SAFETY DATA SHEET
Date Printed: April 27, 2020
Version : -
Revision date: -
Regulation: In accordance with Commission Regulation (EU) CLP 1272/2008
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
1.1 Product identifier
Product name: LLDPE 3120, LLDPE 3120MF, LLDPE 3121UV, LLDPE 3123, LLDPE 3126, LLDPE 3127, LLDPE 3127D,
LLDPE 3224, LLDPE 3303, LLDPE 3304, LLDPE 3305, LLDPE 3306W, LLDPE 4200, LLDPE 4200D, LLDPE 4300N,
LLDPE 4300S, LLDPE 7540, LLDPE 7635, LLDPE 8262, LLDPE 9730, LLDPE 9730D, LLDPE X-8400, LLDPE 2558
EC No.: -
REACH Registration No.: -
CAS No.: 25087-34-7
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Identified Uses
- Raw material for industrial resin
1.2.2. Recommended use
- Raw material for industrial resin
1.2.3. Restrictions on use
- Do not use for purposes other than those recommended
1.3 Details of the manufacturer and supplier & distributor of the safety data sheet
1.3.1. Manufacturer
Company name: Hanwha Solutions Co, Ltd.
Address: Yeosu plant, Hanwha Solutions Co, Ltd., 117, Yeosusandan 3-ro, Yeosu-si, Jeollanam-do, Korea
Prepared by: PE Production 2 Team, PE Production 3 Team
Contact Telephone: +82-61-688-1804 (FAX: +82-61-688-1820)
+82-61-806-7012 (FAX: +82-61-806-7010)
Email Address: pilsung.hwang@hanwha.com, younghwan.choi@hanwha.com
1.3.2. Supplier&Distributor
Company name: Hanwha Solutions Co, Ltd.
Address: 21F, Hanwha Bldg., Janggyo-dong, Jung-gu, Seoul, Korea
Prepared by: PO Global Business Team
Contact Telephone: +82-2-729-5026 (FAX: +82-2-729-2563)
Email Address: hyeonho.yang@hanwha.com
1.4. Emergency telephone number
Emergency Telephone: +49-6196-5016 / +82-61-688-1804 / +82-61-806-7012
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 (CLP)
Physical / Chemical Hazards:
Classification according to Regulation (EC) 1272/2008 (CLP):
Not classified
Health Hazards:
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Classification according to Regulation (EC) 1272/2008 (CLP):
Not classified
Environmental Hazards:
Classification according to Regulation (EC) 1272/2008 (CLP):
Not available
2.2 Label elements
Hazard pictograms: Not applicable
Signal word: Not applicable
Hazard statement: Not applicable
Additional precautionary statements: Not applicable
Precautionary statements
- Precaution: Not applicable
- Treatment: Not applicable
- Storage: Not applicable
- Disposal: Not applicable
2.3 Other hazards
Health: 0
Flammability: 0
Reactivity: -
3. COMPOSITION/INFORMATION ON INGREDIENTS
Classification according
Component CAS No. EC No. Conc. / % Registration No.
to 1272/2008/EEC
Polyethylene 25087-34-7 607-541-7 ≥99.5 Not classified 01-2119462827-27-0000
*Under EU REACH regulation, monomer in Polyethylene is registered.
4. FIRST AID MEASURES
4.1 Description of first aid measures
4.1.1. General information:
Remove soiled or soaked clothing immediately, do not allow to dry.
Adhere to personal protective measures when giving first aid.
Clean body thoroughly (Bad, shower).
4.1.2. Following inhalation:
Specific medical treatment is urgent.
Move victim to fresh air.
Give artificial respiration if victim is not breathing.
Administer oxygen if breathing is difficult.
4.1.3. Following skin contact:
In case of contact with substance, immediately flush skin with running water at least 20 minutes.
Remove and isolate contaminated clothing and shoes.
Get immediate medical advice/attention.
4.1.4. Following eye contact:
In case of contact with substance, immediately flush eyes with running water at least 20 minutes.
Get immediate medical advice/attention.
4.1.5. Following ingestion:
Do not let him/her eat anything, if unconscious.
Get immediate medical advice/attention.
4.1.6. Self-protection of the first aider:
First aider: Pay attention to self-protection!
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4.2 Most important symptoms and effects, both acute and delay Acute effects:
- Symptoms and effect: None known
4.3 Indication of immediate medical attention and notes for physician
- Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
- Suitable extinguishing media: Use, dry fire extinguisher, alcohol foam, water spray, CO2, when fighting
fires involving this material.
- Unsuitable extinguishing media: High Pressure Water Jet
5.2 Special hazards arising from the substance or mixture
- May be ignited by heat, sparks or flames.
- Containers may explode when heated.
- Some of these materials may burn, but none ignite readily.
- Fire will produce irritating and/or toxic gases.
- If inhaled, may be harmful.
5.3 Advice for firefighters
- Move containers from fire area if you can do it without risk.
