: 17. 18. 19. 20. a. Toth Assertion and (a aC aoe ne correct tg If both Assertion and Oc Weasonls aes the of the Assertion. Reason are correct ey 5) If Assertion is true, but Reason is fag 'd Reason are f, assertion : The spectrum of White | known as continuous spectrum” 4) If both Assertion an, ight is Reason Itis continuous because olet meng into blue, blue into green and << on. 7 Assertion : K and Rb are used in ae Photoet effect. lectric Reason : K and Rb ha; (hv,) or less thresho| loosely bonded electr, id frequ fons. - Assertion ; Cathod magnetic field. 0529 A (n?/Z), whe: atomic number. Assertion : ry than X-rays, Subsidiary quantum Reason : Value of nis lower than |, where n is Principal quantum numbers Assertion ; half-fited and fully-filled are more stable. €ason This is due to unsymmetrical Nn of electrons. distibutio Same subshell orbitals which are ‘Medalist SET/NET-JREGATE, DRDO,TIFR qualified —> and orbital represent of finding the ability electr nee » & x S = = = = = - REC ROCF e RCE" ROC Reason : Angular borane OF an claret e 2 given stationary state : is expressed as mor ~ y * where n= 1,2 3, . z 3 31. Assertion : In absorption spectrum n> 4 2g While in emission Spectrum, n > n, 2 Reason : Energy is absorbed in absorption y Spectrum, that is, electron Moves from lower F tohigher orbit ang energy i8 emitted (release u Mm emission sg, Pectrum, because. electron from higher to lower orbit Assertion : Be* ion is which forms similar s 32. hydrogen like Pectrum. Reason : Be* ion has one electron = RCC Page ssAssertion : Only principat Tere enenSng, Afferent from that bags 36, Assertion : Wave number for transition in Assertion: Al d-orbitals have two peg hydrogen atom may given as except d, +d sis spherically symmetiaL Assertion : The 19th 37, Assertion : For a given principal number, s,p, di... subshells, all have di energies ‘Reason : Mutual repulsion exists among the = electrons in a multielectron atoms, wo xl Medal SHUNETJRECATE: ROO aSpin quantum number of an mines the orientation of the spin jeter tron to the chosen axis, ferron relative ee’ Cu hh statement I and IL are correct: 1) Bol posh statement {and I are incorrect ey 3 sta incorrect. 1p satement IL is correct but statement 1 is incorrect tement I is correct but statement II is satement 1: Chemical properties of atoms are sinolled by the number of protons,whichare Setermined by the number of electrons in the valance shell iatement II : The number of proton is equal to the number of electron in an electrically neutral atom. 1) Both statement I and II are correct. 2) Both statement I and II are incorrect. 43) Statement I is correct but statement II is incorrect. 4) Statement II is correct but statement I is incorrect 0, Statement I : The amount of light emitted {intensity of radiation) from a black body and. its spectral distribution depends only on its temperature. Statement II : When a ray of white light is | passed through a prism, the wave with shorter ‘wavelength bends more than the one with a longer wavelength. 1) Both statement I and Il are correct. 2) Both statement I and Il are incorrect. 3) Statement I is correct but statement II is incorrect 4) Statement I is correct but statement I is incorrect, h ‘"fMotegaonkar S.R. M.SeChem.Gold Medalist SET/NEF-JREGATE, DRDO,TIER qualified RCC ** RCC ** RCC ** RCC ** RCC ** RCC * = *RCC** RCC**RCC** RCC**RCC** RCC ** REC** RCC** RCC **RCC* *RCC** REC 52. = —____&¢ Which of the following statement(s) isi incorrect regarding photoelectric effect. i. The number of electrons ejected is proportional to the intensity of light. ii, There is some time lag between the striking of light beam on the metal surgace and the ejection of electrons. The kinetic energy of ejected electrons dpends upon the brightness of light. iv. The kinetic energy of the ejected electron is proportional to the frequency of the incident radiation. 1) iandii 2) iiandiii 3) iionly 4) iiandiv Which of the following statements concerning the quantum numbers are correct. i, Angular quantum number determines the three-dimensional shape of the orbital ii, The principal quantum number determines the orentation and energy of the orbital. iii, Magnetic quantum number determines the size of the orbital iv. Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis The correct set of option is. 1) iand ii 3) iii andiv 2) iand iv 4) ii, ili and iv13. 