SAFETY DATA SHEET

Issuing Date 20-Oct-2014 Revision Date 20-Oct-2014 Revision Number 1

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier Item Nos. 268, 400

Product Name Bowl Fresh Toilet Bowl Deodorizer

Other means of identification N/A

Synonyms N/A

Recommended use of the chemical and restrictions on use

Recommended Use Toilet Bowl Deodorizer

Uses advised against No information available

Details of the supplier of the safety data sheet

Supplier Name Willert Home Products, Inc.

Supplier Address 4044 Park Avenue,
Saint Louis, Missouri 63110 USA
Supplier Phone Number Phone:314-772-2822
(8:30 AM to 4:30 PM CST)
Supplier Email whpcustomerservice@willert.com
Emergency telephone number CHEMTREC 800-424-9300

2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Serious eye damage/eye irritation Category 2

Carcinogenicity Category 1B

GHS Label elements, including

precautionary statements

Emergency Overview

Signal word Danger

Hazard statements
Causes serious eye irritation
May cause cancer

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Appearance White crystalline Physical State Solid Odor Cherry

Precautionary Statements - Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required

Precautionary Statements - Response

IF exposed or concerned: Get medical advice/attention

Precautionary Statements - Storage

Store locked up

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

• Although this product is solid, it can melt and become a combustible liquid at high temperatures (>61 °C/ 141.8 °F). All precautions
for combustible liquids should be taken.

Other information
• Very toxic to aquatic life with long lasting effects

Interactions with Other Chemicals No information available.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight % Trade Secret

p-Dichlorobenzene 106-46-7 99 - 100 *
o-Dichlorobenzene 95-50-1 0.1 - 1 *

* The exact percentage (concentration) of composition has been withheld as a trade secret

4. FIRST AID MEASURES

First aid measures

General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.

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Eye Contact If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the
eyelids, for at least 15 minutes. Remove contact lenses, if applicable, and continue flushing.
Keep eye wide open while rinsing. Do not rub affected area.

Skin Contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a
physician. Wash off with warm water and soap.

Inhalation Move to fresh air. If not breathing, give artificial respiration. Administer oxygen if breathing is
difficult and you are trained.

Ingestion Do NOT induce vomiting. Clean mouth with water and afterwards drink plenty of water. Never
give anything by mouth to an unconscious person. Consult a physician.

Protection of First-aiders Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Remove all sources of ignition. Use personal protective equipment. For
personal protection see Section 8.

Most important symptoms and effects, both acute and delayed

Most Important Symptoms/Effects No information available.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Dry chemical, CO2, water spray or regular foam. Water spray, fog or regular foam. Move containers from fire area if you can do it
without risk. Dike fire-control water for later disposal.

Unsuitable Extinguishing Media

Do not scatter spilled material with high pressure water streams.

Specific Hazards Arising from the Chemical

Some may burn but none ignite readily. Risk of ignition. Keep product and empty container away from heat and sources of ignition. In
the event of fire, cool tanks with water spray Fire residues and contaminated fire extinguishing water must be disposed of in accordance
with local regulations

Uniform Fire Code Irritant: Solid

Hazardous Combustion Products

Carbon oxides.

Explosion Data
Sensitivity to Mechanical Impact No

Sensitivity to Static Discharge Yes

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.

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6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Do not touch or walk through spilled material. Stop leak if you can do it without risk. Evacuate
personnel to safe areas. Use personal protective equipment. Refer to Section 8 Avoid contact
with skin, eyes and clothing. Ensure adequate ventilation. Remove all sources of ignition. Take
precautionary measures against static discharges.

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Refer to protective
measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so.

Methods and material for containment and cleaning up

Methods for Containment Prevent dust cloud.

Methods for Cleaning Up With clean shovel place material into clean, dry container and cover loosely; move containers
from spill area. Take up with sand or other noncombustible absorbent material and place into
containers for later disposal. Take precautionary measures against static discharges. Pick up
and transfer to properly labeled containers.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling Do not breathe vapors, mist or gas. Wear personal protective equipment. Avoid contact with
skin and eyes. Keep away from heat, sparks and open flame. No smoking. Use only in area
provided with appropriate exhaust ventilation. Keep in an area equipped with sprinklers Use
according to package label instructions

Conditions for safe storage, including any incompatibilities

Storage Keep away from heat and sources of ignition. Keep containers tightly closed in a cool, well-
ventilated place. Keep in properly labeled containers.

