Test-2_Paper-1_(Code-A) JEE (Advanced) CoE (XII)-2021-22

Test Date: 23/05/2021 Phase-I

A
CODE

Regd. Office: Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

UNIT TEST For CoE-(XII)

for JEE (Advanced) – 2021-22

Test – 2A (Paper - 1)_Type-III

ANSWERS & SOLUTIONS

PART – I : PHYSICS
1. Answer (D) 6. Answer (A)
Q

R 2
Q 2x dx q02
 dv   R 2 40 x U
2C
Q q02
v  mg 
2  0 R 2C
7. Answer (A, D)
2. Answer (A)
 v  v  8. Answer (A, C)
E i j   a  y i  x j 
x y 9. Answer (A, C)
dy x Solution For Q. No. 7 to 9

dx y
C1C 2
C eq 
y2 – x2 = Constant C1  C 2
3. Answer (C) 2C1C 2
Q V
C1  C 2 0
Maximum potential is at x = 3 m
2
1 1  2V  4V02
V  30   30  3 Ui  C  0 
2  3  18
2
V = 75 V 1
Uf  CV02
4. Answer (C) 2
5
Potential across capacitor 2F, 4F would be U  CV02
18
equal. 10. Answer (B, D)
V = 10 kV 11. Answer (B, C)
5. Answer (A) 12. Answer (B, C)
Q1 Q2 Solution For Q. No. 10 to 12
V 
4 0 R 4  0 R Ceq increases, hence total charge increases.
3Q1 = Q2 Apply KVL and conservation of charge to arrive
2Q1 at required result.
V 
4  0 R

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JEE (Advanced) CoE (XII)-2021-22 UT-2A_Paper-1 (Code-A)

13. Answer (A) 18. Answer (02)

14. Answer (A, D) E  2  x i
15. Answer (B, D)   dx   dy   dz 
2  dx   dy   dz  
Solution For Q. No. 13 to 15 0
2Q 2Q  = 20
V0  
4  0 R 8  0 R
19. Answer (02)
Q
= k
4  0 R E
r
Ceq = 80R b
dr
V  k
 2Q 2
Q 2 x
r
U  
2  20R 40R  b
V0  k ln  
 x
16. Answer (A)  (R); (B)  (P); (C)  (S); (D) 
(Q) V0
k
 b
ln  
 x

V0
E
 b
x ln  
 x

d  b
x ln    0
dx  x
Q2
A : Q1  v  b x  x b
2  ln     2
 x b x
Q2
Q1  Q2  Q1  0  b
2 x 
 e
3Q2 = 4Q1
20. Answer (08)
5Q1
v
3
4v
Q2 
5 PQ = 6 + 2 = 8.
17. Answer (A)  (Q, S, T); (B)  (Q, S, T); (C) 
(P, R); (D)  (Q, S, T)
Based on conductor electrostatics.

PART – II : CHEMISTRY
Note : Activity may be considered same as The space between the electrodes is filled by a
concentration in all expression involving activity. moist paste of ammonium chloride and Zinc
chloride
21. Answer (D)
Cathodic reaction:
H+ ions moves 50 times more rapidly through ice
than through liquid water MnO2  NH4  e–  MnO  OH  NH3
22. Answer (C)
The cell has a potential of nearly 1.5 V
For prolonged period, for passage of direct
current can lead to change in its composition 24. Answer (D)
due to electrochemical reaction Fuel cell produce electricity with an efficiency of
23. Answer (A) about 70% compared to thermal plant whose
efficiency is about 40%

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25. Answer (B) RT  KSP 

E°  ln  
H+ ion is coming from H2CO3. Which is believed 2F  Kw 2 
to be available from dissolution of CO2 from air
0.059 V K 
into water 0   0   40 V    log  SP 
26. Answer (A)
2  Kw 2 

1 K  0.40
H+  e –  H2 log  SP    13.527
2
2  Kw  0.02957
 1/2  KSP = 3.36 × 10–15 mol2 dm–6
RT  PH2 
E = E° – ln 31. Answer (A, B)
nF  a + 
 H 
G = – nFE = 0
Since the activity of single ionic species such as
 E 
H+ or Cl– ion can never be known S  nF  
 T P
27. Answer (C)
= 2 × 96500 × 0.002 = 386 CVK–1 mol–1
[Z2+] will increase and Ag+ will decrease.
= 386 JK–1 mol–1
Ecell  ERed
 