14. Which set of quantum numbers represent 2 15. 16. 17. Which set of quantum number is not 18. Which of the following set (s) of orbitals has (have) equal orbital angular momentum ? 19. How many electrons can fit into the orbitals ~ that comprise the 3rd quantum shell | 20. The correct set of quantum numbers for the 21. The azimuthal quantum number and the ‘ principal quantum number of the 17th Tevel 1S The quantum number for the last electron -1.The . in an atom are n= 3,1=1andm atom is 1) Al 3) Mg asi ac the electron of the lowest energy 1) n=2,1=0,m=0,s=-172 2) I=1,m=0,5=+12 3) ne4,1=0,m=0,5=+1/2 4) n=4,1=0,m=0,s=-1/2 How many electrons can fit into the orbitals that comprise the 3rd quantum shell ? yn2 28 318 4) 32 The quantum levels up to n = 3 has 1) sand pelectrons 2) 5, p,d, felectrons 3) s,p.delectrons 4) s~electrons consistent with the theory 1 1) n=2,1=1,m=0s--> 2) n=4,1 1 =2s--4 }m=28=— 5 1 3) n=3,1=2,ma3,s—+> 4) n=4,1=3,m=3,s=+1/2 1) Isand 2p 3) 3dand 4d 2) 2sand 2p 4) Isand 2s n=3? yn2 28 3) 18d) 32 unpaired electron of Chlorine atom 1) 2,0,0+1/2 2) 2a-1442 3) 3,0,0+1/2 4) 31,1,41/2 electron are 1) l=Ln=3 2) [=3,n=2 > 4) 1=2,n=1 Page: 90 RCC ** RCC ** RCC** RCC ** RCC** RCC** RCC**RCC**RCC**RCC**RCC** RCC** RCC** RCC**RCC**RCC**RCC** RCC* 22. 3 » r 3 is a 8 a y 8 a * oe r 7 sr ProfMotegsonkar S.R. M.Sc.Chem.Gold Medalist SET/NET-JREGATE DRDO! In the 4th quantum level the numbers! Struc The maximum number of sy ble Tey and electrons in N shell. of ec respectively 1) 412,32 2) 416,30 | 3) 4,16,32 4) 432,64 For the dumb-bell shaped ori, of lis ital the vy, n3 a1 30 os The sum of the all four quanty, aa values of the last electron in Born "by mig s 3 ar 32 An orbital may never be occupieg - 1) electron 3) 3electron 2) electron 4) Oelectron, Beryllium's fourth electron wil n four quantum numbers ‘ave nil om os D1 0 0 +12 211 1 +12 320 0 +12 421 0 +12 All electrons in a ‘d’ sub shell should km the quantum number 2)1=0 1) ns3 3) m=-1 electronic subshells are jn 2)2n 3) 2n? 4) n+l If the quantum number 1 has the vt! then 1) there are three possible values of™ 2). the value of m must be zerob 3) I cannot be larger then +2 4) m cannot be larger than -1 oe The number of orbitals in the energy level of an atom is na 2) 32 3) 16 aeStree es of the second 4 41, The orbital with nt re vne fourth main energy level of an atom, possible orientations is 2) 4,3,2,1,0 Hels The toute f ae 432 13,21, (L)42. The total values of ma; } n4u23 4) 310-3 yy umber ofan decom when the vee ofp ‘An electron has principal quantum number, 7218 32: Mie number of its (i) subshells and wy 9. 26 3 pitals would be respectively an 2 4) 3and5 2) 3and7 ig. In order to designate an orbital in an atom the 3) 3and9 4) 2and5 i a a a) 4g, Total number of orbitals in a shell with 34 oe incipal quantum number 'n' is It F 2) ant (44. Three elecrons in p-sublevel must have the ; en a (2 quantum number r F 34. Which set is not correct ? gy oof" ae i ; | 3) Ino 4) s= ford 1) 310-5 2 3.2145 lan; tm theo ot ones \ f F are known as ...... fold degenerate. 3 312-3 4) 3.2045 By 1) Three 2) Two 3) One 4) Four ; ., 46. When the value of azimuthal quantum 45. Fach p-orbital and d-orbital except one has ?, number is |, magnetic quantum oe lobes respectively as have values 24 2L4 923 bl Fy) -Lonly 2) Honly 36. The quantum number that is no way related g 3) +1,0,-1 4) +1and-1 to other quantum number is |S 47. Which represents the correct set of four yi as 30 4m ¥ quantum numbers of a 4d electron ? 37. The quantum number that does not describe bal 1 5 the distance and the angular disposition of © Oa 242,10 fs electron ees joo 21 3) m 4s ol on 2 a) 38. The correct designation of an electron with 2/48, The two electrons present in an orbital are n=4,/=3,m=2ands=1/2is 5 distinguished by : 1) 3d 2) af 3) Sp 4) 65 Z)1) Principal quantum number 38, The energy level quantum sumber a= 3,|;/ 2) Azinuthsl quantum number the number of possible orbitals are Y 3), Magnetic quantum number pi 38 3j3 94 [4 spin quantum number 40, The maximum number of atomic orbitals J 44 When the azimuthal quantum number (/) associated with a principal quantum °°" 03 iy can hav number 5 is Yo tvalue 2) Avalues ine 2) 12 = 7 oe i Ea svatues 4) 7 values beet ati cscacn marcas eChem Gold Medalist SET/NET-JRE GATE: Ree DRDO, THER qualified Page: 9et oo 50. In Row many elements