Safety data sheet

Issue Date 11-Aug-2020 Revision Date 10-Aug-2020 Version 2

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
Product identifier
Product Name
Polyol 3611
Chemical Name CAS No
Propylidynetrimethanol, ethoxylated 50586-59-9

Other means of identification

Pure substance/mixture Substance

Recommended use of the chemical and restrictions on use

Application Manufacture of substances. Industrial manufacturing. Distribution and storage.
Formulations. Use: in flexible foam, in rigid foam, in coatings, in adhesives, in sealants,
in elastomers, in polyamide, in polyimide, in synthetic fibres, in foundry, in thermoplastic
polyurethane, in composite materials based on wood, minerals or natural fibres, in other
composite materials

Uses advised against Not identified.

Details of the supplier of the safety data sheet

E-mail address productinfo@perstorp.com

Emergency telephone number

Europe (+)1 760 476 3961 (contract no: 334101)
Americas (+)1 760 476 3962 (contract no: 334101)
Middle East and Africa (+)1 760 476 3959 (contact no: 334101)
Asia Pacific (+)1 760 476 3960 (contract no: 334101)

2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS).

Label elements
Symbols/Pictograms
Not applicable

Signal word
Not applicable

Hazard statements
Not applicable

Precautionary statements
Not applicable

Other hazards
Note the risk of burn injuries if the product is handled heated.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical Name CAS No Weight-%
Propylidynetrimethanol, ethoxylated 50586-59-9 >98
Propylidynetrimethanol 77-99-6 <1

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4. FIRST AID MEASURES

Description of first aid measures
Inhalation First aid measures not required, but get fresh air for personal comfort.

Skin contact In contact with molten product immediately flush with cold water for at least 10 minutes.
Do not pull solidified product off the skin. In case of burn injury immediately get medical
attention.

Eye contact In contact with molten product immediately flush with tempered water for at least 15
minutes. In case of injury immediately get medical attention.

Ingestion If a large quantity has been ingested or if you feel unwell, get medical advice/attention.

Most important symptoms and effects, both acute and delayed

None known.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
All types of extinguishing media are suitable. Use fire extinguishing methods suitable to surrounding conditions.

Unsuitable extinguishing media

High volume water jet.

Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating and toxic
gases and vapors; Carbon monoxide (CO). Carbon dioxide (CO2).

Protective equipment and precautions for firefighters

In the event of fire, wear self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear safety glasses, gloves, protective clothing and rubber boots for hygienic reasons.

Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. See Section 12 for additional ecological information.

Methods and material for containment and cleaning up

Methods for containment

Small spill Cover liquid spill with sand, earth or other noncombustible absorbent material
Large spill Pump up the product into a spare container suitably labelled.

Methods for cleaning up

Take up mechanically, placing in appropriate containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling
Wear personal protective equipment according to section 8 if risk of exposure.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wash

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contaminated clothing before reuse.

Conditions for safe storage, including any incompatibilities

Keep tightly closed in a dry and cool place. Avoid contact with water or humidity. The product is; Hygroscopic.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Users are advised to consider national Occupational Exposure Limits or other equivalent values, (if existing).

Chemical Name Argentina Russia Egypt

Propylidynetrimethanol Not available MAC: 50 mg/m3 Not available
77-99-6

Appropriate engineering controls

None under normal use conditions.

Individual protection measures, such as personal protective equipment

Eye/face protection If handled where risk of splashes may occur, use safety goggles.
Hand Protection Protective gloves not really required. However, we recommend using protective gloves
made of rubber. Butyl rubber. Chloroprene rubber, CR. Nitrile rubber, NBR.
Skin and body protection Normal work clothes for the chemical industry (long-legged pants and sleeves).
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Physical state liquid
Color colorless
Odor Slight
Odor threshold No information available

Property Value Remarks • Method

pH 5-8
Melting point / freezing point <-20 °C
Boiling point / boiling range - Decomposes, OECD Test No. 103: Boiling Point
Flash point >200 °C Regulation (EC) No. 440/2008, Annex, A.9
Evaporation rate No information available
Flammability (solid, gas) Not applicable
Explosive limits
Upper explosive limits Not applicable
Lower explosive limits Not applicable
Vapor pressure 0.000000264 kPa (@20°C; OECD 104)
Vapor density No information available
Relative density No information available
Water solubility 28 g/L @ 20 °C OECD Test No. 105: Water Solubility
Solubility(ies) No information available
Partition coefficient 1.3 log POW (@25°C) OECD Test No. 117: Partition
Coefficient (n-octanol/water), HPLC Method
Autoignition temperature 370 °C Regulation (EC) No. 440/2008, Annex, A.15
Decomposition temperature 206 °C
Kinematic viscosity No information available
Dynamic viscosity 700 mPa s @ 23 °C
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
Density 1.12 g/cm 3 @ 20 °C, OECD Test No. 109: Density of Liquids
and Solids
Bulk density No information available

Other Information
No information available

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10. STABILITY AND REACTIVITY

Reactivity
There exists no specific test data for this product. For further information, see the subsequent subsections of this chapter.

Chemical stability
The product is stable at normal conditions.

Possibility of Hazardous Reactions

None known.

Conditions to avoid
None known.

Incompatible materials
None known.

Hazardous decomposition products

Thermal decomposition can lead to release of irritating and toxic gases and vapors; Carbon monoxide (CO). Carbon dioxide
(CO2).

