Chapter - 4 PDF
Chapter - 4 PDF
Chapter - 4 PDF
Module-IV Lecture
1
Concepts of Electrical measurements
General Introduction:
Electrical property of the materials is one of the most important properties, which helps to
classify the materials. For instance, solids may be classified in terms of their resistivity or
conductivity as conductors, semiconductors or insulators.
Ohm's law: If physical conditions such as temperature, stress, strain remains unchanged in
the materials, then potential difference (V) across two ends of a conductor is proportional
to current (I) flowing through a conductor, i.e.,
V ∝ I (or)
V=IR
The constant of proportionality, R, is called resistance of the material.
⮚ Conductivity also depends on physical structure. In crystals, the crystal type and orientation
affect conductivity because the electronic structure is intimately tied to the crystal structure.
The size of the crystallites (grains) in polycrystalline materials is also important as it affects the
scattering of carriers, and, at very small sizes may also affect electronic structure.
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21PYB102J Unit IV Lecture-37
Concepts of Electrical measurements
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21PYB102J Unit IV Lecture-37
I-V Characteristics in a Diode
Resistivity is important for devices because it contributes to the device series resistance,
capacitance, threshold voltage, hot carrier degradation of MOS devices, latch up of CMOS
circuits, and other parameters. The wafers resistivity is usually modified locally during device
processing by diffusion and ion implantation.
Two general methods involved for measuring the resistance of the materials are:
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21PYB102J Unit IV Lecture-37
Two-probe method:
In general, we use a multimeter for measuring the resistance of the materials. The typical
range of resistance measured using the multimeter is 1 Ω to 2 MΩ, but varies with the models
and company.
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21PYB102J Unit IV Lecture-37
While the two-probe method is a simple and advantageous method for measuring
resistance above 1Ω directly, this method suffers from certain issues.
Two-probe method:
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21PYB102J Unit IV Lecture-37
DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
21PYB102J –Semiconductor Physics and Computational Methods
Unit -IV
Lecture-38
where probe spacing is uniform. Due to the superposition of current at outer tips, R = V / (2I ).
Therefore,
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21PYB102J Unit IV Lecture-38
Four-probe method: For Thin sheet:
For a very thin layer as shown in Figure, where the thickness of the sheet t << the space
between the probes, s, we can get current rings instead of spheres. Therefore, the
expression for the area is A = 2πx.t. Therefore, the derivation for resistance turns out to be:
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21PYB102J Unit IV Lecture-38
van der Pauw method
⮚ The van der Pauw method is a technique commonly used to measure the resistivity and the
Hall coefficient of a sample. There are five conditions that must be satisfied to use this
technique:
⮚ The sample must have a flat shape of uniform thickness. The sample must not have any
isolated holes. The sample must be homogeneous and isotropic.
⮚ All four contacts must be located at the edges of the sample. The area of contact of any
individual contact should be at least an order of magnitude smaller than the area of the
entire sample.
⮚ In order to use the van der Pauw method, the sample thickness must be much less than
the width and length of the sample. In order to reduce errors in the calculations, it is
preferable that the sample be symmetrical. There must also be no isolated holes within the
sample.
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21PYB102J Unit IV Lecture-38
The resistivity can be derived from a total of eight measurements that are made
around the periphery of the sample with the configurations shown in Figure.
RB
RA RB
where: ρA and ρB are volume resistivity in ohm-cm; ts is the sample thickness in cm; V1–V8
represents the voltages measured by the voltmeter; I is the current through the sample in
amperes; fA and fB are geometrical factors based on sample symmetry. They are related to the two
resistance ratios QA and QB as shown in the following equations (fA = fB = 1 for perfect symmetry).
Four point probe is preferred than two-point probe as the contact and spreading
resistances in two point probe are large and the true resistivity cannot be actually
separated from measured resistivity. In the four probe method, contact and
spreading resistances are very low with voltage probes and hence accuracy in
measurement is usually very high. To measure very low resistance values, four probe
method is used. The resistance of probe will be not be added to that of sample being
tested. It uses two wires to inject current in the resistance and another two wires to
measure the drop against the resistance.
