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Reagents HACH

This document provides a safety data sheet for a laboratory reagent called NitraVer 6 Nitrate Reagent. The reagent contains hazardous chemicals including cadmium and is toxic if inhaled, causes skin and eye irritation, and may cause cancer, genetic defects, and damage to organs. Appropriate personal protective equipment should be worn and the reagent should only be used in well ventilated areas or outdoors.

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Olesea Bolfosu
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0% found this document useful (0 votes)
58 views17 pages

Reagents HACH

This document provides a safety data sheet for a laboratory reagent called NitraVer 6 Nitrate Reagent. The reagent contains hazardous chemicals including cadmium and is toxic if inhaled, causes skin and eye irritation, and may cause cancer, genetic defects, and damage to organs. Appropriate personal protective equipment should be worn and the reagent should only be used in well ventilated areas or outdoors.

Uploaded by

Olesea Bolfosu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 17

SAFETY DATA SHEET

Issue Date 02-Jan-2020 Revision Date 02-Jan-2020 Version 5.3 Page 1 / 17

1. IDENTIFICATION
Product identifier
Product Name NitraVerÒ 6 Nitrate Reagent

Other means of identification


Product Code(s) 2107249

Safety data sheet number M00062

UN/ID no UN3077

Recommended use of the chemical and restrictions on use


Recommended Use Laboratory reagent. Determination of nitrate.
Uses advised against Consumer use.
Restrictions on use For Laboratory Use Only.

Details of the supplier of the safety data sheet

Manufacturer Address
Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050

Emergency telephone number


+1(303) 623-5716 - 24 Hour Service

2. HAZARDS IDENTIFICATION
Classification

Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute toxicity - Inhalation (Dusts/Mists) Category 4


Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Mutagenicity Category 2
Carcinogenicity Category 1B
Reproductive toxicity Category 2
Specific target organ toxicity (repeated exposure) Category 1
Aquatic Acute Toxicity Category 1
Chronic aquatic toxicity Category 1

Hazards not otherwise classified (HNOC)


Not applicable

Label elements

Signal word
Danger

EN / AGHS Page 1 / 17
Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
Issue Date 02-Jan-2020 Revision Date 02-Jan-2020
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Hazard statements
H315 - Causes skin irritation
H318 - Causes serious eye damage
H332 - Harmful if inhaled
H341 - Suspected of causing genetic defects
H350 - May cause cancer
H361 - Suspected of damaging fertility or the unborn child
H372 - Causes damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects

Precautionary statements
P271 - Use only outdoors or in a well-ventilated area
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P201 - Obtain special instructions before use
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P405 - Store locked up
P501 - Dispose of contents/ container to an approved waste disposal plant
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P270 - Do not eat, drink or smoke when using this product
P273 - Avoid release to the environment
P391 - Collect spillage

Other Hazards Known


May be harmful if swallowed

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable

Mixture

Chemical Family Mixture.


Chemical nature Mixture of inorganic salts, Mixture of inorganic compounds, Mixture of organic compounds.

Percent ranges are used where confidential product information is applicable.

Chemical name CAS No. Percent HMRIC #


Range
Sodium sulfate 7757-82-6 40 - 50% -
Glycine, N,N-1,2-cyclohexanediylbis[N-(carboxymethyl)-, trisodium salt 36679-96-6 20 - 30% -
Potassium pyrosulfate 7790-62-7 5 - 10% -
Cadmium 7440-43-9 1 - 5% -

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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Version 5.3 Page 3 / 17

Cuprate(2-), 19332-78-6 <1% -


[[N,N-1,2-cyclohexanediylbis[N-(carboxymethyl)glycinato]](4-)-N,N,O,O,O
N,ON]-, [OC-6-21-(trans)]-
2-Propenamide, homopolymer 9003-05-8 <0.1% -

4. FIRST AID MEASURES


Description of first aid measures

General advice Show this safety data sheet to the doctor in attendance. IF exposed or concerned: Get
medical advice/attention.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur. If breathing has
stopped, give artificial respiration. Get medical attention immediately. If symptoms persist,
call a physician.

Eye contact Get immediate medical advice/attention. Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.

Skin contact Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical
attention if irritation develops and persists.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Get medical attention.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination.

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Coughing and/ or wheezing. Difficulty in breathing.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.

Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.

Specific hazards arising from the No information available.


chemical

Hazardous combustion products Cadmium oxide. Phosphorus oxides. Sulfur oxides.

Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.