doe te lant leon 60, Princ, eimutal sn mage hive the gutta munber of m= and = numbers rspciey ng ag 1 sae, shape and oe 2) shepe Sar and ort 5) sae eretaton and shape nome ot above The quantum number not obi sehrodinger® wave equation tt Le 53. The value of azimuthal quantum number 3) any value between O an 4) 2210 An electron has a spin quantum number 41/2 and a magnetic quantum number-1. yy p13) my 264, The angular momentum of antes, £ 1) orbital an atom depends on 3) orbital pm tan ox 55, The maximum number of electrons in a : 65, A 3d electron having § = + 12 cn bn ssubshell is given by the expression: "magnetic quantum number 243 -3 ant 2p, 2p, and 2p, orbitals ofan sein identical shapes but differ inte Size 1 Shape ym gn at fF 5 8, The set of quantum numbers ret tofee 4) mands + as 1 ee ee 7%. Sectrons. How many unpaired electrons _ Lame ete more : » 22 ) 3 oe = 88. ues of 76, The set of quantum numbers m3, Ie2, m,=0 2 8% TUS VANS 9° Nt ext i : _ eee oer Be eee set of four quantum numbers *° icy (outermost) electron of rabidie= PsbS: M.Sc Chem Gold Medals SETINEFJREGATE, ORDOTIFE ifiedme Sat he ae of eel agai mementam of an electron im the orbitals 15, $8. Sum of slestronic sing yy, the configuration 34°.) Ml 7 ms BS oe x 50. Quantem member accounts for the rotation | 2) Se econ around is own ais Dee — > © anoathel Sos. Ni a Toate quanto manbersn apptcabie | for an electron in an atom is: ¥Ma” 3 a 1) 6th electron i, ‘ . 3) th electro 304.The ee phe has 18 electrons in the outer © 114.Sillicon has te 4) 7th electron re ane 2) The 2 isaresutof Payed electrons. This oo : Le te 2D Autbouprincple 2 2) Hund’srute 405.A neutral atom of an element has 2K, 8L, °, 3) paulisexc 41M and 2N electrons. The total number of 5 4) Thi Bohan Principle electrons in the atom are Flats ne h model 2115. as minim 2 3 ‘ Yo deetectrons mee of unpaired 3) ie i 5) Fe 2) Com jo6.Which metal cation has maximum number 116, Which ee ea Mee of unpaired electrons z filling at pra Nearest to the nucleus after > 2 : lectrons 1) Mn’ pie 2 DS 26 © 3) 6 3) Co* 4) Fee 2 pe F = 117.In the absence of Pauli exclusion pri 107.How many d-electrons in Cu‘ (At, No.=29) °, the electronic configuration a ‘can have the spin quantum number (-1/2)? 21) 1s 2) 1s e us 3 ey +3) 1s? 2p! Eisen 35 oi 2118. The ‘elecironie er Be un : an atom is 408. The number of d-electrons in Ni Is? 2s? 2p’. The number of nupaired (At. N = 28) is equal to that of the : g electrons in this atom is 1) sand p-electrons in F- : yi 2) zero 3) 3. as 2) p-electrons in Ar(At.No.=18) & 119. The electronic configuration of Fe” ion is 3) d-electrons in Ni* FD) [Ard 2) [Ar] 3a* 4) total number of electrons in (At. No.=7) & 3) (Ar set ast 4) [Ar] 3d = 120. Atomic number of the element having 109. According to Aufbau princi 2) 4s<4p<3d 1) 4p<3d<4s 4) 3d<4s<4p 3) 4s<3d <4p 110.How many electrons shell of an atom of the el number Z=24? 5 26 3 12 4) 13 bound to the nucleus si 111.The number of peaks present in the radial pss D4 9M Ps a distribution curve of a 4f orbital is 423.Which electronic level will =!" 1) yi 22 hydrogen atom to absorb photon Me 3 44 y on pu 98 Pr 112. Anfbau principle is not valid for 8 z ge eid 072 1) Cuand Ar ae 2) CuandCr * 124. The last clecron paced g wantum shell is 4 3) Crand Ar 4) Feand Ag 2 ee am 9S ve iple, the correct © order of energy of 34, 4s, and 4p-orbitals is: are present in the M: JJement with atomic care. DRDO.TIER qualified ‘maximum number of unpaired 3p electrons is 1) 15 -2)10 3) 12 121. Total number of unpaired electrons in an ‘unexcited atom of atomic number 29 is Hi 22 a3 4a 4122.In which orbital electron is most os Q g & 2 tS tightly rageao) Rec fete, the newly 138.The correct ground 4, Which 34 orbital is comP! 125. ° 175. tering electron goes into a 3) 4p 1) 4f 2) 4s }) . 126.Number of electrons in the outer most orbit Mf the element of atomic number 25 i 7 25 3) 3 42 127. Which atom has as many as s-electron 28 prelectron y HH 2Mg 9 N 4) Na 128.Predict the total spin in Ni* ion 5 3 gat el ye 94y 942 ) 129.Which has highest number of unpaired electrons 1) Mn 2) Mn 3) Mn* 4) Mn* 130.An improbable configuration is 1) [Ar] 3d* 4s* 2) [Ar] 34° 4s 3) [Ar] 3d° 4s" 4) [Ar] 3d” 4s* 131.Which electronic configuration is no possible 1) 2p* —-2)26° 3) 38! 