge from
the curved surface of rod irrespective of the value of α.
Ans. (1.41)
Sol. The light entering the rod does not emerge from the curved surface of the rod when the angle
90 − r is greater than the critical angle.
1
i.e., μ ≤ sin C where C is the critical angle.
Here C = 90 − r
1 1
⇒μ≤ ⇒μ≤
sin (90 − r) cos r
1
As a limiting case μ = … (i)
cos r
Applying Snell's law at A
sin α sin α
μ= ⇒ sin r = … (ii)
sin r μ
π
The smallest angle of incident on the curved surface is when α = 2 . This can be taken as a
limiting case for angle of incidence on plane surface.

From(ii),
sin π/2 1
sin r = ⇒μ= … (iii)
μ sin r
From (i) and (ii) sin r = cos r
⇒ r = 45∘
1 1
⇒μ= = ⇒ μ = √2 = 1.41
cos 45∘ 1/√2
This is the least value of the refractive index of rod for light entering the rod and not leaving it
from the curved surface.
29. A point object ' O ' is placed at a distance 2f from a thin converging lens of focal length ' f '. The
lens is rotated with a constant angular speed ω about an axis perpendicular to the plane of the
paper as shown in the figure [object remains fixed and the optical axis remains in the plane of
πfω
the paper]. The speed of image when the lens has rotated by 1∘ is then K = ?
K
APNI KAKSHA 13
𝛑𝐟𝛚
Ans. ( 𝟒𝟓 units)
Sol.
By lens formula
1 1 1
− =
v −2fcos θ f
1 1 1
= −
v f 2fcos θ
2fcos θ
v = (this is positive)
2cos θ − 1
Since image is formed on line joining object and pole it will still be formed on original principal
axis AB. It is indicated by I. v calculated above shows the image distance along A′ B′ .
2f
∴ x = vsec θ =
2cos θ − 1
Since the image is always formed on the line AB
∴ It will not have any velocity component ⊥ to
dx
AB. It has velocity only along AB which is dt speed of image
dx −2f dθ 4fωsin θ
= = (−2sin θ) =
dt (2cos θ − 1)2 dt (2cos θ − 1)2
1×π
∴ Now θ = radian and cos θ ≃ 1
180
π
4 ⋅ f ⋅ ω (180)
∴ speed =
(1)2
πfω
v = units
45
30. A particle lies on the bottom of a tank T filled with water upto a height of 90 cm. The medium
above the surface of water is of R.I. = 1.2 above which there is mirror M. Beyond the mirror M
the region contains air (μ = 1). The distance of the image formed by the mirror after reflection
of the rays coming from P is ____ cm (w.r.t mirror).
APNI KAKSHA 14
Ans. (150)
Sol. For refraction at water surface,
u = −90 cm ⇒ μ2 = 1.2 ⇒ μ1 = 4/3
uμ2
v = = −81 cm
μ1
This image formed at 81 + 69 = 150 cm below the mirror, after reflection from the mirror will
form its new image 150 cm above it.
31. Light travelling in air falls at an incidence angle of 2∘ on one refracting surface of a prism of
refractive index 1.5 and angle of refraction 4∘ . The medium on the other side is water (n = 4/
3). Find the deviation produced by the prism.
Ans. (1)
Sol.
We can use sin x = x (where x is in radians)

3 4∘ 8∘
sin 2∘ = sin r1∘ ⇒ r1 = ⇒ r2 = A − r1 =
2 3 3
3 4 9
∴ sin r2 = sin e ⇒ e = r2 = 3∘
2 3 8
∴ δ = i + e − A = 2∘ + 3∘ − 4∘ = 1∘
32. A light ray parallel to the principal axis is incident (as shown in the figure) on a thin plano-
convex lens with radius of curvature of its curved part equal to 10 cm. Assuming that the
refractive index of the material of the lens is 4/3 and medium on both sides of the lens is air,
find the distance of the point from the lens curved surface where this ray meets the principal
X
axis. Find your answer in the form 7 cm and fill value of X.
APNI KAKSHA 15
Ans. (18.5)
Sol.
sin θ 3
Applying Snell′s law = ⇒ r = 53∘
sin r 4
sin (r − θ) sin (π − r)
By sine law in △ ABC =
10 (10 + x)
10 + x 4 4 200
= = ⇒ 10 + x =
10 5(sin r cos θ − cos r sin θ) 5 (4 × 4 − 3 × 3) 7
5 5 5 5
200−70 130
(Note : f = 30 cm for paraxial rays) (fm < fp ) ⇒ x = = = 18.5 cm
7 7

paragraph
Match the column-I with their correct match in column-II.

