Muhammed V V.-2
Muhammed V V.-2
Muhammed V V.-2
SEMINAR REPORT
Submitted by
MUHAMMED V V
REG NO: 2101020245
To
OCTOBER – 2023
DEPARTMENT OF MECHANICAL ENGINEERING
MA'DIN POLYTECHNIC COLLEGE
MELMURI. PO, MALAPPAURAM
CERTIFICATE
This is to certify that this seminar entitled 4D PRINTING
TECHNOLOGY submitted by MUHAMMED.VV (REG NO:
2101020245) to the Department of technical education government of kerala in
partial fulfillment of the requirements for theaward of the Diploma in Mechanical
engineering is a bonafide record of work carried out by him under my supervision and
guidance
GUIDE:
Mr. VIPIN VP. Mr. JITHESH NP.
SI TITLE PAGE
NO
NO
1 ABSTRACT
2 CONTENT
3 INTRODUCTION 1
4 4D PRINTING TECHNOLOGY 2
5 APPLICATION AREA AND PRINTING TECHNOLOGY 16
6 ANALYSIS OF 4D PRINTING TECHNOLOGY 15
7 CONCLUSION 22
8 REFERENCES 23
LIST OF FIGURES
SI NO TITLE PAGE NO
1 SCHEMATIC OF 1-, 2-, 3-, AND 4D CONCEPT 2
2 GENERIC PROCESS OF CAD 4
3 NATURAL PEIZOELECTRIC MATERIAL 8
4 SELF CUBIC FOLDING MECHANISM 10
5 SELF FOLDING STAND 11
6 SELF FOLDING TRUNCATED OCTAHEDRON 12
7 CURVED CREASE ORIGAMI 12
8 SCHEMATIC OF THE FOLDING MECHANISM 13
9 FOLDING PROCESS OF CUBES PRINTED WITH 13
A COMPOSITE MATERIAL
10 COMPUTATIONAL IMAGE BASED DESIGN OF 16
3D PRINTED TRACHEOBRONCHIAL SPLINTS
11 DESIGN MODEL OF MORPHING AIRCRAFT 17
12 CAMOUFLAGE MILITARY VEHICLE 18
13 BMW NEXT 100 4D PRINTED CAR 18
14 DE FORMATIVE SHOES AND FOLDING CLOTHS 19
15 MARKET ANALYSIS 21
LIST OF TABLE
SI NO TITLE PAGE NO
1 LIST OF SMART MATERIALS 7
2 ANALYSIS OF 4D PRINTING 20
CHAPTER-1
INTRODUCTION
Technology has always been amazing us with its beautiful inventions in the nature by
making the life of human simpler to a greater extent. Additive manufacturing, more popularly known
as 3Dimensional (3D) printing technology, has been developed for more than 30 years. Recently, 3D
printing has been recognized as a disruptive technology for future advanced manufacturing systems.
With a great potential to change everything from our daily lives to the global economy, significant
advances in 3D printing technology have been made with respect to materials, printers, and processes
Now an innovative concept of printing technology known as 4D printing technology has been
developed. Although similar to 3D printing, 4D printing technology involves the fourth dimension of
time in addition to the 3D space coordinates. Therefore, one can regard 4D printing as giving the
printed structure the ability to change its form or function with time (t) under stimuli such as pressure,
temperature, wind, water, or light.
1.1 BACKGROUND
The term 4D printing is developed in a collaboration between MIT's Self-Assembly Lab and
Stratasys education and R&D department. In February 2013, Skylab Tibbits, co-director and founder
of the Self-Assembly Lab located at MIT's International Design Center unveiled the technology "4D
printing" during a talk at TED conference held in Long Beach, California. It’s Self-Assembly Lab.
3D printing manufacturer Stratus’s and 3D software company Autodesk are the key players in the
development of 4D printing technology.