Incompatible Products None known based on information supplied.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
p-Dichlorobenzene TWA: 10 ppm TWA: 75 ppm IDLH: 150 ppm
3
106-46-7 TWA: 450 mg/m
(vacated) TWA: 75 ppm
3
(vacated) TWA: 450 mg/m
(vacated) STEL: 110 ppm
3
(vacated) STEL: 675 mg/m
o-Dichlorobenzene STEL: 50 ppm (vacated) Ceiling: 50 ppm IDLH: 200 ppm
3
95-50-1 TWA: 25 ppm (vacated) Ceiling: 300 mg/m Ceiling: 50 ppm
3
Ceiling: 50 ppm Ceiling: 300 mg/m
3
Ceiling: 300 mg/m

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).

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Appropriate engineering controls

Engineering Measures Showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/Face Protection If splashes are likely to occur, wear: Safety glasses with side-shields. None required for
consumer use.

Skin and Body Protection Wear protective gloves/clothing.

Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties

Physical State Solid
Appearance White crystalline Odor Cherry
Color No information available Odor Threshold No information available

Property Values Remarks/ Method

pH N/A None known
Melting/freezing point No data available None known
Boiling Point/Range No data available None known
Flash Point 65C / 149F None known
Evaporation rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limits in Air
Upper flammability limit No data available
Lower flammability limit No data available
Vapor pressure No data available None known
Vapor density No data available None known
Specific Gravity No data available None known
Water Solubility No data available None known
Solubility in other solvents No data available None known
Partition coefficient: n-octanol/water None known
Autoignition temperature None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity None known
Explosive Properties No data available
Oxidizing Properties No data available

Other Information
Softening Point No data available
VOC Content (%) No data available

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10. STABILITY AND REACTIVITY

Reactivity
No data available.

Chemical stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Hazardous Polymerization
Hazardous polymerization does not occur.

Conditions to avoid
Heat, flames and sparks.

Incompatible materials
None known based on information supplied.

Hazardous Decomposition Products

Carbon oxides.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation There is no data available for this product. May cause irritation of respiratory tract.

Eye Contact There is no data available for this product. Expected to be an irritant based on components.
May cause redness, itching, and pain. May cause temporary eye irritation.

Skin Contact There is no data available for this product. May cause irritation. Prolonged contact may cause
redness and irritation.

Ingestion There is no data available for this product. Ingestion may cause irritation to mucous
membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

o-Dichlorobenzene = 500 mg/kg ( Rat ) > 10 g/kg ( Rabbit ) = 8.15 mg/L ( Rat ) 4 h
95-50-1

Information on toxicological effects

Symptoms May cause redness and tearing of the eyes.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Mutagenic Effects No information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH IARC NTP OSHA

p-Dichlorobenzene A3 Group 2A Reasonably Anticipated X
106-46-7 Group 2B
o-Dichlorobenzene Group 3
95-50-1

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ACGIH: (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC: (International Agency for Research on Cancer)
Group 2A - Probably Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans
Group 3 - Not Classifiable as to Carcinogenicity in Humans
NTP: (National Toxicity Program)
Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen
OSHA: (Occupational Safety & Health Administration)
X - Present

Reproductive Toxicity No information available

STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity No known effect based on information supplied. Contains a known or suspected carcinogen
May cause adverse liver effects.
Target Organ Effects Eyes. Respiratory system. Skin. Gastrointestinal tract (GI). Kidney. Liver. Blood.
Aspiration Hazard No information available.

Numerical measures of toxicity Product Information

12. ECOLOGICAL INFORMATION

This product contains a chemical which is listed as a severe marine pollutant according to DOT

Ecotoxicity

Very toxic to aquatic life with long lasting effects

Persistence and Degradability

No information available.

Bioaccumulation
No information available.

Other Adverse Effects

No information available.

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13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).

Contaminated Packaging Dispose of in accordance with local regulations.