33. A bird in air is diving vertically over a tank with speed 6 cm/s. Base of the tank is silvered. A
fish in the tank is rising upward along the same line with speed 4 cm/s. [Take: μwater = 4/3 ]
APNI KAKSHA 16
List-I List-II
(I) Speed (in cm/s) of the image of fish as seen by the bird (P) 12
directly.
(II) Speed (in cm/s) of the image of fish formed after reflection (Q) 4
from the mirror as seen by the bird.
(III) Speed (in cm/s) of image of bird relative to the fish looking (R) 9
upwards.
(IV) Speed (in cm/s) of image of bird relative to the fish looking (S) 3
downwards in the mirror
(T) 20/3
(U) 32/3
(A) I → R; II → S, III → P,IV → Q

(B) I → R, II → S; III → P; IV → T
(C) I → R;II → S;II → U; IV → Q
(D) I → R; II → T; III → P; IV → Q
Ans. (A)
4
Sol. (C) Velocity of bird in water = 6 × 3 = 8 ↓
w.r.t fish = 8 + 4 = 12 ↓
(D) Velocity of bird in water after reflection from mirror = 8 ↑
w.r.t fish = 8 − 4 = 4 ↑
3
(A) Velocity of fish in air = 4 × 4 = 3 ↑ Velocity of fish w.r.t bird = 3 + 6 = 9 ↑
3
(B) Velocity of image of fish after reflection from mirror in air = 4 × 4 = 3 ↓
w.r.t bird = −3 + 6 = 3 ↑
34. A bird in air is diving vertically over a tank with speed 6 cm/s. Base of the tank is silvered. A
fish in the tank is rising upward along the same line with speed 4 cm/s. Water level is falling at
4 cm/s [Take: μwater = 4/3 ]
APNI KAKSHA 17
List-I List-II
(I) Speed (in cm/s) of the image of fish as seen by the bird (P) 8
directly.
(II) Speed (in cm/s) of the image of fish formed after reflection (Q) 2
from the mirror as seen by the bird.
(III) Speed (in cm/s) of image of bird relative to the fish looking (R) 8/3
upwards
(IV) Speed (in cm/s) of image of bird relative to the fish looking (S) 3
downwards in the mirror.
(T) 20/3
(U) 32/3
(A) I → P; II → Q; III → U; IV → T
(B) I → P; II → Q; III → T; IV → R
(C) I → P;II → U; III → U; IV → R
(D) I → P; II → Q; III → U; IV → R
Ans. (D)
μ μ
Sol. (1) ⃗ R (1 − μr ) + v
⃗I = v
v ⃗ 0 ( μr )
i i
1 1
(v
⃗ I )F = −4j (1 − ) + 4j ( )
4/3 4/3
1
= −4j ( ) + 3j = −j + 3j = 2j
4
(v
⃗ I )FB = (v
⃗ I )F − v
⃗ B = 2j − (−6j) = 8j
1 1
(2) (v
⃗ I )F = −4j (1 − 4/3) − 4j (4/3)
= −j − 3j = −4j
(v
⃗ I )FB = (v ⃗ I)
⃗ I )F − (V B
= −4j − (−6j) = 2j
4/3 (4/3) 4 20
(3) (v
⃗ 1 )B = −4j (1 − ) − 6j = 3 j − 8j = − j
1 1 3
20 −32
(v
⃗ I )BF = − j − 4j = j
3 3
4/3 4/3 4 20
(4) (v
⃗ I )B = −4j (1 − ) − 6j ( ) = + 3 j − 8j = − j
1 1 3
20 20 8
⃗ I′ )B =
(v ⃗ 1′ )BF =
j; (v j − 4j = j
3 3 3
APNI KAKSHA 18
Match the column-I with their correct match in column-II.
35. A beam of light is converging towards a point (20 cm, 1 cm). The axis of symmetry of the
conical beam of light is parallel to x axis and the beam is propagating in positive x direction. An
optical system whose principal axis is x axis is kept in the path of the beam. Match the optical
system in List-I with the appropriate reflected/refracted beam in List-II.
List-I List-II
(I) Convex mirror of focal length 12 cm with pole at (P) Diverging in nature
the origin, centre of curvature is on positive side
of x axis.
(II) Concave mirror of focal length 12 cm with pole at (Q) Converging in nature
the origin, centre of curvature is on negative side
of x axis.
(III) Converging lens of focal length 12 cm with pole at (R) Height of the image from
the origin, the principal axis is more
than 1 cm
(IV) Diverging lens of focal length 12 cm with pole at (S) height of the image from
the origin, the principal axis is less
than 1 cm
(T) Image is below x axis
(U) Image is above x axis
(A) I → P,R,U; II → Q,S,T; III → Q,S,U; IV → P,R,T