4) af? 132. The order of filling of electrons in the orbital of an atom will be 2) 4s 3d 4p 58 4d 4) 3d 4p 4s 4d 5s 1) 3d 4s 4p 4d 55 3) 5s 4p 3d 4d 4s 133.1n potassium the order of energy level for ” 19th electron is 1) 3s>3d 2) 4s<3d 3) 4s>4p 4) 4s=3d 134.The valency orbital configuration of an element with Z = 23 is 1) 3 2) 38 4st 3) 3d? 4s! 4p" 4)3d°%4s! 4p! 135.Number of unpaired electrons in the electronic configuration 1s? 2s* 2p* n2 23 34 46 136. The n#l value for the 3p energy level is 4 7 33 41 137.The maximum number of unpaired electrons in 4f energy level is 05 27 3) 10 46 Page: 96 Prof: Motegaonkar S.R. M.Se.Chem.Gold Medalist SET/NETJREGATE a configuration of chromium 1) [Ar] 3d° 4s! 53) fAr3d* 4h g 2.138. afternp-orbitals aw gue filled will be : te 2 1) (nti) 2 inn 3) (n+tyd Done ,140.An ion which has 18 elect, outermost shell as : tS ig DK Yor He YL 3141. After filling the 4-orbitals an we enter in m oe ee ee re 42. According to (n + D rule after, Tevel the electron enters info? 2 1) (n-ijd 2) (nt1)s 5 3) nd 9 (tip 143. If Pauli’s exclusion principle 15 not kage, the electronic arrangement of lth sea, yy iss 2) 1828 = 3) 18 4) 182635 2144. The maximum number of electrons = atom which can have (n+) =4 n2 26 38 at 145. The valency shell electron configaatsn: an atom is 4s? 4p®. The maximum electrons having parallel spin in & configuration are 7 aa 33 4s 146. The electronic configuration of an d= with atomic number 64 ++ RCC 1) 6s? 5d? 4f7 2 ot 3) 6s! 5d? af? 4) oe = 147. The ion that is most stable So Fe 2 Fe 2 oye ae ; 148.n and I values of an orbital A #375 and another orbital B are 5 #™ energy of 1) Bis more than A 3) AandBaresame 4) ABE 149, Which of the following eet" tightly bound by the nucleus 1) 4p 2 38 3) 4d gM + RCC 2) aismonete ya 7 seREC i¢ u shell. The elements are ute of Oe othe 3d ont ccessive elements belonging tothe 3d- 158. The el he same number of electrons Slectronic configurat;, Ree iguration in the c 18 es have jn the &-sub- . yy TY Dee u 3 créMn 4) Mn&F YI Level - II : 1.Which of the following has the maximum 2 150 umber of unpaired d-electrons? |: Nei 2) ow g 9) Zn 4) Fe lf 452.The orbital diagram in which the aufbau |S principle is violated is F 2s 2p 2s 2p g » POL TTT: y) gy a sp 3 (N][t 9 [N ‘ » YT (NINTH 3 153,Which set has the same number of unpaired * electrons in their ground state 1) NPV 2) NaP.Cl 5 3) Na’, Mg*, Al 4) Ch, Fe, Cr” 154.For a given value of m (principal quantum ‘number), the energy of different subshells ‘an be arranged in the order of : 1) f>d>p>s 2) s>p>drt 3) fop>d>s 4) s>f>ped 155:The tule that explains the reason for chromium to have [Arad ds! configuration instead of [Ar] 3d's*? 1) Pauls exclusion principle 2) Aufbau Principle 3) Hund’srule 4) Heisenberg principle 156,Which has the same number of s-electrons ; the deelectrons in Fe ? yi 2) Na : 3N 4aP 187. Total number of electrons in any energy Fl level is U = REE => RCC =RCC**RCC* = REC** REC =ReC* RCC y ka 2 2 20H) | » Learn 3 z yar) S20) i, ae lence Ww 15 The rule 1) Aufbau! rincipl 3) Hunde aie 159.A compound Vanadium moment of (1.73BM, configuration of ‘Vanadium ion in the compound i . s_. 1) [Ard 2) [Arpad 4st 3) [Arp 4) [Arp das! shell of silicon ig violated is has a magnetic The electronic Seon tee Level - I 160, The charge of an electron is 1.46 x 10°C ‘hat will be the value of charge on Nar ion. 1) 16x 10C 2) 32x 105C 3) 24x 10C 4) 10x 16% 10°C 161. The specific charge for positive rays is much Tess than the specific charge for cathode rays, This is because: 1) Positive rays are positively charged 2). Charge on positive rays is less 43) Positive rays comprise ionised atoms whose ‘mass is much higher 4)Experimental method for determinations wrong 162, The specific charge for a cathode ray: “Has the smallest value when the discharge tbe js filled with H, Is constant Varies with the atomic number of discharge tube ‘Varies with the atomic num forming te cathode r3y 6918S, be the specific char Map and, be that of posite? which is true? 1) $,=5) 3) $55: gasinthe er ofan element (elm) of cathode then 2) $75: 4 Anyonectthes page:ce. eo 164:TRe Evalue of proton i 1) Lessthan © value of electon 2) Bqualto valu of electron 2 ceeertan wae ecto isa negatively charged pertiag The mass of electron i. euton Sales, ee 4) Alltheabove, 1 1) Electrons massis [2th ofthe masfpa: 2) Electrons are universal paris nee 169. A neutral atom, with atomic number gre ‘than one consists of 1), Protons