The document contains a sample exam for chemistry students with 10 multiple choice questions covering various topics in instrumental analysis. The questions test understanding of fundamental principles of different spectroscopic techniques including UV-Vis spectroscopy, infrared spectroscopy, NMR spectroscopy and mass spectrometry. They also cover applications of techniques like flame photometry.
The document contains a sample exam for chemistry students with 10 multiple choice questions covering various topics in instrumental analysis. The questions test understanding of fundamental principles of different spectroscopic techniques including UV-Vis spectroscopy, infrared spectroscopy, NMR spectroscopy and mass spectrometry. They also cover applications of techniques like flame photometry.
The document contains a sample exam for chemistry students with 10 multiple choice questions covering various topics in instrumental analysis. The questions test understanding of fundamental principles of different spectroscopic techniques including UV-Vis spectroscopy, infrared spectroscopy, NMR spectroscopy and mass spectrometry. They also cover applications of techniques like flame photometry.
The document contains a sample exam for chemistry students with 10 multiple choice questions covering various topics in instrumental analysis. The questions test understanding of fundamental principles of different spectroscopic techniques including UV-Vis spectroscopy, infrared spectroscopy, NMR spectroscopy and mass spectrometry. They also cover applications of techniques like flame photometry.
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BAHIR DAR UNIVERSITY
COLLEGE OF SCIENCES CHEMISTRY DPARTMENT Instrumental Analysis II Exit EXAMINATION Model Questions for BSc CHEMISTRY STUDENTS, 2016 e.c. I. CHOOSE THE BEST ANSWER FOR THE FOLLOWING QUESTION FROM THEIR GIVEN CHOICES 1. What is the basic principle of spectroscopic analytical methods to get measurable property A. Electric conductivity nature analytical sample. B. Interaction of analytical sample with electromagnetic radiation. C. Rotation of plane polarized light upon passing through optical active sample. D. Solute – solvent interaction or polarity of analytical sample, E. All of the above are correct.
2. A solution of a 5.0 x 10-4 M analyte is placed in a sample cell with a path length of 1.00 cm and measured at a wavelength of 490 nm gives absorbance of 0.338, what would be the concentration of unknown similar solution with absorbance of 0.500 measured in the same sample cell and wavelength of 490 nm is 676 L/mol.cm?
A. 2.5 x 10-4 M B. 7.4 x 10-4 M C. 5.0 x 10-4 M D. 9.8 x 105 M E. None
3. W/ro Alemitu went to buy Areki (Katikala) in local market, but the day was fasting day. So that she can’t taste the Areki to know the quality of it. Thus she pours the Areki in colorless bottle and notices the color of the Areki is very slightly brown, so she smells it and knows that the color is coming due to burning of carbon (smoke). Eventually, Alemitu realized that the quality of areki is poor. These show the qualitative traditional application of spectroscopy. Which of the following is true based on the working principle of spectrometer?
A. The eye lenses act as the wavelength selector.
B. The sample is Areki (Katikala). C. The sample container is colorless bottle. D. The retina (part of image formation) and brain act as detector and readout device, resp. E. All of the above are true.
4. Which of the following absorption spectroscopy technique works best for trace metal analysis in a given sample?
A. Infrared spectroscopy B. Ultraviolet spectroscopy C. Mass spectroscopy
D. Nuclear magnetic resonance spectroscopy E. Microwave spectroscopy
5. Which sentence is false about UV spectroscopy?
A. Benzene is not used as solvent. B. Low temperature gives better result in UV SPECTROSCOPY. C. Chloroform is used as solvent in UV. D. UV ray wavelength is 200- 400 nm. E. All of the above are false.
6. Which of the following factor(s) does not influence measurement of absorption of radiant energy in spectroscopic techniques?
A. Solvent effects B. Effect of temperature C. Inorganic ions
D. Absorbing groups (Chromophores) E. None of the above
7. Which movement is best required for the IR spectroscopy?
A. Dipole movement B. Spin movement C. Round movement D. Polarizability E. All of the above
8. Flame photometer is best for the analysis of ….
A. Potassium B. Hydrogen C. Zinc D. Chromium E. Barium
9. Which of the following is the basis of separation of ions take place in mass spectrometer?
A. Mass B. Charge to Mass ratio C. Molecular weight
D. Mass to charge ratio E. Charge
10. How many 1H-NMR and 13C-NMR signals are there in NMR spectrum of the compound shown below (1,3-Dibromobenzene), respectively?
A. Four 1H-NMR and three 13C-NMR B. Four 1H-NMR and four 13C-NMR C. Three 1H-NMR and four 13C-NMR D. Three 1H-NMR and three 13C-NMR E. Unknown signals
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