(B) I → P,R,T; II → P,S,T; III → P,S,T; IV → P,R,T
(C) I → Q,S,U; II → P,R,T; III → P, R,T; IV → Q, S,U
(D) I → P, R, T; II → Q, S, U; III → Q, S, U; IV → P, R, T
Ans. (D)
APNI KAKSHA 19
36. A beam of light is converging towards a point (−20 cm, −1 cm). The axis of symmetry of the
conical beam of light is parallel to x axis and the beam is propagating in positive x direction. An
optical system whose principal axis is x axis is kept in the path of the beam. Match the optical
system in List-I with the appropriate reflected/refracted beam in List-II.
List-I List-II
(I) Convex mirror of focal length 12 cm with pole at the (P) Diverging in nature
origin, centre of curvature is on positive side of x
axis.
(II) Concave mirror of focal length 12 cm with pole at the (Q) Converging in nature
origin, centre of curvature is on negative side of x
axis.
(III) Converging lens of focal length 12 cm with pole at the (R) Height of the image
origin, from the principal
axis is more than
1 cm
(IV) Diverging lens of focal length 12 cm with pole at the (S) Height of the image
origin, from the principal
axis is less than 1 cm
(T) Image is below x axis
(U) Image is above x axis
(A) I → Q,R,U; II → P,S,T; III → P,S,T; IV → Q,R,U

(B) I → P, S, T; II → Q, R, U; III → Q, R, U; IV → P, S, T
(C) I → P, R, T; II → Q, S, U; III → Q, S, U; IV → P, R, T
(D) I → Q,S,U; II → P,R,T; III → P,R,T; IV → Q,S,U
Ans. (B)
APNI KAKSHA 20
PART – 3 : CHEMISTRY

answer(s).
correct option.
answer, then
37. An ideal gas is taken reversibly from state A(P, V) to the state B(0.5P, 2 V) along a straight line
in PV diagram. Which of the following statement(s) is/are correct regarding the process?
(A) The work done by gas in the process A to B exceeds the work that would be done by it if the
same change in state were performed isothermally.
(B) In the T − V diagram, the path AB becomes a part of parabola.
(C) In the P − T diagram, the path AB becomes a part of hyperbola.
(D) On going from A to B, the temperature of the gas first increases to a maximum value and
then decreases.
Ans. (ABD)
Sol. Figure, shows the straight line path along with the corresponding isothermal path. Since the
work done by the gas is equal to area under the curve (such as shown in the figure by the
shaded portion for the isothermal path), it is obvious that the gas does more work along the
straight line path as compared with that for the isothermal path.
As the volume is increased from V to 2V, the difference of pressure between the straight line
path and isothermal path intially increases and then decreases after attaining a maximum
value. The same trend is observed in the case of temperature (P ∝ T, ∴ V is constant )
APNI KAKSHA 21
Now, the slope of straight line path is
P−P/2 P
m= = 2V or P − 2Vm
V−2V
Putting this in the ideal gas equation,

PV = Nrt or [−2Vm]V = nRT
nR
V2 = − T
2m
V 2 = kT
Which is the equation of a parabola.
Similarly, eliminating V from ideal gas equation, we get
P
P [− 2m] = nRT or P 2 = (constant) T
Which is again an equation of a parabola.