only 2), Protons and neutrons 13) Neutrons and electrons ») Halt 2) Twice ‘times 4) times of theflloingiscomest 0% sme 4 Althesbovesor es ec cone atta ables T8.Te daton Wl ight wave umber Foie cae in more when 1) Microwaves 2) Xerayx 1? nc nervuseotchargectibeparicleimore | 3) tRRadiations 4) Radiowaves 2 Peperiiracton wintheceticormaerete | 197.The energy of photon ia inversely 7 ed asofthe partie Blase eamartat 1) Wavelength 2) Frequency 3) Wavenumber 4) Valeney \dentify the incorrectly matched set from the ove produced when a stream of an X ~ ray tube on following ae £1) Wavelength Nanometers 2 Si ahvough strong magnet Fld 1B 2) Frequency Herz 3 ovate 2) 3) Waveumber at ary CGE 49) Nelocy e 1W9.1f 2, and A, are the wavelength of es of electromagnetic radiations ee characteristic X-rays and gamma rays respectively then the relation between them 2). Frequency 9) Enerey 4), Velosity when they passed through vacum 192. The radiation having maximum wave length = ion, which of the length than : vse light Us 9 canna cys 1M4.The product of wl ‘ual the velocity of light 1. Wve nth and wave number 2) Wavelength and eueney 3) Feuency and wae numer 9 We ength and ample 185.Which of the following statement correct” regarding» eletrom ‘Spectrum? fering 1) The voc of Xess mre than ht of Sol: AE wheecowlctyo ESR 301 meet = feguency 1368 E12 = 136810 ec" radiations have larger wavelength ys F ‘ 9) The frequency of microwaves is less than that Sl Frequency of vokt igh Fultra= violet rays < ' Xrays have larger wave number than micro Y=aos Hee Level = 1 198, Neon gas emits at O16 The distance yetength of green Ught Ls abo travelled by this radiaton in 30 ee Jo. - ame wan the frequency Of It Wave is 1) ote meet wes DOs 1 Mame ‘ osm Vyites DONO et . ass tow * pequency of a wave Hight is | a pet at graces THe wave Lengtt for this wave : ras is 199, Which of the following rela to photons ‘ both as wave motion and . stream of » antotem : particles? SY) tnwertorones 2) Eee store H oxtorem, Say Diteaction wer ghe energy PeF quantum associated with [ 200.The characteristic not associated with yt of wave Fength 250 x 10° m is Planck's theory I DY 7T9S\ 1) u 1) Radiations are associated with energy 3 4 393910) : 2) The magnitude of energy associated vath » arate she nergy of hotane ttl Railton oergy (ered sar comesponds to 4 wave number of 25 x 108); eee absorbe discontinuously 9 497s 1 erg 4) S58 107 erg * 201. Visible light photons do not show Compton a The energy of photon of light having, effect because they frequency of 3x 10S is 1) Move very slowly 2) 19961075] 2 1991077 2) Maveno momentum 3 19910 ergs 4) 1.99 * 10 ergs 3) Have very ess mans 185.The ratio of the energies of two different radiations whose frequencies are 3 x 10" 4) Have larger wavelength He and, 202.As the frequency of the light increases, the 5x10" Hz is 4 momentum of its Photon 3:5 et Sy Increases db 4st YD Decreases H a) Res na same 6.Which one of the following frequency of °, ) a Tadiation(in Hz) has a wavelength of 600nm 4) Cannot be predicte Y 2x 108 2) sx 10! + 203.The ratio of energies of photons with » 219 eee Ywavelengths 2000 A and 4000 A is 2x19" 3*10! gy 97, » $ y ua a4 "Calculate the wavelength of photon having a af snergy 5 e.V. 2 9 D247 <10%em 2) 247 * 10Sem y Y M7 1S em 4) 247 = 10M & K qualified otNeeroakas SIR. MSeChem.Gold Medalist SET/NETJREGATE, DRDO.TIK duaAnette RM soe ay ‘jects photo-electrons from gt (ED, = eV at Find the val of wok font iv Drew 208 8. ‘Stopping potential, v= subj be at OVO Natt, cron rien ae on subjected os me et 206.According to Einstein’s photoelectric * ‘equation, the graph between kinetic energy. of photoelectrons ejected and the frequency © °M**8: of the indicent radiation is : 1) 0, no emission will occur 2) 4352 108 mis REC**REC**REC**REC** REC 207, The photoelectric emission from a surface © ‘starts only when the light incident upon the surface has certain minimums ; 4) None of these oa Prof MolAOMe SR. M.Sc Chen, Gold Medalist SETINEFJREGATE PEee 1) Stars ingaloxy 2) Model planets ving 3). Behaviour of wavesin te 48) Clouds in hy that move shapes mt ag, mest Rutherford's model ofthe specifically include the ny 1) Proton 3) Naleus 26.1n Rutherford's und he ocean 2) Becton 4) Neutron £227. When alpha particles ae sent th thin meta fot mos of them gee | i 221.The conclusions of Rutherford scattering ‘experiment does not inde: ¥ ST Collate rads of ? sab we cow, 222 Rutherford’ experiment on scattering of | "505204 ‘parties showed forthe fist ime thatthe yer ed and = stom has : — 2) defleced 3) thrown back | 4) absorbed Trees hots grenby SH eepantar 5 MscChen old Meda SETINETREGATE, DRDO ———— (Cah Me 7he ratio of 2nd, nce ‘second orbit fo, What isthe crcurmferen? of the hydrogen atom ofhydrogen atom’ 7 1) 2:4:6 2 ia9 ‘sol: Circumference = 2 : b 9 1a 91:25 pute nts 0529 0°22 *0.529A' (2233. According to Bohr theor, =2.116A° 5 ‘momentum of electron in sf *® Angy . 