1.2 OBJECTIVE
Though the knowledge about this technology has not yet reached to common people in the
world still there is a lot of research going on in different labs at universities and research centers, each
one getting different results which demonstrate that this technology could be brought into reality very
soon. Currently 4D-printing requires complex and time-consuming post-processing steps to
mechanically program each component. Also, most commercial printers can only print 4D using a
single material, which greatly limits design choices. But a research team led by Jerry Qi, a mechanical
engineering professor at Georgia Institute of Technology. along with scientists at the Singapore
University of Technology and Design, have developed a powerful new 4D printer that can create
selfassembling 4D-structures much more quickly and efficiently.
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CHAPTER-2
4D PRINTING TECHNOLOGY
4-dimensional printing (4D printing: also known as 4D bio printing, active origami, or
shapemorphing systems) uses the same techniques of 3D printing through computer- programmed
deposition of material in successive layers to create a three-dimensional object. However, 4D printing
adds the dimension of transformation over time. It is therefore a type of programmable matter,
wherein after the fabrication process. the printed product reacts with parameters within the
environment (humidity. temperature, etc.,) and changes its form accordingly. light. Figure 1 depicts
a schematic of the 1-, 2-, 3-, and 4D concepts. The concepts of 1-, 2-, and 3D represent line, plane,
and 3D space structures, respectively. For 4D, the concept of changes in the 3Dstructure (x, y, z) with
respect to time (1) is added, as indicated by curved arrows...
(Fig 1) Schematic of 1-, 2-, 3-, and 4D concepts. A 4D structure is a structure (x, y, z) made by
3Dchanges over time (1). Arrows indicate the direction of change with respect to time.
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2.2 PROCESS FOR 4D PRITNING
AM involves a number of steps that move from the virtual CAD description to the physical
resultant part. Different products will involve AM in different ways and to different degrees. Small,
relatively simple products may only make use of AM for visualization models, while larger, more
complex products with greater engineering content may involve AM during numerous stages and
iterations throughout the development process. Furthermore, early stages of the product development
process may only require rough parts, with AM being used because of the speed at which they can be
fabricated. At later stages of the process, parts may require careful cleaning and post processing
(including sanding, surface preparation and painting) before they are used, with AM being useful here
because of the complexity of form that can be created without having to consider tooling. The use of
AM processes enables freeform objects to be produced directly from digital information without the
need for intermediate shaping tools. Most AM processes can support 4D printing as long as the
selected stimulus-responsive material is supported by or compatible with the printer. steps involved
in process
• CAD
• STL convert
• File transfer to machine
• Machine setup
• Build
• Remove
• Post process
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(Fig 2)Generic process of CAD to part, showing all 7 stages
Step 1: CAD
All AM parts must start from a software model that fully describes the external geometry.
This can involve the use of almost any professional CAD solid modelling software, but the output
must be a 3D solid or surface representation. Reverse engineering equipment (e.g.. laser scanning)
can also be used to create this representation.
Nearly every AM machine accepts the STL file format, which has become a defect standard,
and nearly every CAD system can output such a file format. This file describes the external closed
surfaces of the original CAD model and forms the basis for calculation of the slices.
The STL file describing the part must be transferred to the AM machine. Here, there may be
some general manipulation of the file so that it is the correct size, position, and orientation for
building.
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Step 4: Machine Setup
The AM machine must be properly set up prior to the build process. Such settings would relate
to the build parameters like the material constraints, energy source, layer thickness, timings, etc.
Step 5: Building
Building the part is mainly an automated process and the machines can largely carryon
without supervision. Only superficial monitoring of the machine needs to take place at this time to
ensure no errors have taken place like running out of material, power or software glitches, etc.
Step 6: Removal
Once the AM machine has completed the build, the parts must be removed. This may require
interaction with the machine, which may have safety interlocks ensure for example that the operating
temperatures are sufficiently low or that there are no actively moving parts.