CO

38. Bauxite ⎯⎯ H2O
→ AlN ⎯⎯ → Al (OH )3 ⎯⎯
+C


→ Al2O3
N2
This flow-sheet is not for:

(A) Baeyer's process (B) Serpek's process
(C) Hall's process (D) Kroll's process
Ans. (A,C,D)
Sol. flow-sheet is for: Kroll's process
1800°C
Al2 O3 + C + N2 ⟶ AlN + CO↑
Dilution
AlN + NaOH + H2O → Na  Al ( OH )4  ⎯⎯⎯⎯
with
H2O
→ Al ( OH )3 ⎯⎯⎯
1100c
→ Al2O3
+ NH3  + H2O
HOBr
39. Trans-2-Butene ⎯⎯⎯⎯ → P (product) ; 'P' is :
(A) (B)
CH3 CH3
H Br H Br
(C) (D)
Br H H OH
CH3 CH3
Ans. (AD)
APNI KAKSHA 22
40. Select equations having exothermic step.
−
(I) S(g) ⟶ S 2− (g)
(II) Na+(g) + Cl−
(g) ⟶ NaCl(s)
(III) N(g) ⟶ N− (g)

(IV) Al2+ (g) ⟶ Al3+ (g)
Choose the correct code:
(A) II (B) I, II (C) III and IV (D) III
Ans. (A, D)
− 2−
Sol. S(g) ⟶ S(g) Electron affinity of an anion (endothermic)
Na+(g) + Cl−
(g) ⟶ NaCl(s) Lattice energy (exothermic)
−
N(g) ⟶ N(g) (exothermic)
More stable Less stable
(Half filled 𝑝-subshell)
Al2+ 3+
(g) ⟶ Al(g) (endothermic)
(ionization is endothermic)
41. Identify the alkene which will provide the following alcohol upon oxymercuration
demercuration.
(A) (B)
(C) (D)
Ans. (ABC)
42. Which of the following carbides produces methane on reaction with water?
(A) CaC2 (B) Be2 C (C) Al4 C3 (D) Mg 2 C3
Ans. (B, C)
Sol. Be2 C + H + − OH − ⟶ Be(OH)2 + CH4
Al4 C3 + H + − OH − ⟶ Al(OH)3 + CH4
CaC2 + H + − OH − ⟶ Ca(OH)2 + CH ≡ CH
Mg 2 C3 + H − OH ⟶ Mg(OH)2 + CH3 − C ≡ CH
APNI KAKSHA 23
43. The major product [B] in the following reaction sequences cannot be formed are:
CH 3
→  A alcohol ⎯⎯⎯⎯  
HI H SO
CH 2 − CH 2 − CH − CH 2 − OCH 2 − CH 3 ⎯⎯⎯ 2 4→ B
Heat 
CH 3
(A)
CH3 − CH 2 − C = CH 2
(B) CH3 − CH 2 − CH = CH − CH3

CH 3
(C)
CH3 − CH = C − CH3
(D) CH 2 = CH 2
Ans. (ABD)
Sol.
CH 3
CH3 − CH 2 − CH − CH 2 − OCH 2 − CH 3
HI / 
CH 3

CH 3 − CH 2 − CH − CH 2 − O − CH 2 − CH 3
H
SN 2 SN 2
I−
Prefer to
less hindrance
CH 3
CH 3 − CH 2 − CH − CH 2 − OH + CH 3 − CH 2 − I
 A H 2 SO4 / 
CH 3
CH 3 − CH = C
CH 3
( major )
APNI KAKSHA 24
44. Total number of following reactions are correctly matched with major product and name of
reaction are
SOCl
⎯⎯⎯⎯→
2 (Darzen pocess)
OH Cl
(A)
NaI
(B) CH3–CH2–Br ⎯⎯⎯⎯⎯
acet one
→ CH3–CH2–I (Finkelstein reaction)
HCl
⎯⎯⎯⎯ → (Lucas t est )
(C) OH
ZnCl 2
Cl
AgF
(D) CH3–CH2–Cl ⎯⎯⎯⎯ → CH3–CH2–F (Grooves process)
Ans. (C)
AgF
Sol. CH3–CH2–Cl ⎯⎯⎯⎯ → CH3–CH2–F Swartz reaction