6. ACCIDENTAL RELEASE MEASURES


U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous
substances may respond to a spill according to federal regulations (OSHA 29 CFR
1910.120(a)(v)) and per your company's emergency response plan and

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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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guidelines/procedures. See Section 13, Special Instructions for disposal assistance.


Outside of the US, only persons properly qualified according to state or local regulations
should respond to a spill involving chemicals.

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid generation of dust.
Do not breathe dust.

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

Reference to other sections See section 8 for more information. See section 13 for more information.

7. HANDLING AND STORAGE


Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Remove
contaminated clothing and shoes. Ensure adequate ventilation. Take off contaminated
clothing and wash before reuse. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid
generation of dust.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.

Flammability class Not applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical name ACGIH TLV OSHA PEL NIOSH


Cadmium TWA: 0.01 mg/m3 TWA: 0.1 mg/m3 IDLH: 9 mg/m3 dust IDLH: 9
CAS#: 7440-43-9 TWA: 0.002 mg/m3 TWA: 0.2 mg/m3 mg/m3 Cd dust and fume
respirable particulate matter TWA: 5 µg/m3
TWA: 0.01 mg/m3 Cd (vacated) STEL: 0.3 ppm
TWA: 0.002 mg/m3 Cd Ceiling: 0.3 mg/m3
respirable particulate matter Ceiling: 0.6 mg/m3
Cuprate(2-), TWA: 1 mg/m3 Cu dust and NDF IDLH: 100 mg/m3 Cu dust and

EN / AGHS Page 4 / 17
Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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[[N,N-1,2-cyclohexanediylbis[N-(carbo mist mist


xymethyl)glycinato]](4-)-N,N,O,O,ON, TWA: 1 mg/m3 Cu dust and
ON]-, [OC-6-21-(trans)]- mist
CAS#: 19332-78-6
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems.

Individual protection measures, such as personal protective equipment


Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

Hand Protection Wear suitable gloves. Impervious gloves.

Eye/face protection Tight sealing safety goggles.

Skin and body protection Wear suitable protective clothing. Long sleeved clothing.

General Hygiene Considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Avoid breathing dust/fume/gas/mist/vapors/spray.

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not
allow into any sewer, on the ground or into any body of water.

Thermal hazards None under normal processing.

9. PHYSICAL AND CHEMICAL PROPERTIES


Information on basic physical and chemical properties

Physical state Solid


Appearance powder Color blue
metallic
Odor None Odor threshold Not applicable

Property Values Remarks • Method

Molecular weight Not applicable

pH 4.2 5% Solution

Melting point/freezing point No data available

Boiling point / boiling range No data available

Evaporation rate Not applicable

Vapor pressure Not applicable

Vapor density (air = 1) Not applicable

Specific gravity (water = 1 / air = 1) 2.377

Partition Coefficient (n-octanol/water) log Kow ~ -2.94

Soil Organic Carbon-Water Partition log Koc ~ -0.66


Coefficient
Autoignition temperature No data available

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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Decomposition temperature No data available

Dynamic viscosity Not applicable

Kinematic viscosity Not applicable

Solubility(ies)

Water solubility

Water solubility classification Water solubility Water Solubility Temperature


Slightly soluble > 0.1 mg/L 25 °C / 77 °F

Solubility in other solvents

Chemical Name Solubility classification Solubility Solubility Temperature


Acid Slightly soluble > 0.1 mg/L 25 °C / 77 °F

Other Information

Metal Corrosivity

Steel Corrosion Rate Not applicable


Aluminum Corrosion Rate Not applicable

Volatile Organic Compounds (VOC) Content


Not applicable

Chemical name CAS No. Volatile organic CAA (Clean Air Act)
compounds (VOC) content
Sodium sulfate 7757-82-6 No data available -
Glycine, 36679-96-6 No data available -
N,N-1,2-cyclohexanediylbis[N-(carbox
ymethyl)-, trisodium salt
Potassium pyrosulfate 7790-62-7 No data available -
Cadmium 7440-43-9 Not applicable -
Cuprate(2-), 19332-78-6 No data available -
[[N,N-1,2-cyclohexanediylbis[N-(carbo
xymethyl)glycinato]](4-)-N,N,O,O,ON,
ON]-, [OC-6-21-(trans)]-
2-Propenamide, homopolymer 9003-05-8 No data available -

Explosive properties

Upper explosion limit No data available


Lower explosion limit No data available

Flammable properties

Flash point Not applicable

Flammability Limit in Air


Upper flammability limit No data available
Lower flammability limit No data available

Oxidizing properties No data available.