Once removed from the machine, parts may require an amount of additional cleaning up before
they are ready for use. Parts may be weak at this stage or they may have supporting features that must
be removed. This therefore often requires time and careful, experienced manual manipulation.
The main characteristic of shape memory materials (SMMS) is the ability to recover to their
programmed shape from a temporary shape when stimulus is applied. This is known as the shape
memory effect (SME). SMMs require two processes to form a complete shape memory cycle. The
first step is to deform the material into a temporary shape through the "programming process" (Fig.
4), followed by the "shape recovery process". SMMs will remain constant in its temporary shape until
the right optimum stimulus is applied to trigger the shape recovery process. The rapidity of shape
change from a temporary shape depends on the responsiveness of the material and the physical design
of the geometrical part. The network elasticity of the SMM determines the "memory" of one or more
shapes. The two significant factors that determine the shape memory effect of SMMS are the strain
recovery rate (Rr) and the strain fixity rate (RF). The strain recovery rate (Rr) refers to the ability of
the material to memorize its permanent shape, whereas the strain fixity rate (RF) refers to the ability
of the switching segments within the mechanical deformation. Both Rr and Rf have to add up to 100%
to be measured as an effective SMP. The calculation for strain recovery and fixity rate is made up of
Rr 100% (-rec)/ɛ and R-100% E/E load; whereby == fixed strain after cooling and unloading; grace=
strain after recovery; and load-maximum strain under load.
The majority of SMPs have a one-way shape memory effect which is irreversible. When an
external stimulus is applied, the deformation (temporary) shape will become a permanent shape. A
programming step (Fig. 2) is needed for the object to return back to its temporary shape. Figure 2
describes the process of the one-way shape memory effect where the SMP changes from its temporary
shape (A) back to the permanent original shape (B) under an applied stimulus. In the programming
process, the SMP is first heated above transition temperature to soften the material, so that a
deformation force (e.g., loading) can be applied to the original shape. The preformed shape is cooled
under the load to a fixed temporary shape. When the unloaded fixed temporary shape is exposed to
stimuli, in this case is heat, the original shape (B) is recovered (Fig. 3)
SMP with two-way shape memory effect has the ability to remember two different shapes
when exposed to stimuli. The material can change from a temporary shape back to its permanent
shape zhou emphasized that this behaviour is neither mechanically nor structurally constrained
thereby allowing for multiple switching between encoded shapes without applying any external force.
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The two-way SME can be found in liquid crystalline elastomers and photo-actuated deformation
polymers. Chen et al. successfully demonstrated the two-way shape memory behaviour using a
polymer laminate prepared from a 1.0 mm-thick active layer of PHAG5000 polyurethane-based shape
memory with a 1.0 mm-thick substrate of PBAG600-based polyurethane. The effect was observed by
bending upon heating from 25 to 60 °C and reverse bending upon cooling from 60 LIST OF
SMART MATERIALS
Those materials capable of generating electric charge in response to applied mechanical stress
are piezoelectric materials. Not all the smart materials do exhibit a shape change but they do carry
significant properties such as electro and magneto theological fluids. Those fluids can change
viscosity upon application of external magnetic or electric field. Naturally occurring crystals like
quartz and sucrose, human bone, ceramics, Polyvinyl Dene fluoride (PVDF) are known to have
piezoelectric characteristics. Followed by the automotive industry and medical instruments, global
demands for these materials have huge application in industrial and manufacturing sector.