45. In a conductivity cell the two platinum electrodes each of area 10sq. cm are fixed 1.5 cm apart.
The cell. Contained 0.05N solution of a salt. If the two electrodes are just half dipped into the
solution which has a resistance of 50ohms, find equivalent conductance of the salt solution.
Ans. (120)
Sol. Correct Answer – 120mhocm2 eq−1
Since the electrodes of the cell are just half depped the effective area will be 5 eq cm.
1 1.5
Cell constant = a = = 0.3 cm−1
5
Specific conductance = conductance x cell constant

1 1 3
= × cell constant = × 0.3 = mhocm−1
resistance 50 500
Equivalent conductance = specific conductance x volume..... (8)
3
× 20000 = 120mhocm2
500
(0.05N = N/20 ∴ V = 20,000cc)

APNI KAKSHA 25
46.
Calculate sum of bond order between same bonded atoms in Q and R compounds.
Ans. (3)
Sol.
Bond order of [O − O] in H2 O2 = 1.0

Bond order of [O − O] in O2 = 2.0
47. The major product in the following reaction have double bond equivalent (DBE) is
Ans. (2)
Sol.
48. The vapour pressure of a solvent decreased by 10 mm of mercury when a nonvolatile solute
was added to the solvent. The mole fraction of the solute in the solution is 0.2. What should be
the mole fraction of the solvent if the decrease in the vapour pressure is to be 20 mm of
mercury?
(a) 0.4 (b) 0.6 (c) 0.8 (d) 0.2
Ans. 0.6
Sol. x1 ( mole fraction of solute ) = 0.2 From Raoult's law,
P ∘ − PS 10
∘
= x1 ⇒ ∘ = 0.2 ⇒ P ∘ = 50 mm
P P
Again,
when P ∘ − Ps = 20 mm, then
P∘ −PS
= mole fraction ⇒ mole fraction of solvent
P∘
= 1 − 0.4 = 0.6
APNI KAKSHA 26
49. Identify a and b, in the following reactions and calculate the sum of total number of alcohol
functional groups present in both a and b
NaBH4
a
CH3OH
LiAlH4
b
Ans. (4)
Sol.
50. A metal ' M ' (atomic mass = 31.25 ) crystallizes in CCP but it has some vacancy defect. If the
edge length of the unit cell is 500pm and the density of the metal is 1.6075 g/cm3 , then the
number of moles of metal atoms missing per litre of the crystal is (1amu = 1.67 × 10−24 g)
Ans. (2)
M 31.25
Z× 0 4× 4×31.25×1.67×10−24
NA NA
Sol. ρideal = ⇒ = = 1.67 g/ml
a3 (500×10−10 )3 124×10−24
ρactual = 1.6075 g/ml

Difference due to Schottky effect = 1.67 − 1.6075 ⇒ 0.0625 g/ml
62.5
= 0.0625 × 103 g/L = 62.5 g/L = Mole/L = 2 mole/L
31.25

paragraph
APNI KAKSHA 27
Paragraph – 1
An aqueous solution of ' X ' is added slowly to an aqueous solution of ' Y ' as shown in List I. The
variation in conductivity of these reactions is given in List II. Match List I with List II.
List I X Y List II
(A) (C2 H5 )3 N + CH3 COOH (P) Conductivity decreases and then
increases
(B) KI(0.1M) + AgNO3 (0.01M) (Q) Conductivity decreases and then
does not change much
(C) CH3 COOH + KOH (R) Conductivity increases and then
does not change much
(D) NaOH + HI (S) Conductivity does not change much
and then increases
51. The correct pair of match:

(A) B → P (B) D → R (C) A → S (D) C → Q
Ans. (D)
52. The incorrect pair of match:
(A) C → Q (B) D → P (C) B → S (D) None of the above.
Ans. (D)
Sol. (P)(C2 H5 )3 + CH3 COOH → (C2 H5 )3 NHCH3 COO−
x Y
Initially conductivity increases due to ion formation after that it becomes practially constant
because X alone can not form ions. Hence (3) is the correct match.
(Q)Ki(0.1M) + AgNO3 (0.01M) → AgI ↓ +KNO3
x Y
Number of ions in the solution remains constant until all the AgNO3 precipitated as AgI.
therefore conductance increases due to increase in number of ions. Hence (4) is correct match.
(R) Initially conductance decreases due to the decrease in the number of OH ions tthereafter it
slowly increases due to the increases in number of H + ions. Hence (2) is the correct match. (S)
‾H
Initially it decreases due to decrease in H + ions and then increases due to the increases in O
ions. Hence (1) is the correct match.
APNI KAKSHA 28
Paragraph – 2
Match the column
(A) (P) Finkelstein Reaction
(B) (Q) 𝐻3 𝑃𝑂3 also obtained as by product
(C) (R) 𝑃𝑂𝐶𝑙3 also obtained as by product
(D) (S) Darzen Reaction
53. which of the following is a correct pair of match

(A) B, S
(B) C, P
(C) D, S
(D) A, Q
Ans. (C)
54. which of the following is an incorrect pair of match
(A) B, Q
(B) A, S
(C) C, R
(D) D, S
Ans. (B)
APNI KAKSHA 29
Sol.
APNI KAKSHA 30

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JEE ADVANCED PAPER – 2

CLASS 12th APNI KAKSHA STAR BATCH

Time : 3 Hours Maximum Marks : 180

Solution Sheet Available Only for 24 Hours

SECTION - 1 (Maximum Marks : 24)

cos −1 (cosx), |x| < π

greatest integer function)

number of solution(s) λ1 , λ2 , λ3 respectively, then

5. Let f be a polynomial function satisfying f(x 2 ) − xf(x) = x 4 (x 2 − 1) ∀ x ∈ R. Then, which of the

function less than or equal to k )

SECTION - 2 (Maximum Marks : 18)

13. If a⃗ and ⃗b are perpendicular vectors with |a⃗| = 2, |b

14. If lx + 13y + mz + n = 0 is a plane through intersection of planes 2x + 3y − z + 1 = 0 and

SECTION - 3 (Maximum Marks : 24)

two of the selected objects were consecutive.

(I) R(12,4) + L(8,2) = (P) 81

(II) R(14,5) + L(10,3) = (Q) 9

(III) L(12,4) = (R)124

(IV) L(13,5) = (S) 126

15. Which of the following is correct:

16. Which of the following is correct :

(A) III → (R)

(D) III → (U)

Let f(x) = max{h(x), ϕ(x), ψ(x)} for 0 ⩽ x ⩽ 1, & f(x + 1) = f(x) ∀x ∈ R. If

where h(x) = x 2 , ϕ(x) = (x − 1)2 , ψ(x) = 2x(1 − x)

one solution for x ∈ [−1,1]

17. Which of the following is the only CORRECT combination ?

(A) (II), (Q)

(B) (I), (T)

(C) (I), (R)

(D) (II), (S)

18. Which of the following is the only CORRECT combination ?

(A) (III), (R)

(B) (IV), (U)

(C) (III), (Q)

(D) (IV), (T)

SECTION - 1 (Maximum Marks : 24)

(A) As x is increased from zero intensity continuously decreases

from O to I intensity increases and then decreases at x = 90 cm

From eq. (i) and (ii) we conclude

Relative speed = 2usin θ (perpendicular to mirror)

(A) Height of B, observed by F (from itself) is equal to 8.00 m

For total internal reflection

From equations (i) and (ii)

SECTION - 2 (Maximum Marks : 18)

limiting case for angle of incidence on plane surface.

We can use sin x = x (where x is in radians)

SECTION - 3 (Maximum Marks : 24)

Match the column-I with their correct match in column-II.

(A) I → R; II → S, III → P,IV → Q

(U) Image is above x axis

(A) I → P,R,U; II → Q,S,T; III → Q,S,U; IV → P,R,T

(A) I → Q,R,U; II → P,S,T; III → P,S,T; IV → Q,R,U

SECTION - 1 (Maximum Marks : 24)

Putting this in the ideal gas equation,

Which is again an equation of a parabola.

This flow-sheet is not for:

(III) N(g) ⟶ N− (g)