EN / AGHS Page 6 / 17
Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Bulk density No data available

10. STABILITY AND REACTIVITY


Reactivity
Not applicable.

Chemical stability
Stable under normal conditions.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

Possibility of Hazardous Reactions


None under normal processing.

Hazardous polymerization
Hazardous polymerization does not occur.

Conditions to avoid
Excessive heat.

Incompatible materials
Strong acids. Strong bases. Strong oxidizing agents.

Hazardous Decomposition Products


Sulfur oxides. Phosphorus oxides. Cadmium oxide.

11. TOXICOLOGICAL INFORMATION


Information on Likely Routes of Exposure

Product Information

Inhalation May cause irritation of respiratory tract. Harmful by inhalation.

Eye contact Severely irritating to eyes. Causes serious eye damage. May cause burns. May cause
irreversible damage to eyes.

Skin contact Causes skin irritation.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Symptoms Redness. Burning. May cause blindness. May cause redness and tearing of the eyes.
Coughing and/ or wheezing.

Acute toxicity
Based on available data, the classification criteria are not met

Product Acute Toxicity Data


No data available.

Ingredient Acute Toxicity Data


No data available.

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and

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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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type dose time sources for data


Potassium Rat 2340 mg/kg None None reported Vendor SDS
pyrosulfate LD50 reported
(5 - 10%)
CAS#: 7790-62-7
Cadmium Rat 225 mg/kg None None reported ERMA (New Zealands
(1 - 5%) LD50 reported Environmental Risk
CAS#: 7440-43-9 Management Authority)
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium None None None None reported No information available
(1 - 5%) reported reported reported
CAS#: 7440-43-9
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Rat 0.0125 mg/L 4 hours None reported ERMA (New Zealands
(1 - 5%) LC50 Environmental Risk
CAS#: 7440-43-9 Management Authority)
Unknown Acute Toxicity
3.45% of the mixture consists of ingredient(s) of unknown toxicity.

Acute Toxicity Estimations (ATE)

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral) 3,961.00 mg/kg


ATEmix (dermal) No information available
ATEmix (inhalation-dust/mist) 1.45 mg/L
ATEmix (inhalation-vapor) No information available
ATEmix (inhalation-gas) No information available

Skin corrosion/irritation
Classification based on data available for ingredients. Irritating to skin.

Product Skin Corrosion/Irritation Data


No data available.

Ingredient Skin Corrosion/Irritation Data


No data available.

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sodium sulfate Standard Draize Rabbit 500 mg 4 hours Not corrosive or ECHA (The European
(40 - 50%) Test irritating to skin Chemicals Agency)
CAS#: 7757-82-6
Potassium None reported None None None Corrosive to skin Vendor SDS
pyrosulfate reported reported reported
(5 - 10%)
CAS#: 7790-62-7
Serious eye damage/irritation
Classification based on data available for ingredients. Causes burns. Risk of serious damage to eyes.

Product Serious Eye Damage/Eye Irritation Data


No data available.

Ingredient Eye Damage/Eye Irritation Data


No data available.

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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sodium sulfate Standard Draize Rabbit 90 mg 24 hours Not corrosive or ECHA (The European
(40 - 50%) Test irritating to eyes Chemicals Agency)
CAS#: 7757-82-6
Potassium None reported None None None Corrosive to eyes Vendor SDS
pyrosulfate reported reported reported
(5 - 10%)
CAS#: 7790-62-7
Respiratory or skin sensitization
Based on available data, the classification criteria are not met.

Product Sensitization Data


No data available.

Ingredient Sensitization Data


No data available.

Chemical name Test method Species Results Key literature references and
sources for data
Sodium sulfate OECD Test No. Guinea pig Not confirmed to be a skin sensitizer HSDB (Hazardous Substances Data
(40 - 50%) 406: Skin Bank)
CAS#: 7757-82-6 Sensitization
STOT - single exposure
Based on available data, the classification criteria are not met.

Product Specific Target Organ Toxicity Single Exposure Data


No data available.

Ingredient Specific Target Organ Toxicity Single Exposure Data


No data available.

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Rabbit 70 mg/kg None None reported RTECS (Registry of Toxic
(1 - 5%) TDLo reported Effects of Chemical
CAS#: 7440-43-9 Substances)
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Human 39 mg/m3 20 minutes Vascular RTECS (Registry of Toxic
(1 - 5%) LCLo Thromobosis distant from Effects of Chemical
CAS#: 7440-43-9 injection site Substances)
Lungs, Thorax, or
Respiration
Respiratory depression
STOT - repeated exposure
Causes damage to organs through prolonged or repeated exposure.

