KUAZER BULGE ABS a ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD Pe ML ae OR DEC 07. 2022 SIC No '8620220729-1 Payment T/T IN ADVANCE Inv. No. 0003663 Due Date: DEC 31, 2022 Shipping from NINGBOPORT.CHINA — PerS.S__to SURABAYA, INDONESIA For account and risk of CV. CIPTA SARANA SUKSES JL. IKAN DORANG NO. 1 KEL. PERAK BARAT, KEC. KREMBANGAN SURABAYA NPWP: 42.590.692.2-605.000 Marks and Nos. Description Amount 14 MT SODIUM CYANIDE 98% MIN 50 KG IRON DRUM WITH INNER LAYER G.W. 15,400 KGS: | Naw. 14,000 Kes 280 DRUMS: 2 MT POTASSIUM CYANIDE 99% MIN 50 KG IRON DRUM WITH INNER LAYER GW. 2,200 KGS N.W. 2,000 KGS TOTAL G.W. 17,600 KGS wm TOTAL N.W. 16,000 KGS He te THT CAL 47 0556-5055676 / 5055675 cS UNIT PRICE: RMB 16,000 PER MT CFR SURABAYA, TOTAL AMOUNT CHINA ORIGIN PAYMENT: T/T IN ADVANCE http://www.sgchem.com RMB 256,000.00 47 JINGBEI ROAD, ANQING ANHUI, CHINA ft: 0556-5375706 5372933 fbi: 246005 E-mail: sale@sgchem.comKRRAZER BLU BRSE FBS 8 ANHUI ANQING SHUGUANG CHEMICAL CO., LTD 2s FA AA PACKING LIST DATE: DEC. 07, 2022 INV NO: 0003663 TO: CV. CIPTA SARANA SUKSES JL. IKAN DORANG NO. 1 KEL. PERAK BARAT KEC. KREMBANG SURABAYA NPWP: 42.590.692.2-605.000 COMMODITY : SODIUM CYANIDE 98% MIN QUANTITY 280 DRUMS PACKING 50 KG IRON DRUMS WITH INNER LAYER COMMODITY POTASSIUM CYANIDE 99% MIN QUANTITY : 40 DRUMS PACKING : 50 KG IRON DRUMS WITH INNER LAYER TOTAL QUANTITY : 320 DRUMS TOTAL GROSS WEGHT _ : 17,600 KGS TOTAL NETT WEIGHT : 16,000 KGS SHIPPING MARKS. N/M RAE RULED AROS | ANHUL ANQING CHEMICAL CO.,LTD He 2a TIT IL 47 47 JINGBEI ROAD, ANQING ANHUI, CHINA. FBifi: 0556-5055676 / 5055675 {@3£: 0556-5375706 5372933 Hil sj: 246005 http://www.sgchem.com E-mail: sale@sgchem.comSRARZER BAU RG ABE 8 ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD ATER CERTIFICATE OF ANALYSIS COMMODITY SODIUM CYANIDE 98% MIN (#1(t 44) QUANTITY : 280 DRUMS GROSS WEIGHT : 15,400 KGS NET WEIGHT 114,000 KGS DATE: Dec 20, 2022 WITH THE REFERENCE CHINESE NATIONAL STANDARDS, WE INSPECTED ‘THE GOODS AND THE RESULT OF COMPARISON AND ANALYSIS |S AS BELOW: ITEM SODIUM CYANIDE (NaCN) SODIUM HYDROXIDE (NaOH) SODIUM CARBONATE (Na2CO3) H20 INSOLUBLE RESIDUE FRI Se Be De TTA 47 Hi: 0556-5055676 / 5055675 http://www.sgchem.com SPECIFICATION 98 % MIN 0.20 % MAX 0.10 % MAX 0.10 % MAX 0.1% MAX RESULTS 98.37 % 0.12% 0.08 % 0.08 % NONE, 47 JINGBEI ROAD, ANQING ANHUI, CHINA {£1: 0556-5375706 5372933 iii: 246005 E-mail: sale@sgchem.comREAR RRA UL RGA BRL G] ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD ay PTUEB CERTIFICATE OF ANALYSIS DATE: Dec 20, 2022 COMMODITY : POTASSIUM CYANIDE 99% MIN (#444) QUANTITY 40 DRUMS: GROSS WEIGHT 2,000 KGS NET WEIGHT : 2,200 KGS WITH THE REFERENCE CHINESE NATIONAL STANDARDS, WE INSPECTED THE GOODS AND THE RESULT OF COMPARISON AND ANALYSIS IS AS BELOW: ITEM SPECIFICATION RESULTS POTASSIUM CYANIDE (KCN) 98% MIN 99.00% POTASSIUM HYDROXIDE (KOH) 0.5% MAX 0.30% POTASSIUM CARBONATE (KCO3) 0.5% MAX 0.40% MOISTURE 0.4% MAX 0.30% WATER INSOLUBLE 0.1% MAX 0.05% FRY Be i PP de TAT a ALP 47 1S 47 JINGBEI ROAD, ANQING ANHUI, CHINA, Hil: 0556-5055676 / 5055675 f€9%: 0556-5375706 5372933 lil: 246005 http://www.sgchem.com E-mail: sale@sgchem.comMaterial Safety Data Sheet - Potassium Cyanide REVISION 01 DATED 31 JAN 2022 REALL AA ANHUI ANQING SHUGUANG CHEMICAL CO., LTD POTASSIUM CYANIDE 1. Product Identification and Company ‘Synonyms: Potassium Cyanide, soli; hydrocyanic acid, potassium salt CAS No. 151-508 Molecular Weight: 65.12 Chemical Formula: KCN Manufacturer: Anhui Anging Shuguang Chemical Co,, Lid Address 447 Jingbei Road, Anging Anhui China 246005 Tel/Fax: +86 556 5375706 / 5372933 2. Composition/Information on Ingredients Ingredient CAS No. Percent Hazardous Potassium Cyanide 151-50-8 99-100% Yes 3. Hazards Identification Emergency Overview POISON! DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CONTACT WITH ACIDS LIBERATES POISONOUS GAS. CAUSES BURNS TO SKIN, EYES, AND RESPIRATORY TRACT. AFFECTS BLOOD, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM AND THYROID. SAFETY