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure
Dermal. Inhalation.

Symptoms related to the physical, chemical and toxicological characteristics

None known.

Numerical measures of toxicity

Acute toxicity
Product does not present an acute toxicity hazard based on known or supplied information

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Exposure route Effective dose Remarks
OECD Test No. 423: Acute Rat females Oral >2000 LD50 (lethal dose)
Oral toxicity - Acute Toxic mg/kg
Class Method
OECD Test No. 401: Acute Rat Oral >5000 LD50 (lethal dose)
Oral Toxicity mg/kg
OECD Test No. 402: Acute Rat Dermal >2000 LD50 (lethal dose)
Dermal Toxicity mg/kg

Skin corrosion/irritation
Non-irritating to the skin.

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Exposure route Results:
OECD Test No. 404: Acute Dermal rabbit Dermal Non-irritating to the skin
Irritation/Corrosion

Serious eye damage/eye irritation

Slightly irritating but not relevant for classification.

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Exposure route Results:
OECD Test No. 405: Acute Eye rabbit Eye Non-irritant
Irritation/Corrosion

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Respiratory or skin sensitization

Not a skin sensitizer.

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Exposure route Results:
OECD Test No. 429: Skin Mouse Skin Not a skin sensitizer
Sensitization: Local Lymph Node
Assay

Germ cell mutagenicity

Not mutagenic.

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Results:
OECD Test No. 473: In vitro Mammalian in vitro The substance is not clastogenic.
Chromosome Aberration Test Mammalian Chromosomal Aberration
Test
OECD Test No. 476: In vitro Mammalian Cell in vitro Not mutagenic
Gene Mutation Test
OECD Test No. 471: Bacterial Reverse in vitro Not mutagenic read-across from
Mutation Test supporting substance (structural
analogue)

Carcinogenicity
There is no indication for any carcinogenic potential since all in vitro mutagenicity studies are negative.

Reproductive toxicity
Product is or contains a chemical which is a known or suspected reproductive hazard

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Exposure route Effective dose Remarks
OECD Test No. 421: Rat Oral 1000 NOAEL mg/kg bw/day
Reproduction/Developmental
Toxicity Screening Test

STOT - single exposure No known effect

STOT - repeated exposure The available data indicate that the product is of low toxicity and is not classified for
repeated dose effects.

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Exposure route Effective dose Remarks
OECD Test No. 407: Rat Oral 1000 NOAEL mg/kg bw/day
Repeated Dose 28-day Oral
Toxicity Study in Rodents

Aspiration hazard
No hazard identified.

12. ECOLOGICAL INFORMATION

Toxicity
Low toxicity to aquatic organisms.

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Species Exposure route Effective dose Exposure time Remarks
OECD Test No. 203: Fish, Brachydanio rerio Freshwater >=1000 96h LC50 (lethal
Acute Toxicity Test concentration) mg/l

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OECD Test No. 202: Daphnia magna Freshwater >100000 48h EC50 (effective
Daphnia sp. Acute concentration) mg/l
Immobilization Test
OECD Test No. 201: Scenedesmus Freshwater >1000 72h EC50 (effective
Freshwater Alga and subspicatus concentration) mg/l
Cyanobacteria, Growth
Inhibition Test
OECD Test No. 202: Daphnia magna Freshwater >=10 21d EC50 (effective
Daphnia sp. Acute concentration) mg/l
Immobilization Test

Persistence and degradability

Not readily biodegradable.

Propylidynetrimethanol, ethoxylated (50586-59-9)

Method Value Exposure time Results:
OECD Test No. 302C: Inherent 34% 27d Not inherently biodegradable
Biodegradability: Modified MITI Test
(II)
OECD Test No. 301F: Ready 30.3% 28d Not readily biodegradable
Biodegradability: Manometric
Respirometry Test (TG 301 F)
OECD Test No. 301A: Ready 39% 28d Not readily biodegradable
Biodegradability: DOC Die-Away
Test (TG 301 A)

Bioaccumulative potential
Not likely to bioaccumulate.

Chemical Name Partition coefficient Bioconcentration factor (BCF)

Propylidynetrimethanol, ethoxylated -0,3
Propylidynetrimethanol -0.8

Mobility in soil
The product is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Pow.

Other adverse effects

None known.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues/unused products
Disposal should be in accordance with applicable regional, national and local laws and regulations

Contaminated packaging
Thoroughly emptied and clean packaging may be recycled.

14. TRANSPORT INFORMATION

ADR Road transport Not regulated

RID Rail transport Not regulated

IMDG Sea transport Not regulated

Transport in bulk according to No information available
Annex II of MARPOL 73/78 and

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the IBC Code

IATA Air transport Not regulated

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
International Regulations
Not applicable.

National Regulations

Argentina
Not applicable

Egypt
Not applicable

Malaysia
Not applicable

Russia
See section 8 for national exposure control parameters.

Singapore
Not applicable

Thailand
Not applicable

Other regulations, restrictions and prohibition regulations

Not applicable

16. OTHER INFORMATION

Key or legend to abbreviations and acronyms used in the safety data sheet
Not applicable

Issue Date 11-Aug-2020

Revision Date 10-Aug-2020

Revision Note SDS sections updated: 2, 3, 8, 11, 12, 15.

This safety data sheet complies with the requirements of: Globally Harmonized System (GHS).

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.
The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

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