Researchers from University of Warwick in UK have developed new microstereolithography (MSL)
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3D printing technology that can be used to create piezo ceramic object. Piezo ceramics are special
type of ceramic materials that can create electrical response and responds to external electrical
stimulation by changing shape. These are very useful materials and applicable all around, sensor in
airbag systems, fuel injectors in engines, electric cigarette lighter and electronic equipment
Shape memory alloy or polymers are emerging smart materials that have dual shape
capability. Shape memory alloys go transformation under predefined shape from one to another when
exposed to appropriate stimulus. Initially founded on thermal induced dual shape research, this
concept has been extended to other activating process such as direct thermal actuation or indirect
actuation. The applications can be found in various areas of 41 our everyday life. Heat shrinkable
tubes, intelligent medical parts, self-deployable part in spacecraft are few used area with potential in
broad other applications. The process in shape memory polymer is not intrinsic, it requires
combination of a polymer and programmed afterwards. The structure of polymer is deformed and put
it into temporary shape. Whenever required, the polymer gains its final shape when external energy
is applied. Most of the shape memory polymers required heat as activating agent. The material used
in tube is poly di methacrylate polymer. Initially the shape was programmed to form flat helix, using
heat energy ranging from 10 degree to 50 degree centigrade, flat helix transformed into tube shape
structure.
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2.9 MAGNETOSTRICTIVE MATERIALS
A major challenge for 4D printing technology is design structure including both hardware
section and software section. In order to design hardware part, special measures needs to be
addressed. Since, this requires complex and advanced material programming, precise multi- material
printing, designing complex joints for folding, expansion, contraction, curling, twisting process.
Software section is even challenging that cooperates with hardware design. Sophisticated simulation,
material optimization and topology transformation are few of the challenges for software part.
Following explanation demonstrates structural transformation regarding its joint angle, folding,
curling and bending.
2.11 FABRICATION
As the printer deposits UV curable polymer and cures layer by layer using UV light thereby
creating complete 3D structure, printers are capable of printing multiple composite materials with
various properties such as colour pattern, material hardness and transparency allowing creation of
complex, multiple composite parts in single process. Digital materials can be printed with this
process. The properties can be digitally adjusted and altered with the digital material. The
combination of digital material with different proportion and spatial arrangements plays significant
role providing additional flexibility. 4D printed parts are generally composed of rigid plastic and
digital material that reacts upon external energy source. In case of hydrophilic UV curable polymer,
when exposed to water, the structure absorbs and creates hydrogel with up to 150 percentage of
original volume. The shape transformation of the structure is linear in this case, but when the polymer
structure is combined with different composite material that reacts differently with water, complex
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geometric transformation occurs. Transformation can be controlled by adjusting pure expandable
polymer with digital composite material as per requirement.
For any bending or folding structure, joint plays important role as controlling of joints adjusts
the desired shape of structure. Self-Folding Strand Printing 4D joint includes multiple layers of
material. Composition of rigid polymer, expanding material and digital material depicts the folding
direction and pattern. Those materials are placed above or below of each other depending upon the
type of transformation. If the expanding composite is placed above rigid polymer, the surface will
fold downwards and if placed below, the surface will fold upwards. This folding happens due to
downward or upward force applied to rigid material. With the digital polymer composite, the control
of folding the joints becomes much desirable. The time duration of folding depends upon the
expandable material or digital material. If higher expanding composite is used, there will be more
folding force increasing folding time. Similarly, less expanding composite will generate less folding
force thereby decreasing folding time..
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(Fig 5) Self-Folding Strand
In his research, Skyler Tibbets demonstrated custom angle transformation creating truncated
octahedron shape. Similar mechanism as folding strand described previously. Series of flat two
dimensional structures were generated with edge joints. The position and spacing of materials at each
joint specifies the desired fold angle hence positioned accordingly… After the digital model was sent
to be printed, physical model was immersed in water. The transformation process occurred within
certain time with the final desired model having edges aligned perfectly aligned with neighbouring
edges. With this technique, a two dimensional polyhedral shape was folded and self-transformed into
precise three dimensional structure. Self- Folding Truncated Octahedron. The advantage of this
process includes efficiencies of printing flat shape with quick printing time and minimal resources
used. If the final model were to be printed directly, it would have taken longer time consuming more
support materials. On the long run, this technology can be effective for logistics operation where flat
surface material can be created, shipped and self-transformed into three dimensional structure when
required
Curved surface folding mechanism is based upon a technique called curved-crease origami,
where two dimensional flat sheets are folded along curved creases forming double curved surface
with mountain and valley shaped linear pattern. (Figuring, 2016) This mechanism can be further
explained with the example of concentric circles made of expanding polymers separated by rigid or
less expanding polymer. The position of expanding polymer above or below rigid polymer in each
circle with the ring being neutral, creates mountain and valley folds. When the design print is placed
in water, after certain time period, the structure transforms itself from two dimensional crease to
doubly curved structure.