 Eox
32. Answer (C)
1.05 = 0.8 – Eox H = G + TS

Eox = 0.8 – 1.05 = 290 k × 386 Jk –1 mol–1

= 115.028 kJ mol–1
= –0.25 V
33. Answer (A)
E 2+  0.25 V
M /M 34. Answer (B)
28. Answer (B) 35. Answer (C)
Ag is cathode hence Ag+ will be deposited at Ag Solution for Q 33 to 35
electrode.
Overall cell reaction
29. Answer (B)


H2  Q  2H+  +
 2H  QH2
Z 2+
/Z will become cathode (higher E° than – R  L 
2+
0.76 V) and Zn /Zn will be anode  2 

30. Answer (A)  a
  
RT  H+ L   aQH2 

E = E° – ln    
For the given cell 2F     a
  a +    Q 
  H R  
Cd Cd  OH2  s  NaOH  0.01 M H2 1 bar  Pt
 
We have overall reaction
E = E° –
RT  H+ L
ln
a  

F   H+  
Cd + 2H+  Cd2+ + H2   a  
 R 
Emf of the cell given by
E° = E  E +
QH2 ,Q, H+|Pt

    H |H2|Pt
RT  aCd2+ PH2 
Ecell  E°  ln   = 0.6994 V
 
2F  2
a + 
 H 
E  0.6994 

 
RT  aH+ L 
ln 
Ecell  E° 

RT  aCd2+
ln

  
F  a + 
 H R
2F  a2 

 H+  At 298 K, we have



RT  aCd2+ aOH– 
2
 
 a + 
 H L
E = 0.6994 – 0.05913 log 
 
Ecell  E°  ln 
2F  a2 + a2 –
H OH

  aH+ 


R 
 
 

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JEE (Advanced) CoE (XII)-2021-22 UT-2A_Paper-1 (Code-A)

 
 a + 
 H L  E – 0.6994
 log 
e –  Ag+  Ag

 
 aH+


R 
0.059 4OH–  O2  4e –  2H2 O

E = 0.7314 V O2 is liberated at anode

pH will decrease as H2SO4 will be formed
 
 a + 
 H L  0.7314 – 0.6994
 log  
 
 aH+


R 
0.05913 electrolysis of HgSO4 :

2e–  Hg2+  Hg (metal deposited at Cathode)

 a +
 H R  

log    0.5412
 aH+

 
L


4OH–  O2  4e –  2H2 O
Oxygen liberated at anode formation of H2SO4
 
 a + 
 H R
decreases the pH
Electrolysis of H2SO4(aq) 
log    0.541

 
 aH+ 
L  H+ + e–  H2
1
2
aH R  3.477
+ H2 gas will be liberated at cathode

aH L
+
4OH–  O 2  4e –  2H2O
Oxygen liberated at anode
The acid HA2 is 3.477 times stronger than the Since H2SO4 is decreases the pH of the solution
acid HA1 will decrease also
For the two acid 38. Answer (03)

aH R   K2  aHA
+
2


1/2
Eeq of Ir =
0.288 n 0.02  6  3600

192 96000
aH L  K1  aHA
+ 1


0.02  6  3600  192
n
as acids are weak 96000  0.288
aHA1  aHA2 n=3
39. Answer (02)
 K 2  1/2
   3.477 For galvanic cell E° must be positive
 K1 
Pt, H2 H+ 1 M H+  ?  H2, Pt
4
5  10
K1   4.135  10 5
 3.477 2  H+  
0.118  0.059 log    
1  1 
 H L 
a +  K1aHA1 
1/2
  
4.135  10 5  0.1 2  
0.118 = 0.059 pH
= 2.03 × 10–3
0.118

pH   log 2.03  103  2.69  pH 
0.059
=2

36. Answer A(Q), B(R, T); C(P); D(S) 40. Answer (08)

Fact based  = It = 2.50 × 66 × 60 = 9900C

Cathode reaction is
CuO is semiconductor
Fe3+  e– Fe2+
37. Answer (P, R); B(Q, S, T); C(Q, S, T), D(P, Q, S) 9900
Moles of Fe2+ produced =
Electrolysis of NaCl : H2 gas is liberated at 96500
Cathode NaOH is 9900
formed pH increase = Normality × 0.025
96500
Electrolysis of Ag2SO4 : Metal is deposited at
4.1
Cathode Molarity =  0.82
5

