Reagents HACH
Reagents HACH
1. IDENTIFICATION
Product identifier
Product Name NitraVerÒ 6 Nitrate Reagent
UN/ID no UN3077
Manufacturer Address
Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050
2. HAZARDS IDENTIFICATION
Classification
Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
Signal word
Danger
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Hazard statements
H315 - Causes skin irritation
H318 - Causes serious eye damage
H332 - Harmful if inhaled
H341 - Suspected of causing genetic defects
H350 - May cause cancer
H361 - Suspected of damaging fertility or the unborn child
H372 - Causes damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements
P271 - Use only outdoors or in a well-ventilated area
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P201 - Obtain special instructions before use
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P405 - Store locked up
P501 - Dispose of contents/ container to an approved waste disposal plant
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P270 - Do not eat, drink or smoke when using this product
P273 - Avoid release to the environment
P391 - Collect spillage
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable
Mixture
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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General advice Show this safety data sheet to the doctor in attendance. IF exposed or concerned: Get
medical advice/attention.
Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur. If breathing has
stopped, give artificial respiration. Get medical attention immediately. If symptoms persist,
call a physician.
Eye contact Get immediate medical advice/attention. Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.
Skin contact Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical
attention if irritation develops and persists.
Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Get medical attention.
Self-protection of the first aider Avoid contact with skin, eyes or clothing. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid generation of dust.
Do not breathe dust.
Environmental precautions
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Reference to other sections See section 8 for more information. See section 13 for more information.
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Remove
contaminated clothing and shoes. Ensure adequate ventilation. Take off contaminated
clothing and wash before reuse. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid
generation of dust.
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.
Control parameters
Exposure Guidelines
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Skin and body protection Wear suitable protective clothing. Long sleeved clothing.
General Hygiene Considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Wash hands before breaks and
immediately after handling the product. Avoid breathing dust/fume/gas/mist/vapors/spray.
Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not
allow into any sewer, on the ground or into any body of water.
pH 4.2 5% Solution
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Solubility(ies)
Water solubility
Other Information
Metal Corrosivity
Chemical name CAS No. Volatile organic CAA (Clean Air Act)
compounds (VOC) content
Sodium sulfate 7757-82-6 No data available -
Glycine, 36679-96-6 No data available -
N,N-1,2-cyclohexanediylbis[N-(carbox
ymethyl)-, trisodium salt
Potassium pyrosulfate 7790-62-7 No data available -
Cadmium 7440-43-9 Not applicable -
Cuprate(2-), 19332-78-6 No data available -
[[N,N-1,2-cyclohexanediylbis[N-(carbo
xymethyl)glycinato]](4-)-N,N,O,O,ON,
ON]-, [OC-6-21-(trans)]-
2-Propenamide, homopolymer 9003-05-8 No data available -
Explosive properties
Flammable properties
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Chemical stability
Stable under normal conditions.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Hazardous polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Excessive heat.
Incompatible materials
Strong acids. Strong bases. Strong oxidizing agents.
Product Information
Eye contact Severely irritating to eyes. Causes serious eye damage. May cause burns. May cause
irreversible damage to eyes.
Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Symptoms Redness. Burning. May cause blindness. May cause redness and tearing of the eyes.
Coughing and/ or wheezing.
Acute toxicity
Based on available data, the classification criteria are not met
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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The following values are calculated based on chapter 3.1 of the GHS document
Skin corrosion/irritation
Classification based on data available for ingredients. Irritating to skin.
Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sodium sulfate Standard Draize Rabbit 500 mg 4 hours Not corrosive or ECHA (The European
(40 - 50%) Test irritating to skin Chemicals Agency)
CAS#: 7757-82-6
Potassium None reported None None None Corrosive to skin Vendor SDS
pyrosulfate reported reported reported
(5 - 10%)
CAS#: 7790-62-7
Serious eye damage/irritation
Classification based on data available for ingredients. Causes burns. Risk of serious damage to eyes.
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Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sodium sulfate Standard Draize Rabbit 90 mg 24 hours Not corrosive or ECHA (The European
(40 - 50%) Test irritating to eyes Chemicals Agency)
CAS#: 7757-82-6
Potassium None reported None None None Corrosive to eyes Vendor SDS
pyrosulfate reported reported reported
(5 - 10%)
CAS#: 7790-62-7
Respiratory or skin sensitization
Based on available data, the classification criteria are not met.
Chemical name Test method Species Results Key literature references and
sources for data
Sodium sulfate OECD Test No. Guinea pig Not confirmed to be a skin sensitizer HSDB (Hazardous Substances Data
(40 - 50%) 406: Skin Bank)
CAS#: 7757-82-6 Sensitization
STOT - single exposure
Based on available data, the classification criteria are not met.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Rabbit 70 mg/kg None None reported RTECS (Registry of Toxic
(1 - 5%) TDLo reported Effects of Chemical
CAS#: 7440-43-9 Substances)
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Human 39 mg/m3 20 minutes Vascular RTECS (Registry of Toxic
(1 - 5%) LCLo Thromobosis distant from Effects of Chemical
CAS#: 7440-43-9 injection site Substances)
Lungs, Thorax, or
Respiration
Respiratory depression
STOT - repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Rat 37.5 mg/kg 30 days Biochemical RTECS (Registry of Toxic
(1 - 5%) TDLo Enzyme inhibition, induction, or Effects of Chemical
CAS#: 7440-43-9 change in blood or tissue levels Substances)
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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(other enzymes)
Blood
Other changes
Kidney, Ureter, or Bladder
Other changes in urine
composition
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Man 0.000088 8.6 years Kidney, Ureter, or Bladder RTECS (Registry of Toxic
(1 - 5%) TDLo mg/L Proteinuria Effects of Chemical
CAS#: 7440-43-9 Substances)
Carcinogenicity
Classification based on data available for ingredients. Contains a known or suspected carcinogen.