- Some may be transported hot.
- Runoff from fire control may cause pollution.
- Contact with substance may cause severe burns to skin and eyes.
- Dike fire-control water for later disposal; do not scatter the material.
- Fire involving Tanks; Cool containers with flooding quantities of water until well after fire is out.
- Fire involving Tanks; Withdraw immediately in case of rising sound from venting safety devices or
discoloration of tank.
- Fire involving Tanks; Always stay away from tanks engulfed in fire.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
- Eliminate all ignition sources.
- Stop leak if you can do it without risk.
- Ventilate the area.
- Do not touch or walk through spilled material.
- Powder Spill; Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.
- Prevent dust cloud.
6.2 Environmental precautions
- Prevent entry into waterways, sewers, basements or confined areas.
6.3 The methods of purification and removal
- Small Spill; Flush area with flooding quantities of water. And take up with sand or other non-combustible
absorbent material and place into containers for later disposal.
- Large Spill; Dike far ahead of liquid spill for later disposal.
- With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
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- Wash your hands thoroughly after handling.
- Please work with reference to engineering controls and personal protective equipment.
- Be careful to high temperature.
7.2 Conditions for safe storage, including any incompatibilities
- Store in a closed container.
- Store in cool and dry place.
- Please note that there are materials and conditions to avoid.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Occupational Exposure limits
ο EU regulation: Not available
ο U.S regulation:
- NIOSH: Not available
- OSHA: Not available
ο ACGIH: Not available
ο Biological exposure index: Not available
ο Others:
- Slovak Republic: TWA=5mg/m3 (total solid aerosol)
- Latvia: TWA= 5mg/m3 (dust, listed under Polymers dust)
- China: TWA= 5mg/m3 (total dust), STEL= 10mg/m3 (total dust)
ο DNELs, PNECs: Not available
8.2 Exposure controls
Appropriate engineering controls:
- Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment:
Respiratory protection:
- Wear European Standard type P1(EN 143) approved dust mask respiratory protective equipment
when necessary.
Eye protection:
- Wear safety goggles as follow if eye irritation or other disorder occur.
; In case of gaseous state organic material: enclosed safety goggles
; In case of vapour state organic material: safety goggles or breathable safety goggles
; In case of particulate material: breathable safety goggles
Hand protection:
- Wear appropriate protective gloves (insulated gloves) by considering physical and chemical properties
of chemicals.
Body protection:
- Wear appropriate protective clothing by considering physical and chemical properties of chemicals.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance
Description: Solid
Color: ivory white
Odor: Not available
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Odor threshold: Not available
pH: Not available
Melting point/freezing point: 100℃~115℃
Initial boiling point and boiling range: Not available
Flash point: 221℃
Evaporation rate: Not available
Flammability (solid, gas): Not available
Upper/lower flammability or explosive limits: Not available
Vapor pressure: Not applicable
Vapor density: Not available
Relative density: 0.92~0.95g/cm3(25℃)
Solubility(ies): Soluble in organic solvents above 93℃
Partition coefficient: n-octanol/water: Log Kow=17.04
Auto-ignition temperature: 435℃
Decomposition temperature: Not available
Viscosity: Not available
Explosive properties: Not available
Oxidizing properties: Not available
Molecular weight: 60,000-150,000g/moL
10. STABILITY AND REACTIVITY
10.1 Reactivity/Chemical stability/Possibility of hazardous reactions
- Stable under normal conditions.
- No dangerous reaction under conditions of normal use.
10.2 Conditions to avoid
- Keep away from heat/sparks/open flames/hot surfaces.
10.3 Incompatible materials
- Combustion materials, Irritating, Toxic gases, strong oxidizing agent
10.4 Hazardous decomposition products: CO2, Acrolein, Formaldehyde
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
(a) Acute toxicity Not available
Oral Rat, LD50 >2,000 mg/kg bw
Dermal Not available
Inhalation Not available
(b) Skin Corrosion/ Irritation Not classified
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In test on skin irritation with rabbits, mild skin irritations was observed.
(irritating index: 0.2)
Not classified
At the 24 hours observation, one and two treated eyes suffered from
(c) Serious Eye Damage/ moderate and minimal conjunctival irritation, respectively. Polyethylene
Irritation produced a maximum group mean score of 11.7 and was classified as a mild
irritant to the rabbit eye. All treated eyes appeared normal at the 72 hour
and 7 day observations.
(d) Respiratory sensitization Not available
Not classified
(e) Skin Sensitization In skin sensitization test with guinea pigs, skin sensitizations were not
observed.