22342116 A° g) orbit, Mla Circumference g er h et 0 DT 9 gash mormal electrons of &) | * 50. How many times ~ norma the nucleus it {2 254. In a hydrogen atom if energy ofa x Inydrogen atom reve! in ground state is 13.6 eV, then ty, lecog ‘one sec? 2nd excited state is : at in the yelocryofthectecron 1) 151eV 2) 34ev g 3) 604ev 4)136ev Sol: Number of revolutions = reumference of shell 135. The radius of which of the follow; following oi, : | drogen electron nr, Vloity= 218» 10s +2 For hydrogen: is same as that of the first Bohr’ orp, it of lol Circumference of shell = 2nr 2 hydrogen atom ? = 250.5291" xn'm ) 1) Het(n=2) 2) Lt(n=2) Z # (n=. 3, eae unasi aio ar3se1en FM (a3) 4) Be (n=2) ; Wvecinone see j236-Bohts model can explain : esthe sec Number oftimes the electrons evolvesin onesee [Yr spectrum of hydrogen stm only 21810" 4 Ir 2) The spectrum of atom of ion containin = 655x109 5 g electron only ig one ” 333x107 — 3 = 5 3) Thespectrum of hydrogen molecule an) 4) Thesolar spectrum 1228. The ratio of the difference between Ist and © . '237.Which transition of electron in the ‘2nd Bohr orbits energy to that between 2nd and 3rd orbits energy is hydrogen atom emits maximum energy nw JF} 2a 2194 3) 27/5 4) 527 yo 9) 493 4) 332 2 © 238. According t A 229.1n ground state, the radius of hydrogen * According to Bohr's model of hydrogen ‘atom is 053 A. The radius of Li* ion (Z=3) 2 in the same state is : = 1) Thelinear velocity of the electron is quantised 1) 017A 2) 1.06.4 y ‘The angular velocity is quantised 3) 053A inaas 2 3) Thelinear momentum of electrons quant! ' en * 4) The angular momentum of the electron 230.Which hydrogen like species will have g quantised same radius as that of Bohr orbit of : 239, Which statement does not form part of hydrogen atom? : 1p ne-aLe > & _Bohr’s model of the hydrogen atom ne end F 1). Energy ofthe electron in the orbits quant! os Se J 2) Theelectron in the orbit nearest the nuclews!* 11. The ratio of radii of first orbits of H, He’ = in the lowest energy ed E,9) Electrons revolve indifferent orbits around? 1) 1:2:3 2) 6:3:2 2) nucleus 3) 1:4:9 4) 94d 4) Theposition and velocity of theelectronsin ; ty ‘ orbit can not be determined ‘simultaneously : ProtMotegaona $B: MSe.ChemiGold M pea edaist SET/NETJREGATE, DRDO,TIER asl!tom — aS 0- us AO wcler® evel mreases 2) remains constant 1) ese 4) none 2) ating of spectral Hines when atoms are us Solittfed to strong electric field is called sabjeeen effect 2) Starketfect 9 eat 4) Disintegration 2 F ratio of Kinetic energy and potential Caan y of the electron in Bohr orbit of H- e tom is ' a De 3) 1 4 A value of the total energy of an electron 43-TMine hydrogen atom is given by 2) pm 3d) 4 yy mv? jectron moving in the circular orbit jrogen atom the force of attraction cleus is balanced by the force equal 244.For the el in a hyd of the nut ze = ye 1 energy of electron revolving f radius 'r' in the atom with 1 y zm 2 245.The potential in an_orbit 0! atomic number Z is 2 Ze Ze’ 5) ae Ja 1 7 3) 7 26.The radius of 10th Bohr orbit of the hydrogen atom in A° is 1) 052 2)5.3 3) 53 4) 5.3*5 247. Which of the following transitions are not allowed in the normal electronic emission Spectrum of an atom? )) 2s-+1s 2) 2pals sae 3d 4p 4) 5p+3s “Which of the following gives neither emission spectrum nor absorption Spectrum? D He 2) H, 9 di 4) He *tNoepatar S.R. M.Sc.Chem.Gold Medalist SET/NET-JREGATE, DRDO, TIFR qualified ba RCC FFRCC** RCC“ REC REE REC FREE * FREE ** REE * REE #* REC RECT RECT REC* REC ** REC ** REC Ree <> So race atom — oie aber of orbit increases from the tc te ye nmbe " 249.When the atomic electron is at infinite the pe difference between the adjacent distance from the nucleus, its energy 1® 1) infinity 2) zero 3) negative 250. The ratio of highest possible wavelength ' lowest possible wavelength of Lyman series 4) positive is 1) 48 2 9/8 3) 27/5 4) 165 251.The wave number for the longest Balmer series wavelength transition in the of atomic hydrogen is 1) 15.2« 10° m™! 