Product Specific Target Organ Toxicity Repeat Dose Data


No data available.

Ingredient Specific Target Organ Toxicity Repeat Exposure Data


No data available.

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Rat 37.5 mg/kg 30 days Biochemical RTECS (Registry of Toxic
(1 - 5%) TDLo Enzyme inhibition, induction, or Effects of Chemical
CAS#: 7440-43-9 change in blood or tissue levels Substances)

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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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(other enzymes)
Blood
Other changes
Kidney, Ureter, or Bladder
Other changes in urine
composition
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Man 0.000088 8.6 years Kidney, Ureter, or Bladder RTECS (Registry of Toxic
(1 - 5%) TDLo mg/L Proteinuria Effects of Chemical
CAS#: 7440-43-9 Substances)
Carcinogenicity
Classification based on data available for ingredients. Contains a known or suspected carcinogen.

Product Carcinogenicity Data


No data available.

Ingredient Carcinogenicity Data


No data available.

Chemical name CAS No. ACGIH IARC NTP OSHA


Sodium sulfate 7757-82-6 - - - -
Glycine, 36679-96-6 - - - -
N,N-1,2-cyclohexanediylbi
s[N-(carboxymethyl)-,
trisodium salt
Potassium pyrosulfate 7790-62-7 - - - -
Cadmium 7440-43-9 A2 Group 1 Known X
Cuprate(2-), 19332-78-6 - - - -
[[N,N-1,2-cyclohexanediylb
is[N-(carboxymethyl)glycin
ato]](4-)-N,N,O,O,ON,ON]-
, [OC-6-21-(trans)]-
2-Propenamide, 9003-05-8 - - - -
homopolymer

Legend

ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen


IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program) Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of X - Present
Labor)

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Human 0.129 mg/L 20 years Lungs, Thorax, or RTECS (Registry of Toxic
(1 - 5%) Respiration Effects of Chemical
CAS#: 7440-43-9 Tumors Substances)
Germ cell mutagenicity
Based on available data, the classification criteria are not met.

Product Germ Cell Mutagenicity invitro Data


No data available.

Ingredient Germ Cell Mutagenicity invitro Data


No data available.

Chemical name Test Cell Strain Reported Exposure Results Key literature

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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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dose time references and


sources for data
Cadmium DNA damage Human 0.25 mmol/L 1 hours Positive test result for RTECS (Registry
(1 - 5%) lymphocyte mutagenicity of Toxic Effects of
CAS#: 7440-43-9 Chemical
Substances)
Product Germ Cell Mutagenicity invivo Data
No data available.

Ingredient Germ Cell Mutagenicity invivo Data


No data available.

Reproductive toxicity
Classification based on data available for ingredients. Contains a known or suspected reproductive toxin. The table below indicates
ingredients above the cut-off threshold considered as relevant which are listed as reproductive toxins.

Product Reproductive Toxicity Data


No data available.

Ingredient Reproductive Toxicity Data


No data available.

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Sodium sulfate Mouse 14000 mg/kg 4 days Effects on Newborn RTECS (Registry of Toxic
(40 - 50%) TDLo Other neonatal measures or Effects of Chemical
CAS#: 7757-82-6 effects Substances)
Cadmium Rat 23 mg/kg 22 days Specific Developmental RTECS (Registry of Toxic
(1 - 5%) TDLo Abnormalities Effects of Chemical
CAS#: 7440-43-9 Blood and lymphatic systems Substances)
(including spleen and marrow)
Aspiration hazard
Based on available data, the classification criteria are not met.

12. ECOLOGICAL INFORMATION

This product contains a chemical which is listed as a severe marine pollutant according to DOT.

Ecotoxicity Very toxic to aquatic life with long lasting effects.

Unknown aquatic toxicity 0% of the mixture consists of components(s) of unknown hazards to the aquatic
environment.

Product Ecological Data

Aquatic Acute Toxicity


No data available.

Aquatic Chronic Toxicity


No data available.

Ingredient Ecological Data

Aquatic Acute Toxicity


No data available.

Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Sodium sulfate 96 hours None reported LC50 56 mg/L IUCLID (The International
(40 - 50%) Uniform Chemical Information

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CAS#: 7757-82-6 Database)


Glycine, 96 hours None reported LC50 356000 mg/L Estimation through ECOSARS
N,N-1,2-cyclohexane v1.11 part of the Estimation
diylbis[N-(carboxymet Programs Interface (EPI) SuiteÔ
hyl)-, trisodium salt
(20 - 30%)
CAS#: 36679-96-6
Potassium 96 hours Oncorhynchus mykiss LC50 420 mg/L ERMA (New Zealands
pyrosulfate Environmental Risk Management
(5 - 10%) Authority)
CAS#: 7790-62-7
Cadmium 96 hours Morone saxatilis LC50 0.019 mg/L PEEN (Pan European Ecological
(1 - 5%) Network)
CAS#: 7440-43-9
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Sodium sulfate 48 Hours Daphnia magna EC50 3150 mg/L IUCLID (The International
(40 - 50%) Uniform Chemical Information
CAS#: 7757-82-6 Database)
Glycine, 48 Hours None reported EC50 26162 mg/L Estimation through ECOSARS
N,N-1,2-cyclohexane v1.11 part of the Estimation
diylbis[N-(carboxymet Programs Interface (EPI) SuiteÔ
hyl)-, trisodium salt
(20 - 30%)
CAS#: 36679-96-6
Potassium 48 Hours Daphnia magna EC50 140 mg/L ERMA (New Zealands
pyrosulfate Environmental Risk Management
(5 - 10%) Authority)
CAS#: 7790-62-7
Cadmium 48 Hours None reported EC50 0.58 mg/L PEEN (Pan European Ecological
(1 - 5%) Network)
CAS#: 7440-43-9
2-Propenamide, 48 Hours Daphnia pulex LC50 0.08 mg/L CEPA (Canadian Environmental
homopolymer Protection Agency)
(<0.1%)
CAS#: 9003-05-8
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Glycine, 96 hours None reported EC50 56103 mg/L Estimation through ECOSARS
N,N-1,2-cyclohexane v1.11 part of the Estimation
diylbis[N-(carboxymet Programs Interface (EPI) SuiteÔ
hyl)-, trisodium salt
(20 - 30%)
CAS#: 36679-96-6
Cadmium 72 Hours None reported EC50 0.132 mg/L PEEN (Pan European Ecological
(1 - 5%) Network)
CAS#: 7440-43-9
Aquatic Chronic Toxicity
No data available.

Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Cadmium 7 days Epinephelus coioides NOEC 0.03333 mg/L ECHA (The European Chemicals
(1 - 5%) Agency)
CAS#: 7440-43-9
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Cadmium 21 days Ctenodrilus serratus NOEC 0.001 mg/L ECHA (The European Chemicals
(1 - 5%) Agency)

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CAS#: 7440-43-9
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Cadmium 3 days Chaetoceros compressum EC10 0.00183 mg/L ECHA (The European Chemicals
(1 - 5%) Agency)
CAS#: 7440-43-9
Persistence and degradability

Product Biodegradability Data


No data available.

Bioaccumulation

Product Bioaccumulation Data


No data available.

Partition Coefficient (n-octanol/water) log Kow ~ -2.94

Mobility

Soil Organic Carbon-Water Partition Coefficient log Koc ~ -0.66

Other adverse effects


Contains a substance with an endocrine-disrupting potential.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.

Contaminated packaging Do not reuse empty containers.

US EPA Waste Number D006

Chemical name RCRA RCRA - Basis for RCRA - D Series RCRA - U Series
Listing Wastes Wastes
Cadmium - Included in waste 1.0 mg/L regulatory level -
7440-43-9 streams: F006, F039,
K061, K069, K100

Special instructions for disposal Dispose of material in an E.P.A. approved hazardous waste facility.

14. TRANSPORT INFORMATION


DOT
UN/ID no UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
DOT Technical Name Cadmium
Hazard Class 9
Packing Group III
Reportable Quantity (RQ) Cadmium: RQ kg= 131.59
Marine pollutant This product contains a chemical which is listed as a severe marine pollutant according to
DOT.
Emergency Response Guide 171
Number

EN / AGHS Page 13 / 17
Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
Issue Date 02-Jan-2020 Revision Date 02-Jan-2020
Version 5.3 Page 14 / 17

TDG
UN/ID no UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
TDG Technical Name Cadmium
Hazard Class 9
Packing Group III
Marine pollutant This product contains a chemical which is listed as a severe marine pollutant according to
TDG.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Cadmium), 9, III

IATA
UN/ID no UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
IATA Technical Name Cadmium
Hazard Class 9
Packing Group III
ERG Code 9L
Special precautions for user A158, A179, A97

IMDG
UN/ID no UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
IMDG Technical Name Cadmium
Hazard Class 9
Packing Group III
EmS-No F-A, S-F
Special precautions for user 274, 335, 966, 967
Marine pollutant This material meets the definition of a marine pollutant

Note: No special precautions necessary.