HALL EFFECT
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Definition
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Explanation:
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Case – I If the Material is N-type Semi- Conductor (or) Metal
• If the strip is made up of metal or N-type semiconductor, the charge carriers in the strip
will be electrons.
•As conventional current flows along OX, the electrons must be moving along XO. If the
velocity of the electrons is ‘v’ and charge of the electrons is ‘-e’, the force on the
•F= - Bev, which acts along OZ. This causes the electrons to be deflected and so the
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21PYB102J Module-IV Lecture-3
• Thus, face ABEF will become negative and the face OCDG becomes positive. A
potential difference is therefore established across faces ABEF and OCDG., causing
a field EH.
• This field gives rise to a force of ‘ –eEH’ on the electrons in the opposite direction
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21PYB102J Module-IV Lecture-3
At equilibrium , eEH = Bev (or) EH = Bv (1)
v= J/-ne (3)
EH = BJ/-ne (4) .
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21PYB102J Module-IV Lecture-3
• The Hall Effect is described by means of the Hall coefficient ‘RH ‘ in terms of current
EH = RHBJ
(or) RH = EH / BJ (5)
• Since all the three quantities EH, J and B are measurable , the Hall coefficient RH and
If the strip is a P- type semiconductor, the charge carriers in the strip will be holes i.e.,
positively charged particles. The holes will constitute current in the direction of
conventional current. Therefore, holes move along the direction of the conventional current
itself i.e., along OX. If ‘e’ is the charge of the hole, the force experienced by the holes due
to magnetic field is , F= Bev, which acts along OZ. This causes the holes to accumulate on
the face ABEF- making it positive and leaving the face OCDG as negative.
The Hall coefficient is determined by measuring the Hall voltage that generates the Hall
field.
If ‘w’ is the width of the sample across which the Hall voltage is measured, then
EH = VH/ w (8)
RH = VH / wBJ
(or)
VH = RH w BJ (10)
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21PYB102J Module-IV Lecture-3
If the thickness of the sample is ‘t’ , then its cross sectional area A= wt, and the
current density,
VH = RH w B*I / wt = RH I B /t
(or) RH = VH t / IB (12)
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21PYB102J Module-IV Lecture-3
Experiment
A rectangular slab of the given material having thickness ‘t’ and width ‘w’ is
taken . A current of ‘I’ amperes is passed through this sample by connecting it to a battery,
‘Ba’. The sample is placed between two pole pieces of an electromagnet such that the field
‘B’ is perpendicular to I as shown in the experimental setup.
The Hall voltage ‘ VH’ is then measured by placing two probes at the two side faces of the
slab. If the magnetic flux density is ‘B’ and ‘VH’ is the hall voltage, then the Hall
coefficient.
RH = VH t / IB (m3 /coulomb)
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Applications of Hall effect:
For a N-type semiconductor, the Hall coefficient is negative whereas for a P-type semiconductor, it is
positive. Thus from the direction of the Hall voltage developed, one can find out the type of
semiconductor.
Once Hall coefficient RH is measured, the carrier concentration can be obtained from,
n = 1/eRH or p= 1/eRH
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21PYB102J Module-IV Lecture-3
(3). Determination of mobility
calculated.
Using a semiconductor sample of known ‘RH ‘ the magnetic flux density can
be deduced from RH = VH t/ BI or B = VH t / RH I
Solving Problem
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21PYB102J Module-IV Lecture-4
Problem 1:
Compute the resistivity of the given material whose resistance is 2Ω; area of
cross-section and length are 25cm2 and 15cm respectively?
Answer:
Given
R = 2Ω
l = 15cm = 0.15m
A = 25cm2 = 0.25m2
Resistivity formula is
Problem 2:
The length and area of wire are given as 0.2 m and 0.5 m2 respectively.
The resistance of that wire is 3 Ω, Calculate the resistivity?
Ans: 7.5 Ωm
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Problem 3:
ρ =(V/I) X 2πS
=(180/2)X 2X3.14X 10-2
=565.2X10-2 =5.652 Ω⋅m
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21PYB102J Module-IV Lecture-4
4. A silicon plate of thickness 1 mm, breath 10mm and length 100mm is placed in a magnetic field
of 0.5 Wb/m2 acting perpendicular to its thickness. If 10-2 A current flows along its length, calculate
the Hall voltage developed if the Hall coefficient is 3.66x 10-4 m3 / coulomb.