DATA ™ Ratings (Provided here for your convenience! RRERR ANHULANOING Health Rating :4—Extreme (Poison) Flammability Rating :0-None Reactivity Rating ~Moderate Contact Rating :3~Severe (Life) Lab. Protective Equipment —_: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES. ‘Storage Color Code : Blue (Health) Potential Health Effects In most cases, cyanide poisoning causes a deceptively healthy pink to red skin color. However, if 2 physical injury or lack of oxygen is involved, the skin color may be bluish. Reddening of the eyes and pupil dilation are symptoms of cyanide poisoning. Cyanosis (blue discoloration of the skin) tends to be associated with severe cyanide poisonings. Inhatatio Corrosive to the respiratory tract. The substance inhibits cellular respiration and may cause blood, central nervous systems, and thyroid changes. May cause headache, weakness, iness, labored breathing nausea ‘and vomiting, which can be followed by weak and irregular heart beat, unconsciousness, convulsions, coma 1/6Material Safety Data Sheet ~ Potassium Cyanide REVISION 01 DATED 31 JAN 2022 LAGRANGE A ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD ‘and death. Ingestion: Highly Toxic! Corrosive to the gastro-i pain. Larger doses may produce sudden loss of consciousness and prompt death from respiratory arrest. Smaller but still lethal doses may prolong the illness for one or more hours. Bitter almonds odor may be noted on the breath or vomitus. Other symptoms may be similar to those noted for inhalation exposure. Skin Contact: Corrosive, May cause severe pain and skin burns. Solutions are corrosive to the skin and eyes, and may cause deep ulcers which heal slowly. May be absorbed through the skin, with symptoms similar to those noted for inahalation. Eye Contact: Corrosive. Symptoms may include redness, pain, blurred vision, and eye damage. Chronic Exposure: Prolonged or repeated skin exposure may cause a “cyanide” rash and nasal sores. Aggravation of Pre-existing Conditions: ‘Workers using cyanides should have a preplacement and periodic medical exam. Those with history of central nervous system, thyroid, skin, heart or lung diseases may be more susceptible to theleffects of this substance, estinal tract with burning in the mouth and esophagus, and abdominal 4. First Aid Measures IN CASE OF CYANIDE POISONING, start first aid treatment immediately, then get medical attention. A cyanide antidote kit (amyl nitrite, sodium nitrite and sodium thiosulfate) should be available in any cyanide work area. Actions to be taken in case of cyanide poisoning should be planned and practiced before beginning work with cyanides. Oxygen and amyl nitrite can be given by a first responder before medical help arrives. Allow victim to inhale amyl nitrite for 15-30 seconds per minute until sodium nitrite and sodium thiosulfate can be administered intravenously (see note to phycisian). A new amyl nitrite ampule should be used every 3 minutes. If conscious but symtoms (nausea, difficult breathing, dizziness, etc) are evident, give oxygen. If consciousness is impaired (non-responsiveness, slurred speech, confusion, drowsiness) or the patient is unconscious but breathing, give oxygen and amyl nitrite by means of a respirator. If not breathing, give oxygen and amyl nitrite immediately by means of a positive pressure respirator (artificial respiration). Inhalation: If inhaled, remove to fresh air. Administer antidote kit and oxygen per pre-planned instructions if sysmptoms occur. Keep patient warm and at rest. Do not give mouth to mouth resuscitation. Ingestion: If ingested, antidote kit and oxygen should be administered per above. Ifthe patient is conscious, immediately give the patient activated charcoal slurry, Never give anything by mouth to an unconscious person. Do not induce vomiting as it could interfere with resuscitator use. Skin Contact: immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Administer antidote kit and oxygen per preplanned instructions if symptoms occur. 