Not classified
(f) Carcinogenicity IARC: Group 3
NTP, OSHA, EU CLP 1272/2008, US EPA: Not listed
Not classified
(g) Mutagenicity In vitro: Reverse mutation test (S. typhimurium, Escherichia coli) with/
without metabolic activation: Negative
(h) Reproductive toxicity Not available
(i) Specific target organ
Not available
toxicity (single exposure)
Not classified
Sub-chronic or pre-chronic Exposure/ In a 90-day study, rats and dogs were
fed an extract of low molecular weight PE film; the film had been extracted
(j) Specific target organ with isooctane to yield 568 mg extract/100 g of film. Rats fed at a level of
toxicity (repeat exposure) 13,500 ppm film extract showed liver changes (fat droplets, cloudy swelling,
and increased liver weight) that were considered reversible in all cases. Rats
fed at levels of 2700 and 540 ppm and dogs fed 2700 ppm showed no
adverse effects.
(k) Aspiration Hazard Not available
12. ECOLOGICAL INFORMATION
12.1 Toxicity Not available
Acute toxicity Not available
Chronic toxicity Not available
Persistence: High persistency (log Kow is more than 4 estimated.)
12.2 Persistence and degradability Log Kow =17.04
Degradability: Not available
Bioaccumulation: Bioaccumulation is expected to be low
12.3 Bio-accumulative potential according to the BCF <500. (BCF = 3.162)
Biodegradation: Not available
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12.4 Mobility in soil Not available
12.5 Results of PBT and vPvB
Not available
assessment
12.6 Hazardous to the ozone layer Not applicable
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Waste disposal according to directive 2008/98/EC, covering waste and dangerous waste.
13.1.1 Product/Packaging disposal:
- No waste key number as per the European Waste Types List can be assigned to this product, since such
classification is based on the (as yet undetermined) use to which the product is put by the consumer.
- The waste key number must be determined as per the European Waste Types List (decision on EU Waste
Types List 2000/532/EC) in cooperation with the disposal firm/producing firm/official authority.
13.1.2 Waste treatment-relevant information:
Waste must be disposed of in accordance with directive 2008/98/EC.
13.1.3 Sewage disposal-relevant information:
Release to the environment or sewage system is prohibited. Must be treated as hazardous waste.
13.1.4 Other disposal recommendations: Not available
14. TRANSPORT INFORMATION
14.1 UN No.: Not applicable
14.2 UN Proper shipping name: Not applicable
14.3 Transport Hazard class
ADR: Not applicable
IMDG: Not applicable
ICAO/IATA: Not applicable
RID: Not applicable
14.4 Packing group: Not applicable
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user
in case of fire: Not applicable
in case of leakage: Not applicable
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulation/legislation specific for the substance or mixture
EU Regulatory Information
EU classification
EU 1272/2008(CLP)
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Classification: Not classified
Risk phrases: Not classified
Safety phrases: Not classified
EU SVHC list: Not regulated
EU Authorization list: Not regulated
EU Restriction list: Not regulated
Waste Framework Directive 2008/98/EC: Hazardous waste
Foreign Inventory Status
- Korea management information: Existing Chemical Substance (KE-28877)
- U.S.A management information: Section 8(b) Inventory (TSCA): Present
- China management information: Inventory of Existing Chemical Substances (IECSC): Present
(05721))
- Japan management information: Existing and New Chemical Substances (ENCS): Present ((6)-1)
- Canada management information: Domestic Substances List (DSL): Present
- Australia management information: Australian Inventory of Chemical Substances (AICS): Present
- New Zealand management information: New Zealand Inventory of Chemicals (NZIoC):
May be used as a single component chemical under an
appropriate
group standard.
- Philippines management information: Philippine Inventory of Chemicals and Chemical Substances
(PICCS): Present
15.2 Chemical safety assessment:
For this substance a chemical safety assessment has been carried out.
16. OTHER INFORMATION
Product safety data sheet for prepared in accordance with Regulation (EU) 1272/2008
16.1 Indication of changes:
Version: -
Revision date: -
16.2 Key literature reference and sources for data:
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans; http://monographs.iarc.fr
HSDB; http://toxnet.nlm.nih.gov/
NIOSH (The National Institute for Occupational Safety and Health)
ACGIH (American Conference of Governmental Industrial Hygienists)
TOMES-LOLI®; http://www.rightanswerknowledge.com/loginRA.asp○ National Emergency
Management Agency-Korea dangerous material inventory management system;
http://www.nema.go.kr/hazmat/main/main.jsp
Waste Control Act enforcement regulation attached [1]
National chemicals information systems; http://ncis.nier.go.kr
16.3 Abbreviations
EC50: median effective concentration
LC50: median lethal concentration
LD50: median lethal dose
OEL: Occupational exposure limit
PBT: Persistent, bio-accumulative, toxic chemical
STEL: short-term exposure limit
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TWA: time weighted average
vPvB: very Persistent, very Bio-accumulative chemical
EWC: European Waste Code
16.4 Other
- Product should be handled, stored, and used in accordance with the generally accepted industrial hygiene
practices and in conformity with all the applicable legal regulations.
- The information provided herein is based on the knowledge possessed at this present time from the view point
of
safety requirements.
- It should, therefore, not be construed as guaranteeing specific properties.
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