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PART – III : MATHEMATICS

41. Answer (D)  
2  2   i.e, x = 2 – 3
Let x = tan 3 12

1  tan      
   2 tan–1  2 tan–1  tan      for 2   ,  
1– tan    4  2 
 
2  2 –      i.e, x = 3
–1
 1– tan2 
 –1      3 3
  sin    sin cos 2   sin  – 2  
 1  tan2    2 
  Sum of solution = 2
  43. Answer (D)
when x  (0,1) then x   0, 
 4
Given inequality
1     
  tan  tan     2        
 4  4  cot –1 x  tan–1 x  2 –  – 3  tan–1 x  2 –   0
 2   2 

=  2
2  
 cot –1 x – 3 2 – cot –1 x  0 
   
  sin –1  sin  – 2     2  –1 –1 
 2  2  tan x  cot x  2 
 
 p    
 cot–1 x  2,3

when x > 1,  
4 x  (cot3, cot2) { as cot–1x is decreasing
      3  function}
  2 tan –1  tan       2  –        2
  4    4  2 Hence ,
    sin–1 sin2  tan–1 tan3    – 2   3 –   1
  sin –1  sin   2    – 2
  2  4
44. Answer (B)
 q      
1– x
hence p + q = 0 Put y  x  1– y
1 x 1 y
42. Answer (B)
 1– x 2   2x  
  f ( x )2  f  1– x   64 x
Given : cos –1
   tan–1    1 x 
 1 x 2   1 x2  3
  Squaring and dividing by given relation
 –    1 x 
Let x  tan ,    ,    f ( x )3  64 x 2 .  
 2 2  1– x 
Given equation reduces to 1

  f ( x )  4.  x 2 .  1  x   3
cos –1  cos2   tan –1  tan 2    1– x 
3
45. Answer (A)
 – 
for 2   – ,
 2    f (x)3  1– x3 – 3x.f (x)

–2  2   

3
 No solution f  x 
3
 x 3    1
3
  3   1 x  f  x 
 –   Either f(x) + x – 1 = 0 or f(1) = f(–1) but given
for 2   ,0  f(1)  –1
 2 
Here f(x) = 1 – x

–2  2   No solution
3  h( x )  x  Domain in x  [0,  ) .

 
for 2   0, 
 2
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JEE (Advanced) CoE (XII)-2021-22 UT-2A_Paper-1 (Code-A)

46. Answer (C) Answer for Qs. 50 to 52


f ( x )  tan –1 

 x3 – 3x  x –   

50. Answer (C)
 x– 
 
tan–1 x
 
  2
f (x )  , g(x)  sin–1 x
2
Consider y  x3 – 3x 1  tan–1 x


A rough sketch of y  x3 – 3x is as shown Domain of h(x)  f

2
 x  g(x) is x  [–1, 1]
Now ,

2   
tan –1 x  1 – 1 
   1 
f (x)     1 – 
2 2 2 2
 1  tan x  1  tan –1 x 
–1

     
for f(x) to be onto     2, 2 

2 + 3 = 2(–2) + 3(2) = 2 Minimum value of f ( x)  at x = –1
2
47. Answer (B) 
Maximum value of f (x)  at x = 1
–1 –1
cos 2x  cos 3x   – cos x  cos –1 –1
 –x  6

 2 
 Here f 2 ( x )  0,  with maximum and
 4 
cos –1   2 x  3 x  – 1– 4 x 2 1– 9 x 2   cos–1   x  minimum value at x = –1 and x = 0 respectively
 

 
–1 2  2 
Also g(x)  sin x has range 0, 
 2
6 x – 1– 4 x 2 2
1– 9 x   x  4 

 12 x 3  14 x 2 – 1  0  2 
Here range of h(x) is 0, 
a = 12, b = 14, c = 0  2 

1
48. Answer (B) Here a = 0, b   7a + 4b = 2
2
sin–1  sin b  sin–1  sin14  14 – 4 51. Answer (A)
Obviously a = 0, 1, 2, 3, 4
cos–1 cosa  cos–1  cos12  4 –12 n
 tan –1(tan ai )  tan –1(tan 0)  tan –1(tan1)  tan –1(tan 2)
tan –1
 tanc  tan  tan0  0
–1 i 1

 tan–1(tan3)  tan–1(tan 4)
 sin–1  sinb  cot–1 cosa  tan–1  tanc   2 = 10 – 3
49. Answer (D) 52. Answer (A)
Clearly,  = 4
The bounded area is as shown in graph
–1