2/6‘Material Safety Data Sheet ~ Potassium Cyanide [REVISION 01 DATED 31 JAN 2022 REBROAAKIROARAA ANH! ANQING SHUGUANG CHEMICAL CO.,LTD Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lower and upper eyelids ‘occasionally. Get medical attention immediately. Note to Physician: If patient does not respond to amyl nitrite, inject intravenously with 10 ml of a 3% solution of sodium nitrite at a rate of not more than 2.5 to 5 ml per minute. Once nitrite administration is complete, follow directly with 50 mL of a 25% solution of sodium thiosulfate at the same rate by the same route. Give victim oxygen and keep under observation. If exposure was severe, watch victim for 24-48 hours. if signs of cyanide poisoning persist or reappear, repeat nitrite and thiosulfate injections 1 hour later in 1/2 the original doses Cyanocabalamin (B12), 1 mg intramuscularly, may speed recovery. Moderate cyanide exposures need to treated only by supportive measures such as bed rest and oxygen. Fire Fighting Measures Fir Not combustible, but upon decomposition or contact with acids, this material releases highly flammable and toxic hydrogen cyanide gas. Explosion: Not considered an explosion hazard, but upon heating with chlorates or nitrites to 450° C (842° F) may cause an explosion. Violent explosion occurs if melted with nitrite salt. Sealed containers may rupture when heated. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Do not use carbon dioxide. Carbon dioxide can react with this material in the presence of moisture to produce hydrogen cyanide. Water spray may be used to keep fire exposed containers cool. Reacts slowly with water to foam hydrogen cyanide. Special Information: In event of fire, wear full protective clothing and NIOSH approved self contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Accidental Release Measures Spill: Ventilate area of leak or spill. Allow only qualified personnel to handle spill. Clean up personnel require protective clothing and respiratory protection from vapors. Collect material and place in a closed container for recovery or disposal. Do not flush to sewer! Decontaminate liquid or solid residues in spill area with sodium or calcium hypochlorite solution. 7. Handling and Storage Keep in a tightly closed container, stored in a cold, dry ventilated area. Protect against physical damage. Separate from incompatibles, Workers must carefully follow good hygienic practices, including no eating, drinking, or smoking in workplace. Proper use and maintenance of protective equipment is essential. Workers using cyanide need preplacement and annual medical exams. Special training should be given to works using, cyanide, Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Do not store near combustibles or 3/6[ss] Material Safety Data Sheet ~ Potassium Cyanide REVISION 01 DATED 33 JAN 2022 ZARA ANHUI ANQING SHUGUANG CHEMICAL CO, 1D flammables because subsequent fire fighting with water could lead to eyanide solution runafl. Do not stroe under sprinkler systems. All persons with the potential for cyanide polsoning should be trained to provide immediate fist aid using oxygen and amyl nitrite. A cyanide antidote kit (am nitrite, sodium nitrite and sodium thiosulfate) should be readily available in cyanide workplaces. The antidotes should be checked annually to ensure they are still within their shelf lives. Identification of community hospital resources end ‘emergency medical squads in order to equip and train them on handling cyanide emergencies is essential 8. Exposure Controls/Personal Protection Airborne Exposure Limits: + ACGIH Threshold Limit Value (Tuy): 5 mg/m? (STEL) ceiling, skin as CN = _ OSHA Permissible Exposure Limit (PEL): 5 mg/m? (TWA) as CN Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full face piece respirator with dust/mist filter may be worn up to SO times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dustin Maintain eye wash fountain and quick drench facilities in work area, 9. Physical and Chemical Properties ‘Appearance: white deliquescent granular solid. (Odor: bitter almonds. Solubility: very soluble in water Specific Gravity: 1.55 @ 20° C/4” C pH: 11 (0.1 N aqueous solution) % Volatiles by volume @ 21° €(70" F):0 Boiling Point: 1625° C(2957° F) ‘Melting Point: 634° (173° F) Vapor Density (Air=1): No information found Vapor Pressure (mm Hg): 1@ 87° C(1503° F) Evaporation Rate (BuAc=1): not information found. 