In addition to smart materials, one of the core techniques for 4D printing is the design of
materials for structural change. Although the smart material itself plays a pivotal role in transforming
a printed object into another shape or configuration, sophisticated design based on a rigorous
understanding of mechanisms, predicted behaviours, and required parameters should be performed
to achieve controllable results. By designing the orientation and location of smart materials such as
shape memory polymer fibres within composite materials, we can facilitate morphological changes
in response to external stimuli. For example, Ge et al, investigated the design variables that are
important for creating a laminated architecture. A two-layer laminate consisting of one lamina layer
with fibres at a prescribed orientation and one layer of pure matrix material was constructed (Figure
10a). When the samples were heated, the printed two-layer laminates transformed into bent, coiled,
and twisted strips: folded shapes; and complex contoured shapes with non uniform and spatially
varying curvatures depending on each sample's prescribed fibber architecture (Figure 10b)
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(Fig 8). (a) Schematic of the folding mechanism and (b) representative images for folding by heat.
They also fabricated a self-folding and self-opening box with two-layer printed active composites as
hinges connecting six inactive plates of a stiff plastic as shown in Figure 7a. Using this model, Ge et
al. could actuate the hinges created from composites with polymer fibbers. Making the hinges fold to
a prescribed angle. Finally, the group created a number of active origami components, including a
box, a pyramid, and two origami airplanes based on different design parameters. They demonstrated
that the folding of the printed composite hinges depended on the material properties of the polymers
(including the shape memory behaviour of the fibbers). The lamina and laminate architecture, and the
thermos mechanical loading profile.
(Fig 9) (a) Folding processes of cubes printed with a composite material with a hinge made of shape
memory polymer. Reprinted with permission (b) Folding processes of cubes printed with a single
shape memory material. (c) Hinge design of a heat-induced folding cube made from a single.
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CHAPTER-3
3. APPLICATION AREA AND FUTURE DEVELOPMENT
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(Fig 10) (a) Computational image-based design of 3D-printed tracheobronchial splints. (b) 4d
printed stent that is introduced into an artery.
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(Fig 11) Design model of morphing aircraft
Programmable matter will have vast application areas in military sector. US army and Navy
are developing three dimensional printed spare parts in the field and developing programmable
elements that form into full building with all the necessary components such as electricity, plumbing
and other technical structures. As the technology allows the materials to change its shape, military
equipment, cars and fabrics could enable them to alter its camouflage. Military advancements with
4D printing technology would develop coating material in automobile that changes its structure to
cope with humid environment and corrosion. Similarly, transformation of tires depending upon road
and weather condition. In 2013, US Army Research Office granted $855,000 to researchers at three
universities, Harvard’s School of Engineering and Applied Science, The University of Illinois and
The University of Pittsburgh Swanson School of Engineering. In automobile industries this
technology helps in printing body parts so that they can change their shape with external conditions
for example with variation in speed the front portion will get air foil shape it reduces load on the car.
BMW Company used 4d printing technology for printing body parts.
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(Fig 12) (a) Camouflage military vehicle (Fig 13). (b) BMW NEXT 100 4d printed car
People are much more familiar with IKEA furniture which comes in parts and packed. It takes
lots of time and effort for normal customer to assemble and make ready. However, one could imagine
the relief when those flat packaged furniture self assembles and the furniture is ready to use without
any hassle similarly, self-disassembling of furniture while moving from one location is comforting.