Additional information
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.

15. REGULATORY INFORMATION


National Inventories
TSCA Complies
DSL/NDSL Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

International Inventories
EINECS/ELINCS Does not comply
ENCS Does not comply
IECSC Complies
KECL Complies
PICCS Does not comply
TCSI Complies
AICS Complies
NZIoC Does not comply

EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances

EN / AGHS Page 14 / 17
Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
Issue Date 02-Jan-2020 Revision Date 02-Jan-2020
Version 5.3 Page 15 / 17

IECSC - China Inventory of Existing Chemical Substances


KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical name SARA 313 - Threshold Values %


Cadmium (CAS #: 7440-43-9) 0.1
Cuprate(2-), 1.0
[[N,N-1,2-cyclohexanediylbis[N-(carboxymethyl)glycinato]](4-)-N,
N,O,O,ON,ON]-, [OC-6-21-(trans)]- (CAS #: 19332-78-6)
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)


This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

Chemical name CWA - Reportable CWA - Toxic Pollutants CWA - Priority CWA - Hazardous
Quantities Pollutants Substances
Cadmium - X X -
7440-43-9
Cuprate(2-), - X - -
[[N,N-1,2-cyclohexanediyl
bis[N-(carboxymethyl)gly
cinato]](4-)-N,N,O,O,ON,
ON]-, [OC-6-21-(trans)]-
19332-78-6
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material

Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)


Cadmium 10 lb - RQ 10 lb final RQ
7440-43-9 RQ 4.54 kg final RQ
US State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals

Chemical name California Proposition 65


Cadmium (CAS #: 7440-43-9) Carcinogen
Developmental
Male Reproductive

WARNING: This product can expose you to chemicals including Cadmium, which is known to the State of California to

EN / AGHS Page 15 / 17
Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
Issue Date 02-Jan-2020 Revision Date 02-Jan-2020
Version 5.3 Page 16 / 17

cause cancer and birth defects or other reproductive harm.


For more information, go to http://www.P65Warnings.ca.gov

IMERC: Not applicable

U.S. State Right-to-Know Regulations

This product does not contain any substances regulated by state right-to-know regulations.

Chemical name New Jersey Massachusetts Pennsylvania


Sodium sulfate - X X
7757-82-6
Cadmium X X X
7440-43-9
Cuprate(2-), X - X
[[N,N-1,2-cyclohexanediylbis[N-(
carboxymethyl)glycinato]](4-)-N,
N,O,O,ON,ON]-,
[OC-6-21-(trans)]-
19332-78-6
U.S. EPA Label Information

Chemical name FIFRA FDA


Sodium sulfate - 21 CFR 186.1797

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION


Special Comments
None

Additional information

Global Automotive Declarable Substance List (GADSL)

Chemical name Global Automotive Declarable Global Automotive Declarable


Substance List Classifications Substance List Thersholds
Cadmium Declarable Substance (LR) 0%
7440-43-9 Prohibited Substance (LR) 0.01 % 0.1 %
NFPA and HMIS Classifications

NFPA Health hazards - 3 Flammability - 0 Instability - 0 Physical and chemical


properties -
HMIS Health hazards - 3 Flammability - 0 Physical hazards - 0 Personal protection -
-* X

Key or legend to abbreviations and acronyms used in the safety data sheet

NIOSH IDLH Immediately Dangerous to Life or Health


ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)
NDF no data

Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)

MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value

EN / AGHS Page 16 / 17
Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
Issue Date 02-Jan-2020 Revision Date 02-Jan-2020
Version 5.3 Page 17 / 17

X Listed Vacated These values have no official status. The only


binding levels of contaminants are those
listed in the final OSHA PEL. These lists are
for reference purposes only. Please note that
some reference state regulations of these
"liberated" exposure limits in their state
regulations.

SKN* Skin designation SKN+ Skin sensitization


RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen

Prepared By Hach Product Compliance Department

Issue Date 02-Jan-2020

Revision Date 02-Jan-2020

Revision Note SDS sections updated


2

Disclaimer

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO


WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.

Ó2019
HACH COMPANYÓ

End of Safety Data Sheet

EN / AGHS Page 17 / 17

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