4/6Material Safety Data Sheet ~ Potassium Cyanide REVISION 01 DATED 31 JAN 2022 REGRET DL RARER ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD 10.Stability and Reactivity Stability: very stable when dry, Moisture will cause slow decomposition, releasing poisonous hydrogen gas. Hazardous Decomposition Products: emits toxic fumes of cyanide and oxides of nitrogen when heated to decomposition. Hazardous Polymerization: will not occur. Incompatibilities: strong acids and strong oxidizers, Reacts with acids to liberate toxic and flammable hydrogen cyanide gas. Water or weak alkaline solutions can produce dangerous amounts of hydrogen cyanide in confined areas. Can react with carbon dioxide in ordinary air to form hydrogen cyanide gas. Conditions to avoid: heat, moisture, incompatibles 11. Toxicological Information Oral rat LDSO: 6 mg/kg. Investigated as a mutagen, reproductive effector. 12.Ecological Information Environmental Fate: this material has an estimated bioconcentration factor (BCF) of less than 100. This materials no expected to significantly bioaccumulate. Environmental Toxicity: this material is expected to be very toxic to aquatic life. This mater very toxic to terrestrial is expected to be 13. Cyanides must be oxidized to harmless waste before disposal. An alkaline solutions (pH about 10) is treated with chlorine or commercial bleach in excess to decompose cyanide. When cyanide free, it can be neutralized. Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and logalrequiements. posal Considerations 14. Transport Information Domestic (Land, 0.0.1) Proper Shipping Name: POTASSIUM CYANIDE SOLID Hazard Class: 6.1 UN/NA: UNI680 Packing Group: | International (Water, .M.O.) Proper Shipping Name: POTASSIUM CYANIDE SOLD Hazard Class: 6.1 UN/NA: UN1680 Packing Group: | 5/6Material Safety Dat Sheet Potassium Cyanide REVISION 02 DATED 31 1AN 2022, ROSE TAALLRHARA A ANHUI ANQING SHUGUANG CHEMICAL CO., LTD 15.Other Information NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 1 Label Hazard Warning: DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CONTACT WITH ACIDS LIBERATES POISONOUS GAS. CAUSES BURNS TO SKIN, EYES, AND RESPIRATORY TRACT. AFFECTS BLOOD, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM AND THYROID. Label Precautions: Do not breathe dust Do not get in eyes, on skin, or on clothing. Keep container closed. Use only with adequate ventilation. ‘Wash thoroughly after handling. Label First Aid: IN ALL CASES, GET MEDICAL ATTENTION IMMEDIATELY. KEEP A CYANIDE ANTIDOTE KIT (amyl nitrite, sodium nitrite and sodium thiosulfate) in area of product use or storage. First aiders must take precautions to avoid contact with cyanide substance. if ingested, administer antidote kit and oxygen per pre-planned instructions. If the patient is conscious, immediately give the patient activated charcoal slurry. Never give anything by mouth to an unconscious person. Do not induce voriting as it could interfere with resuscitator use. If inhaled, remove to fresh air. Administer antidote kit and oxygen per pre-planned instructions if symptoms occur. Keep patient warm and at rest. Do not give mouth to mouth resuscitation. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Administer antidote kit and oxygen per preplanned instructions if symptoms occur. Product Use: Laboratory Reagent. Revision Information: No Changes. 