2) 136% 10% m . 3) 1.5*10°m* 252.The wave length of a spectral line for electronic transition is inversely related to 1) Velocity of electron undergoing transition 2) Number of elctrons undergoing transaction 3) the 4) 13 -10°m! in ‘The difference in energy levels involved in transition 4) None of these 253. According to Bohr's theory, the angular momentum for an electron of 5th orbit is; 2) Sh/2 3) 25/7 4) 570/2h The change in velocity when hydrogen electron jumps from K shell to L shell is 1) 10b/r 254. 1) One-half ofits original velocity 2) Twice to its original velocity 3) One-quarter of its original velocity 4). Equal to its original velocity 255.The difference in angular momentum associated with the electron in two successive orbits of hydrogen atom is hin 3) W2 Dh 256. Properties of electrons that are quantized in Bohr's atomic model are a) 2 a 4 2 ) h/2n a(n Qn Mass and energy Energy and angular momentum Angular momentum and mass Mass and chargeress of acd opr 26 NH of eal jn in hydrogen atom al ‘equivalent 2) hehe nr anes 9) Theintenstyof nes tyman seine 2 4) Both the int jand numberof lines in Ly 1, 265.1f the spec ° since aan ee abi ofkydrogen nx he 4) Frstincreases flowed bya decrease 3 259, How much energy is required to ionise a H stom ifthe electron occupies n = 5 orbit? D) Sater : 3) o5Hev 260.The velocity of an 4) 87610'me! 261. Energy of electron moving in the second = Page 110 _ Peto 88 MSchem Gl Meda SEE AAT OO _sin visible and 1 Paschen linen © eet eens 55, venumber ofthe irstspectral Lyman series of He” spectrum 2) Anemissionine spectrum 3). Anabsorption band spectrum 4) An absorption ine spectrum 276.Rydberg constant is given by the equation 4) Is diferent for ightor heavier element, 277. When the electron of Sth orbit js ing the first orbit, the number of spec ioe Produced in hydrogen specium is 20 3 a semen bie Wave number fist inein Lyman series of Hes 329.105 cm Fa eee aang 58. What isthe wavelength of light emitied wh the electron in a hye ¥ 3) 21/100 9 aRy4 gt Page:t12 ProtMetegaonkar 82, M.Scchem Gold Medalist SETINETJREGATE, DRDOFee ot AO (i is of hydrogen specs le sels of bydogen space ee eters et 289; Whatis he waveengh of» photon emied eon 8 Nearing ep diring st mots Bua he rowen spec sZt in the hydrogen 310m uy pydrogen SPEStTUm Least energetic ater 2 Die series 2) Balmer series F 9 76am 4) Man rears 4) Phindames, © 280Which one of the following transitions of com N= EO am electrons in hydrogen atom emits 29 Reion £002, = 45,6 10 m3 in ect earn 2 gen spectrum gives series 2) Paschen series, jerseries. 4) und series Molecules y }) atoms g 2 Any substance sold state 3 Kay substance in liquid state dye spectrum with all wavelengths may 1) Absorption spectrum 2) Emission spectrum 3) Continuous spectrum 4} Discontinuous spectrum ags.tine spectrum is characteristic of 4) Atoms 2) Moloculee 3) Any substance in the slid state 4), Any substance in the liquid state 2 116, The only series of hydrogen emission with © cslours is g 1) Lyman 2) Balmer y 3) Paschen ‘Bracket g 287.0f the following atom the one which of lowest frequency in hydrogen © bsorption line Ynelton=2 2) ne3ton-8 ga . Sne2ton=1 4) n=Bton=3 soma 2 286.The electron present in 5th orbit in excited | hydrogen atoms returned back to ground = “ appear in : Lyman series of hy spectrum Q Ds g v4 Ht 291. Which of the following lines wave no. equal in magnitude to the value of R in the H - Spectral series 3 m3. ” 295. The wave length of the radiation emitted by Hydrogen when compared to He" ion is radiation of the lowest wavelength have & 1) Limiting line of Balmer series 2 iting line of Lyman series 3) First line of Lyman series 4) First line of Balmer series in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4 to m= 2 of He spectrum ? 