Along with the time saving, it could help people get rid of complex assembling process and mistakes.
3.5 FASHION
The idea of clothes and trainers adjusting their shape and function in response to external
environment and comforting the user, sounds fascinating. Fitting perfectly upon pressure being
applied or gears becoming water proof itself when raining. Massachusetts based design studio
Nervous System have developed 4D printed wearable which is composed of thousands of unique
interlocking component and the dress responds to the wearer’s body. It is to fold the dress and reduces
the space required. It can act like insulation for environment conditions like hot and cold. Experiments
involving 4D printing have been few and limited to the date as there are only few major players
actively in the field of research. Imagine a single shoe for multiple activities: If you start running, it
adapts to being running shoes. If you play basketball, it adapts to support your ankles. If you go on
grass, it grows cleats. If it is raining, it becomes waterproof.
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(Fig 14). De formative shoes and folding cloths
This technology can be formulated into action for manufacturing and construction idea at
extremely large scale and complex environments. Printing small materials and transforming into
gigantic shapes in extreme locations such as radiation zone, deep trench, space, war zone. Building
materials that are capable of adjusting fluctuating environment, self-healing, maximum shock
absorption and mediating moisture, sound, pressure, temperature varying the thickness. A good
example of the potentially inevitable revolution of 4D printing in the field of construction can be
smart water pipes, which have the ability to adjust and assemble themselves as per the changing water
pressure and temperature. As the pipes adapts and adjust independently, no need of any digging
preventing internal damages, this mechanism will help in easy and cost effective maintenance.
Insulation wall that can adapt to outside temperature. Self adaptive wall that maintain heat during
winter and less insulation property during summer. Many studies are pursued in the renewable energy
field to improve the current wind turbine blades from various perspectives. To convey the whole
relevant studies, we organize the important concepts as the following sub-sections by considering
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CHAPTER-4
4. ANALYSIS OF 4D PRINTING TECHNOLOGY
A SWOT analysis is carried out for any company, person or product. This
process involves specifying objective of any project identifying internal and external
factor that are suitable and unsuitable to achieve project goal The analysis of
4Dprinting is useful to identify strengths, weakness opportunities and threats related
components for 4Dprinting
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4.2 4D PRINTING MARKET ANALYSIS
Upon analysing the trends in 4D printing market on the basis of programmable matter, end user
industry and future scope, 4D printing market is expected to be commercialized by 2019. As the
printing technology is in its initial developing phase, the global market is expected to grow with
compound annual growth of 42.5% between 2019 and 2025 reaching USD 537.8 million as shown in
Figure 22. As North America expected to hold the majority market size, market development will be
driven by the necessity to reduce manufacturing cost, logistic problems and secure sustainable
development. Similar to 3D printing technology, 4D printing industry will have major impact into
aerospace, military and defence healthcare, automotive, clothing and construction sector.
The need to reduce the costs of manufacturing and processing, would accelerate the global
market of 4D printing over the coming years. This technology possess a new business model to cater
to the current business requirements by offering reduced need for capital, inventories, time- tomarket,
which increases the market efficiency. A 4D printed product would lead to lesser manufacturing,
transportation and handling costs which would lead to saving of resources and efforts.sustaining the
environment. The global 4D printing market size is expected to be USD 65.4 million by 2019
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CHAPTER-5
5. CONCLUSION
5.3 TECHNOLOGY
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CHAPTER-6
6. REFERENCES
• https://www.asme.org/engineering-topics/articles/manufacturing-design/4d-printing-
• https://en.wikipedia.org/wiki/Fourdimensional
• http://manufacturing.materialise.com/stereolithography
• http://www.technologyreview.com/article/401750/electroactive
• http://www.youtube.com/watch?v=0gMCZFHv9v8
• https://www.theseus.fi/bitstream/handle/10024/130325/thesis_dilip.sequence=1
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