16, Additional Information MSDS Creation Date: 31 Dec 1995 Revision # 13 Date: 31 Jan 2022Matera Safety Data sheet ~Sodium Cyanide REVISION DATED 33 1AN 2022 RI RTA T RABAT [ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD SODIUM CYANIDE 1. Product Identification and Company ‘Synonyms: Sodium Cyanide; Hydrocyanic acid, sodium salt; cyanogran CAS No.: 143-33-9 Molecular Weight: 49.01 ‘Chemical Formula: NaCN Manufacturer = Anhui Anqing Shuguang Chemical Co.,Ltd Address +47 Jingbet Road, Anging Anhui China 246005 Tel/Fax: +86 556 5375706 / 5372933 2. Composition/Information on Ingredients Ingredient CAS No. Percent Hazardous Sodium Cyanide 143-33-9 98 - 100% Yes Gand? 3. Hazards Identification & Emergency Overview DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CONTACT WITH ACIDS LIBERATES POISONOUS GAS. CAUSES BURNS TO SKIN, EYES, AND RESPIRATORY TRACT. AFFECTS BLOOD, ‘CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM AND THYROID. SAFETY DATA ™ Ratings (Provided here for your convenience) Health Rating 3~Severe (Poison) Flammability Rating 0-None Reactivity Rating 2-Moderate Contact Rating 3 ~Severe (Life) Lab. Protective Equipment: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code : Blue (Heath) Potential Health Effects In most cases, cyanide poisoning causes a deceptively healthy pink to red skin color. However, if ‘a physical injury or lack of oxygen is involved, the skin color may be bluish. Reddening of the ‘eyes and pupil dilation are symptoms of cyanide poisoning. Cyanosis (blue discoloration of the skin) tends to be associated with severe cyanide poisonings. Inhalation: Corrosive to the respiratory tract. The substance inhibits cellular respiration and may cause blood, central nervous systems, and thyroid changes. May cause headache, weakness, dizziness, labored breathing nausea and vomiting, which can be followed by weak and irregular heart beat, unconsciousness, convulsions, coma and death. 1/6Materia Safety Data Sheet ~ Sodium Cyanide [REVISION DATED 31 JAN 2022 Se INR RAAT ANHUL ANQING SHUGUANG CHEMICAL CO, LTD. Ingestion: ly Toxic! Corrosive to the gastro-intestinal tract with burning in the mouth and esophagus, and abdominal Larger doses may produce sudden loss of consciousness and prompt death from respiratory arrest. ‘Smaller but still lethal doses may prolong the illness for one or more hours. Bitter almonds odor may be noted con the breath or vomitus. Other symptoms may be similar to those noted for inhalation exposure. Skin Contact: Corrosive. May cause severe pain and skin burns. Solutions are corrosive to the skin and eyes, and may cause deep ulcers which heal slowly. May be absorbed through the skin, with symptoms similar to those noted for inahalation, Eye Contact: Corrosive. Symptoms may include redness, pain, blurred vision, and eye damage. Chronic Exposure: Prolonged or repeated skin exposure may cause a “cyanide” rash and nasal sores. Aggravation of Pre-existing Condi ‘Workers using cyanides should have a preplacement and periodic medical exam. Those ot pntral First Aid Measures IN CASE OF CYANIDE POISONING, start first aid treat immediately, then get medical attention. A cyanide antidote kit (amyl nitrite, sodium nitrite and sodium thiosulfate) should be available in any cyanide work area. Actions to be taken in case of cyanide poisoning should be planned and practiced before beginning work with cyanides. Oxygen and amyl nitrite can be given by a first responder before medical help arrives. Allow victim to inhale amyl nitrite for 15-30 seconds per minute until sodium nitrite and sodium thiosulfate can be administered intravenously (see note to phycisian). A new amyl nitrite ampule should be used every 3 minutes. If conscious but symtoms (nausea, difficult breathing, dizziness, etc) are evident, give oxygen. If consciousness is impaired (non-responsiveness, slurred speech, confusion, drowsiness) or the patient is unconscious but breathing, give oxygen and amyl nitrite by means of a respirator. If not breathing, give oxygen and amyl nitrite immediately by means of a positive pressure respirator (artifical respiration). Inhalation: If inhaled, remove to fresh air. Administer antidote kit and oxygen per pre-planned instructions ‘occur. Keep patient warm and at rest, Do not give mouth to mouth resuscitation, Ingestion: If ingested, antidote kit and oxygen should be adi is, immediately give the patient activated charcoal slurry. Never give anything by mouth to an unconscious person. Do not induce vomiting as it could interfere with resuscitator use. ‘Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Administer antidote kit and oxygen per preplanned instructions if symptoms occur. 