Given Data:
Solution:
Hall coefficient R = VH t/ IB
VH = RHIB/t
1.A semiconducting crystal 12mm long, 5mm wide and 1mm thick has a magnetic flux
density of 0.5 Wb/m2 applied from front to back perpendicular to largest faces.When a
current of 20mA flows lengthwise through the specimen , the voltage measured across
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21PYB102J Module-IV Lecture-4
2. A n-type semiconductor has Hall coefficient = 4.16 x10 -4 m3c-1. The
conductivity is 108 ohm-1m-1. Calculate its charge carrier density ne and electron
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21PYB102J Module-IV Lecture-4
DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
21PYB102J –Semiconductor Physics and Computational Methods
37
21PYB102J Module-IV Lecture-41
∙ Physical properties of thin films significantly differ from those of bulk
material
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21PYB102J Module-IV Lecture-41
Principle:
•A conventional Hot-Probe experiment enables a
simple and efficient way to distinguish between
n-type and p-type semiconductors using a hot
probe and a standard multi- meter.
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21PYB102J Module-IV Lecture-41
Experiment:
∙ A couple of a cold probe and a hot probe are attached to the semiconductor film
surface.
∙ The hot probe is connected to the positive terminal of the multimeter while the
cold probe is connected to the negative terminal.
∙ The thermally excited majority free charged carriers are translated within the
semiconductor from the hot probe to the cold probe.
∙ Mechanism for this motion within the semiconductor is of a diffusion type since
the material is uniformly doped due to the constant heating in the hot probe
contact.
∙ These translated majority carriers define the electrical potential sign of the
measured current in the multimeter
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21PYB102J Module-IV Lecture-41
∙ The Hot-Probe measurement may be described as a three-step process:
(1) the heated probe excites additional free charged carriers of two
types(electron and hole)
(2) The hot majority carriers begin to leave the heated part of the
semiconductor surface by a diffusion mechanism. Simultaneously, a built-
in electrical field is created between the electrodes and the second
(cold) electrode is warmed as well. This warming and the built-in
electrical field tend to prevent the diffusion process up to a halt at a steady
state. This steady state condition exists until the heated source is switched
off.
(3) The third process is actually a recombination of the excited additional
charged carriers.
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Steady state
Generation
Recombination
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21PYB102J Module-IV Lecture-41
Capacitance-Voltage measurements
∙ Hillibrand and Gold (1960) first described the use of capacitance –voltage
(C-V) methods to determine the majority carrier concentration in
semiconductors.
∙ C-V measurements are capable of yielding quantitative information about
the diffusion potential and doping concentration in semiconductor materials.
∙ The technique employs PN-junctions, metal- semiconductor junctions
(Schottky barriers), electrolyte –semiconductor junction MIS (metal
insulator semiconductor) field effect semiconductors.
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Principle:
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21PYB102J Module-IV Lecture-41
∙ Abrupt PN junction in thermal equilibrium (no bias).
∙ A. Space charge distribution in the depletion approximation.
The dashed lines indicate the majority carrier distribution tails.
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∙ B. Electric field across the depletion region
∙ C. Potential distribution due to the electric field where Vbi is the (built –in)
diffusion potential
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∙ In this region from Poisson’s equations
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21PYB102J Module-IV Lecture-41
DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
21PYB102J –Semiconductor Physics and Computational Methods
Module- IV S8 - Lecture-42
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21PYB102J Module-IV Lecture-42
PN Junction Diode
➢ if we join P-type and N-type semiconductor materials together they behave in
a very different way and producing what is generally known as a “PN
Junction“.
➢ The charge transfer of electrons and holes across the PN junction is known
as diffusion. The width of these P and N layers depends on how heavily each
side is doped with acceptor density NA, and donor density ND, respectively.
➢ Due to diffusion processes potential barrier is formed around the area of the
junction as the donor atoms repel the holes and the acceptor atoms repel the
electrons.
➢ At room temperature the voltage across the depletion layer for silicon is about
0.6 – 0.7 volts and for germanium is about 0.3 – 0.35 volts. This potential
barrier will always exist even if the device is not connected to any
external power source, as seen in diodes.