–1 3 x  x
3
1
and 3 tan x    tan   for x 
 1– 3 x 2  3
 
 52 
Hence 3 tan–1 4    tan –1  
 47 
Answer for Qs. 53 to 55

2 1 For R1 to be real – 1  f1  x , y   1
2
Required area = 4. –  4  – 12 
4 2 2 2
x2 y 2
i.e, –1  x  y  1   –1 0
16 9 16 9
= –7  2  48  – 72

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Test-2_Paper-1_(Code-A) JEE (Advanced) CoE (XII)-2021-22

Here R1 represents the region inside the ellipse

2 2
For sin
–1
f1  x, y   to be defined
x y
  1 , for R2 to be real – 1  f 2  x   1
16 9 x2 y 2
–1   1 …. (ii)
16 9
x y 3
 –1   1
8 6 Regions represented by (i) and (ii) are shown
below.
For R3 to be real – 1  f3  x , y   1

x y
i.e, –1   1
4 3
The region R1, R2 and R3 are as shown

There is only one point for which expression is

53. Answer (C) defined.

x y 3 x2 y2
As  1 are tangent to ellipse i.e, point of tangency of   1 and
8 6 16 9

x2 y2 x y 3
  1 region common to R1 and R2 in the  1
16 9 8 6
complete ellipse, required area = .4.3  3 3
The point is  2, 
= 12 sq. units  2 

54. Answer (B) Given expression

Region common to R1 and R3 in as shown below  3
= sin 1  cos  –1 
–1 –1

2 2
56. Answer (A  P,S, B  P,S,T, C  Q,R, D 
P,S,T)

(A) Clearly x – x 4 + x 7 – x 9 –1 < 0 x  R 

Hence sgn(x – x4 + x7 – x9 – 1) = –1 x  R 
(B) Given f ( x )  xf (– x )  x  1 eq… (i)

x  –x
f ( x ) – xf ( x )  1 – x eq… (ii)
1 From (i) and (ii)
Required area = (Area of ellipse)
2
 f(x) . (1 + x2) = 1 + x2
+ 2 Area of OAB
f(x) = 1
1 1
= .12  2.  4  3 (C) f ( x )  x  1  x  2  x  3  x  4
2 2
for x  [3, 4]
= 6+ 12 sq. units.
55. Answer (C) f(x) = (x – 1)+ (x – 2)+ (x – 3) – x + 4
= 2x – 2
For cos
–1
 f2  x, y  – 2 to be defined range of f(x) for x  [3, 4] is [4, 6]
x y 3
–1   –21 …..(i) (D) f ( x )  tan5   x 2  2 x  3 
8 6  

Clearly f(x) = 0, x  R

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JEE (Advanced) CoE (XII)-2021-22 UT-2A_Paper-1 (Code-A)

57. Answer (A  R,S,T, B  Q,R,S,T, C  Q,R,S,T Obviously the number of solution in [–2n to
D  Q,S)
2n] can be any odd number.
(A) For f(x) to be defined.
58. Answer (03)
2 3
 x –1 x
4x  8 3 – 72 – 4 2 0 a = 20 – 6, b = 10 – 30, c = sin–1sin(4 – 10) =
10 – 3
 2 2 x  2 2 x – 2 – 72 – 2 2 x  3  0
hence a + b + c = 
2x  1 1
2  1  4  8   72  
sin1  sin x   x    x   ,  

 
2 
 22 x  26 So largest integer x = 3
 x3 59. Answer (09)
(B) f(x) = 0 and g(x) = 3 is the only possibility. 1 0 0  3 2   3 2   1 0 0  9 
Hence (1 – f(x))3 + (g(x) – 3)3 = 1 =9
100
 xf ( x ) –1 60. Answer (00)
(C) Given sum: 0 xf(x) = –1
 

xf ( x ) – 1 sin sin 1   x    x  if  x     1,1 i.e x  [–1,2]
hence f(1) = –1 and 1 – f(1) = 2
co s  1 co s x  x if x  0,  
(D) Consider the graph of y  sin x and y  x  x
Given equation  [x] + x = 1 for x  [0,2)
This equation has no solution

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