US EPA Waste Number D027 U070 U072

Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
p-Dichlorobenzene waste number U072 Included in waste streams: = 7.5 mg/L regulatory level U072
106-46-7 F039, K149, K150
o-Dichlorobenzene U070 Included in waste streams: U070
95-50-1 F002, F039, K042

Chemical Name RCRA - Halogenated RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes
Organic Compounds
p-Dichlorobenzene Category II – Semi-volatiles
106-46-7
o-Dichlorobenzene Category II - Semi-volatiles
95-50-1

California Hazardous Waste Codes 232

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste

p-Dichlorobenzene Toxic
106-46-7
o-Dichlorobenzene Toxic
95-50-1

14. TRANSPORT INFORMATION

DOT
Proper Shipping Name CONSUMER COMMODITY
Hazard Class ORM-D
Subsidiary Class
Marine Pollutant This product contains a chemical which is listed as a severe marine pollutant according to DOT
Description CONSUMER COMMODITY, ORM-D, MARINE POLLUTANT
Emergency Response Guide 171
Number

TDG
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
Marine Pollutant This product contains a chemical which is listed as a marine pollutant according to TDG.
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, MARINE POLLUTANT

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14. TRANSPORT INFORMATION
MEX
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
Description UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, MARINE POLLUTANT

ICAO
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, MARINE POLLUTANT

IATA
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, MARINE POLLUTANT

IMDG/IMO
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
EmS No. F-A, S-F
Marine Pollutant Product is a marine pollutant according to the criteria set by IMDG/IMO
Description UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, MARINE POLLUTANT

RID
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
Classification Code M7
Description UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, MARINE POLLUTANT

ADR
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
Classification Code M7
Description UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, , MARINE POLLUTANT

ADN
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class 9
Packing Group III
Classification Code M7

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14. TRANSPORT INFORMATION
Special Provisions 274, 335, 601
Description UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(P-
DICHLOROBENZENE, O-DICHLOROBENZENE ), 9, III, MARINE POLLUTANT
Hazard Labels 9
Limited Quantity 5 kg

15. REGULATORY INFORMATION

International Inventories

TSCA Complies
DSL All components are listed either on the DSL or NDSL.

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical Name CAS-No Weight % SARA 313 – Threshold

Values %
p-Dichlorobenzene - 106-46-7 106-46-7 99 - 100 0.1
o-Dichlorobenzene - 95-50-1 95-50-1 0.1 - 1 1.0

SARA 311/312 Hazard Categories

Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No

Clean Water Act

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42):

Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA – Hazardous
Quantities Substances
p-Dichlorobenzene 100 lb X X X
106-46-7
o-Dichlorobenzene 100 lb X X X
95-50-1

CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQ

RQs
p-Dichlorobenzene 100 lb RQ 100 lb final RQ
106-46-7 RQ 45.4 kg final RQ
o-Dichlorobenzene 100 lb RQ 100 lb final RQ
95-50-1 RQ 45.4 kg final RQ

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U.S. State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals:

Chemical Name California Prop. 65

p-Dichlorobenzene - 106-46-7 Carcinogen

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

p-Dichlorobenzene X X X
106-46-7
o-Dichlorobenzene X X X
95-50-1

International Regulations
Mexico - Grade Moderate risk, Grade 2

Chemical Name Carcinogen Status Exposure Limits

p-Dichlorobenzene A3 Mexico: TWA 75 ppm
3
Mexico: TWA 450 mg/m
Mexico: STEL 110 ppm
3
Mexico: STEL 675 mg/m
o-Dichlorobenzene Mexico: TWA 50 ppm
3
Mexico: TWA 300 mg/m

Canada
WHMIS Hazard Class
D2A Very toxic materials

16. OTHER INFORMATION

NFPA Health Hazard 2 Flammability 2 Instability 0 Physical and Chemical

Hazards -
HMIS Health Hazard 2 * Flammability 2 Physical Hazard 0 Personal Protection X
Chronic Hazard Star Legend *Indicates a chronic health hazard.

Prepared By Product Stewardship

23 British American Blvd.
Latham, NY 12110
1-800-572-6501

Issuing Date 20-Oct-2014

Revision Date 20-Oct-2014

Revision Note No information available

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General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials
or in any process, unless specified in the text

End of Safety Data Sheet

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