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21PYB102J Module-IV Lecture-42
I-V Characteristics in a Diode
➢ If a suitable positive voltage (forward bias) is applied between the two ends of
the PN junction, it can supply free electrons and holes with the extra energy
they require to cross the junction as the width of the depletion layer around the
PN junction is decreased.
➢ By applying a negative voltage (reverse bias) results in the free charges being
pulled away from the junction resulting in the depletion layer width being
increased. This has the effect of increasing or decreasing the effective
resistance of the junction itself allowing or blocking current flow through the
diode. 53
21PYB102J Module-IV Lecture-42
➢When a diode is connected in a Forward Bias condition, a negative
voltage is applied to the N-type material and a positive voltage is applied to
the P-type material. If this external voltage becomes greater than the value of
the potential barrier, approx. 0.7 volts for silicon and 0.3 volts for
germanium, the potential barriers opposition will be overcome and current
will start to flow.
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➢ Due to forward biasing the negative voltage pushes or repels electrons towards
the junction giving them the energy to cross over and combine with the holes
being pushed in the opposite direction towards the junction by the positive
voltage. This results in a characteristics curve of zero current flowing up to this
voltage point, called the “knee” on the static curves and then a high current
flow through the diode with little increase in the external voltage.
➢ The point at which this sudden increase in current takes place is represented on
the static I-V characteristics curve above as the “knee” point.
➢ Since the diode can conduct “infinite” current above this knee point as it
effectively becomes a short circuit, therefore resistors are used in series with
the diode to limit its current flow. Exceeding its maximum forward current
specification causes the device to dissipate more power in the form of heat than
it was designed for resulting in a very quick failure of the device.
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21PYB102J Module-IV Lecture-42
➢ When a diode is connected in a Reverse Bias condition, a positive voltage is
applied to the N-type material and a negative voltage is applied to the P-type
material.
➢ The net result is that the depletion layer grows wider due to a lack of
electrons and holes and presents a high impedance path, almost an insulator.
The result is that a high potential barrier is created thus preventing current
from flowing through the semiconductor material.
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21PYB102J Module-IV Lecture-42
➢ This condition represents a high resistance value to the PN junction and
practically zero current flows through the junction diode with an increase
in bias voltage. However, a very small leakage current does flow through
the junction which can be measured in micro-amperes, (μA).
➢ When the reverse voltage is increased beyond the limit, then the reverse
current increases drastically. This particular voltage that causes the drastic
change in reverse current is called Reverse Breakdown voltage. Diode
breakdown occurs by two mechanisms: Avalanche breakdown and Zener
breakdown. 58
21PYB102J Module-IV Lecture-42
DEPARTMENT OF PHYSICS AND
NANOTECHNOLOGY SRM
21PYB102J –Semiconductor Physics
5
21PYB102J Module-I Lecture-31 9
Technology Computer-Aided Design
(TCAD)
I. TCAD is a computer simulation technique that is widely used in the semiconductor industry to
design, optimize, and analyze semiconductor devices and processes. It is a numerical modeling
method for semiconductor devices.
I. TCAD is a branch of Electronic Design Automation (EDA) that models semiconductor fabrication
and semiconductor device operation. TCAD software solutions are key to developing new
semiconductor processes and devices, dramatically reducing costs and time to market.
I. Objectives:
❖ Understand relationships between various potentials and energies important for understanding
device operation.
❖ Understand how biasing affects various potentials and energies at device terminals / ohmic
contacts.
• Process TCAD
• Modeling of semiconductor-chip process-manufacturing steps like lithography, deposition, etching, ion
implantation, diffusion, oxidation, silicidation, mechanical stress, etc.
• Requires detailed modeling of the physical principles of manufacturing, Calibration of models needs
expensive experiments (ad-hoc wafer fabrication)
• Device TCAD
• Modeling of electrical, thermal, optical and mechanical behavior of semiconductor devices (e.g.,
diode, BJT (bipolar junction transistor ), MOSFET, solar cell,…). (metal oxide semiconductor
field-effect transistor).
• Focuses on the physical principles at the basis of carrier transport and of optical generation in
semiconductor devices. Models are more easily generalized than for process physics
Principle tools inside TCAD
device simulation suites with
input and output files.