Legend
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Cadmium Human 0.129 mg/L 20 years Lungs, Thorax, or RTECS (Registry of Toxic
(1 - 5%) Respiration Effects of Chemical
CAS#: 7440-43-9 Tumors Substances)
Germ cell mutagenicity
Based on available data, the classification criteria are not met.
Chemical name Test Cell Strain Reported Exposure Results Key literature
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Reproductive toxicity
Classification based on data available for ingredients. Contains a known or suspected reproductive toxin. The table below indicates
ingredients above the cut-off threshold considered as relevant which are listed as reproductive toxins.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Sodium sulfate Mouse 14000 mg/kg 4 days Effects on Newborn RTECS (Registry of Toxic
(40 - 50%) TDLo Other neonatal measures or Effects of Chemical
CAS#: 7757-82-6 effects Substances)
Cadmium Rat 23 mg/kg 22 days Specific Developmental RTECS (Registry of Toxic
(1 - 5%) TDLo Abnormalities Effects of Chemical
CAS#: 7440-43-9 Blood and lymphatic systems Substances)
(including spleen and marrow)
Aspiration hazard
Based on available data, the classification criteria are not met.
This product contains a chemical which is listed as a severe marine pollutant according to DOT.
Unknown aquatic toxicity 0% of the mixture consists of components(s) of unknown hazards to the aquatic
environment.
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Sodium sulfate 96 hours None reported LC50 56 mg/L IUCLID (The International
(40 - 50%) Uniform Chemical Information
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Cadmium 7 days Epinephelus coioides NOEC 0.03333 mg/L ECHA (The European Chemicals
(1 - 5%) Agency)
CAS#: 7440-43-9
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Cadmium 21 days Ctenodrilus serratus NOEC 0.001 mg/L ECHA (The European Chemicals
(1 - 5%) Agency)
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CAS#: 7440-43-9
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Cadmium 3 days Chaetoceros compressum EC10 0.00183 mg/L ECHA (The European Chemicals
(1 - 5%) Agency)
CAS#: 7440-43-9
Persistence and degradability
Bioaccumulation
Mobility
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.
Chemical name RCRA RCRA - Basis for RCRA - D Series RCRA - U Series
Listing Wastes Wastes
Cadmium - Included in waste 1.0 mg/L regulatory level -
7440-43-9 streams: F006, F039,
K061, K069, K100
Special instructions for disposal Dispose of material in an E.P.A. approved hazardous waste facility.
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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TDG
UN/ID no UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
TDG Technical Name Cadmium
Hazard Class 9
Packing Group III
Marine pollutant This product contains a chemical which is listed as a severe marine pollutant according to
TDG.
Description UN3077, Environmentally hazardous substance, solid, n.o.s. (Cadmium), 9, III
IATA
UN/ID no UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
IATA Technical Name Cadmium
Hazard Class 9
Packing Group III
ERG Code 9L
Special precautions for user A158, A179, A97
IMDG
UN/ID no UN3077
Proper shipping name Environmentally hazardous substance, solid, n.o.s.
IMDG Technical Name Cadmium
Hazard Class 9
Packing Group III
EmS-No F-A, S-F
Special precautions for user 274, 335, 966, 967
Marine pollutant This material meets the definition of a marine pollutant
Additional information
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
International Inventories
EINECS/ELINCS Does not comply
ENCS Does not comply
IECSC Complies
KECL Complies
PICCS Does not comply
TCSI Complies
AICS Complies
NZIoC Does not comply
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
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US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical name CWA - Reportable CWA - Toxic Pollutants CWA - Priority CWA - Hazardous
Quantities Pollutants Substances
Cadmium - X X -
7440-43-9
Cuprate(2-), - X - -
[[N,N-1,2-cyclohexanediyl
bis[N-(carboxymethyl)gly
cinato]](4-)-N,N,O,O,ON,
ON]-, [OC-6-21-(trans)]-
19332-78-6
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
California Proposition 65
This product contains the following Proposition 65 chemicals
WARNING: This product can expose you to chemicals including Cadmium, which is known to the State of California to
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Product Code(s) 2107249 Product Name NitraVerÒ 6 Nitrate Reagent
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This product does not contain any substances regulated by state right-to-know regulations.
Additional information
Key or legend to abbreviations and acronyms used in the safety data sheet
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
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Disclaimer
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.
Ó2019
HACH COMPANYÓ
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