1) 2times that of He" ton. 2) 3times that of He" ion 3) times that of He" ton, 4) Sameas He The best e jence that electrons are arranged in definite orbits or energy levels is based on the observation that » 2 2 a Atomic spectra consist of discrete ines ane nt continuous bands Electrons in the beta ray have high hinets energy ‘The penetrating theater electrons depends upon the aed price thet Etectrons revolve around the mucless tear 51m: MScChem Gold Medalist SET/NEFIREGATE, DRDO.TIFR qualified regenStructure 73, Find the momentum of a particle whose] 176. A pol Gall Nae a Tener tt omy id the momentum of a particle whose 76. A golf ball has a mass 40g and « mas de Broglie wavelength is 14°, 45 ms Ifthe speed can be measured at! Sol: de Broglie wave length, inaccuracy of 2%, calculate thy “th fe uncertai position, Srainty ig A =1A? =1.0%10% m Momentum of a particle, P=? Sol: Av=The uncertainty in speed = 45 x2. aa 199s: pol 6.625%10°*kgm's" 5 Tx 10 m Momentum of a particle is 6.625 * 10 kg m: culate the uncertainity in the velocity ofan Using ecg, ie = 6.62610 kgm’s" : : aie "5416 x09me Sa electron, if the uncertainty in position is 100 AX* 953.1416 0.9me 40510 kg a x= 1.4610 m Sok: Given Ax=100pm =100* 10-2 m This is nearly 10" times smaller than the di 10 m of atypical atomic nucleus. nd ‘mass of electron, m= 9.1 « 10>" kg Level - I i Ave? 295. The velocities of two particles A and Bare x =3.1416 0.05 and 0.02m/s respectively. The mass of a B is five times the mass of A. The ratio of Axx ave their de-Broglies wavelength is Yo 2s 2d b 6.62510 kgm's" = = RIO gms 31d 4 “Ten Esler Zw a A cricket ball of 0.5 Kg is moving wit =5.8 10 mst era The uncertainity in velocit velocity of 100m per sec. the wavelength =5.8x105 mst associated with its motion is 75. The uncertainity in the position and velocity Rages aces = kCcr ence =RGCee CO#*RCC* * REC ** RCC * REC ** REC ** RCC ** REC* FRCC** RCC** RCC of ny es by 1) 1/100m_ 2) 6.6 10m of a particle are 10m and 5.25 x 10 ms, 3 13210% ates What is the mass of the particle? (h= 6.625 x i 2 ued 10) 297. The wavelengths of electron waves in two Sol: axe io» orbits is 3 : 5. The ratio of kinetic energy of ori axs 10s a : electrons will be 47525 «10 me 1) 25:9 2) 53 . 6.625 x 10™ kgm?s 3) 9:25 4) 35 43.1416 «10 mx 5.25 x10™ms* 298.1f the radius of the first Bohr orbit of Hydrogen atom is ‘x’, then the de-Broglit wavelength of electron in third orbit s Mass of a particle = 0.1004 kg or 1004 g 76. What is the product of uncertainities in position and velocity of an electron? nearly. h 1) 2m 2) 6m Sol: ax x av> 7 3) 9 aie 6.625 «10 kgm's"! 299. Diffraction of the electron beam is * 4x3.1416%9. 10 kg, evidence of the fact that int 1) Electrons repel each other The product of uncertainties = ax x Av Dre = 5.79105 mis"! 3) Electron has wave property RCC ** RCC ** REC * * REC RCE ** RCC * * RE 4) Electron has momentum os Prof.Motegao TR Page 116 a a snkar S.R, M.Se.Chem.Gold Medalist SET/NET-JREGATE, DRDO’ atom operties are o ree having 400 ast mass and low velocities ” a ‘mass and no velocity 2) fgsmass and high velocities 2) Be mass and high velocities 2 Lam of the following is responsible to © on gat the existence of definite paths or 2 mule O ries of electrons? : wal v 2 pauli’sexclusion principle, pleisenberss uncertainty principle. e Hund’s rule of maximum multiplicity. 1p Aufbau principle. Je momentum of electron is = ‘Directly proportional to wave length 3) inversly proportional to wave number 3} inversy Proportional to wave length 4) Unable tobe determined gpnaccording to de Broglie’s concept, the circumference of each electron of which must be equal to 4) Diameter of a electron 2) The wave length of an electron 3) The integral no of electron wavelength 4) Planck's constant divided by 2 jo4.Among the following particles, which will 2 have the shortest wavelength when : & Beacce C#* RCE* REE ** REC accelerated by one million eV? y 1) Neutron 2) Tritium atom = 3) a-particle 4) Electron ‘ 305.1 moving with equal speeds, the longest wavelength of the following matter waves +e RCC is that for a (an) g 1) Electron 2) orparticle 5 3) Proton 4) Neutron 306.The momentum of radiation of wavelength : 0.33 nm is y 1) 2x 10% 2) 210" = 3) 2x 10-6 4) 2x10 ‘ SV will be g ) 5 ; 2) Seng 3 3 » Sev 4) 8x10 eV g a 1) §9.67am 3) 456.7nm 309. The mass of photon with wave length is 1) 6.135 «10 kg. 3) 4.126 « 10 kg. 310. The kinetic energy of electrom is 3.9 * J. The wave length of the electro iS 2) 46254 8 96nm 4) 896. 7am 364 2) 6.135 + 10-7 ke $4126 + 10> ke wo 5 Level - c BIL.1f E,, E, and E, represents the kinetic electron alpha particle and 2 4) E+E, gm is moving with If the error im the 3) E, Jo Pape (Prot Mategaonkar 5.8. M.ScChem.Gold Medalist SET/NEFJRFGATE, DRDSSTIE x Tea