SAFETY DATA SHEET
Revision Date 11-May-2020 Version 12
1. IDENTIFICATION
Product identifier
Product Name 2AR FORM A GASKET #2 SEALANT 1.5OZ
Other means of identification
Product Code 80015
Recommended use of the chemical and restrictions on use
Recommended Use Sealant
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, Ohio 44139 USA Oakville, ON Canada L6H 6M5
Telephone: 1-87-Permatex Telephone: (800) 924-6994
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
E-mail address: mail@permatex.com
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Carcinogenicity Category 1A
Label elements
Emergency Overview
Signal word
Danger
May cause cancer
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Appearance Black Physical state Paste Liquid Odor Alcohol
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Toxic to aquatic life with long lasting effects.
Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
KAOLIN 1332-58-7 30 - 60
ETHANOL 64-17-5 5 - 10
2-PROPANOL 67-63-0 1-5
CRYSTALLINE SILICA 14808-60-7 1-5
TITANIUM DIOXIDE 13463-67-7 0.1 - 1
CARBON BLACK 1333-86-4 0.1 - 1
METHYL ISOBUTYL KETONE 108-10-1 0.1 - 1
4. FIRST AID MEASURES
Description of first aid measures
General advice Get medical advice/attention if you feel unwell.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Wash contaminated clothing before reuse.
Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.
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Most important symptoms and effects, both acute and delayed
Symptoms May cause allergic skin reaction.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Use dry chemical, Foam
Unsuitable extinguishing media
None
Specific hazards arising from the chemical
None in particular.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.
Environmental precautions
Environmental precautions See section 12 for additional ecological information.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel
into suitable containers for disposal. Use personal protective equipment as required.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions Store in a well-ventilated place. Keep cool.
Incompatible materials Strong oxidizing agents
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
KAOLIN TWA: 2 mg/m3 particulate matter TWA: 15 mg/m3 total dust TWA: 10 mg/m3 total dust
1332-58-7 containing no asbestos and <1% TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust
crystalline silica, respirable (vacated) TWA: 10 mg/m3 total
particulate matter dust
(vacated) TWA: 5 mg/m3 respirable
fraction
ETHANOL STEL: 1000 ppm TWA: 1000 ppm IDLH: 3300 ppm
64-17-5 TWA: 1900 mg/m3 TWA: 1000 ppm
(vacated) TWA: 1000 ppm TWA: 1900 mg/m3
(vacated) TWA: 1900 mg/m3
2-PROPANOL STEL: 400 ppm TWA: 400 ppm IDLH: 2000 ppm
67-63-0 TWA: 200 ppm TWA: 980 mg/m3 TWA: 400 ppm
(vacated) TWA: 400 ppm TWA: 980 mg/m3
(vacated) TWA: 980 mg/m3 STEL: 500 ppm
(vacated) STEL: 500 ppm STEL: 1225 mg/m3
(vacated) STEL: 1225 mg/m3
CRYSTALLINE SILICA TWA: 0.025 mg/m3 respirable TWA: 50 µg/m3 TWA: 50 µg/m3 IDLH: 50 mg/m3 respirable dust
14808-60-7 particulate matter excludes construction work, TWA: 0.05 mg/m3 respirable dust
agricultural operations, and
exposures that result from the
processing of sorptive clays
(vacated) TWA: 0.1 mg/m3
respirable dust
: (250)/(%SiO2 + 5) mppcf TWA
respirable fraction
: (10)/(%SiO2 + 2) mg/m 3 TWA
respirable fraction
TITANIUM DIOXIDE TWA: 10 mg/m3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3
13463-67-7 (vacated) TWA: 10 mg/m3 total TWA: 2.4 mg/m3 CIB 63 fine
dust TWA: 0.3 mg/m3 CIB 63 ultrafine,
including engineered nanoscale
CARBON BLACK TWA: 3 mg/m3 inhalable particulate TWA: 3.5 mg/m3 IDLH: 1750 mg/m3
1333-86-4 matter (vacated) TWA: 3.5 mg/m3 TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
METHYL ISOBUTYL KETONE STEL: 75 ppm TWA: 100 ppm IDLH: 500 ppm
108-10-1 TWA: 20 ppm TWA: 410 mg/m3 TWA: 50 ppm
(vacated) TWA: 50 ppm TWA: 205 mg/m3
(vacated) TWA: 205 mg/m3 STEL: 75 ppm
(vacated) STEL: 75 ppm STEL: 300 mg/m3
(vacated) STEL: 300 mg/m3
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.
Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
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appropriate.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Physical state Paste Liquid
Appearance Black
Odor Alcohol
Odor threshold No information available
Property Values Remarks • Method
pH No information available
Melting point / freezing point No information available
Boiling point / boiling range 82 °C / 180 °F
Flash point No information available ASTM D 4359
Evaporation rate 7.7 Ether = 1
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure 33 mm Hg @ 68°F
Vapor density 2.0 Air = 1
Relative density 1.5
Water solubility Partially soluble
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available
Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) 10.978
Density No information available
Bulk density No information available
SADT (self-accelerating No information available
decomposition temperature)
10. STABILITY AND REACTIVITY
Reactivity
No information available
Chemical stability
Stable under normal conditions
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Excessive heat.
Incompatible materials
Strong oxidizing agents
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Hazardous Decomposition Products
Carbon oxides
Aldehydes
Carboxylic acids
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation May cause irritation of respiratory tract.
Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
Skin contact May cause skin irritation and/or dermatitis. Repeated or prolonged skin contact may cause
allergic reactions with susceptible persons.
Ingestion Ingestion may cause irritation to mucous membranes.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
KAOLIN > 5000 mg/kg ( Rat ) > 5000 mg/kg ( Rat ) -
1332-58-7
ETHANOL = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h
64-17-5
2-PROPANOL 5050 mg/kg 12800 mg/kg = 72600 mg/m3 ( Rat ) 4 h
67-63-0
TITANIUM DIOXIDE > 10000 mg/kg ( Rat ) - -
13463-67-7
CARBON BLACK > 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit ) -
1333-86-4
METHYL ISOBUTYL KETONE = 2080 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) 2000 - 4000 ppm ( Rat ) 4 h
108-10-1
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA
ETHANOL A3 Group 1 Known X
64-17-5
CRYSTALLINE SILICA A2 Group 1 Known X
14808-60-7
TITANIUM DIOXIDE - Group 2B - X
13463-67-7
CARBON BLACK A3 Group 2B - X
1333-86-4
METHYL ISOBUTYL A3 Group 2B - X
KETONE
108-10-1
ACGIH (American Conference of Governmental Industrial Hygienists)
A2 - Suspected Human Carcinogen
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause
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adverse liver effects. Contains a known or suspected reproductive toxin.
Target Organ Effects Blood, Central nervous system, Eyes, Liver, Reproductive System, Respiratory system,
Skin, Thyroid, Lungs.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 7016 mg/kg
ATEmix (dermal) 58017 mg/kg
ATEmix (inhalation-dust/mist) 102.2 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
0.042 % of the mixture consists of component(s) of unknown hazards to the aquatic environment
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
ETHANOL -0.32
64-17-5
2-PROPANOL 0.05
67-63-0
METHYL ISOBUTYL KETONE 1.19
108-10-1
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Do not reuse container.
US EPA Waste Number U154 U161
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
ETHANOL Toxic
64-17-5 Ignitable
2-PROPANOL Toxic
67-63-0 Ignitable
14. TRANSPORT INFORMATION
DOT
Proper shipping name: Not regulated
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IATA
Proper shipping name: Not regulated
IMDG
Proper shipping name: Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Not determined
IECSC Complies
KECL Not determined
PICCS Complies
AICS Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
2-PROPANOL - 67-63-0 1.0
METHYL ISOBUTYL KETONE - 108-10-1 0.1
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
METHYL ISOBUTYL KETONE 5000 lb - RQ 5000 lb final RQ
108-10-1 RQ 2270 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
ETHANOL Carcinogen
64-17-5 Developmental
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CRYSTALLINE SILICA *Carcinogen
14808-60-7
TITANIUM DIOXIDE *Carcinogen (airborne, unbound particles of respirable
13463-67-7 size)
METHANOL Developmental
67-56-1
CARBON BLACK *Carcinogen (airborne, unbound particles of respirable
1333-86-4 size)
METHYL ISOBUTYL KETONE Carcinogen
108-10-1 Developmental
• *The asterisked chemical(s) listed are not subject to Proposition 65 because they are not airborne in the finished product
• Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage
• Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
KAOLIN X X X
1332-58-7
ETHANOL X X X
64-17-5
2-PROPANOL X X X
67-63-0
CRYSTALLINE SILICA X X X
14808-60-7
TITANIUM DIOXIDE X X X
13463-67-7
METHANOL X X X
67-56-1
CARBON BLACK X X X
1333-86-4
METHYL ISOBUTYL KETONE X X X
108-10-1
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable
WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 2 Flammability 1 Instability 0 -
HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date 11-May-2020
Disclaimer
Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled.
However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness
of the information. User is responsible for evaluating whether such information or this product is fit for a particular
purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this
product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc.
disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or
use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web
site.
End of Safety Data Sheet
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