2/6Matra Safety Data sheet ~Sodlam Cyanide REVISION DATED 31 JAN 2022 Sell RBH ATLA RAL [ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids ‘occasionally. Get medical attention immediately. Note to Physician: If patient does not respond to amyl nitrite, inject intravenously with 10 ml of a 3% solution of sodium nitrite at a rate of not more than 2.5 to 5 mL per minute. Once nitrite administration is complete, follow directly with '50 mL of a 25% solution of sodium thiosulfate at the same rate by the same route. Give victim oxygen and keep under observation. If exposure was severe, watch victim for 24-48 hours. If signs of cyanide poisoning persist or reappear, repeat nitrite and thiosulfate injections 1 hour later in 1/2 the original doses. Cyanocabalamin (B12), 1 mg intramuscularly, may speed recovery. Moderate cyanide exposures need to treated only by supportive measures such as bed rest and oxygen. 5. Fire Fighting Measures Fire: Not combustible, but upon decomposition or contact with acids, this material releases high! le and ‘toxic hydrogen cyanide gas. Explosion: Not considered an explosion hazard, but upon heating with chlorates,o¢ c (842° F) may cause an explosion. Violent explosion occurs if melted with nee Mginers may rupture when heated. Fire Extinguishing Medi: Use any means suitable for extinguishing surrounding fire. Do not use carbon dioxide. Carbon dioxide can react with this material in the presence of moisture to produce hydrogen cyanide. Water spray may be used to keep fire exposed containers cool. Reacts slowly with water to foam hydrogen cyanide. Special Information: In event of fire, wear full protective clothing and NIOSH approved self contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Spill: Ventilate area of leak or spill. Allow only qualified personnel to handle spill. Clean up personnel require protective clothing and respiratory protection from vapors. Collect material and place in a closed container for recovery or disposal. Do not flush to sewer! Decontaminate liquid or solid residues in spill area with sodium or calcium hypochlorite solution. 7. Handling and Storage Keep in a tightiy closed container, stored in a cold, dry ventilated area. Protect against physical damage Separate from incompatibles. Workers must carefully follow good hygienic practices, including no eating, drinking, or smoking in workplace. Proper use and maintenance of protective equipment is essential. Workers using cyanide need preplacement and annual medical exams. Special training should be given to works using cyanide. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Do not store near combustibles or 3/6[Letsps ] mse sstey ont sheot—soaum cane REVISION DATED 33 JAN 2022 RB RANA RL ANHUI ANQING SHUGUANG CHEMICAL CO., LTD flammables because subsequent fire fighting with water could lead to cyanide solution runoff. Do not stroe Under sprinkler systems. All persons with the potential for cyanide poisoning should be trained to provide immediate first aid using oxygen and amyl nitrite. A cyanide antidote kit (amyl nitrite, sodium nitrite and sodium thiosulfate) should be readily available in cyanide workplaces. The antidotes should be checked annually to ensure they are still within their shelf lives. Identification of community hospital resources and emergency medical squads in order to equip and train them on handling cyanide emergencies is essential. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: = ACGIH Threshold Limit Value (TLV): 5 mg/m? (STEL) ceiling, skin as CN = _ OSHA Permissible Exposure Limit (PEL): 5 mg/m? (TWA) as CN Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full face piece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact, Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solution Is possible. Maintain eye wash fountain and quick drench facilities in work area. 9. Physical and Chemical Propet ‘Appearance: white deliquescent granular soi ‘Odor: almond odor, bitter almonds. Solubility: 48 ¢/100 cc @ 10° C(50° F) Specific Gravity: 1.6 @ 25° c/a? C pH: aqueous solutions are strongly alkaline. % Volatiles by volume @ 21° ¢ (70° F):0 Boiling Point: 1496" C(2725* F) Melting Point: 564° C(1047° F) Vapor Density (Air=1): No information found @ 87° c(1503° F) 1ot information found. ‘Vapor Pressure (mm H Evaporation Rate (BuAe 10.Stability and Reactivity 4/6‘Material Safety Data Sheet ~ Sodium Cyanide REVISION DATED 31 JAN 2022 RUARRAALIRAARAR [ANHUI ANQING SHUGUANG CHEMICAL CO.,LTD. ‘Stability: very stable when dry. Moisture will cause slow decomposition, releasing poisonous hydrogen gas. Hazardous Decomposition Products: emits toxic fumes of cyanide and oxides of nitrogen when heated to decomposition. Hazardous Polymerization: will not occur. Incompatibilities: acid, nitrates, nitrites, chlorates, fluorine, magnesium and strong oxidizers. Reacts with acids to liberate toxic and flammable hydrogen cyanide gas. Water or weak alkaline solutions can produce dangerous amounts of hydrogen cyanide in confined area. Reacts with carbon dioxide in air to foam hydrogen cyanide gas. Conditions to avoid: heat, moisture, inompatibles. 11. Toxicological Information Oral rat LDSO: 6440 ug/kg. Investigated as a tumorigen, mutagen, reproductive effector, 12.Ecological Information Environmental Fate: No information found. Environmental Toxicity: this material is expected to be very toxic to aquatic life. This material is expected to be very toxic to terrestrial 13.Disposal Considerations Cyanides must be oxidized to harmless waste before disposal. An alkaline solutions (pH about 10) is treated with chlorine or commercial bleach in excess to decompose cyanide. When cyanide free, It can be neutralized. Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. ae 14.Transport Information : ane ens Domestic (Land, D.0:T) ah Proper Shipping Name: SODIUM CYANIDE SOLID Hazard Class: 6.1 UN/NA: UN1689 Packing Group: I Marine pollutant: P Proper Shipping Name: SODIUM CYANIDE SOLID Hazard Class: 6.1 UN/NA: UN1689 Packing Group: 5/6Materia safety Data est ~Soium Cyanide REVISION DATED 31 JAN 2022 RA RK TATE AA ANHUI ANQING SHUGUANG CHEMICAL Co., LTD 15.Other Informat NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 1 Label Hazard Warning: DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CONTACT WITH ACIDS LIBERATES POISONOUS GAS. CAUSES BURNS TO SKIN, EYES, AND RESPIRATORY TRACT. AFFECTS BLOOD, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM AND THYROID. Label Precautions: Do not breathe dust Do not get in eyes, on skin, or on clothing Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: IN ALL CASES, GET MEDICAL ATTENTION IMMEDIATELY. KEEP A CYANIDE ANTIDOTE KIT (amyl nitrite, sodium nitrite and sodium thiosulfate) in area of product use or storage. First aiders must take precautions to avoid contact with cyanide substance. If ingested, administer antidote kit and oxygen per pre-planned instructions. If the patient is conscious, immediately give the patient activated charcoal slurry. Never give anything by mouth to an unconscious person. Do not induce vomiting as it could interfere with resuscltator use. If inhaled, remove to fresh ait, Administer antidote kit and oxygen per pre-planned instructions if symptoms occur. Keep patient warm and at rest. Do not give mouth to mouth resuscitation. Incase of contact, Immediately flush coors eyes or skin with plenty of water for at least 15 minutes while removing contar Wash clothing before reuse, Administer antidote kit and oxygen per preplanned occur. 7 Product Use: Laboratory Reagent. see Revision Information: No Changes. 16.Other Reference The reference are provided as followings: CICAD lucuiD